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CN105753252A - Device for treating nickel-copper containing electroplating wastewater - Google Patents

Device for treating nickel-copper containing electroplating wastewater Download PDF

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Publication number
CN105753252A
CN105753252A CN201610196883.7A CN201610196883A CN105753252A CN 105753252 A CN105753252 A CN 105753252A CN 201610196883 A CN201610196883 A CN 201610196883A CN 105753252 A CN105753252 A CN 105753252A
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filter tower
water
aeration
inlet pipe
tank
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CN201610196883.7A
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CN105753252B (en
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王莉
万玉山
李大伟
邹涛
陈艳秋
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Shanghai Doctoral High Environmental Protection Technology Co ltd
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Changzhou University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

一种含镍铜电镀废水处理装置,包括废水调节池、吸附沉淀池、曝气氧化池和好氧滤塔,废水调节池、吸附沉淀池、曝气氧化池和好氧滤塔依次连通;吸附沉淀池包括混合吸附区和沉淀区,混合吸附区的中上部设置有吸附沉淀池进水管,混合吸附区的上部设置有钢渣吸附剂添加计量系统,混合吸附区的中部设置有搅拌器;曝气氧化池中下部设置有曝气氧化池进水管,曝气氧化池进水管下部设有布水三角锥,布水三角锥下部设有曝气调控系统;好氧滤塔包括滤塔顶盖、好氧滤塔进水管、好氧滤塔布水管、滤料、滤料支撑架、进风口和好氧滤塔出水管。

A nickel-containing copper electroplating wastewater treatment device, including a wastewater regulating tank, an adsorption sedimentation tank, an aeration oxidation tank, and an aerobic filter tower, the wastewater adjustment tank, the adsorption sedimentation tank, an aeration oxidation tank, and an aerobic filter tower are connected in sequence; the adsorption The sedimentation tank includes a mixed adsorption area and a sedimentation area. The upper middle part of the mixed adsorption area is equipped with an adsorption sedimentation tank inlet pipe, the upper part of the mixed adsorption area is equipped with a steel slag adsorbent addition metering system, and the middle part of the mixed adsorption area is equipped with an agitator; aeration The lower part of the oxidation tank is provided with an aeration oxidation tank inlet pipe, the lower part of the aeration oxidation tank inlet pipe is equipped with a water distribution triangle cone, and the lower part of the water distribution triangle cone is equipped with an aeration control system; the aerobic filter tower includes a filter tower top cover, a well Oxygen filter tower water inlet pipe, aerobic filter tower cloth water pipe, filter material, filter material support frame, air inlet and aerobic filter tower outlet pipe.

Description

A kind of containing ambrose alloy electroplating waste processing equipment
Technical field
The present invention relates to technical field of waste water processing, especially a kind of containing ambrose alloy electroplating waste processing equipment.
Background technology
The discharge capacity of annual China electroplating wastewater is huge, accounts for 1/10th of industrial wastewater total release, and electroplating wastewater poisonous and harmful, acid-base value is big, content of beary metal is high, enters nature if processing not in time, environment can cause the severe contamination of unrepairable.
Copper-plating technique and nickel plating technology are modal two kinds of techniques, and general identical device, thus copper ion and nickel ion are concurrently present in same electroplating wastewater.
Administering numerous containing the method for ambrose alloy electroplating wastewater, wherein absorption method is because of simple to operation, and processing cost is low, high treating effect becomes the prefered method processed containing ambrose alloy electroplating wastewater.And for absorption method, seek a kind of cheap efficient adsorbing material and carry out the expensive activated carbon of fictitious hosts and ion exchange resin is crucial, therefore in recent years, Cheap highly effective, eco-friendly adsorbing material receive publicity gradually.
Slag belongs to industrial solid wastes, faces disposal difficulties.
Summary of the invention
Present invention aim to address the process problem containing ambrose alloy electroplating wastewater, solve the disposal difficulties of slag, it is provided that be a kind of containing ambrose alloy electroplating waste processing equipment, slag is used for the absorption of ambrose alloy ion.
