CN102217632A - Insecticidal composition containing sulfoxaflor and carbamates - Google Patents
Insecticidal composition containing sulfoxaflor and carbamates Download PDFInfo
- Publication number
- CN102217632A CN102217632A CN2011100742012A CN201110074201A CN102217632A CN 102217632 A CN102217632 A CN 102217632A CN 2011100742012 A CN2011100742012 A CN 2011100742012A CN 201110074201 A CN201110074201 A CN 201110074201A CN 102217632 A CN102217632 A CN 102217632A
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- CN
- China
- Prior art keywords
- fluorine pyridine
- amine nitrile
- worm amine
- pyridine worm
- nitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 claims abstract description 41
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 239000011347 resin Substances 0.000 description 1
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- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal composition containing sulfoxaflor and carbamates. The insecticidal composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is the sulfoxaflor; the active ingredient B is any of the following insecticides: carbaryl, indoxacarb, metolcarb, fenobucarb, and isoprocarb; and the weight ratio of the active ingredient A to the active ingredient B is 1-50 percent:1-80 percent. The composition can control various insect pests, has a remarkable synergistic effect, widens a bactericidal spectrum, and has relatively high activity on cotton bollworms, aphids, rice planthoppers, rice leafhoppers, and Cnaphalocrocis medinalis as well as Plutella xylostella, cabbage caterpillars and beet armyworms on cruciferous vegetables; the using amount of pesticides is reduced, the residual amount of the pesticides on crops is reduced, and the environmental pollution is reduced; and the insecticidal composition is safe to people and livestock, has high environmental compatibility, and ensures that pests cannot produce the pesticide resistance easily.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination that contains fluorine pyridine worm amine nitrile and carbamates.
Background technology
Fluorine pyridine worm amine nitrile, English common name (sulfoxaflor), molecular formula: C
10H
10F
3N
3OS chemical name: [1-[6-(trifluoromethyl) pyridin-3-yl] ethyl] methyl (oxygen)-λ 4-sulfydryl cyanamide.Fluorine pyridine worm amine nitrile is an insecticide of sulfimide, and sulfimide acts on the nervous system of insect, promptly acts on binding site unique in the choline receptor and brings into play insecticidal function.Can be through leaf, stem, root absorption and enter in the plant corpus.
Yet in the real process of agricultural production, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.
The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Through inventor's research, discovery can produce good synergistic effect with fluorine pyridine worm amine nitrile and carbaryl, indenes worm prestige, meta-tolyl-N-methylcarbamate (MTMC), Bassa, Mobucin after composite, and still unexposed about the composite relevant report of fluorine pyridine worm amine nitrile and carbaryl, indenes worm prestige, meta-tolyl-N-methylcarbamate (MTMC), Bassa, Mobucin.
Summary of the invention
Degradation problem under the resistance generation that the long-term use of fluorine pyridine worm amine nitrile list agent may bring, the drug effect, the Pesticidal combination that the present invention proposes contains two kinds of active components of A, B, and an amount of surfactant and carrier.
A kind of Pesticidal combination that contains fluorine pyridine worm amine nitrile and carbamates, comprise effective active component, auxiliary agent and filler, it is characterized in that: active component A, B percentage by weight are 1～50%: 1～80%, described active component A is selected from fluorine pyridine worm amine nitrile, and active component B is selected from a kind of in carbaryl, indenes worm prestige, meta-tolyl-N-methylcarbamate (MTMC), Bassa, the Mobucin.
The described Pesticidal combination that contains fluorine pyridine worm amine nitrile is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～40%: 1～60%.
The described Pesticidal combination that contains fluorine pyridine worm amine nitrile, it is characterized in that: the percentage by weight of fluorine pyridine worm amine nitrile and carbaryl is 5～20%: 5～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and indenes worm prestige is 5～20%: 5～20%;
The percentage by weight of fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 5～20%: 1～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and Bassa is 5～20%: 5～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and Mobucin is 5～20%: 5～40%.
The percentage by weight of A, two kinds of active components of B is 1～50%: 1～80%.Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of Pesticidal combination of the present invention is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the defoamer one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, during the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, the aluminium chloride.
Described binding agent is selected from: one or more in gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described defoamer is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (as capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), farming newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (the pure APEO of fat) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the defoamer etc. one or more again.
Pesticidal combination of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent or suspension emulsion.
When making wetting powder, composition comprises following constituent content: fluorine pyridine worm amine nitrile 1～50%, active component B 1～80%, dispersant 5～10%, wetting agent 2～10%, filler 8～91%.
