CN105734611B - A kind of preparation method of novel energy-conserving anode steel claw - Google Patents
A kind of preparation method of novel energy-conserving anode steel claw Download PDFInfo
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- CN105734611B CN105734611B CN201510457676.8A CN201510457676A CN105734611B CN 105734611 B CN105734611 B CN 105734611B CN 201510457676 A CN201510457676 A CN 201510457676A CN 105734611 B CN105734611 B CN 105734611B
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- Prior art keywords
- welding
- transverse arm
- pawl head
- cosolvent
- anode steel
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 31
- 239000010959 steel Substances 0.000 title claims abstract description 31
- 210000000078 claw Anatomy 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 238000003466 welding Methods 0.000 claims abstract description 40
- 238000002844 melting Methods 0.000 claims abstract description 17
- 230000008018 melting Effects 0.000 claims abstract description 17
- 239000006184 cosolvent Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 230000004927 fusion Effects 0.000 claims abstract description 11
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 238000005275 alloying Methods 0.000 claims abstract description 4
- 238000006722 reduction reaction Methods 0.000 claims abstract description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 5
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 5
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910008455 Si—Ca Inorganic materials 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 19
- 238000005266 casting Methods 0.000 abstract description 5
- 229910001338 liquidmetal Inorganic materials 0.000 abstract description 3
- 238000005457 optimization Methods 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
Landscapes
- Nonmetallic Welding Materials (AREA)
- Arc Welding In General (AREA)
Abstract
A kind of novel energy-conserving anode steel claw, including transverse arm and pawl head, it is characterized in that;Transverse arm and pawl head are fixed together by electroslag molten welding；Preparation method is：It pawl head well prepared in advance and transverse arm parent Q235 blanks, is placed in the corresponding water cooling model cavity of anode steel claw structure, assembling positioning connection；The fluxing agent melted is poured into water cooling model cavity, startup power supply, cosolvent is by the process of melting refinement between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent and metallurgical binding welding.Active rare-earth Elements C e in cosolvent carries out chemical reduction reaction, and rare earth element ce is made to enter fusion welding metal region alloying, purifies material.Another aspect liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.The present invention is welded using whole electroslag molten welding, melting welding uniform temperature fields, fusion welding quality optimization, and properties of product intensity and toughness are high, and electric conductivity is superior.
Description
Technical field
The invention belongs to electrolytic aluminum anodic steel claw and its manufacturing technology fields, are especially a kind of new structural anode steel
Pawl.
Background technology
The making of electrolytic aluminum anodic steel claw component requires dense structure, without casting flaw, and chemical composition is uniformly accurate, traditional
Casting method making anode steel claw processing step is cumbersome, easily causes the secondary oxidation of molten steel, and degree of purity cannot be guaranteed, and
The controllability of scaling loss elemental composition is poor.It is extremely difficult to the making requirement that electrolytic aluminum anodic steel claw resistivity is low, conducts electricity very well.
Invention content
The technical problem to be solved by the present invention is to provide a kind of special electroslag metallurgy welding process method and prepare Novel anode
The method of steel claw component can improve the compactness of novel anode steel claw melting welding, obtain high quality, the production of high performance anode steel claw
Product.
The purpose of the present invention is what is be accomplished by the following way：
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, it is characterized in that;Transverse arm 1 and pawl head 2 are molten by electroslag
Weldering 3 is fixed together；
A kind of preparation method of above-mentioned novel energy-conserving anode steel claw is as follows：
（1）Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds
Metal carrier body stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection；
（2）The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、
CaF2、CaCO3、AL2O3, composition, wherein each ingredient is by mass percentage：CeO2 5-18%、CaF2 43-58%、CaCO3 5-
15%、AL2O3 18-25%；
（3）Cosolvent is being exported two between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent by transformer
Secondary low-voltage and electric current cooperation, are formed into a loop in the slag bath that cosolvent is formed, and the electric energy of circuit input generates height in slag bath
The heat of resistance, high activity, cosolvent slag bath temperature are 1600--18500C leads to the identical parent of chemical composition material and oneself
It consumes consumable electrode and forms melting refinement and metallurgical binding welding；
（4）Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein
Si：Ca is 30 by mass percentage：70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.On the other hand
Liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.
