CN105821204A - Method for producing cold bound pellet agglomerate through solid waste and hazardous waste - Google Patents
Method for producing cold bound pellet agglomerate through solid waste and hazardous waste Download PDFInfo
- Publication number
- CN105821204A CN105821204A CN201610361963.3A CN201610361963A CN105821204A CN 105821204 A CN105821204 A CN 105821204A CN 201610361963 A CN201610361963 A CN 201610361963A CN 105821204 A CN105821204 A CN 105821204A
- Authority
- CN
- China
- Prior art keywords
- solid waste
- danger
- useless
- pelletizing
- sintering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002910 solid waste Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000002920 hazardous waste Substances 0.000 title abstract description 6
- 239000008188 pellet Substances 0.000 title abstract description 5
- 238000005245 sintering Methods 0.000 claims abstract description 39
- 239000010802 sludge Substances 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 13
- 239000002893 slag Substances 0.000 claims abstract description 9
- 238000009713 electroplating Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000003208 petroleum Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 20
- 238000005453 pelletization Methods 0.000 claims description 20
- 239000011651 chromium Substances 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 238000003889 chemical engineering Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 3
- 238000009851 ferrous metallurgy Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000010881 fly ash Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/16—Sintering; Agglomerating
- C22B1/20—Sintering; Agglomerating in sintering machines with movable grates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
- C22B1/248—Binding; Briquetting ; Granulating of metal scrap or alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a method for producing cold bound pellet agglomerate through solid waste and hazardous waste. The solid waste and hazardous waste such as converter sludge, power sludge, different types of fly ash produced in ferrous metallurgy production, and a large amount of sulfuric-acid residues, chromic slag, electroplating sludge, chemical industry sludge, petroleum sludge (catalysts) and other chemical industry solid waste and hazardous waste which are produced in the chemical industry production are subjected to technology processing such as crushing, levigating, burdening, mixing, disc balling and sintering to produce the agglomerate which can be used for a blast furnace, so that the ultimate purposes of harmlessness and reclamation of the solid waste and hazardous waste are achieve, and the good socioeconomic benefits and eco-environment benefits are achieved.
Description
Technical field
The present invention relates to solid waste, the useless field of comprehensive utilization of danger, relate more specifically to a kind of method utilizing solid waste danger useless production cold-consolidated ball sintering deposit.
Background technology
Turning during Ferrous Metallurgy produces converter mud, power mud, the solid waste such as all kinds of dedusting ash and the danger produced at present useless, the useless main processing ways of the chemical industry solid waste such as a large amount of sulfate slags of producing in Chemical Manufacture, chromium slag, electroplating sludge, chemical engineering sludge, petroleum sludge (catalyst), danger is:
Landfill stabilization: floor space is big, it is impossible to realize innoxious, minimizing, the final purpose of resource, the gradually seepage of passage in time and produce secondary pollution.
With the cooperative disposal such as cement kiln: can only add on a small quantity, it is impossible to solve a large amount of this type of Industrial Solid Waste produced and danger refuse.Can not be fully achieved innoxious, it is impossible to thoroughly detoxify.Special flue gas processing device is not had to cause secondary pollution.
The collaborative metallurgical equipment of burning mode processes: only use burning mode, many heavy metals cannot process, serious secondary pollution will be produced, Cr VI such as can only be converted into the trivalent chromium of instability, oxidizing atmosphere or have humidity air in can be reoxidized for Cr VI, if crome metal need to be converted into, needing great amount of investment to build up smelting system and dispose, its investment and cost all can be the highest.
Therefore, can solve the problem that the indeterminable problem of said method in the urgent need to one, and realize the comprehensive utilization that solid waste, danger are given up, thus reach solid waste, the useless innoxious and final purpose of resource of danger.
Summary of the invention
The present invention discloses and a kind of utilizes the useless method producing cold-consolidated ball sintering deposit of metallurgy, chemical industry solid waste, danger, will Ferrous Metallurgy produce in the converter mud, power mud, the solid waste such as all kinds of dedusting ash and the danger that produce useless, a large amount of sulfate slags of producing in Chemical Manufacture, chromium slag, electroplating sludge, chemical engineering sludge, the chemical industry solid waste such as petroleum sludge (catalyst), danger are useless by pulverizing the PROCESS FOR TREATMENT such as levigate, dispensing, mixing, disk pelletizing, sintering, produce into and be available for the sintering deposit that blast furnace uses, thus reach solid waste, the useless innoxious and final purpose of resource of endangering.