The technical solution adopted for the present invention to solve the technical problems is: a kind of containing ambrose alloy electroplating waste processing equipment, including regulating reservoir, adsorption precipitation pond, aeration oxidation pool and aerobic filter tower, regulating reservoir, adsorption precipitation pond, aeration oxidation pool and aerobic filter tower are sequentially communicated.
Described regulating reservoir includes regulating reservoir water inlet pipe and regulating reservoir outlet pipe, for regulating the pH value of waste water, water quality and the water yield.Waste water is entered regulating reservoir by regulating reservoir water inlet pipe, regulating reservoir outlet pipe flow out, enter adsorption precipitation pond water inlet pipe.
Described adsorption precipitation pond includes mixing and absorption district and settling zone.
The middle and upper part in described mixing and absorption district is provided with adsorption precipitation pond water inlet pipe, and the top in mixing and absorption district is provided with steel scoria adsorbent and adds metering system;The middle and lower part in mixing and absorption district is provided with agitator.
The preparation process of steel scoria adsorbent is:
1. 20~100 order metallic screens are utilized to be sieved by slag particle;
2. the slag after screening is put into drying baker, dry one hour under 150~200 degrees celsius, prepare steel scoria adsorbent.
It is provided with dividing plate between described mixing and absorption district and settling zone, the inwall in this dividing plate and adsorption precipitation pond forms the waste water runner entering settling zone as waste water, the exit of settling zone is provided with adsorption precipitation pond three phase separator, the outlet top of settling zone is provided with adsorption precipitation pond overfalling weir, the tapered structure of settling zone bottom design, is provided with sediment discharge valve bottom pyramidal structure.Adsorption precipitation pond overfalling weir connects adsorption precipitation pond outlet pipe, and adsorption precipitation pond outlet pipe connects aeration oxidation pool water inlet pipe.
Described aeration oxidation pool middle and lower part is provided with aeration oxidation pool water inlet pipe, and described aeration oxidation pool water inlet pipe bottom is provided with water distribution pyrometric cone;Described water distribution pyrometric cone bottom is provided with aeration regulator control system, and described aeration regulator control system includes aeration plate, aerator and dissolved oxygen sensing regulation device;Described aeration plate is the pore type aeration plate being evenly arranged with micropore, described aeration plate connects aerator by aeration tube, aerator is arranged on outside aeration oxidation pool, the top of aeration oxidation pool and waste water underwater arrange dissolved oxygen sensing regulation device, and described dissolved oxygen sensing regulation device regulates and controls aerator work according to oxygen capacity;Described aeration oxidation pool water inlet pipe top is built-in with filler;The water outlet of described aeration oxidation pool is laid with aeration oxidation pool downflow weir.Aeration oxidation pool downflow weir connects aeration oxidation pool outlet pipe, and aeration oxidation pool outlet pipe connects aerobic filter tower water inlet pipe.
Described aerobic filter tower includes filter tower top cover, aerobic filter tower water inlet pipe, aerobic filter tower water distributor, filtrate, filtrate bracing frame, air inlet and aerobic filter tower outlet pipe;Aerobic filter tower adopts multilamellar to arrange, and top is provided with filter tower top cover, leaves air outlet between filter tower top cover and tower body;Filter tower top cover is arranged below aerobic filter tower water inlet pipe, and aerobic filter tower water inlet pipe connects aerobic filter tower water distributor;Aerobic filter tower water distributor is placed in the filtrate top of topmost one layer;Filtrate is placed on every metafiltration material bracing frame, and from upper strata to lower floor, the particle diameter of filtrate tapers into;The filtrate bracing frame of every metafiltration tower is designed to inverted trapezoidal drawer type, adds forced ventilation on the one hand, it is to avoid produce foul smell, is easy on the other hand observe and change filtrate, when this layer of filter clogging is serious, when filtering velocity is very low, only this metafiltration material need to be extracted out and change;The bottom of filter tower is provided with air inlet and aerobic filter tower outlet pipe.
Water after the process of aerobic filter tower is by aerobic filter tower outlet pipe qualified discharge.
