CN105685045A - Insecticide composition containing SIOC-I-002 - Google Patents
Insecticide composition containing SIOC-I-002 Download PDFInfo
- Publication number
- CN105685045A CN105685045A CN201610087971.3A CN201610087971A CN105685045A CN 105685045 A CN105685045 A CN 105685045A CN 201610087971 A CN201610087971 A CN 201610087971A CN 105685045 A CN105685045 A CN 105685045A
- Authority
- CN
- China
- Prior art keywords
- louse
- fluorine
- sulfanilamide
- acre
- grams
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- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 59
- 239000002917 insecticide Substances 0.000 title abstract description 16
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000005926 Pyridalyl Substances 0.000 claims abstract description 64
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000005912 Lufenuron Substances 0.000 claims abstract description 63
- 239000005914 Metaflumizone Substances 0.000 claims abstract description 63
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 claims abstract description 63
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 229960000521 lufenuron Drugs 0.000 claims abstract description 63
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 13
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 113
- 229910052731 fluorine Inorganic materials 0.000 claims description 113
- 239000011737 fluorine Substances 0.000 claims description 113
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims description 110
- 229940124530 sulfonamide Drugs 0.000 claims description 110
- 239000000375 suspending agent Substances 0.000 claims description 56
- 241000238631 Hexapoda Species 0.000 claims description 18
- 241000500437 Plutella xylostella Species 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 15
- 241000255967 Helicoverpa zea Species 0.000 claims description 14
- 230000000361 pesticidal effect Effects 0.000 claims description 13
- 241001414989 Thysanoptera Species 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 11
- 241000258937 Hemiptera Species 0.000 claims description 11
- 241000907661 Pieris rapae Species 0.000 claims description 11
- 241000985245 Spodoptera litura Species 0.000 claims description 10
- 241000218475 Agrotis segetum Species 0.000 claims description 9
- 241001124076 Aphididae Species 0.000 claims description 9
- 241000426497 Chilo suppressalis Species 0.000 claims description 9
- 241001498622 Cixius wagneri Species 0.000 claims description 9
- 241001465977 Coccoidea Species 0.000 claims description 9
- 241001517923 Douglasiidae Species 0.000 claims description 9
- 241001232130 Maruca testulalis Species 0.000 claims description 9
- 241000256247 Spodoptera exigua Species 0.000 claims description 9
- 239000000725 suspension Substances 0.000 claims description 9
- 239000002023 wood Substances 0.000 claims description 9
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 239000004563 wettable powder Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 abstract description 19
- 239000000470 constituent Substances 0.000 abstract description 14
- 239000005927 Pyriproxyfen Substances 0.000 abstract description 6
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 239000005931 Spirotetramat Substances 0.000 abstract description 2
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 abstract description 2
- 230000012865 response to insecticide Effects 0.000 abstract description 2
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 abstract description 2
- 244000144972 livestock Species 0.000 abstract 1
- 125000004494 ethyl ester group Chemical group 0.000 description 60
- 239000003814 drug Substances 0.000 description 56
- 238000012360 testing method Methods 0.000 description 38
- 239000002131 composite material Substances 0.000 description 26
- 239000004615 ingredient Substances 0.000 description 22
- 230000003449 preventive effect Effects 0.000 description 19
- 230000010165 autogamy Effects 0.000 description 16
- 239000006071 cream Substances 0.000 description 16
- 239000000575 pesticide Substances 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- 230000002045 lasting effect Effects 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 231100000820 toxicity test Toxicity 0.000 description 12
- 229940079593 drug Drugs 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 11
- 230000002265 prevention Effects 0.000 description 11
- 239000013530 defoamer Substances 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 235000007164 Oryza sativa Nutrition 0.000 description 9
- 230000002528 anti-freeze Effects 0.000 description 8
- 239000008346 aqueous phase Substances 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000002562 thickening agent Substances 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- 241000209094 Oryza Species 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 238000013401 experimental design Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 235000009566 rice Nutrition 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 230000001988 toxicity Effects 0.000 description 6
- 231100000419 toxicity Toxicity 0.000 description 6
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 5
- 206010011732 Cyst Diseases 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- -1 4-Phenoxyphenyl Chemical group 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000273311 Aphis spiraecola Species 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 241000255777 Lepidoptera Species 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 210000002784 stomach Anatomy 0.000 description 3
- 241000254127 Bemisia tabaci Species 0.000 description 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 2
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 2
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 241001525654 Phyllocnistis citrella Species 0.000 description 2
- 241000125167 Rhopalosiphum padi Species 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 230000001537 neural effect Effects 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005758 Cyprodinil Substances 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000018135 Trialeurodes Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000007957 coemulsifier Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 230000008175 fetal development Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 210000000087 hemolymph Anatomy 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229930014550 juvenile hormone Natural products 0.000 description 1
- 239000002949 juvenile hormone Substances 0.000 description 1
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 239000003987 organophosphate pesticide Substances 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticide composition containing SIOC-I-002.The insecticide composition contains an active constituent A and an active constituent B, wherein the active constituent A is SIOC-I-002, the active constituent B is optional one of spirotetramat, chlorfenapyr, lufenuron, pyriproxyfen, metaflumizone and pyridalyl, and the weight ratio of the active constituent A to the active constituent B is 1:70-70:1.The insecticide composition has the advantages that the insecticide composition can control various pests, has an evident synergism effect, can expand insecticidal spectrum, is high in activity on various pests on vegetables, fruit trees, grain crops and fiber crops, reduces insecticide use amount, lowers insecticide residues on the crops, relieves environment pollution and is safe to human and livestock and good in environment compatibility, and pest insecticide resistance cannot be generated easily.
