[go: up one dir, main page]

CN105820375A - 一种复合阻燃剂 - Google Patents

一种复合阻燃剂 Download PDF

Info

Publication number
CN105820375A
CN105820375A CN201610346169.1A CN201610346169A CN105820375A CN 105820375 A CN105820375 A CN 105820375A CN 201610346169 A CN201610346169 A CN 201610346169A CN 105820375 A CN105820375 A CN 105820375A
Authority
CN
China
Prior art keywords
parts
composite flame
retardant
flame retardant
app
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610346169.1A
Other languages
English (en)
Inventor
单来
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xuzhou Lieqi Commerce And Trade Co Ltd
Original Assignee
Xuzhou Lieqi Commerce And Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xuzhou Lieqi Commerce And Trade Co Ltd filed Critical Xuzhou Lieqi Commerce And Trade Co Ltd
Priority to CN201610346169.1A priority Critical patent/CN105820375A/zh
Publication of CN105820375A publication Critical patent/CN105820375A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵30～40份、三聚氰胺20～35份、季戊四醇为4～10份、氢氧化镁6～13份、氢氧化铝5～12份、硼酸锌4～6份、氧化锌2～4份、八钼酸铵0.5～5份、碳酸钙3～5份、膨胀石墨2～5份、硅烷偶联剂0.02～3份。本发明的复合阻燃剂在聚灵酸铵、三聚氰胺、季戊四醇、膨胀石墨的协同作用下构成膨胀型阻燃剂，不产生有毒气体，抑烟性能良好，阻燃效果好。