A kind of adopt the above-mentioned method carrying out wastewater treatment containing ambrose alloy electroplating waste processing equipment, there are following steps:
1. waste water enters regulating reservoir by regulating reservoir water inlet pipe, regulates the pH value of waste water, water quality and the water yield.
2. then waste water enters the mixing and absorption district in adsorption precipitation pond by adsorption precipitation pond water inlet pipe, and steel scoria adsorbent adds metering system and adds steel scoria adsorbent, and waste water is stirred mixing by agitator, and the ambrose alloy ion in waste water is adsorbed by steel scoria adsorbent and absorbs.
3. then waste water enters the waste water runner of settling zone, adsorption precipitation pond three phase separator realizes the separation of waste water and solid, precipitate sinks to the bottom of settling zone under gravity, being discharged by the sediment discharge valve of bottom, the waste water after precipitation enters aeration oxidation pool water inlet pipe by adsorption precipitation pond overfalling weir and adsorption precipitation pond outlet pipe.
4. waste water enters the middle and lower part of aeration oxidation pool by aeration oxidation pool water inlet pipe, water distribution uniformity under the effect of water distribution pyrometric cone, the aeration plate of aeration oxidation pool produces substantial amounts of microbubble, dissolved oxygen sensing regulation device regulates and controls aerator work according to oxygen capacity, it is ensured that the dissolved oxygen in aeration oxidation pool water is more than 2mg/L.Water after aeration oxidation pool process enters aerobic filter tower water inlet pipe through aeration oxidation pool downflow weir and aeration oxidation pool outlet pipe.
5. waste water enters aerobic filter tower by aerobic filter tower water inlet pipe, aerobic filter tower water distributor, and air and waste water cross generation biochemical reaction in filtrate, and waste water is filtered by filtrate simultaneously, aerobic filter tower process after water by aerobic filter tower outlet pipe qualified discharge.
6. adsorption precipitation pond sediment discharge valve discharge absorption saturated after slag dehydration after identical with original slag, it it is still a kind of well engineer applied material, by selecting the technological means of reasonable benefit/risk that being fixed of waste residue after absorption is utilized, thus reducing the heavy metal ion pollution to environment.
Accompanying drawing explanation
Fig. 1 is the structural representation in embodiment of the present invention adsorption precipitation pond;
In Fig. 1: 1. adsorption precipitation pond, 1-1. mixing and absorption district, 1-2. settling zone, 1-3. adsorption precipitation pond water inlet pipe, 1-4. steel scoria adsorbent adds metering system, 1-5. agitator, 1-6. dividing plate, 1-7. adsorption precipitation pond three phase separator, 1-8. adsorption precipitation pond overfalling weir, 1-9. sediment discharge valve.
Fig. 2 is the structural representation of embodiment of the present invention aeration oxidation pool.
In Fig. 2: 2. aeration oxidation pool, 2-1. aeration oxidation pool water inlet pipe, 2-2. water distribution pyrometric cone, 2-3. aeration regulator control system, 2-4. filler, 2-5. aeration oxidation pool downflow weir.
Fig. 3 is the structural representation of the aerobic filter tower of the embodiment of the present invention.
In Fig. 3: 3. aerobic filter tower, 3-1. filter tower top cover, the aerobic filter tower water inlet pipe of 3-2., the aerobic filter tower water distributor of 3-3., 3-4. filtrate, 3-5. filtrate bracing frame, 3-6. air inlet, the aerobic filter tower outlet pipe of 3-7..
Fig. 4 is the process chart of the embodiment of the present invention.
Detailed description of the invention
In conjunction with the accompanying drawings, the present invention is further detailed explanation.
These accompanying drawings are the schematic diagram of simplification, and the basic structure of the present invention is only described in a schematic way, and therefore it only shows the composition relevant with the present invention.
Embodiment
One as shown in Figure 1 to 4 is containing ambrose alloy electroplating waste processing equipment, and including regulating reservoir, adsorption precipitation pond 1, aeration oxidation pool 2 and aerobic filter tower 3, regulating reservoir, adsorption precipitation pond 1, aeration oxidation pool 2 and aerobic filter tower 3 are sequentially communicated.