Description
The application is divisional application, and original application is the patent application " Pesticidal combination of a kind of fluorine-containing louse sulfanilamide " of Shaanxi Welch Crop Protection Co., Ltd., and the application number of original application is
201210112747.7, original application day is 2012.04.17。
Technical field
The invention belongs to technical field of pesticide, relate to the Pesticidal combination of a kind of fluorine-containing louse sulfanilamide。
Background technology
Spiral shell worm ethyl ester (spirotetramat) chemical name: 4-(ethoxy carbonyl oxygen base)-8-methoxyl group-3-(2,5-xylyl)-1-azaspiro [4, the 5]-last of the ten Heavenly stems-3-alkene-2-ketone, molecular formula: C21H27NO5, spiral shell worm ethyl ester is a kind of Novel special window acids insecticide, and insecticidal spectrum is wide, and the lasting period is long。It is that the fatty biosynthesis by interference insect causes dead larvae, reduces the fertility of adult。Due to the mechanism of action of its uniqueness, can effectively prevent and treat the insect that existing insecticide is produced resistance, at the same time as the important kind of nicotinic insecticide resistance management。
Capillary (chlorfenapyr) chemical name: 4-bromo-2-(4-chlorphenyl)-1-(ethoxyl methyl)-5-(trifluoromethyl) pyrroles-3-nitrile, molecular formula: C15H11BrClF3N2O, this product of capillary is new pyrrole class parasite killing, acaricide。Various pests has stomach toxicity and action of contace poison, and to crop safety, preventing and treating diamondback moth has the advantages such as preventive effect height, the lasting period is longer, dosage is low。
Lufenuron (lufenuron) chemical name: N-[[[the chloro-4-of 2,5-bis-(1,1,2,3,3,3-hexafluoro the third oxygen) phenyl] amino] carboxyl]-2,6-difluorobenzamide；Molecular formula: C17H8C12F8N2O3, lufenuron is latest generation substituted urea class insecticide。Medicament is by acting on insect larvae, preventionDecorticationProcess and kill off the insect pests, especially the food leaf caterpillar such as fruit tree is had outstanding preventive effect, rightThrips, rust mite,Trialeurodes vaporariorumWhat have uniqueness kills mechanism, is suitable to prevent and treat that pyrethroid and organophosphorus pesticide are produced resistant insect。
Nylar (pyriproxyfen) chemical name: 4-Phenoxyphenyl (RS)-2-(2-pyridine radicals oxygen) propyl ether, molecular formula: C20H19NO3, Nylar is the chitin synthesis inhibitor of a kind of juvenile hormone type, has strong ovicidal action。Pyriproxyfen also has interior absorption transfer activity, it is possible to impact is hidden in blade larva behind。The inhibitory action of insecticide is shown that affecting insecticide changes in quality and breeding。The toxicological test of Prodenia litura is showed, and pyriproxyfen retains hemolymph middle and high concentration, accelerates the secretion of insecticide prothoracotropic hormone；On the other hand, owing to pyriproxyfen can make insecticide lack required stimulating factor of laying eggs, it is suppressed that the hatching of fetal development and ovum, or the ovum not having viability is generated, thus effectively controlling and reach the purpose of Pest control。
Metaflumizone (metaflumizone) chemical name: (E+Z)-[2-(4-cyano group benzene)-1-[3-(trifluoromethyl) benzene] ethylidene]-N-[4-(trifluoromethyl) benzene]-hydrazine carbonyl oxamides, molecular formula: C24H16F6N4O2, metaflumizone is mainly stomach poison function, band action of contace poison, hinders neural sodium path to cause neural paralysis, preventing and treating lepidoptera and coleopteran pest, to mammal and non-target organism low-risk。
Pyridalyl (Pyridalyl) chemical name: 2-[3-[2,6-bis-chloro-4-[(3,3-bis-chloro-2-acrylic) oxygen base] phenoxy group] propoxyl group]-5-(trifluoromethyl) pyrimidine, molecular formula: C32H14F3NO3。Pyridalyl has structure diverse with existing insecticide, and the many lepidoptera pests on vegetable and Cotton Gossypii have the insecticidal activity of brilliance。There is the effect tagged with stomach toxicity simultaneously, lepidoptera pest is had original preventive effect, thrips is also showed that certain activity, and pyridalyl is only small on various arthropodan impacts, so it is expected to become an effective instrument in integrated pest management。
But, in the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide。Different cultivars composition carries out composite, is prevent and treat the method that resistant insect is very common。Heterogeneity carries out composite, according to practical application effect, judge certain composite be potentiation, add and, antagonism。In most cases, the composite effect of pesticide is all additive effect, really have potentiation composite seldom, especially potentiation clearly, significantly high composite just less of co-toxicity coefficient。Study through inventor, find to produce after composite to fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl good potentiation, and not yet open about the relevant report that fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl are composite。
Summary of the invention
Fluorine louse sulfanilamide single dose life-time service be likely to the resistance brought occur, degradation problem under drug effect, the Pesticidal combination that the present invention proposes contains active components A and active component B, and appropriate surfactant and carrier。