Description

一种复合阻燃剂
技术领域
本发明涉及一种阻燃剂，具体涉及一种复合阻燃剂。
背景技术
随着高分子材料工业的发展，塑料愈来愈广泛地应用于生产和生活的各个领域，与此同时，由于塑料的可燃性引起的火灾也给人们酿成了惨重的人员伤亡和巨大的经济损失，一些工业发达国家开始生产和应用阻燃塑料。随着电器、电子、机械、汽车、船舶、航空和航天的发展，对产品材质的阻燃要求也愈来愈高，是阻燃剂和阻燃材料的研制、生产及推广应用得以迅速发展。
膨胀型阻燃剂是近年来开发的以磷、氮为主要组成的阻燃剂，具有绿色环保、高效、低烟低毒、添加量低及对聚合物机械性能影响较小等优点，含这类阻燃剂的材料受热时表面能形成一层致密泡沫炭层，起到隔热、隔氧、抑烟作用，又能防止熔滴，在阻燃聚丙烯塑料中应用越来越广泛。目前，以聚磷酸铵为基础的磷氮体系无卤膨胀型阻燃剂研究较多，但是当阻燃剂添加量较小时，阻燃效果不明显，达不到国家建筑材料标准；当阻燃剂添加量较大时，虽然解决了阻燃问题，但严重影响到材料的性能。
发明内容
本发明的目的是提供一种复合阻燃剂，阻燃效果好，无毒环保。
为实现上述目的，本发明的一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵30～40份、三聚氰胺20～35份、季戊四醇为4～10份、氢氧化镁6～13份、氢氧化铝5～12份、硼酸锌4～6份、氧化锌2～4份、八钼酸铵0.5～5份、碳酸钙3～5份、膨胀石墨2～5份、硅烷偶联剂0.02～3份。
优选的，所述的复合阻燃剂，由以下重量份的组分组成：聚磷酸铵32～37份、三聚氰胺25～32份、季戊四醇为5～8份、氢氧化镁7～11份、氢氧化铝8～10份、硼酸锌4～6份、氧化锌2～3.5份、八钼酸铵2～3.5份、碳酸钙3～4份、膨胀石墨3～4份、硅烷偶联剂0.8～2份。
优选的，所述的复合阻燃剂，由以下重量份的组分组成：聚磷酸铵35份、三聚氰胺28份、季戊四醇为6份、氢氧化镁10份、氢氧化铝8份、硼酸锌5份、氧化锌3份、八钼酸铵3份、碳酸钙4份、膨胀石墨3份、硅烷偶联剂1.5份。
优选的，所述的聚磷酸铵为高聚合度、水难溶的磷酸铵聚合物，聚合度为1000～1500。
优选的，所述的硅烷偶联剂选自γ-甲基丙烯酰氧基三甲氧基硅烷、γ-氨丙基三乙氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、γ-乙烯基三乙氧基硅烷、γ-氨乙基-β-氨丙基三甲氧基硅烷中的一种或多种。
上述复合阻燃剂的制备方法为：将各组分原料按比例投入到高速混料机内混合均匀，即可得到该阻燃剂。
本发明的复合阻燃剂采用的是经过热处理后的高聚合度聚磷酸铵，其热稳定性好，阻燃性能持久，无毒抑烟，属于磷系阻燃剂。三聚氰胺是一种常用的氮系阻燃剂，含氮阻燃剂受热放出二氧化碳、氮气、氨气等不燃气体，这类阻燃剂还可用作其它阻燃剂如磷系阻燃剂的协效剂，在磷-氮协同体系中作为发泡剂。季戊四醇的加入，与磷系、氮系阻燃剂可形成膨胀型阻燃剂。添加膨胀型阻燃剂的聚合物燃烧时会在表面上形成一层均匀的炭质泡沫层，此炭层在凝聚相能起到隔热、隔氧、抑烟和防熔滴的作用。本发明的复合阻燃剂不产生有毒气体，抑烟性能良好，阻燃效果好。
具体实施方式
下面结合具体实施例对本发明作进一步详细说明。
实施例1
一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵35份、三聚氰胺28份、季戊四醇为6份、氢氧化镁10份、氢氧化铝8份、硼酸锌5份、氧化锌3份、八钼酸铵3份、碳酸钙4份、膨胀石墨3份、γ-甲基丙烯酰氧基三甲氧基硅烷1.5份。
上述复合阻燃剂的制备方法为：将各组分原料按比例投入到高速混料机内混合均匀，即可得到该阻燃剂。
实施例2
一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵30份、三聚氰胺20份、季戊四醇为4份、氢氧化镁6份、氢氧化铝5份、硼酸锌4份、氧化锌2份、八钼酸铵0.5份、碳酸钙3份、膨胀石墨2份、γ-氨丙基三乙氧基硅烷0.02份。
其制备方法同实施例1。
实施例3
一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵40份、三聚氰胺35份、季戊四醇为10份、氢氧化镁13份、氢氧化铝12份、硼酸锌6份、氧化锌4份、八钼酸铵5份、碳酸钙5份、膨胀石墨5份、γ-甲基丙烯酰氧基丙基三甲氧基硅烷3份。
其制备方法同实施例1。
实施例4
一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵32份、三聚氰胺25份、季戊四醇为5份、氢氧化镁7份、氢氧化铝8份、硼酸锌4份、氧化锌2份、八钼酸铵2份、碳酸钙3份、膨胀石墨4份、γ-乙烯基三乙氧基硅烷0.8份。
其制备方法同实施例1。
实施例5
一种复合阻燃剂，由以下重量份的组分组成：聚磷酸铵37份、三聚氰胺32份、季戊四醇为8份、氢氧化镁11份、氢氧化铝10份、硼酸锌6份、氧化锌3.5份、八钼酸铵3.5份、碳酸钙4份、膨胀石墨4份、γ-氨乙基-β-氨丙基三甲氧基硅烷2份。
其制备方法同实施例1。

Claims (5)

1.一种复合阻燃剂，其特征在于，由以下重量份的组分组成：聚磷酸铵30～40份、三聚氰胺20～35份、季戊四醇为4～10份、氢氧化镁6～13份、氢氧化铝5～12份、硼酸锌4～6份、氧化锌2～4份、八钼酸铵0.5～5份、碳酸钙3～5份、膨胀石墨2～5份、硅烷偶联剂0.02～3份。
2.如权利要求1所述的复合阻燃剂，其特征在于，由以下重量份的组分组成：聚磷酸铵32～37份、三聚氰胺25～32份、季戊四醇为5～8份、氢氧化镁7～11份、氢氧化铝8～10份、硼酸锌4～6份、氧化锌2～3.5份、八钼酸铵2～3.5份、碳酸钙3～4份、膨胀石墨3～4份、硅烷偶联剂0.8～2份。
3.如权利要求1所述的复合阻燃剂，其特征在于，由以下重量份的组分组成：聚磷酸铵35份、三聚氰胺28份、季戊四醇为6份、氢氧化镁10份、氢氧化铝8份、硼酸锌5份、氧化锌3份、八钼酸铵3份、碳酸钙4份、膨胀石墨3份、硅烷偶联剂1.5份。
4.如权利要求1至3任一项所述的复合阻燃剂，其特征在于，所述的聚磷酸铵为高聚合度、水难溶的磷酸铵聚合物，聚合度为1000～1500。
5.如权利要求1至3任一项所述的复合阻燃剂，其特征在于，所述的硅烷偶联剂选自γ-甲基丙烯酰氧基三甲氧基硅烷、γ-氨丙基三乙氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、γ-乙烯基三乙氧基硅烷、γ-氨乙基-β-氨丙基三甲氧基硅烷中的一种或多种。
CN201610346169.1A 2016-05-23 2016-05-23 一种复合阻燃剂 Pending CN105820375A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610346169.1A CN105820375A (zh) 2016-05-23 2016-05-23 一种复合阻燃剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610346169.1A CN105820375A (zh) 2016-05-23 2016-05-23 一种复合阻燃剂

