CN105794825A - Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters - Google Patents
Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters Download PDFInfo
- Publication number
- CN105794825A CN105794825A CN201610202694.6A CN201610202694A CN105794825A CN 105794825 A CN105794825 A CN 105794825A CN 201610202694 A CN201610202694 A CN 201610202694A CN 105794825 A CN105794825 A CN 105794825A
- Authority
- CN
- China
- Prior art keywords
- chlorantraniliproles
- chlorantraniliprole
- carbamates
- test
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses insecticide composition containing tetrachlorantraniliprole and carbamic acid esters. The insecticide composition comprises effective active ingredients including an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from tetrachlorantraniliprole, the active ingredient B is selected from any one of compounds including indoxacarb, isoprocarb, metolcarb, carbaryl or fenobucarb, and the weight ratio of the active ingredient A to the active ingredient B is (1:80)-(60:1). The composition has a synergistic effect on multiple pests damaging agricultural production, the pesticide use amount is reduced, the residual quantity of pesticides on crops is reduced, environment pollution is reduced, and the insecticide composition is safe to human and animals and good in environmental compatibility, and insecticide resistance of the pests is not easily caused.
Description
The application is divisional application, and original application is the patent application " a kind of Pesticidal combination containing four chlorantraniliproles Yu carbamates " of Shanxi Thompson Biological Technology Co., Ltd., and the application number of original application is 201310025129.3, and original application day is 2013.1.19.
Technical field
The invention belongs to technical field of pesticide, relate to the application on crop pests of a kind of Pesticidal combination containing four chlorantraniliproles and carbamates.
Background technology
Four chlorantraniliproles: being used for preventing and treating rice leaf roller, compound insecticidal spectrum is close to Rynaxypyr, in actual use, dead worm speed ratio is very fast and the lasting period is longer.
Indoxacarb (indoxacarb) chemical name: 7-chloro-2,3,4a; 5-tetrahydrochysene-2-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] indeno [1,2-e] [1,3; 4-] oxadiazines-4a-carboxylate methyl ester, molecular formula: C22H17ClF3N3O7.Indoxacarb mainly blocks the sodium channel in insect neurocyte, causes that target pest coordinates poor, paralysis, finally dead.Medicament is by tagging and the entrance polypide that ingests, and the behavior of insect changes rapidly, causes insect to terminate rapidly ingesting, thus fabulous protects Target crops.Test shows and other insecticide no interactions resistance.
Mobucin (isoprocarb) chemical name: o-isopropylphenyl-N-methylcarbamate, molecular formula: C11H15NO2.Mobucin belongs to carbamate insecticides, and insecticide is mainly acetylcholine esterase inhibition, causes insect paralysis to dead.
Meta-tolyl-N-methylcarbamate (MTMC) (metolcarb) chemical name: a tolyl-N-methyl carbamate, molecular formula: C9H11NO2.Meta-tolyl-N-methylcarbamate (MTMC) has tags and fumigation action, and power of knocking down is strong, and the lasting period is short, general only 3-4 days, and to planthopper, rice leafhopper and rice thrips, and tea lesser leafhopper etc. has specially good effect.
Carbaryl (carbaryl) chemical name: 1 naphthyl N methyl carbamate, molecular formula: C12H11NO2.Carbaryl tool broad spectrum activity, it is suppressed that the acetylcholinesterase in pest body, has favorable effect to the insect such as pink bollworm of leafhopper, plant hopper and some biting mouthpartses not easily prevented and treated, and the insect preventive effect that Gamma Hexaochlorocyclohexane, clofenotane, parathion etc. have produced resistance is good.This medicine toxic action is slow, can be mixed with some organophosphorus pesticides, anti-heterodyne during low temperature.
Bassa (fenobucarb) chemical name: 2-secondary butyl phenenyl-N-methyl carbamate, molecular formula: C12H17NO2, belong to carbamate insecticides, make insect be poisoned to death mainly through acetylcholine esterase inhibition.Plant hopper, spider mite kind are had specially good effect, and parasite killing is rapid, but residual effect is short, can only maintain 4-5 days.
But, in the real process of agricultural production, pest control is easiest to generate the problem that the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is prevent and treat the method that resistant insect is very common.Heterogeneity carries out composite, according to practical application effect, judge certain composite be potentiation, add and or antagonism.In most cases, the composite effect of pesticide is all additive effect, really have potentiation composite seldom, especially potentiation clearly, significantly high composite just less of co-toxicity coefficient.Study through inventor, find will to produce good potentiation after four chlorantraniliproles and indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or fenobucarb composite, and not yet open with the relevant report of indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or fenobucarb composite about four chlorantraniliproles.
Summary of the invention
The purpose of the present invention is to propose to a kind of there is synergistic function, use cost is low, preventive effect the is good Pesticidal combination containing four chlorantraniliproles Yu carbamates.
