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CN105860694A - 一种高耐热可剥离金属防锈剂 - Google Patents

一种高耐热可剥离金属防锈剂 Download PDF

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CN105860694A
CN105860694A CN201610387247.2A CN201610387247A CN105860694A CN 105860694 A CN105860694 A CN 105860694A CN 201610387247 A CN201610387247 A CN 201610387247A CN 105860694 A CN105860694 A CN 105860694A
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calcium phosphate
ultrasonic disperse
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郑之松
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HEFEI ZHENGHAO MACHINERY TECHNOLOGY CO LTD
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Abstract

本发明公开了一种高耐热可剥离金属防锈剂，由以下重量份的原料制备制成：甲基硅油0.3‑0.5、聚丙烯酸0.7‑0.9、聚乙烯醇40‑50、聚乙二醇12‑15、乳化剂op100.4‑0.6、丙三醇0.3‑0.5、三乙醇胺0.6‑0.8、苯并三氮唑6‑8、苯甲酸钠6‑7、十二烷基硫酸钠2‑3、丁二醛0.4‑0.6、纳米纤维素4‑5、马来酸酐2.1‑2.4、磷酸钙3.2‑3.4、硅胶2.5‑3、三乙烯四胺0.5‑0.7、氧化铝2.8‑3.3、磷酸钙2.8‑3、去离子水适量；本发明制备的金属防锈剂能够在工件表面形成一层薄膜，防水防油、不易破裂，耐热和耐老化性能好，起到良好的防锈防腐作用，后期剥离方便，值得推广。

