CN105702815A - Manufacturing method for flip LED chip - Google Patents
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- CN105702815A CN105702815A CN201610220840.8A CN201610220840A CN105702815A CN 105702815 A CN105702815 A CN 105702815A CN 201610220840 A CN201610220840 A CN 201610220840A CN 105702815 A CN105702815 A CN 105702815A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 230000004888 barrier function Effects 0.000 claims abstract description 16
- 238000005530 etching Methods 0.000 claims abstract description 16
- 230000008021 deposition Effects 0.000 claims abstract description 9
- 239000010410 layer Substances 0.000 claims description 98
- 239000011241 protective layer Substances 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 16
- 238000000151 deposition Methods 0.000 claims description 15
- 229920002120 photoresistant polymer Polymers 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims 1
- 230000008569 process Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 230000005012 migration Effects 0.000 description 6
- 238000013508 migration Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229910008599 TiW Inorganic materials 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/01—Manufacture or treatment
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- H—ELECTRICITY
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- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
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Abstract
Description
技术领域 technical field
本发明属于光电技术领域,具体涉及倒装LED芯片的制作方法。 The invention belongs to the field of photoelectric technology, and in particular relates to a manufacturing method of a flip-chip LED chip.
背景技术 Background technique
发光二极管(LED)具有寿命长、节能环保等显著优点,被认为是继白炽灯、荧光灯之后又一次照明技术的革命,是目前国际上半导体和照明领域研发和产业关注的焦点,拥有巨大的应用前景。为了解决电极遮光问题、提高亮度,倒装LED芯片工艺越来越具有研发价值和市场前景。 Light-emitting diode (LED) has significant advantages such as long life, energy saving and environmental protection. It is considered to be another revolution in lighting technology after incandescent lamps and fluorescent lamps. It is currently the focus of research and development and industry attention in the field of semiconductors and lighting in the world. prospect. In order to solve the problem of electrode shading and improve brightness, flip-chip LED chip technology has more and more research and development value and market prospects.
如图1所示,倒装芯片设计中涉及到一层保护层包裹反射层银镜的结构,但由于蒸镀、黄光的缺陷等,会存在银迁移导致漏电等异常。 As shown in Figure 1, the flip-chip design involves a structure in which a protective layer wraps the reflective silver mirror. However, due to evaporation, yellow light defects, etc., there will be abnormalities such as silver migration and leakage.
发明内容 Contents of the invention
本发明的目的在于:提供一种倒装LED芯片的制作方法,解决习知倒装LED芯片容易由于银迁移发生漏电的问题。 The object of the present invention is to provide a method for manufacturing a flip-chip LED chip, which solves the problem that the conventional flip-chip LED chip is prone to electric leakage due to silver migration.
根据本发明,提供一种倒装LED芯片的制作方法,包括步骤: According to the present invention, a method for manufacturing a flip-chip LED chip is provided, comprising steps:
S1、提供一发光外延层,在发光外延层上生长ITO层; S1. Provide a light-emitting epitaxial layer, and grow an ITO layer on the light-emitting epitaxial layer;
S2、将发光外延层、ITO层图形化; S2, patterning the light-emitting epitaxial layer and the ITO layer;
S3、沉积保护层,所述保护层覆盖所述ITO层; S3, depositing a protective layer, the protective layer covering the ITO layer;
S4、制作图形保护层,并在图形保护层上制作贯穿至所述ITO层的凹坑,制作后的保护层呈漏斗状,所述漏斗状的开口上大下小; S4, making a pattern protective layer, and making pits penetrating to the ITO layer on the pattern protective layer, the protective layer after making is funnel-shaped, and the funnel-shaped opening is large and small at the bottom;
S5、在所述凹坑内沉积反射层,所述反射层部分或者全部沉积在凹坑内,在所述反射层上覆盖阻挡层。 S5. Deposit a reflective layer in the pit, partially or completely deposit the reflective layer in the pit, and cover the barrier layer on the reflective layer.
进一步地,步骤4通过光罩蚀刻在保护层上制作凹坑。 Further, in step 4, pits are formed on the protective layer by photomask etching.
进一步地,步骤4光罩通过光刻胶进行光罩蚀刻,所述光刻胶对保护层的蚀刻选择比小于所述光刻胶对ITO层的蚀刻选择比。 Further, in step 4, the photomask is etched through the photoresist, and the etching selectivity of the photoresist to the protective layer is smaller than that of the photoresist to the ITO layer.
进一步地,步骤5通过小角度沉积生长所述反射层,通过大角度沉积生长所述阻挡层。 Further, in step 5, the reflective layer is grown by small-angle deposition, and the barrier layer is grown by large-angle deposition.