Described regulating reservoir includes regulating reservoir water inlet pipe and regulating reservoir outlet pipe, for regulating the pH value of waste water, water quality and the water yield.Waste water is entered regulating reservoir by regulating reservoir water inlet pipe, regulating reservoir outlet pipe exit into adsorption precipitation pond water inlet pipe.
Described adsorption precipitation pond 1 includes mixing and absorption district 1-1 and settling zone 1-2.
The middle and upper part of described mixing and absorption district 1-1 is provided with adsorption precipitation pond water inlet pipe 1-3, and the top in mixing and absorption district is provided with steel scoria adsorbent and adds metering system 1-4;The middle and lower part in mixing and absorption district is provided with agitator 1-5.
The preparation process of steel scoria adsorbent is:
1. 50 order metallic screens are utilized to be sieved by slag particle;
2. the slag after screening is put into drying baker, dry one hour under 150 degrees celsius, prepare steel scoria adsorbent.
It is provided with dividing plate 1-6 between described mixing and absorption district 1-1 and settling zone 1-2, the inwall in this dividing plate and adsorption precipitation pond forms the waste water runner entering settling zone as waste water, the exit of settling zone is provided with adsorption precipitation pond three phase separator 1-7, the outlet top of settling zone is provided with adsorption precipitation pond overfalling weir 1-8, the tapered structure of settling zone bottom design, is provided with sediment discharge valve 1-9 bottom pyramidal structure.Adsorption precipitation pond overfalling weir 1-8 connects adsorption precipitation pond outlet pipe, and adsorption precipitation pond outlet pipe connects aeration oxidation pool water inlet pipe 2-1.
Described aeration oxidation pool 2 middle and lower part is provided with aeration oxidation pool water inlet pipe 2-1, and described aeration oxidation pool water inlet pipe 2-1 bottom is provided with water distribution pyrometric cone 2-2;Described water distribution pyrometric cone 2-2 bottom is provided with aeration regulator control system 2-3, and described aeration regulator control system 2-3 includes aeration plate, aerator and dissolved oxygen sensing regulation device;Further, described aeration plate is the pore type aeration plate being evenly arranged with micropore.Described aeration plate connects aerator by aeration tube, aerator is arranged on outside aeration oxidation pool, the top of aeration oxidation pool, waste water underwater arrange dissolved oxygen sensing regulation device, and described dissolved oxygen sensing regulation device regulates and controls the work of aeration oxidation pool aerator according to oxygen capacity;Described aeration oxidation pool water inlet pipe top is built-in with filler 2-4;The exit of aeration oxidation pool is laid with aeration oxidation pool downflow weir 2-5.Aeration oxidation pool downflow weir connects aeration oxidation pool outlet pipe, and aeration oxidation pool outlet pipe connects aerobic filter tower water inlet pipe 3-2.
Aerobic filter tower 3 includes filter tower top cover 3-1, aerobic filter tower water inlet pipe 3-2, aerobic filter tower water distributor 3-3, filtrate 3-4, filtrate bracing frame 3-5, air inlet 3-6 and aerobic filter tower outlet pipe 3-7;Aerobic filter tower 3 adopts multilamellar to arrange, and top is provided with filter tower top cover 3-1, leaves air outlet between filter tower top cover 3-1 and tower body;Filter tower top cover 3-1 is arranged below aerobic filter tower water inlet pipe 3-2, aerobic filter tower water inlet pipe 3-2 and connects aerobic filter tower water distributor 3-3;Aerobic filter tower water distributor 3-3 is placed in the filtrate top of topmost one layer;Filtrate 3-4 is placed on filtrate bracing frame 3-5, and from upper strata to lower floor, the particle diameter of filtrate tapers into;The filtrate bracing frame of every metafiltration tower is designed to inverted trapezoidal drawer type, adds forced ventilation on the one hand, it is to avoid produce foul smell, is easy on the other hand observe and change filtrate, when this layer of filter clogging is serious, when filtering velocity is very low, only this metafiltration material need to be extracted out and change;The bottom of filter tower is provided with air inlet 3-6 and aerobic filter tower outlet pipe 3-7.