A kind of Pesticidal combination of fluorine-containing louse sulfanilamide, it is characterized in that: containing active components A and active component B, the weight ratio of active components A and active component B is 1 70～70 1, described active components A is selected from fluorine louse sulfanilamide, active component B one in spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl, the weight ratio of active components A and active component B is preferably 1 50～30 1, and the weight ratio of fluorine louse sulfanilamide and spiral shell worm ethyl ester is more preferably 10 1～1 20；The weight ratio of fluorine louse sulfanilamide and capillary is more preferably 10 1～1 20；The weight ratio of fluorine louse sulfanilamide and lufenuron is more preferably 10 1～1 10；The weight ratio of fluorine louse sulfanilamide and Nylar is more preferably 10 1～1 20；The weight ratio of fluorine louse sulfanilamide and metaflumizone is more preferably 10 1～1 30；The weight ratio of fluorine louse sulfanilamide and pyridalyl is more preferably 10 1～1 20。
The Pesticidal combination of described fluorine-containing louse sulfanilamide is for preventing and treating the purposes of crop pest, and described crops include the purposes of insect on vegetable, fruit tree, cereal crops, fibre crops。
Described purposes, it is characterized in that, described insect includes: planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer。
The weight ratio of active components A and active component B is 1 70～70 1。In usual compositions, the weight percentage of active component is the 1%～90% of gross weight, it is advantageous to be 5%～85%。According to different preparation types, active component content scope is different。Generally, liquid preparation contains the active substance of by weight 1%～70%, it is preferred that be 5%～50%；Solid preparation contains the active substance of by weight 5%～85%, it is preferred that be 10%～70%。
The Pesticidal combination of the present invention at least contains a kind of surfactant, active component dispersion in water when being beneficial to use。Surface-active contents is the 5%～40% of total formulation weight amount, and surplus is solid or liquid diluent。
The compositions of the present invention can by user before use through diluting or directly using。Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, add one or more in surfactant such as dispersant, stabilizer, wetting agent, emulsifying agent, binding agent, defoamer etc.。
The Pesticidal combination of the present invention, acceptable dosage form on any pesticide can be processed on demand, wherein excellent relatively select the dosage form to be: wettable powder, suspending agent, suspension emulsion, water dispersible granules, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspending agent-suspending agent。
Compositions comprises following constituent content when making wettable powder: active components A 1%～70%, active component B1%～70%, dispersant 1.5%～10%, wetting agent 1%～10%, filler surplus。
Compositions includes following constituent content when making water dispersible granules: active components A 1%～70%, active component B1%～70%, dispersant 1%～12%, wetting agent 1%～8%, disintegrating agent 1%～10%, binding agent 0%～8%, filler surplus。
Compositions includes following constituent content when making suspending agent: active components A 1%～50%, active component B1%～50%, dispersant 1%～10%, wetting agent 1%～10%, defoamer 0.1%～1%, thickening agent 0.05%～2%, antifreeze 0%～8%, deionized water add to 100%。
Compositions includes following constituent content when making suspension emulsion: active components A 1%～50%, active component B1%～50%, solvent 0～15%, emulsifying agent 2%～12%, and dispersant 2%～10%, defoamer 0.1%～2%, thickening agent 0.05%～2%, antifreeze 0%～8%, stabilizer 0%～3%, water add to 100%。
Compositions comprises following constituent content when making aqueous emulsion: active components A 1%～50%, active component B1%～50%, solvent 1%～30%, emulsifying agent 1%～20%, co-emulsifier 1%～8%, antifreeze 0%～8%, thickening agent 0.05%～2%, defoamer 0%～2%, deionized water supply surplus。
Compositions comprises following constituent content when making microemulsion: active components A 1%～50%, active component B1%～50%, solvent 1%～30%, emulsifying agent 3%～20%, antifreeze 0%～8%, thickening agent 0.05%～2%, defoamer 0.01%～2%, stabilizer 0%～4%, deionized water supplies surplus。
Compositions includes following constituent content when making microcapsule suspending agent: active components A 1%～50%, active component B1%～50%, macromolecule cyst material 3%～10%, dispersant 2%～10%, organic solvent 0%～10%, emulsifying agent 2%～7%, pH adjusting agent 0.1%～5%, deionized water adds to 100%。
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 1%～40%, active component B1%～60%, macromolecule cyst material 2%～12%, surfactant 3%～15%, organic solvent 1%～5%, emulsifying agent 1%～6%, defoamer 0.2%～5%, thickening agent 0.05%～1%, pH adjusting agent 1%～5%, water add to 100%。
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
(1) fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl composite after, there is notable synergistic and lasting effect；(2) expand insecticidal spectrum, the planthopper on vegetable, fruit tree, cereal crops, fibre crops, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer etc. are all had greater activity；(3) decrease the dosage of pesticide, reduce pesticide residual quantity on crop；(4) to person poultry safety, Environmental compatibility is good, and insect is not likely to produce Drug resistance。
Detailed description of the invention
Below in conjunction with embodiment to further instruction of the present invention, the percentage ratio in embodiment is all weight percentage, but the invention is not limited in this。
Application Example one
Embodiment 1～15 wettable powder