进一步地,步骤3通过沉积具备反射和惰性特性的材料形成保护层。 Further, in step 3, a protective layer is formed by depositing a material with reflective and inert properties.
进一步地,步骤3通过沉积Ti、TiW、DBR的材料中的一种或任意组合,沉积形成保护层。 Further, in step 3, a protective layer is formed by depositing one or any combination of Ti, TiW, and DBR materials.
进一步地,步骤1中的ITO层生长厚度di为0.06μm到0.2μm,相比常规ITO层,较厚便于步骤4制作ITO层凹坑,扩大包裹反射层的保护效果。 Further, the growth thickness d i of the ITO layer in step 1 is 0.06 μm to 0.2 μm, which is thicker than the conventional ITO layer, which is convenient for making pits in the ITO layer in step 4, and enlarging the protective effect of wrapping the reflective layer.
与现有技术相比,本发明的倒装LED芯片的制作方法,至少包括以下技术效果: Compared with the prior art, the manufacturing method of the flip-chip LED chip of the present invention at least includes the following technical effects:
(1)通过光刻胶对保护层和ITO层蚀刻比的差异,形成漏斗状保护层; (1) Form a funnel-shaped protective layer through the difference in etching ratio between the photoresist and the protective layer and the ITO layer;
(2)通过小角度生产沉积反射层和大角度生长沉积阻挡层,从而高效的完成倒装LED芯片的工艺流程,同时解决传统金属剥离工艺后金属边缘翘曲导致的保护层未完全覆盖住反射层或残留光刻胶等问题导致的反射层材料迁移。。 (2) Through the small-angle production deposition of the reflective layer and the large-angle growth of the deposition barrier layer, the process flow of the flip-chip LED chip is efficiently completed, and at the same time, the protective layer does not completely cover the reflection caused by the warping of the metal edge after the traditional metal lift-off process Migration of reflective layer material caused by problems such as layer or residual photoresist. .
(3)相比常规工艺,加厚生长ITO层降低制作凹坑包裹反射层的难度,同时避免损伤发光外延层。 (3) Compared with the conventional process, thickening and growing the ITO layer reduces the difficulty of making the pit-wrapped reflective layer, while avoiding damage to the light-emitting epitaxial layer.
本发明的其它特征和优点将在随后的说明书中阐述,并且,部分地从说明书中变得显而易见,或者通过实施本发明而了解。本发明的目的和其他优点可通过在说明书、权利要求书以及附图中所特别指出的特征来实现和获得。 Additional features and advantages of the invention will be set forth in the description which follows, and in part will be apparent from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention may be realized and attained by the features particularly pointed out in the written description, claims hereof as well as the appended drawings.
附图说明 Description of drawings
附图用来提供对本发明的进一步理解,并且构成说明书的一部分,与本发明的实施例一起用于解释本发明,并不构成对本发明的限制。此外,附图数据是描述概要,不是按比例绘制。 The accompanying drawings are used to provide a further understanding of the present invention, and constitute a part of the description, and are used together with the embodiments of the present invention to explain the present invention, and do not constitute a limitation to the present invention. In addition, the drawing data are descriptive summaries and are not drawn to scale.
图1:现有的倒装LED芯片结构剖面示意图; Figure 1: A cross-sectional schematic diagram of an existing flip-chip LED chip structure;
图2:实施例制作到步骤1的剖面示意图; Fig. 2: the sectional schematic diagram that embodiment is made to step 1;
图3:实施例制作到步骤2的剖面示意图; Fig. 3: the sectional schematic diagram that embodiment is made to step 2;
图4:实施例制作到步骤3的剖面示意图; Fig. 4: the sectional schematic diagram that embodiment is made to step 3;
图5~图6:实施例制作步骤4的剖面示意图; Fig. 5 ~ Fig. 6: the cross-sectional schematic diagram of embodiment making step 4;
图7:实施例制作到步骤5的剖面示意图; Fig. 7: the sectional schematic diagram that embodiment is made to step 5;
图中各标号表示:1:发光外延层,2:反射层,3:阻挡层,4:ITO层,5:保护层。 The symbols in the figure indicate: 1: light-emitting epitaxial layer, 2: reflective layer, 3: barrier layer, 4: ITO layer, 5: protective layer.