Water after the process of aerobic filter tower is by aerobic filter tower outlet pipe 3-7 qualified discharge.
A kind of adopt the above-mentioned method carrying out wastewater treatment containing ambrose alloy electroplating waste processing equipment, there are following steps:
1. waste water enters regulating reservoir by regulating reservoir water inlet pipe, regulates the pH value of waste water, water quality and the water yield.
2. then waste water enters the mixing and absorption district 1-1 in adsorption precipitation pond by regulating reservoir outlet pipe and adsorption precipitation pond water inlet pipe 1-3, steel scoria adsorbent adds metering system 1-4 and adds steel scoria adsorbent, waste water is stirred mixing by agitator 1-5, and the ambrose alloy ion in waste water is adsorbed by steel scoria adsorbent and absorbs.
3. then waste water enters the waste water runner of settling zone, adsorption precipitation pond three phase separator 1-7 realizes the separation of waste water and solid, precipitate sinks to the bottom of settling zone under gravity, being discharged by the sediment discharge valve 1-9 of bottom, the waste water after precipitation enters aeration oxidation pool water inlet pipe 2-1 by adsorption precipitation pond overfalling weir 1-8 and adsorption precipitation pond outlet pipe.
4. waste water enters the middle and lower part of aeration oxidation pool by aeration oxidation pool water inlet pipe 2-1, water distribution uniformity under the effect of water distribution pyrometric cone 2-2, the aeration plate of aeration oxidation pool produces substantial amounts of microbubble, dissolved oxygen sensing regulation device regulates and controls aerator work according to oxygen capacity, it is ensured that the dissolved oxygen in aeration oxidation pool water is more than 2mg/L.Water after aeration oxidation pool process enters aerobic filter tower water inlet pipe 3-2 through aeration oxidation pool downflow weir 2-5 and aeration oxidation pool outlet pipe.
5. waste water enters aerobic filter tower by aerobic filter tower water inlet pipe 3-2, aerobic filter tower water distributor 3-3, air and waste water cross generation biochemical reaction in filtrate 3-4, waste water is filtered by filtrate simultaneously, and the water after the process of aerobic filter tower is by aerobic filter tower outlet pipe 3-7 qualified discharge.
6. adsorption precipitation pond sediment discharge valve discharge absorption saturated after slag dehydration after identical with original slag, it it is still a kind of well engineer applied material, by selecting the technological means of reasonable benefit/risk that being fixed of waste residue after absorption is utilized, thus reducing the heavy metal ion pollution to environment.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not necessarily departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content in description, it is necessary to determine its technical scope according to right.

Claims (2)