Active component fluorine pyridine worm amine nitrile, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: active component fluorine pyridine worm amine nitrile 1～50%, active component B 1～80%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler 10～92%.
Active component fluorine pyridine worm amine nitrile, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that product are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is made suspending agent: active component fluorine pyridine worm amine nitrile 1～20%, active component B 1～40%, dispersant 2～10%, wetting agent 2～10%, defoamer 0.1～1%, binding agent 0.1～2%, antifreeze 0.1～8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear, add active component fluorine pyridine worm amine nitrile, active component B, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
Comprise following constituent content when composition is made suspension emulsion: fluorine pyridine worm amine nitrile 1～20%, active component B 1～40%, emulsifier 2～12%, dispersant 2～10%, defoamer 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear, add the former medicine of fluorine pyridine worm amine nitrile, ball milling is 2～3 hours in ball mill, make diameter of particle all below 5 μ m, make fluorine pyridine worm amine nitrile suspending agent, then with the former medicine of active component B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
The invention has the advantages that: after (1) fluorine pyridine worm amine nitrile and active component B are composite, have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum, cotton bollworm, aphid, rice hoppers, rice-leaf hopper, rice leaf roller and brassicaceous vegetable diamond-back moth, cabbage caterpillar, beet armyworm have been had greater activity; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4), insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application Example one
Example 150% fluorine pyridine worm amine nitrile carbaryl wetting powder
Fluorine pyridine worm amine nitrile 5%, carbaryl 45%, alkylphenol-polyethenoxy are phonetic 7%, spaonin powder 5%, attapulgite add to 100%, and mixture carries out comminution by gas stream, makes 50% fluorine pyridine worm amine nitrile carbaryl wetting powder.
Example 280% fluorine pyridine worm amine nitrile carbaryl wetting powder
Fluorine pyridine worm amine nitrile 20%, carbaryl 60%, ester polyoxyethylene are phonetic 5%, wetting and penetrating agent F 4%, white carbon add to 100%, and mixture carries out comminution by gas stream, makes 80% fluorine pyridine worm amine nitrile carbaryl wetting powder.
Example 352% fluorine pyridine worm amine nitrile carbaryl water dispersible granules
Fluorine pyridine worm amine nitrile 12%, carbaryl 40%, polycarboxylate 6%, soapberry powder 4%, sodium bicarbonate 2%, kaolin add to 100%, the mixed 52% fluorine pyridine worm amine nitrile carbaryl water dispersible granules that gets.
Example 460% fluorine pyridine worm amine nitrile carbaryl water dispersible granules
Fluorine pyridine worm amine nitrile 10%, carbaryl 50%, aliphatic amine polyoxyethylene are phonetic 5%, tea is withered 5%, bentonite adds to 100%, mixed 60% fluorine pyridine worm amine nitrile carbaryl water dispersible granules.
Example 510% fluorine pyridine worm amine nitrile carbaryl suspending agent
Fluorine pyridine worm amine nitrile 5%, carbaryl 5%, lignosulfonates 6%, Nekal BX 5%, C
8～10Aliphatic alcohols 0.1%, PAA 1.5%, glycerine 1.2%, deionized water add to 100%, the mixed 10% fluorine pyridine worm amine nitrile carbaryl suspending agent that gets.
Example 636% fluorine pyridine worm amine nitrile carbaryl suspending agent
Fluorine pyridine worm amine nitrile 6%, carbaryl 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, silicone compound 0.3%, gum Arabic 1.1%, triethylene glycol 2%, deionized water add to 100%, the mixed 36% fluorine pyridine worm amine nitrile carbaryl suspending agent that gets.
Example 724% fluorine pyridine worm amine nitrile carbaryl suspension emulsion
Fluorine pyridine worm amine nitrile 4%, carbaryl 20%, alkyl benzene sulfonate calcium salt 7%, lauryl sodium sulfate 6%, polyvinyl alcohol 1.2%, tween series 8%, ethylene glycol 1.9%, silicone oil 0.4%, water add to 100%, through the mixed 24% fluorine pyridine worm amine nitrile carbaryl suspension emulsion that gets.
Example 845% fluorine pyridine worm amine nitrile carbaryl suspension emulsion
Fluorine pyridine worm amine nitrile 10%, carbaryl 35%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, soapberry powder 5%, sodium alginate 1.7%, agricultural newborn 600#5%, propane diols 1.3%, C
10～20Saturated fat acids 0.6%, water add to 100%, through the mixed 45% fluorine pyridine worm amine nitrile carbaryl suspension emulsion that gets.