A kind of Pesticidal combination containing four chlorantraniliproles Yu carbamates that the present invention proposes, containing active components A and active component B, active components A and active component B weight ratio are 1 80～60 1, described active components A is selected from four chlorantraniliproles, active component B one in indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or Bassa, active components A and the preferred weight ratio of active component B are 1 60～40 1；The weight ratio being more preferably four chlorantraniliproles and indoxacarb is 1 30～30 1, and four chlorantraniliproles and Mobucin or meta-tolyl-N-methylcarbamate (MTMC) or Bassa weight ratio are 1 35～10 1, and the weight ratio of four chlorantraniliproles and carbaryl is 1 40～5 1；The weight ratio most preferably being four chlorantraniliproles and indoxacarb is 1 11～11 1, and four chlorantraniliproles and Mobucin or meta-tolyl-N-methylcarbamate (MTMC) or Bassa weight ratio are 1 19～1 9, and the weight ratio of four chlorantraniliproles and carbaryl is 1 24～1 14.
The Pesticidal combination containing four chlorantraniliproles that the present invention proposes is for preventing and treating the purposes of insect on crops, and described crops include cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, green manure pasture crop；Described insect includes rice leaf roller, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, thrips or flea beetle.
Active components A, active component B weight ratio be 1 80～60 1.In usual compositions, the weight percentage of active component is the 0.5%～90% of gross weight, it is advantageous to be 5%～80%.According to different preparation types, active component content scope is different.Generally, liquid preparation contains the active substance of by weight 1%～70%, it is preferred that be 5%～50%；Solid preparation contains the active substance of by weight 5%～80%, it is preferred that be 10%～80%.
The Pesticidal combination of the present invention at least contains a kind of surfactant, active component dispersion in water when being beneficial to use.Surface-active contents is the 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The bactericidal composition of the present invention can by user before use through diluting or directly using.Its preparation can be prepared by common processing method known in those skilled in the art, after mixing with liquid flux or solid carrier by active substance, add one or more in surfactant such as dispersant, stabilizer, wetting agent, binding agent, defoamer, disintegrating agent, antifreeze etc..
The Pesticidal combination of the present invention, it is possible to be processed on any pesticide acceptable dosage form on demand, wherein more excellent dosage form is: wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
Compositions comprises following constituent content when making wettable powder: active components A 0.5%～60%, active component B0.5%～80%, dispersant 2%～10%, wetting agent 2%～10%, filler surplus.
Compositions includes following constituent content when making water dispersible granules: active components A 0.5%～60%, active component B0.5%～80%, dispersant 3%～12%, wetting agent 1%～8%, disintegrating agent 1%～10%, binding agent 0～8%, filler surplus.
Compositions includes following constituent content when making suspending agent: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, wetting agent 2%～10%, defoamer 0.01%～2%, thickening agent 0～2%, antifreeze 0～8%, deionized water add to 100%.
Compositions includes following constituent content when making suspension emulsion: active components A 0.5%～50%, active component B0.5%～50%, dispersant 2%～10%, defoamer 0.01%～2%, solvent 0～15%, thickening agent 0%～2%, emulsifying agent 2%～12%, antifreeze 0～8%, stabilizer 0～3%, deionized water add to 100%.
Compositions comprises following constituent content when making aqueous emulsion: active components A 0.5%～50%, active component B0.5%～50%, solvent 0～30%, emulsifying agent 1%～15%, antifreeze 0～8%, thickening agent 0～2%, defoamer 0.01%～2%, deionized water supply surplus.
Compositions comprises following constituent content when making microemulsion: active components A 0.5%～50%, active component B0.5%～50%, solvent 0～30%, emulsifying agent 3%～25%, antifreeze 0～8%, defoamer 0.01%～2%, stabilizer 0～4%, deionized water supplies surplus.
Compositions includes following constituent content when making microcapsule suspending agent: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～10%, dispersant 1%～10%, organic solvent 0～10%, emulsifying agent 1%～7%, pH adjusting agent 0.01%～5%, deionized water add to 100%.
Compositions includes following constituent content when making microcapsule suspension-suspendinagent agent: active components A 0.5%～50%, active component B0.5%～50%, macromolecule cyst material 2%～12%, dispersant 1%～12%, wetting agent 1%～8%, organic solvent 1%～15%, emulsifying agent 1%～6%, defoamer 0.01%～2%, thickening agent 0～2%, pH adjusting agent 0.01%～5%, deionized water add to 100%；
The wettable powder the key technical indexes of the present invention:
The water dispersible granules the key technical indexes of the present invention:
The suspending agent the key technical indexes of the present invention:
The suspension emulsion the key technical indexes of the present invention:
The aqueous emulsion the key technical indexes of the present invention:
The microemulsion the key technical indexes of the present invention:
The microcapsule suspending agent the key technical indexes of the present invention:
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
It is an advantage of the current invention that:
After (1) four chlorantraniliprole and indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or fenobucarb composite, there is obvious potentiation and lasting effect；(2) to cereal crops, legume crop, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flower crop, medicinal crop, crop, rice leaf roller on green manure pasture crop, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, thrips or flea beetle etc. all have greater activity；(3) decrease pesticide usage amount, reduce pesticide residual quantity on crop, alleviate environmental pollution；(4) to person poultry safety, Environmental compatibility is good；And preparation adhesion strength strengthens, resistance of rainwater washing against.