By fluorine louse sulfanilamide, effective ingredient B, dispersant, wetting agent, filler mix homogeneously in mixed cylinder, remix uniformly after jet mill is pulverized, namely can be made into fluorine louse sulfanilamide effective ingredient B wettable powder product, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 1。
Table 1 embodiment 1～15 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 2 fluorine louse sulfanilamide prevents and treats the rice hoppers test of pesticide effectiveness with spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and mixture thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 1 | 8 grams/acre | 98.75 | 99.13 |
| Embodiment 2 | 5 grams/acre | 99.42 | 99.35 |
| Embodiment 5 | 12 grams/acre | 97.51 | 98.27 |
| Embodiment 6 | 4 grams/acre | 99.36 | 99.14 |
| Embodiment 9 | 6 grams/acre | 98.59 | 99.01 |
| Embodiment 11 | 4 grams/acre | 98.63 | 99.48 |
| Embodiment 13 | 10 grams/acre | 97.84 | 98.26 |
| Embodiment 15 | 5 grams/acre | 98.77 | 99.12 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 25 grams/acre | 65.45 | 68.76 6 --> |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 25 grams/acre | 64.31 | 69.23 |
| 10% capillary suspending agent | 30 grams/acre | 66.52 | 70.15 |
| 100 g/l of Nylar cream | 45 grams/acre | 67.58 | 71.42 |
| 50 g/l of lufenuron suspension agents | 50 grams/acre | 65.29 | 68.31 |
| 22% metaflumizone suspending agent | 75 grams/acre | 68.74 | 70.28 |
| 10% pyridalyl cream (autogamy) | 60 grams/acre | 64.38 | 69.53 |
As can be seen from Table 2, being better than compareing medicament to rice hoppers prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to rice safety in test scope of medication。
Table 3 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating Citrus scale insect test of pesticide effectiveness thereof
| Treatment agent | Extension rate | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 3 | 7500 times | 99.27 | 98.84 |
| Embodiment 4 | 8500 times | 99.06 | 98.59 |
| Embodiment 7 | 6000 times | 98.42 | 99.37 |
| Embodiment 8 | 5500 times | 98.76 | 99.02 |
| Embodiment 10 | 6500 times | 99.24 | 98.48 |
| Embodiment 12 | 7000 times | 99.85 | 99.09 |
| Embodiment 14 | 4500 times | 98.52 | 99.46 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 3000 times | 66.93 | 68.73 |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 4000 times | 64.29 | 65.39 |
| 10% capillary suspending agent | 1500 times | 67.84 | 69.76 |
| 100 g/l of Nylar cream | 1500 times | 65.31 | 68.25 |
| 50 g/l of lufenuron suspension agents | 2000 times | 63.76 | 69.41 |
| 22% metaflumizone suspending agent | 1000 times | 65.45 | 68.92 |
| 10% pyridalyl cream (autogamy) | 1200 times | 64.52 | 66.73 |
As can be seen from Table 3, being better than compareing medicament to Citrus scale insect prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to Citrus safety in test scope of medication。
Embodiment 16～31 water dispersible granules
Fluorine louse sulfanilamide, effective ingredient B, dispersant, wetting agent, disintegrating agent, filler etc. are obtained through comminution by gas stream together the particle diameter needed, adds other auxiliary agents such as binding agent, obtain granulation materials。Item is quantitatively sent in fluidized bed granulating dryer through granulating and dried, preparing fluorine louse sulfanilamide effective ingredient B water dispersible granules product, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Table 4 embodiment 16～23 each component and weight portion
Table 5 embodiment 24～31 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 6 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating wheat aphid test of pesticide effectiveness thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 16 | 7 grams/acre | 98.67 | 99.58 |
| Embodiment 17 | 5 grams/acre | 99.68 | 99.61 |
| Embodiment 18 | 6 grams/acre | 97.82 | 98.76 |
| Embodiment 19 | 8 grams/acre | 98.79 | 98.84 |
| Embodiment 20 | 10 grams/acre | 99.16 | 99.28 |
| Embodiment 21 | 5 grams/acre | 98.73 | 98.95 |
| Embodiment 22 | 10 grams/acre | 99.13 | 99.85 |
| Embodiment 23 | 5 grams/acre | 98.76 | 99.37 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 20 grams/acre | 68.25 | 66.46 |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 28 grams/acre | 67.51 | 65.92 |
| 10% capillary suspending agent | 25 grams/acre | 68.36 | 69.49 |
| 100 g/l of Nylar cream | 48 grams/acre | 67.82 | 68.03 |
| 50 g/l of lufenuron suspension agents | 55 grams/acre | 65.23 | 70.14 |
| 22% metaflumizone suspending agent | 80 grams/acre | 64.41 | 72.32 |
| 10% pyridalyl cream (autogamy) | 55 grams/acre | 65.75 | 69.85 |
As can be seen from Table 6, being better than compareing medicament to wheat aphid prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Table 7 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating Fructus Lycopersici esculenti Bemisia tabaci test of pesticide effectiveness thereof
As can be seen from Table 7, being better than compareing medicament to Fructus Lycopersici esculenti Bemisia tabaci prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Embodiment 25～36 suspending agent
By fluorine louse sulfanilamide, effective ingredient B, dispersant, wetting agent, defoamer, thickening agent, antifreeze through high speed shear mix homogeneously, add former medicine, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, deionized water supplies surplus, preparing fluorine louse sulfanilamide effective ingredient B suspending agent product, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 8, table 9, table 10, table 11。
Table 8 embodiment 32～35 each component and weight portion
Table 9 embodiment 36～39 each component and weight portion
Table 10 embodiment 40～43 each component and weight portion