1.一种含镍铜电镀废水处理装置,其特征在于:包括调节池、吸附沉淀池(1)、曝气氧化池(2)和好氧滤塔(3),调节池、吸附沉淀池(1)、曝气氧化池(2)和好氧滤塔(3)依次连通;1. a nickel-containing copper electroplating waste water treatment device is characterized in that: comprise adjustment tank, adsorption sedimentation tank (1), aerated oxidation tank (2) and aerobic filter tower (3), adjustment tank, adsorption sedimentation tank ( 1), the aeration oxidation tank (2) and the aerobic filter tower (3) are connected in sequence; 所述的调节池包括调节池进水管和调节池出水管,用于调节废水的pH值、水质和水量;废水由调节池进水管进入调节池,由调节池出水管流出进入吸附沉淀池进水管;The regulating pond includes a regulating pond inlet pipe and a regulating pond outlet pipe, which are used to adjust the pH value, water quality and water quantity of the waste water; the waste water enters the regulating pond from the regulating pond inlet pipe, and flows out from the regulating pond outlet pipe into the adsorption sedimentation pond inlet pipe ; 所述的吸附沉淀池(1)包括混合吸附区(1-1)和沉淀区(1-2);The adsorption sedimentation tank (1) includes a mixed adsorption area (1-1) and a precipitation area (1-2); 所述的混合吸附区(1-1)的中上部设置有吸附沉淀池进水管(1-3),混合吸附区的上部设置有钢渣吸附剂添加计量系统(1-4);混合吸附区的中下部设置有搅拌器(1-5);The upper middle part of the mixed adsorption area (1-1) is provided with an adsorption sedimentation tank inlet pipe (1-3), and the upper part of the mixed adsorption area is provided with a steel slag adsorbent addition metering system (1-4); A stirrer (1-5) is arranged at the middle and lower part; 钢渣吸附剂的制备过程为:The preparation process of steel slag adsorbent is as follows: ①利用20~100目金属筛将钢渣碎料筛分;①Use a 20-100 mesh metal sieve to screen the steel slag fragments; ②将筛分后的钢渣放入干燥箱,在150~200摄氏度条件下干燥一小时,制得钢渣吸附剂;②Put the sieved steel slag into a drying box, and dry it at 150-200 degrees Celsius for one hour to prepare a steel slag adsorbent; 所述混合吸附区(1-1)和沉淀区(1-2)之间设有隔板(1-6),隔板与吸附沉淀池的内壁形成作为废水进入沉淀区的废水流道,沉淀区的出口处设有吸附沉淀池三相分离器(1-7),沉淀区的出口上部设有吸附沉淀池溢水堰(1-8),沉淀区底部设计成锥形结构,在锥形结构底部设置有沉淀物排放阀(1-9);吸附沉淀池溢水堰(1-8)连接吸附沉淀池出水管,吸附沉淀池出水管连接曝气氧化池进水管(2-1);A dividing plate (1-6) is arranged between the mixed adsorption zone (1-1) and the settling zone (1-2), and the dividing plate and the inner wall of the adsorption sedimentation tank form a waste water flow path that enters the settling zone as waste water, and the sedimentation Adsorption sedimentation tank three-phase separator (1-7) is installed at the outlet of the area, and the upper part of the outlet of the sedimentation area is provided with an adsorption sedimentation tank overflow weir (1-8). The bottom of the sedimentation area is designed as a conical structure. A sediment discharge valve (1-9) is arranged at the bottom; the overflow weir (1-8) of the adsorption sedimentation tank is connected to the outlet pipe of the adsorption sedimentation tank, and the outlet pipe of the adsorption sedimentation tank is connected to the inlet pipe (2-1) of the aeration oxidation tank; 所述曝气氧化池(2)中下部设置有曝气氧化池进水管(2-1),所述曝气氧化池进水管(2-1)下部设有布水三角锥(2-2);所述布水三角锥(2-2)下部设有曝气调控系统(2-3),所述曝气调控系统(2-3)包括曝气盘、鼓风机和溶解氧测量调控装置;进一步,所述的曝气盘是均匀设置有微孔的微孔式曝气盘;所述曝气盘通过曝气管连接鼓风机,鼓风机设置在曝气氧化池外,曝气氧化池的上部和废水水面下设置溶解氧测量调控装置,溶解氧测量调控装置根据氧容量调控鼓风机工作;所述曝气氧化池进水管上部内置有填料(2-4);曝气氧化池的出口处布设有曝气氧化池溢流堰(2-5);曝气氧化池溢流堰连接曝气氧化池出水管,曝气氧化池出水管连接好氧滤塔进水管(3-2);The lower part of the aeration oxidation tank (2) is provided with an aeration oxidation tank water inlet pipe (2-1), and the lower part of the aeration oxidation tank water inlet pipe (2-1) is provided with a water distribution triangle cone (2-2) ; The lower part of the triangular cone of water distribution (2-2) is provided with an aeration control system (2-3), and the aeration control system (2-3) includes an aeration disc, a blower and a dissolved oxygen measurement control device; further , the aeration pan is a microporous aeration pan that is evenly provided with micropores; the aeration pan is connected to a blower through an aeration pipe, and the blower is arranged outside the aeration oxidation