具体实施方式 detailed description
为了能彻底地了解本发明,将在下列的描述中提出详尽的步骤及其组成,另外,众所周知的组成或步骤并未描述于细节中,以避免造成本发明不必要之限制。本发明的较佳实施例会详细描述如下,然而除了这些详细描述之外,本发明还可以广泛地施行在其它的实施例中,且本发明的范围不受限定,以专利权利范围为准。 For a thorough understanding of the present invention, detailed steps and components thereof will be presented in the following description. In addition, well-known components or steps are not described in detail to avoid unnecessary limitations of the present invention. The preferred embodiments of the present invention will be described in detail as follows. However, in addition to these detailed descriptions, the present invention can also be widely implemented in other embodiments, and the scope of the present invention is not limited, and the scope of patent rights shall prevail.
本发明提出一适用于倒装LED芯片之工艺,改善习知倒装LED芯片容易发生漏电的问题。 The present invention proposes a process suitable for flip-chip LED chips, which improves the conventional problem that flip-chip LED chips are prone to electric leakage.
实施例 Example
本实施例提供倒装LED芯片的制作方法,包括步骤: This embodiment provides a method for manufacturing a flip-chip LED chip, including steps:
S1、参照图2,提供一发光外延层1,在发光外延层1上生长ITO层4; S1. Referring to FIG. 2, a light emitting epitaxial layer 1 is provided, and an ITO layer 4 is grown on the light emitting epitaxial layer 1;
S2、参照图3,制作出芯粒图形发光外延层1、制作图形ITO层4; S2. Referring to FIG. 3 , making a core pattern light-emitting epitaxial layer 1 and making a patterned ITO layer 4;
S3、参照图4,沉积保护层1,覆盖ITO层4,保护层5由惰性材料组成,优选为具备反射性能的惰性材料,本实施例优选为Ti,也可以为TiW、DBR等材料或者任意组合。在改善反射层材料迁移的同时,增大背向出光; S3, with reference to Fig. 4, deposit protection layer 1, cover ITO layer 4, protection layer 5 is made up of inert material, preferably has the inert material of reflective property, and this embodiment is preferably Ti, also can be materials such as TiW, DBR or any combination. While improving the material migration of the reflective layer, increase the backlight;
S4、参照图5和图6,制作图形保护层,并在图形保护层上制作贯穿至ITO层4的凹坑,制作后的保护层呈漏斗状,所述漏斗状的开口上大下小; S4, with reference to Fig. 5 and Fig. 6, make graphic protective layer, and make the pit that runs through to ITO layer 4 on graphic protective layer, the protective layer after making is funnel-shaped, and the opening of described funnel-shaped is big on the bottom and small;
S5、参照图7,在所述凹坑内沉积反射层2,所述反射层2部分或者全部沉积在凹坑内,在反射层2上覆盖阻挡层3。 S5 , referring to FIG. 7 , depositing a reflective layer 2 in the pit, partially or completely depositing the reflective layer 2 in the pit, and covering the barrier layer 3 on the reflective layer 2 .
具体来说,步骤1相对常规工艺,本实施例生长更厚的ITO层4,以利于步骤4中制作贯穿至ITO层4的凹坑,ITO层4的厚度di为0.06μm~0.2μm,相比常规工艺,加厚生长ITO层4降低步骤4制作凹坑包裹反射层2的难度,同时避免蚀刻损伤发光外延层1。ITO层4上表面部分区域与保护层5接触,反射层2部分或者全部位于凹坑内。形成阻挡层3和ITO层4包裹反射层2的结构,阻挡反射层2材料迁移。。 Specifically, compared with the conventional process in step 1, a thicker ITO layer 4 is grown in this embodiment to facilitate the formation of pits penetrating to the ITO layer 4 in step 4. The thickness d i of the ITO layer 4 is 0.06 μm to 0.2 μm, Compared with the conventional process, thickening and growing the ITO layer 4 reduces the difficulty of making the pit-wrapping reflective layer 2 in step 4, and at the same time avoids etching damage to the light-emitting epitaxial layer 1 . Part of the upper surface of the ITO layer 4 is in contact with the protective layer 5 , and part or all of the reflective layer 2 is located in the pit. A structure in which the barrier layer 3 and the ITO layer 4 are wrapped around the reflective layer 2 is formed to prevent material migration of the reflective layer 2 . .