Detailed description of the invention
Below in conjunction with embodiment to further instruction of the present invention, the percentage ratio in embodiment is all weight percentage, but the invention is not limited in this.
Application Example one
Embodiment 1～12 wettable powder
By four chlorantraniliproles, active component B, dispersant, wetting agent, filler mix homogeneously in mixed cylinder, remix uniformly after jet mill is pulverized, can be prepared by wettable powder product of the present invention, be specifically shown in table 1.
Table 1 embodiment 1～12 each component and weight portion
Embodiment 13～24 water dispersible granules
Four chlorantraniliproles, active component B, dispersant, wetting agent, disintegrating agent, filler etc. are obtained through comminution by gas stream together the particle diameter needed, adds other auxiliary agents such as binding agent, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and dried, can be prepared by water dispersible granules product of the present invention, be specifically shown in table 2.
Table 2 embodiment 13～24 each component and weight portion
Embodiment 25～36 suspending agent
By dispersant, wetting agent, defoamer, thickening agent, antifreeze, through high speed shear mix homogeneously, add four chlorantraniliproles, active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, surplus deionized water is supplied, and can be prepared by suspending agent product of the present invention, is specifically shown in table 3.
Table 3 embodiment 25～36 each component and weight portion
Embodiment 37～42 suspension emulsion
By dispersant, defoamer, thickening agent, antifreeze, solvent, stabilizer through high speed shear mix homogeneously, add four chlorantraniliproles, active component B ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, prepare suspension emulsion product of the present invention.It is specifically shown in table 4.
Table 4 embodiment 37～42 each component and content
Embodiment 43～54 aqueous emulsion
Four chlorantraniliproles, active component B, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Deionized water, antifreeze, thickening agent, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase adding oil phase, surplus deionized water is supplied；Can be prepared by aqueous emulsion product of the present invention, be specifically shown in table 5.
Table 5 embodiment 43～54 each component and weight portion
Indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or Bassa in table 1～5 are exchanged, novel formulation can be prepared.
Embodiment 55～57 microemulsion
Four chlorantraniliproles, active component B, solvent, emulsifying agent, antifreeze, thickening agent, defoamer are sufficiently mixed uniformly transparent oil phase, under agitation it is slowly added into deionized water, form Water in Oil emulsion, then through agitating heating, so as to phase inversion becomes oil-in-water type rapidly, being cooled to room temperature and make up to balance, through filtering, surplus deionized water is supplied；Can be prepared by microemulsion product of the present invention, be specifically shown in table 6.
Table 6 embodiment 55～57 each component and weight portion
Embodiment 58,59 microcapsule suspending agent
By four chlorantraniliproles, active component B, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, in a shear condition, oil phase is joined containing emulsifying agent, pH adjusting agent, dispersant aqueous phase solution in, surplus deionized water is supplied, and bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, make the finely disseminated microcapsule suspending agent product of the present composition, be specifically shown in table 7.
Table 7 embodiment 58,59 each component and weight portion
Embodiment 60,61 microcapsule suspension-suspendinagent agent
By four chlorantraniliproles, macromolecule cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition containing emulsifying agent, pH adjusting agent aqueous phase solution in, make finely disseminated microcapsule suspending agent.By defoamer, thickening agent through high speed shear mix homogeneously, add active component B, ball milling 2～3 hours in ball mill, make diameter of particle all below 5 μm, preparing suspending agent, then joined by suspending agent in the aqueous phase solution of micro-capsule suspension, deionized water supplies surplus, make the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition, be specifically shown in table 8.
Table 8 embodiment 60,61 each component and weight portion
The embodiment of the present invention is the method adopting Toxicity Determination and field test to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is potentiation, on this basis, then carry out field test.
Test method: respectively the mother solution of each mixed agent is diluted to during test five series concentration, is respectively placed in beaker standby.Adopt the method that first leaching leaf is followed by worm, take out after blade of the same size not in contact with any medicament is soaked 5s in the medicinal liquid configured, naturally dry, put in insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process 3 times and repeat, often repeating examination borer population used is 50, sets blank simultaneously, checks dead borer population in 72h, calculate mortality rate and corrected mortality, try to achieve virulence regression equation and calculate LC50Value.If comparison mortality rate is more than 10%, then it is considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least square, and thus calculates the value of every kind of medicament.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (with four chlorantraniliproles for standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (TTI)=tetra-chlorantraniliprole of MFour chlorantraniliprolesTI × the P of+effective active composition BEffective active composition B
In formula: M is the mixture of different ratio
PEffective active composition BFor the ratio that effective active composition B is shared in the composition
PFour chlorantraniliprolesIt is the shared in the composition ratios of four chlorantraniliproles
B one in indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or Bassa.