Process route is as follows:
Raw material processing system (by all raw materials and solid, danger is useless is finely ground to about 200 mesh sieve) feed proportioning system (reasonable dispensing, both reach purpose solid, that danger is useless of dissolving, ensure that again the every physicochemical property of blast furnace ironmaking requires) mixing disk pelletizing (uniformly causing the pelletizing of 5～15mm by sintering requirement) continuous pallettype sintering machine sintering sintering deposit (final products).
Gu, heavy metal such as the chromium, nickel of hazardous waste pollution thing predominantly severe toxicity and Organic substance such as coal-tar residue, phenols.Being postponed by the place of above rationally dispensing and process route, under high temperature and reducing atmosphere, heavy metal is partly or entirely reduced and is stayed in sintering deposit, and Organic substance is burnt by pyrolytic, no longer produces harm.Sintering deposit is the base stock of metallurgical industry blast furnace, finally thoroughly eliminates weight, danger Substances Pollution in blast furnace process, reaches innoxious and resource purpose.
According to solid waste of the present invention, the useless proportion scale of danger to be prone to pelletizing and to meet sintering deposit product quality and require as principle, be not specially limited at this, i.e. solid waste, danger useless both can independent pelletizing, again can mixed pelletizing, also can be with iron mine raw ore mixture pelletizing.The temperature range that continuous pallettype sintering machine uses is 1000～1300 DEG C, and preferred range is 1100 ± 50 DEG C.Belt sintering can be produced and be available for the sintering deposit that industry blast furnace uses, and has both guaranteed removing toxic substances, realizes again solid waste, useless innoxious and resource of endangering, has good social economy and ecological environment benefit.
Detailed description of the invention
Embodiment 1
Take blast furnace dust 2 tons, iron scale 8 tons, levigate to particle diameter 200 mesh, sieve, allocate the auxiliary agent such as bentonite, soda lime of about 200 kilograms, mix homogeneously into, then use disc balling machine pelletizing, the particle diameter of pelletizing is 5～15mm, drop number reaches more than 3 times, is re-fed into continuous pallettype sintering machine sintering, and sintering temperature is 1100 DEG C, obtain sintering deposit, can be used for blast furnace process.Index of correlation is shown in Table 1, table 2.
The metallurgical solid waste cooled agglomerated pellet physical and chemical composition (%, green-ball) of table 1
Index synopsis before and after the metallurgical solid waste cooled agglomerated pellet of table 2 sintering application
The metallurgical solid waste cooled agglomerated pellet of sintering application sinters each leading indicator after being sintered and is obviously improved as can be seen from the above table, being significantly improved quality index such as drum strength, the rate of return mine reduces, and adds yield, reduce cost, there is significant economic results in society and ecological environment benefit.
Embodiment 2
Take chromium slag 1 ton, dedusting ash 9 tons, levigate, 200 mesh sieve, the auxiliary agent such as bentonite, soda lime of allocating about 200 kilograms into, mix homogeneously, then using disc balling machine pelletizing, drop number reaches more than 3 times, is re-fed into continuous pallettype sintering machine sintering, cooling obtains, containing chromium sintering deposit, can be used for blast furnace ferrochrome smelting.
Embodiment 3
Take electroplating sludge 1 ton, sintering dust separation ash 9 tons, 200 mesh sieve, allocate the auxiliary agent such as bentonite, soda lime of about 100 kilograms, mix homogeneously into, then use disc balling machine pelletizing, drop number reaches more than 3 times, being re-fed into continuous pallettype sintering machine sintering, cooling obtains, containing chromium, nickel sintering deposit, can be used for blast furnace process.