步骤4使用光刻胶进行光罩蚀刻,利用BCl3、SiCl4或Cl2气体在保护层5进行干蚀刻制作凹坑,所述光刻胶对保护层5的蚀刻选择比小于光刻胶对ITO层4的蚀刻选择比,即相比蚀刻ITO层4,光刻胶对保护层5蚀刻更慢。优选的,所述光刻胶对保护层5的蚀刻选择比为0.3~0.8,而对ITO层4的蚀刻选择比为1~1.4。通过蚀刻选择比的差异,保护层5蚀刻后为漏斗状、开口上大下小,保护层5内侧至少具有一个斜坡面,斜坡面的斜角α为30°~75°,保护层5将ITO层4、反射层2和阻挡层3包裹在内,并且由于漏斗状结构,增大阻挡层3与保护层5接触面积,同时漏斗状结构影响下,阻挡层3上表面的面积Su大于下表面的面积Sd,为反射层2材料提供更优良的密封效果,提高稳定性和可靠性。 Step 4 uses photoresist to carry out photomask etching, utilizes BCl 3 , SiCl 4 or Cl 2 gas to carry out dry etching to make pits on protective layer 5, and the etching selectivity ratio of described photoresist to protective layer 5 is smaller than photoresist to photoresist to The etching selectivity of the ITO layer 4 means that the photoresist etches the protective layer 5 more slowly than the etching of the ITO layer 4 . Preferably, the etching selectivity ratio of the photoresist to the protection layer 5 is 0.3-0.8, and the etching selectivity ratio to the ITO layer 4 is 1-1.4. According to the difference in etching selectivity, the protective layer 5 is funnel-shaped after etching, with a large opening and a small opening. The inner side of the protective layer 5 has at least one slope surface, and the slope angle α of the slope surface is 30°~75°. Layer 4, reflective layer 2 and barrier layer 3 are wrapped inside, and due to the funnel-shaped structure, the contact area between barrier layer 3 and protective layer 5 is increased, and under the influence of funnel - shaped structure, the area Su of the upper surface of barrier layer 3 is larger than that The area S d of the surface provides a better sealing effect for the material of the reflective layer 2 and improves stability and reliability.
阻挡层3的材料可选Ti、TiW、Ni、Pt中的一种或者任意组合,阻挡层3厚度db是反射层2厚度dr的2倍或以上,保护层5厚度dp是反射层2厚度dr的4倍或以上。 The material of the barrier layer 3 can be selected from one of Ti, TiW, Ni, Pt or any combination, the thickness d b of the barrier layer 3 is twice or more than the thickness d r of the reflective layer 2, and the thickness d p of the protective layer 5 is the reflective layer 2 Thickness d r 4 times or more.
步骤5利用E-Gun等蒸镀设备在凹坑内小角度沉积反射层2,避免反射层2利用Sputter溅镀设备在反射层2上大角度覆盖阻挡层3,从而通过蒸镀跟溅镀快速制作反射层2和阻挡层3,除了减短生产周期,节省生产资源,降低生产成本,还能解决传统金属剥离工艺后金属层边缘由于剥离产生的翘曲导致保护层5未完全覆盖住反射层2或清洗不完全导致残留光刻胶等问题引起的反射层2材料迁移。 Step 5. Deposit the reflective layer 2 in the pit at a small angle using evaporation equipment such as E-Gun to prevent the reflective layer 2 from covering the barrier layer 3 at a large angle on the reflective layer 2 with Sputter sputtering equipment, so that it can be produced quickly by evaporation and sputtering The reflective layer 2 and the barrier layer 3, in addition to shortening the production cycle, saving production resources, and reducing production costs, can also solve the problem that the protective layer 5 does not completely cover the reflective layer 2 due to the warping of the edge of the metal layer after the traditional metal stripping process. Or incomplete cleaning leads to the migration of the material of the reflective layer 2 caused by problems such as residual photoresist.
步骤5中反射层2材料优选为Ag或Al,保护层5阻止反射层2材料迁移。 In step 5, the material of the reflective layer 2 is preferably Ag or Al, and the protective layer 5 prevents the material of the reflective layer 2 from migrating.
需要说明的是,以上实施方式仅用以说明本发明的技术方案,而非对其限制;尽管参照前述实施方式对本发明进行详细的说明,本领域的普通技术人员应当理解;其依然可以对前述实施例所记载的技术方案进行修改,或者对其中部分或者全部技术特征进行等同替换,而这些修改或者替换,并不使相应技术方案的本质脱离本发明各实施方案的范围。 It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit them; although the present invention is described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand; The technical solutions described in the examples are modified, or some or all of the technical features are equivalently replaced, and these modifications or replacements do not make the essence of the corresponding technical solutions depart from the scope of the embodiments of the present invention.
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CN104037295A (en) * | 2014-06-16 | 2014-09-10 | 江苏汉莱科技有限公司 | LED (Light-Emitting Diode) flip chip and manufacturing method thereof |
CN104134723A (en) * | 2014-08-08 | 2014-11-05 | 映瑞光电科技(上海)有限公司 | Vertical type LED chip structure and manufacturing method thereof |
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CN109461803A (en) * | 2018-09-29 | 2019-03-12 | 江苏芯力特电子科技有限公司 | A kind of processing method of flip-chip |
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