Application Example two
For examination insect: Laphygma exigua Hubner
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of four chlorantraniliproles and the former medicine of indoxacarb and the two different ratio mixture through pilot study.
Table 9 four chlorantraniliprole and the composite toxicity test analysis of results table to Laphygma exigua Hubner of indoxacarb
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Four chlorantraniliproles | — | 0.85 | — |
| Indoxacarb | — | 1.00 | — |
| Four chlorantraniliprole indoxacarbs | 60:1 | 0.50 | 170.42 |
| Four chlorantraniliprole indoxacarbs | 50:1 | 0.45 | 189.45 |
| Four chlorantraniliprole indoxacarbs | 40:1 | 0.42 | 203.12 |
| Four chlorantraniliprole indoxacarbs | 30:1 | 0.38 | 224.77 |
| Four chlorantraniliprole indoxacarbs | 20:1 | 0.37 | 231.38 |
| Four chlorantraniliprole indoxacarbs | 11:1 | 0.35 | 245.93 |
| Four chlorantraniliprole indoxacarbs | 4:1 | 0.34 | 257.73 |
| Four chlorantraniliprole indoxacarbs | 1:1 | 0.35 | 262.55 |
| Four chlorantraniliprole indoxacarbs | 1:4 | 0.38 | 254.19 |
| Four chlorantraniliprole indoxacarbs | 1:11 | 0.40 | 246.38 |
| Four chlorantraniliprole indoxacarbs | 1:20 | 0.43 | 230.62 |
| Four chlorantraniliprole indoxacarbs | 1:30 | 0.45 | 220.96 |
| Four chlorantraniliprole indoxacarbs | 1:40 | 0.49 | 203.21 |
| Four chlorantraniliprole indoxacarbs | 1:60 | 0.52 | 191.75 |
| Four chlorantraniliprole indoxacarbs | 1:80 | 0.55 | 181.42 |
As shown in Table 9, four chlorantraniliproles and indoxacarb to Laphygma exigua Hubner proportioning when 1 80～60 1, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of four chlorantraniliproles and indoxacarb is when 1 30～30 1, potentiation becomes apparent from highlighting, co-toxicity coefficient is all higher than 220, when proportioning potentiation in the scope of 1:11～11:1 is best, wherein when four chlorantraniliproles and indoxacarb weight ratio are 1:1, co-toxicity coefficient is maximum, and potentiation is the most obvious.Testing discovery four chlorantraniliproles through applicant is 30:1 with indoxacarb proportioning, 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:10, 1:15, 1:20, during 1:30, to the rice leaf roller in various crop after four chlorantraniliproles are composite with indoxacarb, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, the preventing and treating of thrips or flea beetle has obvious potentiation potentiation obvious, co-toxicity coefficient is all higher than 120.
Application Example three:
For examination insect: Cucumber blight
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of four chlorantraniliproles and the former medicine of Mobucin and the two different ratio mixture through pilot study.
Toxicity test result
Table 10 4 chlorantraniliprole and the composite toxicity test analysis of results table to Cucumber blight of Mobucin
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Four chlorantraniliproles | — | 0.68 | — |
| Mobucin | — | 9.35 | — 12 --> |
| Four chlorantraniliprole Mobucins | 60:1 | 0.40 | 172.63 |
| Four chlorantraniliprole Mobucins | 40:1 | 0.38 | 183.10 |
| Four chlorantraniliprole Mobucins | 20:1 | 0.36 | 197.64 |
| Four chlorantraniliprole Mobucins | 10:1 | 0.33 | 225.09 |
| Four chlorantraniliprole Mobucins | 1:1 | 0.54 | 235.38 |
| Four chlorantraniliprole Mobucins | 1:5 | 1.25 | 241.78 |
| Four chlorantraniliprole Mobucins | 1:9 | 1.63 | 255.94 |
| Four chlorantraniliprole Mobucins | 1:14 | 1.97 | 261.50 |
| Four chlorantraniliprole Mobucins | 1:19 | 2.32 | 251.59 |
| Four chlorantraniliprole Mobucins | 1:25 | 2.61 | 246.33 |
| Four chlorantraniliprole Mobucins | 1:30 | 2.89 | 235.29 |
| Four chlorantraniliprole Mobucins | 1:35 | 3.21 | 221.05 |
| Four chlorantraniliprole Mobucins | 1:40 | 3.60 | 203.80 |
| Four chlorantraniliprole Mobucins | 1:60 | 4.03 | 197.94 |
| Four chlorantraniliprole Mobucins | 1:80 | 4.49 | 185.87 |
As shown in Table 10, four chlorantraniliproles and Mobucin to Cucumber blight proportioning when 1 80～60 1, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of four chlorantraniliproles and Mobucin is when 1 35～10 1, potentiation becomes apparent from highlighting, co-toxicity coefficient is all higher than 220, when proportioning potentiation in the scope of 1:19～1:9 is best, wherein when four chlorantraniliproles and Mobucin weight ratio are 1:14, co-toxicity coefficient is maximum, and potentiation is the most obvious.Testing discovery four chlorantraniliproles through applicant is 10:1 with Mobucin proportioning, 5:1, 1:1, 1:5, 1:6, 1:8, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1:25, 1:30, during 1:35, to the rice leaf roller in various crop after four chlorantraniliproles are composite with Mobucin, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, the preventing and treating of thrips or flea beetle has obvious potentiation potentiation obvious, co-toxicity coefficient is all higher than 120.