Publications (1)

Publication Number Publication Date
CN105820375A true CN105820375A (zh) 2016-08-03

Family

ID=56530302

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610346169.1A Pending CN105820375A (zh) 2016-05-23 2016-05-23 一种复合阻燃剂

Country Status (1)

Country Link
CN (1) CN105820375A (zh)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317463A (zh) * 2016-08-23 2017-01-11 成都米特瑞新材料科技有限公司 一种具有阻燃性的柠檬酸增塑剂
CN106589656A (zh) * 2016-10-12 2017-04-26 广州市德錾科技有限公司 一种阻燃母粒及其制备得到的阻燃型pvc木塑墙板
CN106835833A (zh) * 2017-02-21 2017-06-13 浙江科技学院 一种环保型阻燃填料及其制备方法
CN106868916A (zh) * 2017-02-21 2017-06-20 浙江科技学院 一种环保型阻燃纸板及其制备方法
CN107266890A (zh) * 2017-07-11 2017-10-20 济南泰星精细化工有限公司 一种不饱和聚酯树脂无卤阻燃剂及其制备方法和应用
CN107881576A (zh) * 2017-12-23 2018-04-06 湖南辰砾新材料有限公司 一种有机复合阻燃剂及其制备方法
CN108642962A (zh) * 2018-05-21 2018-10-12 浙江鸿浩科技有限公司 一种耐高温纸张无卤阻燃剂
CN109135208A (zh) * 2018-08-30 2019-01-04 宏佩（上海）建筑科技有限公司 一种pet抗菌母粒及其制备方法
CN109401406A (zh) * 2018-10-30 2019-03-01 巩义市宏盛稀有金属有限公司 一种水性涂料用膨胀型抑烟阻燃剂及其制备方法
CN112266501A (zh) * 2020-10-29 2021-01-26 刘士福 一种阻燃性消烟剂
CN118634470A (zh) * 2024-08-15 2024-09-13 大连理工大学 一种可膨胀磷-硼复合抑制剂及对铝粉尘爆炸抑制应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153820A (zh) * 2011-03-22 2011-08-17 天津工业大学 一种阻燃苯乙烯聚合物复合材料的制备方法
WO2012025362A1 (de) * 2010-08-23 2012-03-01 Catena Additives Gmbh & Co. Kg Flammschutzmittelzusammensetzungen enthaltend triazin-interkalierte metall-phosphate
CN105238222A (zh) * 2015-11-13 2016-01-13 海洋化工研究院有限公司 一种环保型环氧膨胀型防火涂料及其制备方法
CN105238221A (zh) * 2015-11-13 2016-01-13 海洋化工研究院有限公司 柔性环氧膨胀型防火涂料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012025362A1 (de) * 2010-08-23 2012-03-01 Catena Additives Gmbh & Co. Kg Flammschutzmittelzusammensetzungen enthaltend triazin-interkalierte metall-phosphate
CN102153820A (zh) * 2011-03-22 2011-08-17 天津工业大学 一种阻燃苯乙烯聚合物复合材料的制备方法
CN105238222A (zh) * 2015-11-13 2016-01-13 海洋化工研究院有限公司 一种环保型环氧膨胀型防火涂料及其制备方法
CN105238221A (zh) * 2015-11-13 2016-01-13 海洋化工研究院有限公司 柔性环氧膨胀型防火涂料及其制备方法