Embodiment 4
Take coking sludge 1 ton, sulfate slag 3 tons, iron scale 6 tons, levigate to particle diameter 200 mesh, mixing, allocate the auxiliary agent moons 150 kilograms such as bentonite, soda lime, dolomite dust, mix homogeneously into, then use disc balling machine pelletizing, drop number reaches more than 3 times, being re-fed into continuous pallettype sintering machine sintering, cooling obtains sintering deposit, can be used for blast furnace process.
It should be noted that above example is intended to technical scheme is described, not for the scope limiting invention.It should be appreciated that the amendment in the case of without departing from the objective of the technical program and scope, technical scheme carried out or equivalent, all should contain in the middle of scope of the invention as claimed.
Claims (6)
1. one kind utilizes the useless method producing cold-consolidated ball sintering deposit of solid waste, danger, it is characterised in that comprise the following steps:
1) by useless to solid waste, danger by pulverize levigate, sieve；
2) dispensing, mixing, disk pelletizing；
3) sintering processes, produces into and is available for the sintering deposit that blast furnace uses.
Method the most according to claim 1, it is characterised in that described solid waste, danger are useless includes that the metallurgical solid waste such as converter mud, power mud, dedusting ash and danger are useless, the chemical industry solid waste such as sulfate slag, electroplating sludge, chemical engineering sludge, petroleum sludge and chromium slag, danger are useless.
Method the most according to claim 1, it is characterised in that levigate mix useless to solid waste, danger to 100～300 mesh, preferably 200 mesh with auxiliary agent, then use disc balling machine pelletizing.
Method the most according to claim 1, it is characterised in that solid waste, the useless proportion scale of danger to be prone to pelletizing and to meet sintering deposit product quality and require as principle, solid waste, danger useless can individually pelletizing or mixed pelletizing, also can be with iron mine raw ore mixture pelletizing.
Method the most according to claim 1, it is characterised in that the pelletizing made is sent into continuous pallettype sintering machine sintering, and the temperature range that sintering uses is 1000～1300 DEG C, and preferred range is 1100 ± 50 DEG C.
Method the most according to claim 1, it is characterised in that the particle diameter that pelletizing obtains is the granule of 5～15mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361963.3A CN105821204A (en) | 2016-05-30 | 2016-05-30 | Method for producing cold bound pellet agglomerate through solid waste and hazardous waste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610361963.3A CN105821204A (en) | 2016-05-30 | 2016-05-30 | Method for producing cold bound pellet agglomerate through solid waste and hazardous waste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105821204A true CN105821204A (en) | 2016-08-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610361963.3A Pending CN105821204A (en) | 2016-05-30 | 2016-05-30 | Method for producing cold bound pellet agglomerate through solid waste and hazardous waste |
Country Status (1)
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| CN (1) | CN105821204A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319200A (en) * | 2016-10-25 | 2017-01-11 | 重庆文渠环保科技有限公司 | Method for harmlessly treating chromium-containing waste by utilizing rotary kiln technology |
| CN110055403A (en) * | 2019-05-31 | 2019-07-26 | 衢州市业胜金属材料有限公司 | Method for joint treatment of electroplating sludge and blast furnace gas ash |
| CN110760672A (en) * | 2019-09-30 | 2020-02-07 | 浙江特力再生资源有限公司 | Method for producing sintered ore by using industrial solid wastes |
| CN111961844A (en) * | 2020-08-27 | 2020-11-20 | 中冶东方工程技术有限公司 | Stainless steel metal-containing solid waste ore grinding method |
| CN111961841A (en) * | 2020-08-27 | 2020-11-20 | 中冶东方工程技术有限公司 | Process for stainless steel containing metal solid waste pellets |