Application Example four
For examination insect: Oryza sativa L. rice leaf roller
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of four chlorantraniliproles and the former medicine of meta-tolyl-N-methylcarbamate (MTMC) and the two different ratio mixture through pilot study.
Table 11 4 chlorantraniliprole and the composite toxicity test analysis of results table to Oryza sativa L. rice leaf roller of meta-tolyl-N-methylcarbamate (MTMC)
As shown in Table 11, four chlorantraniliproles and meta-tolyl-N-methylcarbamate (MTMC) to Oryza sativa L. rice leaf roller proportioning when 1 80～60 1, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of four chlorantraniliproles and meta-tolyl-N-methylcarbamate (MTMC) is when 1 35～10 1, potentiation becomes apparent from highlighting, co-toxicity coefficient is all higher than 215, when proportioning potentiation in the scope of 1:19～1:9 is best, wherein when four chlorantraniliproles and meta-tolyl-N-methylcarbamate (MTMC) weight ratio are 1:14, co-toxicity coefficient is maximum, and potentiation is the most obvious.Testing discovery four chlorantraniliproles through applicant is 10:1 with meta-tolyl-N-methylcarbamate (MTMC) proportioning, 5:1, 1:1, 1:5, 1:6, 1:8, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1:25, 1:30, during 1:35, to the rice leaf roller in various crop after four chlorantraniliproles are composite with meta-tolyl-N-methylcarbamate (MTMC), planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, the preventing and treating of thrips or flea beetle has obvious potentiation potentiation obvious, co-toxicity coefficient is all higher than 120.
Application Example five
For examination insect: cotton boll worm
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of four chlorantraniliproles and the former medicine of carbaryl and the two different ratio mixture through pilot study.
Table 12 4 chlorantraniliprole and the composite toxicity test analysis of results table to cotton boll worm of carbaryl
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Four chlorantraniliproles | — | 0.85 | — |
| Carbaryl | — | 12.20 | — |
| Four chlorantraniliprole carbaryls | 60:1 | 0.50 | 172.66 |
| Four chlorantraniliprole carbaryls | 40:1 | 0.46 | 189.12 14 --> |
| Four chlorantraniliprole carbaryls | 15:1 | 0.45 | 200.68 |
| Four chlorantraniliprole carbaryls | 5:1 | 0.45 | 223.98 |
| Four chlorantraniliprole carbaryls | 1:1 | 0.68 | 235.85 |
| Four chlorantraniliprole carbaryls | 1:10 | 2.42 | 241.48 |
| Four chlorantraniliprole carbaryls | 1:14 | 2.73 | 253.82 |
| Four chlorantraniliprole carbaryls | 1:19 | 2.95 | 269.29 |
| Four chlorantraniliprole carbaryls | 1:24 | 3.45 | 252.44 |
| Four chlorantraniliprole carbaryls | 1:29 | 3.75 | 248.18 |
| Four chlorantraniliprole carbaryls | 1:35 | 4.22 | 233.91 |
| Four chlorantraniliprole carbaryls | 1:40 | 4.62 | 221.86 |
| Four chlorantraniliprole carbaryls | 1:50 | 5.29 | 204.87 |
| Four chlorantraniliprole carbaryls | 1:60 | 5.65 | 199.50 |
| Four chlorantraniliprole carbaryls | 1:80 | 6.60 | 179.86 |
As shown in Table 12, four chlorantraniliproles and carbaryl to cotton boll worm proportioning when 1 80～60 1, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of four chlorantraniliproles and carbaryl is when 1 40～5 1, potentiation becomes apparent from highlighting, co-toxicity coefficient is all higher than 220, when proportioning potentiation in the scope of 1:24～1:14 is best, wherein when four chlorantraniliproles and carbaryl weight ratio are 1:19, co-toxicity coefficient is maximum, and potentiation is the most obvious.Discovery four chlorantraniliproles and carbaryl proportioning 5:1 is tested through applicant, 2:1, 1:1, 1:2, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1:25, 1:30, 1:35, during 1:40, to the rice leaf roller in various crop after four chlorantraniliproles are composite with carbaryl, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, the preventing and treating of thrips or flea beetle has obvious potentiation potentiation obvious, co-toxicity coefficient is all higher than 120.
Application Example six
For examination insect: rice hoppers
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
EXPERIMENTAL DESIGN: determine effective lethasl concentration scope of four chlorantraniliproles and the former medicine of Bassa and the two different ratio mixture through pilot study.