Table 11 embodiment 44～47 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 12 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating pear sucker test of pesticide effectiveness thereof
| Treatment agent | Extension rate | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 32 | 4500 times | 99.37 | 99.85 |
| Embodiment 33 | 5500 times | 98.56 | 98.62 |
| Embodiment 36 | 6000 times | 98.24 | 99.01 |
| Embodiment 37 | 5000 times | 98.79 | 99.13 |
| Embodiment 40 | 4500 times | 98.91 | 98.54 |
| Embodiment 42 | 5000 times | 97.62 | 97.48 |
| Embodiment 44 | 3500 times | 98.24 | 98.65 |
| Embodiment 46 | 4000 times | 99.37 | 98.89 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 3200 times | 68.51 | 66.27 |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 4500 times | 66.48 | 95.58 |
| 10% capillary suspending agent | 1200 times | 67.39 | 68.42 |
| 100 g/l of Nylar cream | 1500 times | 67.82 | 69.14 |
| 50 g/l of lufenuron suspension agents | 1600 times | 65.76 | 70.26 |
| 22% metaflumizone suspending agent | 1100 times | 64.83 | 68.97 |
| 10% pyridalyl cream (autogamy) | 1000 times | 6847 | 6613 |
As can be seen from Table 12, being better than compareing medicament to pear sucker prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Table 13 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating Caulis et Folium Brassicae capitatae diamondback moth test of pesticide effectiveness thereof
As can be seen from Table 13, being better than compareing medicament to Caulis et Folium Brassicae capitatae diamondback moth prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Embodiment 48～53 suspension emulsion
Effective ingredient B, solvent, emulsifying agent, dispersant are added together, make to be dissolved into homogeneous oil phase；Fluorine louse sulfanilamide, water, antifreeze, defoamer etc. are mixed, becomes homogeneous aqueous phase；Under high velocity agitation, aqueous phase is added oil phase or oil phase is added aqueous phase, preparing fluorine louse sulfanilamide effective ingredient B suspension emulsion product after good dispersion, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 14。
Table 14 embodiment 48～53 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 15 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating Fructus Solani melongenae thrips test of pesticide effectiveness thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 48 | 4 grams/acre | 97.37 | 98.15 |
| Embodiment 49 | 18 grams/acre | 99.25 | 98.36 |
| Embodiment 50 | 12 grams/acre | 98.74 | 98.82 |
| Embodiment 51 | 5 grams/acre | 98.23 | 99.24 |
| Embodiment 52 | 10 grams/acre | 98.59 | 98.47 |
| Embodiment 53 | 6 grams/acre | 99.28 | 99.36 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 25 grams/acre | 68.57 | 66.84 |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 25 grams/acre | 68.13 | 66.47 |
| 10% capillary suspending agent | 30 grams/acre | 69.02 | 67.15 |
| 100 g/l of Nylar cream | 45 grams/acre | 58.64 | 68.29 |
| 50 g/l of lufenuron suspension agents | 50 grams/acre | 59.35 | 69.01 |
| 22% metaflumizone suspending agent | 75 grams/acre | 67.61 | 68.56 |
| 10% pyridalyl cream (autogamy) | 60 grams/acre | 65.29 | 69.48 |
As can be seen from Table 15, being better than compareing medicament to Fructus Solani melongenae thrips prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Embodiment 54～59 aqueous emulsion
Fluorine louse sulfanilamide, effective ingredient B, solvent and emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water, antifreeze, defoamer etc. are mixed, becomes homogeneous aqueous phase；Under high velocity agitation, aqueous phase is added oil phase or oil phase is added aqueous phase, preparing fluorine louse sulfanilamide spiral shell worm ethyl ester aqueous emulsion product after good dispersion, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 16。
Table 16 embodiment 54～59 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 17 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating rice leaf roller test of pesticide effectiveness thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 54 | 10 grams/acre | 98.76 | 99.58 |
| Embodiment 55 | 9 grams/acre | 99.24 | 98.76 |
| Embodiment 56 | 8 grams/acre | 97.35 | 98.81 |
| Embodiment 57 | 4 grams/acre | 98.48 | 99.25 |
| Embodiment 58 | 12 grams/acre | 99.37 | 97.37 |
| Embodiment 59 | 11 grams/acre | 98.49 | 98.74 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 23 grams/acre | 59.48 | 67.52 15 --> |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 27 grams/acre | 60.07 | 67.86 |
| 10% capillary suspending agent | 31 grams/acre | 58.51 | 66.47 |
| 100 g/l of Nylar cream | 48 grams/acre | 57.69 | 66.03 |
| 50 g/l of lufenuron suspension agents | 52 grams/acre | 59.78 | 68.35 |
| 22% metaflumizone suspending agent | 78 grams/acre | 58.24 | 67.41 |
| 10% pyridalyl cream (autogamy) | 64 grams/acre | 64.25 | 68.68 |
As can be seen from Table 17, being better than compareing medicament to rice leaf roller prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
Embodiment 60～65 microemulsion
Fluorine louse sulfanilamide, effective ingredient B, solvent, emulsifying agent are sufficiently mixed uniformly transparent oil phase, under agitation it is slowly added into deionized water, form Water in Oil emulsion, then through agitating heating, so as to phase inversion becomes oil-in-water type rapidly, being cooled to room temperature and make up to balance, through filtering prepared stable cyprodinil hexaconazole microemulsion product, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 18。
Table 18 embodiment 60～65 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 19 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating phyllocnistis citrella stainton test of pesticide effectiveness thereof