| CN113005288A (en) * | 2021-02-26 | 2021-06-22 | 安徽工业大学 | Titanium-containing pellet containing waste SCR catalyst and preparation method thereof |
| CN113846210A (en) * | 2021-08-23 | 2021-12-28 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw18 by sintering machine |
| CN113862466A (en) * | 2021-08-23 | 2021-12-31 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw17 by sintering machine |
| CN113862465A (en) * | 2021-08-23 | 2021-12-31 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw11 by sintering machine |
| CN113881822A (en) * | 2021-08-23 | 2022-01-04 | 浙江省工业设计研究院有限公司 | Novel process method for blast furnace co-processing hazardous waste hw17 |
| WO2022218043A1 (en) * | 2021-04-16 | 2022-10-20 | 中冶长天国际工程有限责任公司 | Solid waste treatment process centered on sintering and pelletizing procedures |
| CN115287395A (en) * | 2022-01-13 | 2022-11-04 | 王强 | Method for producing high-strength construction steel HRB500 by using deactivated residual oil hydrogenation catalyst |
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| CN101250624A (en) * | 2008-03-31 | 2008-08-27 | 重庆钢铁(集团)有限责任公司 | Technique of dedusting gray for sintered mine |
| CN101554632A (en) * | 2009-05-20 | 2009-10-14 | 重庆瑞帆再生资源开发有限公司 | Harmless regeneration recycling method of trash fly ash by using blast furnace |
| CN102266863A (en) * | 2011-07-01 | 2011-12-07 | 重庆钢铁(集团)有限责任公司 | Method for harmless sintering treatment of fly ash in garbage incineration power plants |
| CN104846201A (en) * | 2015-05-08 | 2015-08-19 | 内蒙古科技大学 | Method for enriching rare earth and preparing iron with coal slime rich in rare earth in ash |
-
2016
- 2016-05-30 CN CN201610361963.3A patent/CN105821204A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101250624A (en) * | 2008-03-31 | 2008-08-27 | 重庆钢铁(集团)有限责任公司 | Technique of dedusting gray for sintered mine |
| CN101554632A (en) * | 2009-05-20 | 2009-10-14 | 重庆瑞帆再生资源开发有限公司 | Harmless regeneration recycling method of trash fly ash by using blast furnace |
| CN102266863A (en) * | 2011-07-01 | 2011-12-07 | 重庆钢铁(集团)有限责任公司 | Method for harmless sintering treatment of fly ash in garbage incineration power plants |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106319200A (en) * | 2016-10-25 | 2017-01-11 | 重庆文渠环保科技有限公司 | Method for harmlessly treating chromium-containing waste by utilizing rotary kiln technology |
| CN110055403A (en) * | 2019-05-31 | 2019-07-26 | 衢州市业胜金属材料有限公司 | Method for joint treatment of electroplating sludge and blast furnace gas ash |
| CN110760672A (en) * | 2019-09-30 | 2020-02-07 | 浙江特力再生资源有限公司 | Method for producing sintered ore by using industrial solid wastes |
| CN111961844A (en) * | 2020-08-27 | 2020-11-20 | 中冶东方工程技术有限公司 | Stainless steel metal-containing solid waste ore grinding method |
| CN111961841A (en) * | 2020-08-27 | 2020-11-20 | 中冶东方工程技术有限公司 | Process for stainless steel containing metal solid waste pellets |
| CN113005288A (en) * | 2021-02-26 | 2021-06-22 | 安徽工业大学 | Titanium-containing pellet containing waste SCR catalyst and preparation method thereof |
| CN113005288B (en) * | 2021-02-26 | 2023-08-29 | 安徽工业大学 | Titanium-containing pellets containing waste SCR catalyst and preparation method thereof |
| WO2022218043A1 (en) * | 2021-04-16 | 2022-10-20 | 中冶长天国际工程有限责任公司 | Solid waste treatment process centered on sintering and pelletizing procedures |
| CN113846210A (en) * | 2021-08-23 | 2021-12-28 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw18 by sintering machine |
| CN113881822A (en) * | 2021-08-23 | 2022-01-04 | 浙江省工业设计研究院有限公司 | Novel process method for blast furnace co-processing hazardous waste hw17 |
| CN113862465A (en) * | 2021-08-23 | 2021-12-31 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw11 by sintering machine |
| CN113862466A (en) * | 2021-08-23 | 2021-12-31 | 浙江省工业设计研究院有限公司 | Novel process method for co-processing hazardous waste hw17 by sintering machine |
| CN115287395A (en) * | 2022-01-13 | 2022-11-04 | 王强 | Method for producing high-strength construction steel HRB500 by using deactivated residual oil hydrogenation catalyst |
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Application publication date: 20160803 |
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