Table 13 4 chlorantraniliprole and the fenobucarb composite toxicity test analysis of results table to rice hoppers
| Reagent agent | Proportioning | LC50(ug/mL) | Co-toxicity coefficient (CTC) |
| Four chlorantraniliproles | — | 0.52 | — |
| Bassa | — | 8.10 | — |
| Four chlorantraniliprole Bassas | 60:1 | 0.32 | 165.04 |
| Four chlorantraniliprole Bassas | 40:1 | 0.30 | 177.40 |
| Four chlorantraniliprole Bassas | 20:1 | 0.28 | 194.42 |
| Four chlorantraniliprole Bassas | 10:1 | 0.26 | 218.69 |
| Four chlorantraniliprole Bassas | 1:1 | 0.43 | 228.17 |
| Four chlorantraniliprole Bassas | 1:5 | 1.02 | 235.29 |
| Four chlorantraniliprole Bassas | 1:9 | 1.40 | 241.19 15 --> |
| Four chlorantraniliprole Bassas | 1:14 | 1.65 | 256.92 |
| Four chlorantraniliprole Bassas | 1:19 | 2.00 | 242.99 |
| Four chlorantraniliprole Bassas | 1:25 | 2.32 | 233.10 |
| Four chlorantraniliprole Bassas | 1:30 | 2.59 | 222.28 |
| Four chlorantraniliprole Bassas | 1:35 | 2.78 | 217.22 |
| Four chlorantraniliprole Bassas | 1:40 | 3.20 | 195.96 |
| Four chlorantraniliprole Bassas | 1:60 | 3.65 | 188.92 |
| Four chlorantraniliprole Bassas | 1:80 | 4.00 | 181.55 |
As shown in Table 13, four chlorantraniliproles and Bassa to rice hoppers proportioning when 1 80～60 1, co-toxicity coefficient is all higher than 120, illustrate that both all show potentiation at mixture in 1 80～60 1 scopes, when the proportioning of four chlorantraniliproles and Bassa is when 1 35～10 1, potentiation becomes apparent from highlighting, co-toxicity coefficient is all higher than 215, when proportioning potentiation in the scope of 1:19～1:9 is best, wherein when four chlorantraniliproles and Bassa weight ratio are 1:14, co-toxicity coefficient is maximum, and potentiation is the most obvious.Testing discovery four chlorantraniliproles through applicant is 10:1 with Bassa proportioning, 5:1, 1:1, 1:5, 1:6, 1:8, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, 1:20, 1:21, 1:25, 1:30, during 1:35, to the rice leaf roller in various crop after four chlorantraniliproles and fenobucarb composite, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, the preventing and treating of thrips or flea beetle has obvious potentiation potentiation obvious, co-toxicity coefficient is all higher than 120.
Test drug effect part: test medicine is researched and developed by Shanxi Thompson Biological Technology Co., Ltd., provided, comparison medicament 10% 4 chlorantraniliprole suspending agent (autogamy), 30% indoxacarb water dispersible granule (commercial), 20% Mobucin cream (commercial), 20% meta-tolyl-N-methylcarbamate (MTMC) cream (commercial), 25% carbaryl wettable powder (commercial), 20% Bassa cream (commercial).
Application Example seven or four chlorantraniliprole and carbamates and the composite preventing and treating Fructus Cucumidis sativi aleyrodid test of pesticide effectiveness thereof
This test arrangement, at Xian District, Shanxi Province suburban area, investigates cucumber powder mite evil index before medicine, in insect pest early period of origination dispenser, within after dispenser 1 day, 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 14 4 chlorantraniliprole and carbamates and the composite preventing and treating Fructus Cucumidis sativi aleyrodid test of pesticide effectiveness thereof
As can be seen from Table 14, effectively preventing and treating Fructus Cucumidis sativi aleyrodid after four chlorantraniliproles are composite with carbamates, test finding that four chlorantraniliproles and carbamates can also be used for preventing and treating Cucumber blight after composite through applicant, prevention effect is above 96%, it is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example eight or four chlorantraniliprole and carbamates and the composite preventing and treating cotton boll worm test of pesticide effectiveness thereof
This test arrangement, in Weinan City Dali County, Shaanxi Province, investigates cotton boll pests index before medicine, in insect pest early period of origination dispenser, within after dispenser 1 day, 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 15 4 chlorantraniliprole and carbamates and the composite preventing and treating cotton boll worm test of pesticide effectiveness thereof
As can be seen from Table 15, cotton boll worm can be effectively prevented and treated after four chlorantraniliproles are composite with carbamates, test through applicant and find that four chlorantraniliproles and carbamates can also be used for preventing and treating Cotton Gossypii pink bollworm, thrips after composite, prevention effect is above 95%, it is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 94 chlorantraniliprole and carbamates and the composite preventing and treating Oryza sativa L. rice leaf roller test of pesticide effectiveness thereof