The present invention has the following advantages compared with the anode steel claw work that existing conventional preparation techniques technology makes：
1, traditional handicraft or existing welding procedure are avoided there are " pollution " of metallurgical quality in metallic object, is avoided due to system
Uneven the influences welding quality of series of temperature in standby technique, the deficiency of obdurability and bring anode steel claw in Aluminum Electrolysis Production fortune
Security risk during row.
During anode steel claw entirety electroslag molten welding process, active rare-earth chemical reaction handling novel technique makes melting welding
Uniform temperature fields, fusion welding quality optimization, properties of product intensity and toughness are high, and electric conductivity is superior.
Compared with tradition prepares anode steel claw technique and existing welding procedure, hence it is evident that be that electroslag molten welding rare earth slag pond body is accumulated
Loop process method is simple, scientific and reasonable, effective.Fully phase out existing unreasonable metallurgical method conventional cast, human weld
Technique.Electroslag molten welding new process more meets the progress of melting welding product, has more, fast, good, province, scientific and reasonable.Because welding melting zone domain
Reaction interface is increased, is the complete metallurgical fusion process of authenticity.
Apparatus and process is easy to operate, applied widely, can be flexible and changeable to the type of anode steel claw product, molten by changing
Mounted welder just reaches the technology requirement of the steel pawl diameter and height that meet different size.
The novel technique melting welding activity duration is short, and producing cost is lower than traditional handicraft, cost-effective to avoid wasting.It produces simultaneously
Product are more notable using rear energy-saving economic benefit.
Description of the drawings
Fig. 1 is anode steel claw structural schematic diagram in the prior art；
Fig. 2 is anode steel claw structural schematic diagram of the present invention.
Specific implementation mode
Embodiment 1
A kind of novel energy-conserving anode steel claw, including transverse arm 1 and pawl head 2, it is characterized in that;Transverse arm 1 and pawl head 2 are molten by electroslag
Weldering 3 is fixed together；
A kind of preparation method of above-mentioned novel energy-conserving anode steel claw is as follows：
（1）Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds
Metal carrier body stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection；
（2）The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、
CaF2、CaCO3、AL2O3, composition, wherein each ingredient is by mass percentage： CeO2 5-18%、CaF2 43-58%、CaCO3
5-15%、AL2O3 18-25%；
（3）Cosolvent is being exported two between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent by transformer
Secondary low-voltage and electric current cooperation, are formed into a loop in the slag bath that cosolvent is formed, and the electric energy of circuit input generates height in slag bath
The heat of resistance, high activity, cosolvent slag bath temperature are 1600--18500C leads to the identical parent of chemical composition material and oneself
It consumes consumable electrode and forms melting refinement and metallurgical binding welding；
（4）Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein
Si：Ca is 30 by mass percentage：70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.On the other hand
Liquid metal is comprehensive in melting welding volumetric region to be gradually risen and solidifies, to avoid shrinkage cavity, the generation of stomata casting flaw.
Anode steel claw of the present invention is using whole electroslag molten welding slag welding, melting welding uniform temperature fields, fusion welding quality optimization, product
Performance Strength and toughness are high, and electric conductivity is superior.