As can be seen from Table 19, being better than compareing medicament to phyllocnistis citrella stainton prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to Target crops safety in test scope of medication。
Example 66～71 microcapsule suspending agent
Macromolecule cyst material is added PH regulator and is heated to uniform temperature, obtain thick liquid, then dilute, form stable prepolymer solution, by fluorine louse sulfanilamide, effective ingredient B is dissolved in organic solvent, it is then added in prepolymer solution, add emulsifying agent, surfactant, and fully shear agitation is dispersed into superfine microgranular, add PH regulator, and heat up, catalyzed polycondensation forms the firm microcapsule not easily permeated, prepare micro-capsule suspension of the present invention, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 20。
Table 20 embodiment 66～71 each component and weight portion
Spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl in table are exchanged, novel formulation can be prepared。
Table 21 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating cotton boll worm test of pesticide effectiveness thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 66 | 7 grams/acre | 99.85 | 98.79 |
| Embodiment 67 | 8 grams/acre | 98.92 | 98.24 |
| Embodiment 68 | 15 grams/acre | 99.07 | 99.36 |
| Embodiment 69 | 4 grams/acre | 97.46 | 98.65 |
| Embodiment 70 | 6 grams/acre | 98.61 | 98.43 |
| Embodiment 71 | 20 grams/acre | 97.98 | 99.02 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 28 grams/acre | 69.69 | 67.58 |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 24 grams/acre | 68.45 | 96.82 |
| 10% capillary suspending agent | 33 grams/acre | 68.76 | 67.17 |
| 100 g/l of Nylar cream | 40 grams/acre | 67.58 | 66.24 |
| 50 g/l of lufenuron suspension agents | 45 grams/acre | 58.52 | 68.73 |
| 22% metaflumizone suspending agent | 70 grams/acre | 59.24 | 69.05 |
| 10% pyridalyl cream (autogamy) | 65 grams/acre | 60.17 | 68.26 |
As can be seen from Table 21, being better than compareing medicament to cotton boll worm prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, at test scope of medication to crop safety。
Example 72～77 microcapsule suspending agents-suspending agent
Adopt interfacial polymerization, by effective ingredient B, macromolecule cyst material, organic solvent mixing in above-mentioned formula, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition containing emulsifying agent, pH adjusting agent aqueous phase solution in, bi-material reacts at oil-water interfaces, around the droplet formation macromolecule cyst wall containing chemical substance, make effective ingredient B micro-capsule suspension。By surfactant, defoamer, thickening agent, antifreeze through high speed shear mix homogeneously, add the fluorine former medicine of louse sulfanilamide, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, prepare fluorine louse sulfanilamide suspending agent, then it is dissolved in the aqueous phase solution that fluorine louse sulfanilamide suspending agent stable in water joins effective ingredient B micro-capsule suspension, making the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition, effective ingredient B includes spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl one therein。
Concrete formula is in Table 22。
Table 22 embodiment 72～77 each component and weight portion
Table 23 fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl and the mixture preventing and treating Chinese cabbage Pieris rapae test of pesticide effectiveness thereof
| Treatment agent | Preparation dosage | 3 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
| Embodiment 72 | 12 grams/acre | 98.64 | 98.71 |
| Embodiment 73 | 14 grams/acre | 99.59 | 98.82 |
| Embodiment 74 | 8 grams/acre | 98.13 | 99.46 |
| Embodiment 75 | 15 grams/acre | 97.95 | 99.27 |
| Embodiment 76 | 5 grams/acre | 98.41 | 98.35 |
| Embodiment 77 | 4 grams/acre | 97.26 | 97.53 |
| 5% fluorine louse sulfanilamide suspending agent (autogamy) | 25 grams/acre | 68.37 | 66.85 19 --> |
| 240 g/l of spiral shell worm ethyl ester suspending agents | 25 grams/acre | 69.15 | 67.24 |
| 10% capillary suspending agent | 30 grams/acre | 68.74 | 67.02 |
| 100 g/l of Nylar cream | 45 grams/acre | 87.86 | 66.37 |
| 50 g/l of lufenuron suspension agents | 50 grams/acre | 67.18 | 67.45 |
| 22% metaflumizone suspending agent | 75 grams/acre | 68.29 | 68.36 |
| 10% pyridalyl cream (autogamy) | 60 grams/acre | 65.31 | 69.27 |
As can be seen from Table 23, being better than compareing medicament to Chinese cabbage Pieris rapae prevention effect after fluorine louse sulfanilamide and spiral shell worm ethyl ester, capillary, Nylar, lufenuron, metaflumizone, pyridalyl are composite, the lasting period is long, to crop safety in test scope of medication。
The embodiment of the present invention is the method adopting Toxicity Determination and field test to combine。First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is potentiation, on this basis, then carry out field test。
Test method: respectively the mother solution of each mixed agent is diluted to during test five series concentration, is respectively placed in beaker standby。Adopt the method that first leaching leaf is followed by worm, take out after blade of the same size not in contact with any medicament is soaked 5s in the medicinal liquid configured, naturally dry, put in insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process 3 times and repeat, often repeating examination borer population used is 50, sets blank simultaneously, checks dead borer population in 72h, calculate mortality rate and corrected mortality, try to achieve virulence regression equation and calculate LC50Value。If comparison mortality rate is more than 10%, then it is considered as invalid test。Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least square, and thus calculates the value of every kind of medicament。Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun。Computing formula following (with fluorine louse sulfanilamide for standard agent, its toxicity index is 100):