Description

一种高耐热可剥离金属防锈剂
技术领域
本发明涉及金属表面处理剂技术领域，尤其涉及一种高耐热可剥离金属防锈剂。
背景技术
根据统计，世界上每年会有总重相当于金属年产量10-20%的钢铁制品由于腐蚀、锈蚀等原因造成不能使用，为此人们采取了各种各样的防锈方法来避免锈蚀，减少损失。防锈剂的种类多种多样，其中亚硝酸钠因其防锈性能优异并且价格低廉一直备受青睐并广泛使用，但是因其它具有强致癌基因的物质，因此在20世纪80年代，国内外便进行了大量的研发工作，制备了多种以烷基、烷氧基、卤代基、萘酸类及其衍生物、硝基苯甲酸类以及硼酸酯、硼酸盐和钼酸盐等为主的材料来取代亚硝酸钠的新型水溶性防锈剂。尽管这些新型防锈剂较亚硝酸钠更加的安全合理，但是在其成膜使用过程中，存在着较复杂的去膜处理问题，通常要采用碱水处理，或者用竹刀和刮片等物理方法处理，这样的处理不仅不能够除尽涂膜还有可能损伤金属表面，还耗工费时增加成本。因此随着防锈技术的不断发展，人们对防锈液及其成膜的应用要求也逐渐提高，出现了新型的防锈膜，可剥性防锈膜。
郭俊在《PVA水溶性高分子可剥防锈膜的研制》一文中提出了通过向聚乙烯醇中加入防锈剂及其他添加剂，将其放置在烧杯中在温度为99℃的恒温水浴锅中加热至完全溶解，再利用涂布流延法将其均匀涂覆在金属表面，干燥成膜，测定膜的性能，实验结果表面具有良好的防锈性，在40℃以下的冷水中，几乎完全不溶于水，但是置于40℃以上的热水中，膜会逐渐变软变薄，最后全部溶解，所以限制了使用区域。本发明针对这个缺点对聚乙烯醇膜改性提高其耐水、耐热、抗油等性能，使其能够满足多种领域的需求，使达到更好的防锈效果和防蚀时期。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种高耐热可剥离金属防锈剂。
本发明是通过以下技术方案实现的：
一种高耐热可剥离金属防锈剂，由以下重量份的原料制备制成：甲基硅油0.3-0.5、聚丙烯酸0.7-0.9、聚乙烯醇40-50、聚乙二醇12-15、乳化剂op100.4-0.6、丙三醇0.3-0.5、三乙醇胺0.6-0.8、苯并三氮唑6-8、苯甲酸钠6-7、十二烷基硫酸钠2-3、丁二醛0.4-0.6、纳米纤维素4-5、马来酸酐2.1-2.4、磷酸钙3.2-3.4、硅胶2.5-3、三乙烯四胺0.5-0.7、氧化铝2.8-3.3、磷酸钙2.8-3、去离子水适量。
所述一种高耐热可剥离金属防锈剂，由以下具体步骤制备制成：
（1）将甲基硅油、聚丙烯酸和马来酸酐在40-50℃下搅拌1-2h，搅拌均匀后加入硅胶和三乙烯四胺，然后继续升高温度至55-75℃时加入氧化铝和磷酸钙，以600-800℃下搅拌40-50min，然后加到胶磨机中磨成微粉备用；
(2)将聚乙烯醇用去离子水在温度为95℃时加热和搅拌下配置成8Wt%溶液，待全部溶解后和步骤（1）制备的产物混合，超声搅拌均匀后降温至30℃，加入丁二醛和适量浓硫酸，在搅拌下使其充分反应，反应结束后加入除纳米纤维素之外其余的剩余物料，超声分散；
（3）将纳米纤维素用2-3倍量的去离子水溶解超声分散制成悬浮液，超声分散均匀后和步骤（2）制备的产物混合，搅拌均匀后超声分散，常温下静置脱泡，然后将产物喷涂在金属工件表面，干燥成膜即可。
本发明的优点是：本发明根据聚乙烯醇能被微生物分解，对环境没有伤害，是一种环境友好型材料，由于表面含有大量的羟基，致使薄膜的吸水能力强，水溶液好，成膜后具有优异的可剥性和塑性，根据聚乙烯醇本身的化学结构及性质，选择丁二醛对其进行交联改性，提高了聚乙烯醇膜的抗溶胀、渗透气化和拉伸强度，利用纳米纤维素的纳米效应，高机械强度、强亲水性等特性，提高聚乙烯醇膜的机械强度、热稳定性和降低断裂伸长率等性能，还利用改性剂对氧化铝和磷酸钙改性，使其具有优秀的防腐、防锈和高的粘结性，能够在聚乙烯醇溶液中分散良好，并且不影响成膜性能，提高膜的韧性、强度及其机械性能，使膜不易破裂，本发明制备的金属防锈剂能够在工件表面形成一层薄膜，防水防油、不易破裂，耐热和耐老化性能好，起到良好的防锈防腐作用，后期剥离方便，值得推广。
具体实施方式
一种高耐热可剥离金属防锈剂，由以下重量份（公斤）的原料制备制成：甲基硅油0.3、聚丙烯酸0.7、聚乙烯醇40、聚乙二醇12、乳化剂op100.4、丙三醇0.3、三乙醇胺0.6、苯并三氮唑6、苯甲酸钠6、十二烷基硫酸钠2、丁二醛0.4、纳米纤维素4、马来酸酐2.1、磷酸钙3.2、硅胶2.5、三乙烯四胺0.5、氧化铝2.8、磷酸钙2.8、去离子水适量。
所述一种高耐热可剥离金属防锈剂，由以下具体步骤制备制成：
（1）将甲基硅油、聚丙烯酸和马来酸酐在40℃下搅拌1h，搅拌均匀后加入硅胶和三乙烯四胺，然后继续升高温度至55℃时加入氧化铝和磷酸钙，以600℃下搅拌40min，然后加到胶磨机中磨成微粉备用；
(2)将聚乙烯醇用去离子水在温度为95℃时加热和搅拌下配置成8Wt%溶液，待全部溶解后和步骤（1）制备的产物混合，超声搅拌均匀后降温至30℃，加入丁二醛和适量浓硫酸，在搅拌下使其充分反应，反应结束后加入除纳米纤维素之外其余的剩余物料，超声分散；
（3）将纳米纤维素用2倍量的去离子水溶解超声分散制成悬浮液，超声分散均匀后和步骤（2）制备的产物混合，搅拌均匀后超声分散，常温下静置脱泡，然后将产物喷涂在金属工件表面，干燥成膜即可。
将清洗干净的金属工件浸渍到按照实施例制备的防锈液中，干燥成膜后进行性能测试，结果如下：
外观：膜光滑完整，无破洞和赘余；
盐雾试验（5%氯化钠，48h）：A级；
可剥性试验：良好；
水溶性：＞70℃。