This test arrangement, in Hanzhong City Chenggu County, Shaanxi Province, investigates Oryza sativa L. rice leaf roller insect pest index before medicine, in insect pest early period of origination dispenser, within after dispenser 1 day, 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 16 4 chlorantraniliprole and carbamates and the composite preventing and treating Oryza sativa L. rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 16, Oryza sativa L. rice leaf roller can be effectively prevented and treated after four chlorantraniliproles are composite with carbamates, test through applicant and find that four chlorantraniliproles and carbamates can also be used for preventing and treating rice hoppers, pachydiplosis oryzae, striped rice borer, yellow rice borer after composite, prevention effect is above 96%, it is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 14 chlorantraniliprole and carbamates and the composite preventing and treating cabbage pieris test of pesticide effectiveness thereof
This test arrangement, at Xian District, Shanxi Province suburban area, investigates cabbage pieris insect pest index before medicine, in insect pest early period of origination dispenser, within after dispenser 1 day, 3 days, 7 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 17 4 chlorantraniliprole and carbamates and the composite preventing and treating cabbage pieris test of pesticide effectiveness thereof
As can be seen from Table 17, cabbage pieris can be effectively prevented and treated after four chlorantraniliproles are composite with carbamates, test through applicant and find that four chlorantraniliproles and carbamates can also be used for preventing and treating diamondback moth, beet armyworm, flea beetle after composite, prevention effect is above 96%, it is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 11 chlorantraniliprole and carbamates and the composite preventing and treating phyllocnistis citrella stainton test of pesticide effectiveness thereof
This test arrangement, in Hanzhong City suburb, Shaanxi Province, investigates phyllocnistis citrella stainton insect pest index before medicine, in insect pest early period of origination dispenser, within after dispenser 3 days, 7 days, 15 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 18 4 chlorantraniliprole and carbamates and the composite preventing and treating phyllocnistis citrella stainton test of pesticide effectiveness thereof
As can be seen from Table 18, effectively preventing and treating phyllocnistis citrella stainton after four chlorantraniliproles are composite with carbamates, test finding that four chlorantraniliproles and carbamates can also be used for anti-eliminating aphis after composite through applicant, prevention effect is above 95%, it is better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example 12 chlorantraniliprole and carbamates and the composite preventing and treating apple tree apple leaf miner test of pesticide effectiveness thereof
This test arrangement, at Xian District, Shanxi Province suburban area, investigates apple tree apple leaf miner insect pest index before medicine, in insect pest early period of origination dispenser, within after dispenser 3 days, 7 days, 15 days, investigate insect pest indexes and calculate preventive effect.Result of the test is as follows:
Table 19 4 chlorantraniliprole and carbamates and the composite preventing and treating apple tree apple leaf miner test of pesticide effectiveness thereof
As can be seen from Table 19, energy effectively preventing and treating apple-tree apple leaf miner after four chlorantraniliproles are composite with carbamates, prevention effect is superior to the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, after four chlorantraniliproles and indoxacarb, Mobucin, meta-tolyl-N-methylcarbamate (MTMC), carbaryl or fenobucarb composite to the preventive effect of the common insect pests such as the rice leaf roller in various crop, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, thrips or flea beetle all more than 95%, being better than single dose preventive effect, potentiation is obvious.
Claims (6)
1. the Pesticidal combination containing four chlorantraniliproles Yu carbamates, effective active composition is active components A and active component B, it is characterized in that: active components A and active component B weight ratio are 1 80～60 1, described active components A is selected from four chlorantraniliproles, and active component B is selected from indoxacarb.
2. the Pesticidal combination containing four chlorantraniliproles Yu carbamates according to claim 1, it is characterised in that: the weight ratio of active components A and active component B is 1 60～40 1.
3. the Pesticidal combination containing four chlorantraniliproles Yu carbamates according to claim 2, it is characterised in that: the weight ratio of four chlorantraniliproles and indoxacarb is 1 30～30 1.
4. the Pesticidal combination containing four chlorantraniliproles Yu carbamates according to any one of claim 1 to 3, it is characterised in that: compositions makes wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent or microcapsule suspension-suspending agent.
5. the Pesticidal combination containing four chlorantraniliproles and carbamates according to claim 4 is for preventing and treating the purposes of insect on crops.