tank, and the upper part of the aeration oxidation tank and the waste water A dissolved oxygen measurement and control device is set under the water surface, and the dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity; the upper part of the inlet pipe of the aeration oxidation tank is equipped with fillers (2-4); the outlet of the aeration oxidation tank is equipped with an aeration The overflow weir of the oxidation tank (2-5); the overflow weir of the aeration oxidation tank is connected to the outlet pipe of the aeration oxidation tank, and the outlet pipe of the aeration oxidation tank is connected to the inlet pipe of the aerobic filter tower (3-2); 好氧滤塔(3)包括滤塔顶盖(3-1)、好氧滤塔进水管(3-2)、好氧滤塔布水管(3-3)、滤料(3-4)、滤料支撑架(3-5)、进风口(3-6)和好氧滤塔出水管(3-7);好氧滤塔(3)采用多层设置,最顶部设有滤塔顶盖(3-1),滤塔顶盖(3-1)与塔体之间留有出风口;滤塔顶盖(3-1)下面设有好氧滤塔进水管(3-2),好氧滤塔进水管(3-2)连接好氧滤塔布水管(3-3);好氧滤塔布水管(3-3)安置在最上面一层的滤料上部;滤料(3-4)放置在滤料支撑架(3-5)上,从上层到下层,滤料的粒径逐渐变小;每层滤塔的滤料支撑架设计成倒梯形抽屉式,一方面加强通风,避免产生臭气,另一方面便于观察和更换滤料,当该层滤料堵塞严重,需把该层滤料抽出更换;滤塔的底部设有进风口(3-6)和好氧滤塔出水管(3-7);The aerobic filter tower (3) includes a filter tower top cover (3-1), an aerobic filter tower water inlet pipe (3-2), an aerobic filter tower cloth water pipe (3-3), a filter material (3-4), Filter material support frame (3-5), air inlet (3-6) and aerobic filter tower outlet pipe (3-7); the aerobic filter tower (3) adopts multi-layer arrangement, and the top of the filter tower is provided with a filter tower top cover (3-1), there is an air outlet between the filter tower top cover (3-1) and the tower body; the aerobic filter tower water inlet pipe (3-2) is arranged below the filter tower top cover (3-1), so that The oxygen filter tower water inlet pipe (3-2) is connected to the aerobic filter tower cloth water pipe (3-3); the aerobic filter tower cloth water pipe (3-3) is placed on the filter material upper part of the uppermost layer; the filter material (3- 4) Placed on the filter material support frame (3-5), the particle size of the filter material gradually becomes smaller from the upper layer to the lower layer; the filter material support frame of each layer of filter tower is designed as an inverted trapezoidal drawer type, on the one hand, it strengthens ventilation, To avoid odor, on the other hand, it is convenient to observe and replace the filter material. When the filter material of this layer is seriously blocked, it needs to be taken out and replaced; the bottom of the filter tower is equipped with an air inlet (3-6) and an aerobic filter tower Outlet pipe (3-7); 好氧滤塔处理后的水通过好氧滤塔出水管(3-7)达标排放。The water treated by the aerobic filter tower is discharged up to the standard through the outlet pipe (3-7) of the aerobic filter tower. 2.采用权利要求1所述的一种含镍铜电镀废水处理装置进行废水处理的方法,其特征在于:具有如下步骤;2. adopt a kind of nickel-containing copper electroplating waste water treatment device described in claim 1 to carry out the method for waste water treatment, it is characterized in that: have the following steps; ①废水通过调节池进水管进入调节池,调节废水的pH值、水质和水量;①Wastewater enters the regulating pond through the inlet pipe of the regulating pond to adjust the pH value, water quality and water quantity of the waste water; ②然后废水通过调节池出水管和吸附沉淀池进水管(1-3)进入吸附沉淀池的混合吸附区(1-1),钢渣吸附剂添加计量系统(1-4)添加钢渣吸附剂,搅拌器(1-5)对废水进行搅拌混合,废水中的镍铜离子被钢渣吸附剂吸附和吸收;② Then the wastewater enters the mixed adsorption area (1-1) of the adsorption sedimentation tank through the outlet pipe of the regulating tank and the inlet pipe (1-3) of the adsorption sedimentation tank, and