TI × the P of the theoretical toxicity index (TTI) of M=fluorine louse sulfanilamideFluorine louse sulfanilamideTI × the P of+effective active composition BEffective active composition B
In formula: M is the mixture of different ratio
PEffective active composition BFor the ratio that effective active composition B is shared in the composition
PFluorine louse sulfanilamideFor the ratio that fluorine louse sulfanilamide is shared in the composition
B is selected from any one compound following: the one in spiral shell worm ethyl ester, capillary, lufenuron, Nylar, metaflumizone, pyridalyl。
Application Example two: for examination insect: rice hoppers。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of fluorine louse sulfanilamide, the former medicine of spiral shell worm ethyl ester and the two different ratio mixture through pilot study。
Toxicity test result one
Table 24 fluorine louse sulfanilamide and the spiral shell worm ethyl ester different ratio toxicity test to rice hoppers
As shown in Table 24, fluorine louse sulfanilamide and spiral shell worm ethyl ester be composite prevents and treats the proportioning of rice hoppers when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1:70 scope, especially when the proportioning of fluorine louse sulfanilamide and spiral shell worm ethyl ester is when 10:1 to 1:20, potentiation becomes apparent from highlighting, wherein when fluorine louse sulfanilamide and spiral shell worm ethyl ester weight ratio are 16, co-toxicity coefficient is maximum, potentiation is the most obvious, finding, fluorine louse sulfanilamide and spiral shell worm ethyl ester proportioning are at 10:1 simultaneously, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also has good potentiation, and co-toxicity coefficient is all higher than 200。
Application Example three: for examination insect: apple aphid。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of fluorine louse sulfanilamide, the former medicine of capillary and the two different ratio mixture through pilot study。
Toxicity test result two
Table 25 fluorine louse sulfanilamide and the capillary different ratio toxicity test to apple aphid
As shown in Table 25, the proportioning of fluorine louse sulfanilamide and the composite preventing and treating apple aphid of capillary is when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1 70 scope, especially when fluorine louse sulfanilamide and capillary obtain proportioning when 10:1 to 1:20, potentiation becomes apparent from highlighting, and tests through applicant, when fluorine louse sulfanilamide and capillary weight ratio are 16, co-toxicity coefficient is maximum, and potentiation is the most obvious。Find simultaneously, fluorine louse sulfanilamide and capillary proportioning are at 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:16, 1:17, 1:18, 1:19, 1:20 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also has good potentiation, co-toxicity coefficient is all higher than 200。
Application Example four: for examination insect: pear sucker。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of fluorine louse sulfanilamide, the former medicine of Nylar and the two different ratio mixture through pilot study。
Toxicity test result three
Table 26 fluorine louse sulfanilamide and the Nylar different ratio toxicity test to pear sucker
As shown in Table 26, fluorine louse sulfanilamide and pyriproxyfen compound prevent and treat the proportioning of pear sucker when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1 70 scope, especially when fluorine louse sulfanilamide and Nylar obtain proportioning when 10:1 to 1:20, potentiation becomes apparent from highlighting, and tests through applicant, when fluorine louse sulfanilamide and Nylar weight ratio are 16, co-toxicity coefficient is maximum, and potentiation is the most obvious。Find simultaneously, fluorine louse sulfanilamide and Nylar proportioning are at 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also has good potentiation, co-toxicity coefficient is all higher than 200。
Application Example five: for examination insect: Oryza sativa L. trialeurodes vaporariorum。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine that fluorine louse sulfanilamide is in effective lethasl concentration scope of the former medicine of lufenuron and the two different ratio mixture through pilot study。
Toxicity test result four
Table 27 fluorine louse sulfanilamide and the lufenuron different ratio toxicity test to Oryza sativa L. trialeurodes vaporariorum
As shown in Table 27, the proportioning of fluorine louse sulfanilamide preventing and treating composite with lufenuron Oryza sativa L. trialeurodes vaporariorum is when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1 70 scope, especially when fluorine louse sulfanilamide and lufenuron obtain proportioning when 10:1 to 1:10, potentiation becomes apparent from highlighting, and tests through applicant, when fluorine louse sulfanilamide and lufenuron weight ratio are 12, co-toxicity coefficient is maximum, and potentiation is the most obvious。Find simultaneously, fluorine louse sulfanilamide also has good potentiation with lufenuron proportioning 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer, and co-toxicity coefficient is all higher than 200。