Claims (2)

1.一种高耐热可剥离金属防锈剂，其特征在于，由以下重量份的原料制备制成：甲基硅油0.3-0.5、聚丙烯酸0.7-0.9、聚乙烯醇40-50、聚乙二醇12-15、乳化剂op100.4-0.6、丙三醇0.3-0.5、三乙醇胺0.6-0.8、苯并三氮唑6-8、苯甲酸钠6-7、十二烷基硫酸钠2-3、丁二醛0.4-0.6、纳米纤维素4-5、马来酸酐2.1-2.4、磷酸钙3.2-3.4、硅胶2.5-3、三乙烯四胺0.5-0.7、氧化铝2.8-3.3、磷酸钙2.8-3、去离子水适量。
2.根据权利要求1所述一种高耐热可剥离金属防锈剂，其特征在于，由以下具体步骤制备制成：
（1）将甲基硅油、聚丙烯酸和马来酸酐在40-50℃下搅拌1-2h，搅拌均匀后加入硅胶和三乙烯四胺，然后继续升高温度至55-75℃时加入氧化铝和磷酸钙，以600-800℃下搅拌40-50min，然后加到胶磨机中磨成微粉备用；
(2)将聚乙烯醇用去离子水在温度为95℃时加热和搅拌下配置成8Wt%溶液，待全部溶解后和步骤（1）制备的产物混合，超声搅拌均匀后降温至30℃，加入丁二醛和适量浓硫酸，在搅拌下使其充分反应，反应结束后加入除纳米纤维素之外其余的剩余物料，超声分散；
（3）将纳米纤维素用2-3倍量的去离子水溶解超声分散制成悬浮液，超声分散均匀后和步骤（2）制备的产物混合，搅拌均匀后超声分散，常温下静置脱泡，然后将产物喷涂在金属工件表面，干燥成膜即可。
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Cited By (5)

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CN107033776A (zh) * 2017-04-06 2017-08-11 天长市润达金属防锈助剂有限公司 一种高耐磨性能的金属防锈剂
CN108467615A (zh) * 2018-03-13 2018-08-31 合肥择浚电气设备有限公司 一种金属制品防锈剂的制备方法
WO2019006678A1 (zh) * 2017-07-04 2019-01-10 深圳市长宏泰科技有限公司 防锈剂、金属工件及其防锈处理方法
CN109401407A (zh) * 2018-10-16 2019-03-01 惠州迪赛恩润滑科技有限公司 一种可剥式防锈剂喷剂及其制备方法
CN110408312A (zh) * 2018-05-04 2019-11-05 新疆苏中建设工程有限公司 一种临时性防锈液及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1513924A (zh) * 2003-05-30 2004-07-21 中国科学院金属研究所 纳米氧化铝浆组合物及其制备方法
CN102877052A (zh) * 2011-07-15 2013-01-16 日本帕卡濑精株式会社 水系金属表面处理剂及利用该处理剂处理而得到的金属材料

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1513924A (zh) * 2003-05-30 2004-07-21 中国科学院金属研究所 纳米氧化铝浆组合物及其制备方法
CN102877052A (zh) * 2011-07-15 2013-01-16 日本帕卡濑精株式会社 水系金属表面处理剂及利用该处理剂处理而得到的金属材料

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭俊等: "PVA水溶性高分子可剥防锈膜的研制", 《塑料工业》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107033776A (zh) * 2017-04-06 2017-08-11 天长市润达金属防锈助剂有限公司 一种高耐磨性能的金属防锈剂
WO2019006678A1 (zh) * 2017-07-04 2019-01-10 深圳市长宏泰科技有限公司 防锈剂、金属工件及其防锈处理方法
CN108467615A (zh) * 2018-03-13 2018-08-31 合肥择浚电气设备有限公司 一种金属制品防锈剂的制备方法
CN110408312A (zh) * 2018-05-04 2019-11-05 新疆苏中建设工程有限公司 一种临时性防锈液及其制备方法
CN109401407A (zh) * 2018-10-16 2019-03-01 惠州迪赛恩润滑科技有限公司 一种可剥式防锈剂喷剂及其制备方法

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