the steel slag adsorbent is added to the metering system (1-4) to add the steel slag adsorbent and stir The device (1-5) stirs and mixes the waste water, and the nickel and copper ions in the waste water are adsorbed and absorbed by the steel slag adsorbent; ③然后废水进入沉淀区的废水流道,吸附沉淀池三相分离器(1-7)实现废水和固体的分离,沉淀物在重力的作用下下沉到沉淀区的下部,通过底部的沉淀物排放阀(1-9)排出,沉淀后的废水通过吸附沉淀池溢水堰(1-8)和吸附沉淀池出水管进入曝气氧化池进水管(2-1);③ Then the wastewater enters the wastewater flow channel of the sedimentation area, and the three-phase separator (1-7) of the adsorption sedimentation tank realizes the separation of wastewater and solids, and the sediment sinks to the lower part of the sedimentation area under the action of gravity, and the sediment at the bottom passes through The discharge valve (1-9) is discharged, and the settled wastewater enters the aeration oxidation tank inlet pipe (2-1) through the adsorption sedimentation tank overflow weir (1-8) and the adsorption sedimentation tank outlet pipe; ④废水通过曝气氧化池进水管(2-1)进入曝气氧化池的中下部,在布水三角锥(2-2)的作用下均匀布水,曝气氧化池的曝气盘产生大量的微气泡,溶解氧测量调控装置根据氧容量调控鼓风机工作,确保曝气氧化池水中的溶解氧大于2mg/L;曝气氧化池处理后的水经曝气氧化池溢流堰(2-5)和曝气氧化池出水管进入好氧滤塔进水管(3-2);④Wastewater enters the middle and lower part of the aeration oxidation tank through the water inlet pipe (2-1) of the aeration oxidation tank, and the water is evenly distributed under the action of the water distribution triangle cone (2-2), and the aeration plate of the aeration oxidation tank produces a large amount of water. The dissolved oxygen measurement and control device regulates the work of the blower according to the oxygen capacity to ensure that the dissolved oxygen in the water in the aeration oxidation tank is greater than 2mg/L; the water treated in the aeration oxidation tank passes through the overflow weir of the aeration oxidation tank (2-5 ) and the outlet pipe of the aeration oxidation tank enters the water inlet pipe (3-2) of the aerobic filter tower; ⑤废水通过好氧滤塔进水管(3-2)、好氧滤塔布水管(3-3)进入好氧滤塔,空气与废水在滤料(3-4)中交汇发生生化反应,同时滤料对废水进行过滤,好氧滤塔处理后的水通过好氧滤塔出水管(3-7)达标排放;⑤ The waste water enters the aerobic filter tower through the aerobic filter tower water inlet pipe (3-2) and the aerobic filter tower cloth water pipe (3-3), and the air and waste water meet in the filter material (3-4) for biochemical reactions, and at the same time The filter material filters the wastewater, and the water treated by the aerobic filter tower is discharged up to the standard through the outlet pipe (3-7) of the aerobic filter tower; ⑥吸附沉淀池的沉淀物排放阀排出的吸附饱和后的钢渣脱水后进行利用。⑥ The saturated steel slag discharged from the sediment discharge valve of the adsorption sedimentation tank is dehydrated and utilized.
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CN106277460A (en) * 2016-09-06 2017-01-04 常州大学 A kind of waste water containing thallium processing means
CN106430479A (en) * 2016-09-19 2017-02-22 上海中冶环境工程科技有限公司 Application of electric furnace slag in preparation of nickel-containing sewage treating agent
CN106882903A (en) * 2017-03-09 2017-06-23 常州大学 A kind of steel chlorohydric acid pickling sewage pretreatment device and method
CN106892537A (en) * 2017-03-13 2017-06-27 常州大学 A kind of methacrylic acid wastewater processing system
CN111777148A (en) * 2020-07-25 2020-10-16 黄冬冬 Electroplating wastewater treatment tank

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CN111777148A (en) * 2020-07-25 2020-10-16 黄冬冬 Electroplating wastewater treatment tank

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