Application Example five: for examination insect: Caulis et Folium Brassicae capitatae diamondback moth。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of fluorine louse sulfanilamide and the former medicine of metaflumizone and the two different ratio mixture through pilot study。
Toxicity test result four
Table 28 fluorine louse sulfanilamide and the metaflumizone different ratio toxicity test to Caulis et Folium Brassicae capitatae diamondback moth
As shown in Table 28, the proportioning of fluorine louse sulfanilamide and the composite preventing and treating Caulis et Folium Brassicae capitatae diamondback moth of metaflumizone is when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1 70 scope, especially when fluorine louse sulfanilamide and metaflumizone obtain proportioning when 10:1 to 1:30, potentiation becomes apparent from highlighting, and tests through applicant, when fluorine louse sulfanilamide and metaflumizone weight ratio are 1 10, co-toxicity coefficient is maximum, and potentiation is the most obvious。Find simultaneously, fluorine louse sulfanilamide and metaflumizone proportioning are at 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:25, 1:30 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also has good potentiation, co-toxicity coefficient is all higher than 200。
Application Example five: for examination insect: cotton boll worm。
Test medicine provides by Shaanxi Welch Crop Protection Co., Ltd.。
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of fluorine louse sulfanilamide and the former medicine of pyridalyl and the two different ratio mixture through pilot study。
Toxicity test result four
Table 29 fluorine louse sulfanilamide and the pyridalyl different ratio toxicity test to cotton boll worm
As shown in Table 29, the proportioning of fluorine louse sulfanilamide and the composite preventing and treating cotton boll worm of pyridalyl is when 70 1 to 1:70, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 70:1 to 1 70 scope, especially when fluorine louse sulfanilamide and pyridalyl obtain proportioning when 10:1 to 1:20, potentiation becomes apparent from highlighting, and tests through applicant, when fluorine louse sulfanilamide and pyridalyl weight ratio are 16, co-toxicity coefficient is maximum, and potentiation is the most obvious。Find simultaneously, fluorine louse sulfanilamide and pyridalyl proportioning are at 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20 recurrence of disease at the same time next year pairing planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer also has good potentiation, co-toxicity coefficient is all higher than 200。
Claims (6)
1. the Pesticidal combination of a fluorine-containing louse sulfanilamide, it is characterized in that: containing active components A and active component B, the weight ratio of active components A and active component B is 1 70～70 1, described active components A is selected from fluorine louse sulfanilamide, active component B one in capillary, lufenuron, Nylar, metaflumizone, pyridalyl。
2. the Pesticidal combination of fluorine-containing louse sulfanilamide according to claim 1, it is characterised in that: the weight ratio of active components A and active component B is 1 50～30 1。
3. the Pesticidal combination of fluorine-containing louse sulfanilamide according to claim 2, its feature exists
In: the weight ratio of fluorine louse sulfanilamide and capillary is 10 1～1 20；
The weight ratio of fluorine louse sulfanilamide and lufenuron is 10 1～1 10；
The weight ratio of fluorine louse sulfanilamide and Nylar is 10 1～1 20；
The weight ratio of fluorine louse sulfanilamide and metaflumizone is 10 1～1 30；
The weight ratio of fluorine louse sulfanilamide and pyridalyl is 10 1～1 20。
4. the Pesticidal combination of fluorine-containing louse sulfanilamide according to any one of claim 1 to 3, it is characterised in that: compositions makes wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspending agent-suspending agent。
5. the Pesticidal combination of fluorine-containing louse sulfanilamide according to claim 4 is for preventing and treating the purposes of crop pest。
6. purposes according to claim 5, it is characterized in that, described insect includes: planthopper, aphid, wood louse, aleyrodid, mealybug, scale insect, thrips, Pieris rapae, Prodenia litura, diamondback moth, beet armyworm, bean-pod borer, bollworm, leaf miner, blister mite, olethreutid, black cutworm, rice leaf roller, rice-stem borer。
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Citations (3)
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|---|---|---|---|---|
| US4087525A (en) * | 1975-12-08 | 1978-05-02 | American Cyanamid Company | Pentadienone hydrazones as insecticides |
| US4921696A (en) * | 1982-03-25 | 1990-05-01 | The United States Of America As Represented By The Secretary Of Agriculture | Method for the control of insects |
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4087525A (en) * | 1975-12-08 | 1978-05-02 | American Cyanamid Company | Pentadienone hydrazones as insecticides |
| US4921696A (en) * | 1982-03-25 | 1990-05-01 | The United States Of America As Represented By The Secretary Of Agriculture | Method for the control of insects |
| CN1858038A (en) * | 2006-06-09 | 2006-11-08 | 中国科学院上海有机化学研究所 | Oxo fluoroalkyl sulfamide compound and its preparing method and use |
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| 付群梅 等: ""氟虱磺胺(SIOC-I-002)对水稻褐飞虱的生物活性及田间防效"", 《植物保护学报》 * |
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Address after: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
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