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106317463A (zh) * 2016-08-23 2017-01-11 成都米特瑞新材料科技有限公司 一种具有阻燃性的柠檬酸增塑剂
CN106589656A (zh) * 2016-10-12 2017-04-26 广州市德錾科技有限公司 一种阻燃母粒及其制备得到的阻燃型pvc木塑墙板
CN106589656B (zh) * 2016-10-12 2018-09-21 广州市恒德环保材料有限公司 一种阻燃母粒及其制备得到的阻燃型pvc木塑墙板
CN106868916A (zh) * 2017-02-21 2017-06-20 浙江科技学院 一种环保型阻燃纸板及其制备方法
CN106835833A (zh) * 2017-02-21 2017-06-13 浙江科技学院 一种环保型阻燃填料及其制备方法
CN107266890A (zh) * 2017-07-11 2017-10-20 济南泰星精细化工有限公司 一种不饱和聚酯树脂无卤阻燃剂及其制备方法和应用
CN107881576A (zh) * 2017-12-23 2018-04-06 湖南辰砾新材料有限公司 一种有机复合阻燃剂及其制备方法
CN108642962A (zh) * 2018-05-21 2018-10-12 浙江鸿浩科技有限公司 一种耐高温纸张无卤阻燃剂
CN108642962B (zh) * 2018-05-21 2020-11-24 浙江鸿浩科技有限公司 一种耐高温纸张无卤阻燃剂
CN109135208A (zh) * 2018-08-30 2019-01-04 宏佩（上海）建筑科技有限公司 一种pet抗菌母粒及其制备方法
CN109401406A (zh) * 2018-10-30 2019-03-01 巩义市宏盛稀有金属有限公司 一种水性涂料用膨胀型抑烟阻燃剂及其制备方法
CN112266501A (zh) * 2020-10-29 2021-01-26 刘士福 一种阻燃性消烟剂
CN118634470A (zh) * 2024-08-15 2024-09-13 大连理工大学 一种可膨胀磷-硼复合抑制剂及对铝粉尘爆炸抑制应用

Similar Documents

Publication Publication Date Title
CN105820375A (zh) 一种复合阻燃剂
US11608472B2 (en) Method for imparting flame retardancy to a substrate material
CN102174223B (zh) 一种阻燃发泡聚乙烯材料及其制备方法
Shen et al. Zinc borates as multifunctional polymer additives
CN102559022B (zh) 聚脲膨胀型防火涂料及其制备方法和用途
CN1876740A (zh) 无溶剂环氧膨胀型防火涂料及其制备方法
JP2003517493A (ja) リグノセルロース物質用の難燃剤膨張性コーティング
CN101693835A (zh) 具有高效阻燃性能的环保型聚丙烯复合材料
CN102492348B (zh) 一种具有双核结构的防火装饰墙面涂料
CN102746608A (zh) 一种abs树脂专用的环保无卤阻燃剂
CN104479258A (zh) 一种高阻燃抑烟建筑用硬聚氯乙烯电工套管
US7217753B2 (en) Fire retardant intumescent coating
CN106752594A (zh) 一种石墨烯类膨胀型低烟防火涂料及其制备方法
CN107936410A (zh) 一种无卤阻燃木塑复合材料及其制备方法
HU206739B (en) Latexbinded anti-burning materials and layered materials against burning
CN101284994B (zh) 聚磷酸根柱撑水滑石无机阻燃剂及其制备方法
CN105754239A (zh) 一种可陶瓷化复合改性树脂包覆eps泡沫阻燃保温材料的制备方法
Bourbigot Intumescence‐based flame retardant
CN102352057B (zh) 无卤复合阻燃剂及在制备阻燃热塑性弹性体复合材料中的应用
Loredo et al. Enhanced flame retardancy of flax bio-composites for the construction market
CN109280201A (zh) 一种含氧化石墨烯的阻燃建筑装饰板材及制备方法
CN117534894B (zh) 一种抗静电阻燃聚乙烯复合材料及其制备方法和应用
CN105949933B (zh) 一种防火木门
CN109467878A (zh) 一种轻质多效膨胀型防火密封材料
KR102237988B1 (ko) 난연성 발포 폴리스티렌 비드의 제조방법 및 이를 이용하여 제조된 난연성 발포 폴리스티렌 비드

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: 221000 No. 99 University Road, copper mountain, Jiangsu, Xuzhou

Applicant after: Xuzhou Houqi Decoration Technology Co., Ltd

Address before: 221000 No. 99 University Road, copper mountain, Jiangsu, Xuzhou

Applicant before: XUZHOU LIEQI COMMERCE AND TRADE Co.,Ltd.

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160803