Claims (1)
1. a kind of energy-conserving anode steel pawl, including transverse arm and pawl head, it is characterized in that：Transverse arm and pawl head are combined by electroslag molten welding to be fixed
Together；
A kind of preparation method of above-mentioned energy-conserving anode steel pawl is as follows：
（1）Previously prepared cuboid pawl head and cylinder metal transverse arm parent blank, blank material Q235, this 2 kinds of metals
Parent stock is placed in the corresponding water cooling model cavity of anode steel claw structure, is assembled positioning connection；
（2）The fluxing agent melted is poured into water cooling model cavity, startup power supply, the melting welding fluxing agent is by CeO2、CaF2、
CaCO3、AL2O3Composition, wherein each ingredient is CeO by mass percentage25-18%、CaF243-58%、CaCO35-15%、
AL2O318-25%；
（3）Cosolvent exported by transformer between the cuboid pawl head of fusion welding and cylinder metal transverse arm parent it is secondary low
Voltage and current coordinate, cosolvent formed slag bath in be formed into a loop, circuit input electric energy generated in slag bath high resistance,
The heat of high activity, cosolvent slag bath temperature are 1600--1850 DEG C so that the identical parent of chemical composition material and consumable are molten
Polarizing electrode forms melting refinement and metallurgical binding welding；
（4）Chemical reduction reaction is carried out to the active rare-earth Elements C e in cosolvent, reducing agent is Si-Ca alloys, wherein Si：Ca
It is 30 by mass percentage：70, so that rare earth element ce is entered fusion welding metal region alloying, purifies material.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510457676.8A CN105734611B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of novel energy-conserving anode steel claw |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510457676.8A CN105734611B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of novel energy-conserving anode steel claw |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105734611A CN105734611A (en) | 2016-07-06 |
| CN105734611B true CN105734611B (en) | 2018-09-07 |
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|---|---|---|---|
| CN201510457676.8A Active CN105734611B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of novel energy-conserving anode steel claw |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108500241A (en) * | 2018-05-10 | 2018-09-07 | 饶云福 | Anode steel claw row's weldering one-step shaping manufacturing process |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105177626A (en) * | 2015-09-22 | 2015-12-23 | 内蒙古世星新材料科技有限公司 | Method for manufacturing novel energy-saving anode steel jaw |
| CN110079830B (en) * | 2018-01-26 | 2024-06-11 | 洛阳斌拓新材料科技有限公司 | Anode claw for electrolytic aluminum and electrolytic aluminum equipment using same |
| CN110170624B (en) * | 2019-06-04 | 2023-10-13 | 甘肃酒钢集团西部重工股份有限公司 | Crystallizer for steel claw and manufacturing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709384A (en) * | 2009-11-26 | 2010-05-19 | 上海大学 | Novel slag system for improving quality of electroslag remelted steel ingots |
| CN102534677A (en) * | 2012-01-04 | 2012-07-04 | 饶云福 | Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding |
| CN102560552A (en) * | 2012-01-04 | 2012-07-11 | 饶云福 | Fusing agent for electrolytic aluminium anodic steel claws repairing |
| CN103769772A (en) * | 2014-01-15 | 2014-05-07 | 王会智 | Welding agent and welding method for welding anode steel claw |
| CN104139253A (en) * | 2014-07-31 | 2014-11-12 | 新昌县雷凯科技有限公司 | Welding agent formula and process |
-
2015
- 2015-07-30 CN CN201510457676.8A patent/CN105734611B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709384A (en) * | 2009-11-26 | 2010-05-19 | 上海大学 | Novel slag system for improving quality of electroslag remelted steel ingots |
| CN102534677A (en) * | 2012-01-04 | 2012-07-04 | 饶云福 | Device for repairing electrolytic aluminium anode steel claw by total cross-section fusion welding |
| CN102560552A (en) * | 2012-01-04 | 2012-07-11 | 饶云福 | Fusing agent for electrolytic aluminium anodic steel claws repairing |
| CN103769772A (en) * | 2014-01-15 | 2014-05-07 | 王会智 | Welding agent and welding method for welding anode steel claw |
| CN104139253A (en) * | 2014-07-31 | 2014-11-12 | 新昌县雷凯科技有限公司 | Welding agent formula and process |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108500241A (en) * | 2018-05-10 | 2018-09-07 | 饶云福 | Anode steel claw row's weldering one-step shaping manufacturing process |
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| CN105734611A (en) | 2016-07-06 |
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| CB03 | Change of inventor or designer information |
Inventor after: Jiang Yanping Inventor before: Zhang Guicai Inventor before: Jiang Yanping Inventor before: Zhao Yuchun Inventor before: Sun Jian Inventor before: Zhang Ping Inventor before: Li Haiyan Inventor before: Zheng Yongjun |
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Effective date of registration: 20180306 Address after: 014000 Inner Mongolia Baotou city rare earth mansion Huafeng Garden No. 26 Applicant after: INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD. Applicant after: Jiang Yanping Address before: 014010 the Inner Mongolia Autonomous Region Baotou Kunqu District 4 on the east side of friendship Applicant before: INNER MONGOLIA SHIXING NEW MATERIAL SCIENCE & TECHNOLOGY CO., LTD. Applicant before: Zhang Guicai Applicant before: Jiang Yanping |
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