6. purposes according to claim 5, it is characterised in that: described insect includes rice leaf roller, planthopper, pachydiplosis oryzae, striped rice borer, yellow rice borer, aphid, aleyrodid, diamondback moth, Pieris rapae, beet armyworm, leaf roller, apple leaf miner, bollworm, pink bollworm, thrips or flea beetle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610202694.6A CN105794825A (en) | 2013-01-19 | 2013-01-19 | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310025129.3A CN103931641A (en) | 2013-01-19 | 2013-01-19 | Insecticidal composition containing silvchongxian'an and carbamate |
| CN201610202694.6A CN105794825A (en) | 2013-01-19 | 2013-01-19 | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310025129.3A Division CN103931641A (en) | 2013-01-19 | 2013-01-19 | Insecticidal composition containing silvchongxian'an and carbamate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105794825A true CN105794825A (en) | 2016-07-27 |
Family
ID=51179725
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610202694.6A Pending CN105794825A (en) | 2013-01-19 | 2013-01-19 | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters |
| CN201310025129.3A Pending CN103931641A (en) | 2013-01-19 | 2013-01-19 | Insecticidal composition containing silvchongxian'an and carbamate |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310025129.3A Pending CN103931641A (en) | 2013-01-19 | 2013-01-19 | Insecticidal composition containing silvchongxian'an and carbamate |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN105794825A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103688973A (en) * | 2013-12-19 | 2014-04-02 | 北京燕化永乐生物科技股份有限公司 | Composite insecticide |
| CN104738063B (en) * | 2013-12-31 | 2017-02-15 | 沈阳中化农药化工研发有限公司 | Binary insecticide composition and application |
| CN104610098B (en) * | 2014-12-09 | 2017-03-15 | 上海化工研究院 | A kind of synthetic method of isotope marks MTMC D3 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010046463A1 (en) * | 2008-10-23 | 2010-04-29 | Basf Se | Use of selected insecticides on cultivated plants |
| CN102047914A (en) * | 2009-10-29 | 2011-05-11 | 中国中化股份有限公司 | Pesticide composition |
| CN102349528A (en) * | 2011-07-28 | 2012-02-15 | 尹小根 | Insecticidal composition containing chlorantraniliprole and indoxacarb |
| CN103155935A (en) * | 2011-12-09 | 2013-06-19 | 中国中化股份有限公司 | Binary pesticide composition |
-
2013
- 2013-01-19 CN CN201610202694.6A patent/CN105794825A/en active Pending
- 2013-01-19 CN CN201310025129.3A patent/CN103931641A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010046463A1 (en) * | 2008-10-23 | 2010-04-29 | Basf Se | Use of selected insecticides on cultivated plants |
| CN102047914A (en) * | 2009-10-29 | 2011-05-11 | 中国中化股份有限公司 | Pesticide composition |
| CN102349528A (en) * | 2011-07-28 | 2012-02-15 | 尹小根 | Insecticidal composition containing chlorantraniliprole and indoxacarb |
| CN103155935A (en) * | 2011-12-09 | 2013-06-19 | 中国中化股份有限公司 | Binary pesticide composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103931641A (en) | 2014-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104996431B (en) | A kind of Efficient insecticidal composition containing propylene glycol alginate | |
| CN104115845A (en) | Efficient pesticide composition containing flubendiamide | |
| CN104738045B (en) | A kind of Pesticidal combination containing propylene glycol alginate | |
| CN105794825A (en) | Insecticide composition containing tetrachlorantraniliprole and carbamic acid esters | |
| CN103960280A (en) | High-efficiency insecticidal composition containing tetrachlorantraniliprole | |
| CN103651403A (en) | Efficient insecticidal composition containing spiromesifen | |
| CN104106587A (en) | Insecticidal composition containing flubendiamide and carbamate | |
| CN104115830A (en) | Insecticidal composition containing flubendiamide and nereistoxin | |
| CN103563956B (en) | Insecticidal composition containing propylene glycol alginate and carbamates | |
| CN103651488A (en) | Pesticide composition containing fluorin pyrazol furan ketone and carbamates | |
| CN105794859A (en) | Insecticidal compound containing conidioblous thromboides and biological sources | |
| CN103461366B (en) | A kind of Pesticidal combination containing CGA 183893 and carbamates | |
| CN103651548A (en) | Pesticidal composition containing spiromesifen | |
| CN105746526B (en) | A kind of Pesticidal combination for containing four chlorantraniliproles and biogenic substances | |
| CN104738064B (en) | A kind of composition pesticide containing Spiromesifen and carbamatess | |
| CN103858925B (en) | A kind of Pesticidal combination containing carbosulfan and diazinon | |
| CN102657209B (en) | The insect-killing composition of a kind of fluorine-containing lice sulfanilamide (SN) and amino formate | |
| CN103503913A (en) | Insecticidal composition containing chlorfenapyr benzamide | |
| CN105707105A (en) | Insecticidal composition containing Wufuchongzong and carbamate | |
| CN105613555A (en) | Pesticide composition containing pentaflumizone and carbamates | |
| CN105613535A (en) | Insecticidal composition containing N-(2-(tert-butylaminoformyl)-4-chloro-6-methylphenyl)-1-(3-chloropyridin-2-yl)-3-fluoromethoxy-1H-pyrazolyl-5-formamide (ZJ3757) and carbamate | |
| CN105707098A (en) | Insecticidal composition containing Wufuchongzong | |
| CN103931663A (en) | Insecticidal composition containing conidioblous thromboides and carbamates | |
| CN105685075A (en) | Insecticidal composition containing wufuchongzong | |
| CN105685074A (en) | High-efficiency insecticidal composition containing Wufuchongzong |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160727 |
|
| WD01 | Invention patent application deemed withdrawn after publication |