Example 948% fluorine pyridine worm amine nitrile indenes worm prestige wetting powder
Fluorine pyridine worm amine nitrile 12%, indenes worm prestige 36%, polyoxyethylene carboxylate 7%, wetting and penetrating agent F 5%, diatomite add to 100%, make 48% fluorine pyridine worm amine nitrile indenes worm prestige wetting powder.
Example 1050% fluorine pyridine worm amine nitrile indenes worm prestige wetting powder
Fluorine pyridine worm amine nitrile 10%, indenes worm prestige 40%, naphthalene sulfonic acid-formaldehyde condensation product 5%, lauryl sodium sulfate 5%, kaolin add to 100%, make 50% fluorine pyridine worm amine nitrile indenes worm prestige wetting powder.
Example 1150% fluorine pyridine worm amine nitrile indenes worm prestige water dispersible granules
Fluorine pyridine worm amine nitrile 20%, indenes worm prestige 30%, alkyl benzene sulfonate calcium salt 9%, spaonin powder 6%, urea 2.6%, attapulgite add to 100%, the mixed 50% fluorine pyridine worm amine nitrile indenes worm prestige water dispersible granules that gets.
Example 1260% fluorine pyridine worm amine nitrile indenes worm prestige water dispersible granules
Fluorine pyridine worm amine nitrile 40%, indenes worm prestige 20%, lignosulfonates 7%, neopelex 4%, bentonite add to 100%, the mixed 60% fluorine pyridine worm amine nitrile indenes worm prestige water dispersible granules that gets.
Example 1320% fluorine pyridine worm amine nitrile indenes worm prestige suspending agent
Fluorine pyridine worm amine nitrile 5%, indenes worm prestige 15%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 8%, wetting and penetrating agent F 5%, methylcellulose 1.4%, C
10～20Saturated fat acids 0.5%, diethylene glycol (DEG) 1.6%, deionized water add to 100%, the mixed 20% fluorine pyridine worm amine nitrile indenes worm prestige suspending agent that gets.
Example 1430% fluorine pyridine worm amine nitrile indenes worm prestige suspending agent
Fluorine pyridine worm amine nitrile 15%, indenes worm prestige 15%, alkylphenol-polyethenoxy are phonetic 6%, Nekal BX 5%, silicone compound 0.3%, polyvinylpyrrolidone 1.7%, glycerine 2.3%, deionized water add to 100%, mixed 30% fluorine pyridine worm amine nitrile indenes worm prestige suspending agent.
Example 1520% fluorine pyridine worm amine nitrile indoxacarb suspending agent
Fluorine pyridine worm amine nitrile 10%, indenes worm prestige 10%, aryl phenol polyoxyethylene succinate sulfonate 8%, silkworm excrement 7%, C
8～10Aliphatic alcohols 0.4%, white dextrin 1.5%, By series 6%, triethylene glycol 1.1%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 20% fluorine pyridine worm amine nitrile indoxacarb suspending agent.
Example 1635% fluorine pyridine worm amine nitrile indoxacarb suspending agent
Fluorine pyridine worm amine nitrile 5%, indenes worm prestige 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, spaonin powder 4%, silicone oil 0.2%, sodium phosphate trimer 1.6%, agricultural newborn 1600#7%, polyethylene glycol 1.8%, water add to 100%, the aforementioned formula material is mixed, promptly make 35% fluorine pyridine worm amine nitrile indoxacarb suspending agent.
Example 1760% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder
Fluorine pyridine worm amine nitrile 15%, meta-tolyl-N-methylcarbamate (MTMC) 45%, aliphatic amine polyoxyethylene are phonetic 4%, soapberry powder 5%, kaolin add to 100%, make 60% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder.
Example 1870% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder
Fluorine pyridine worm amine nitrile 10%, meta-tolyl-N-methylcarbamate (MTMC) 60%, polycarboxylate 7%, lauryl sodium sulfate 6%, attapulgite add to 100%, make 70% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) wetting powder.
Example 1955% fluorine pyridine worm amine nitrile Tsumacide water dispersible granule
Fluorine pyridine worm amine nitrile 15%, meta-tolyl-N-methylcarbamate (MTMC) 40%, lignosulfonates 9%, tea are withered 8%, bentonite adds to 100%, make 55% fluorine pyridine worm amine nitrile Tsumacide water dispersible granule.
Example 2065% fluorine pyridine worm amine nitrile Tsumacide water dispersible granule
Fluorine pyridine worm amine nitrile 20%, meta-tolyl-N-methylcarbamate (MTMC) 45%, naphthalene sulfonic acid-formaldehyde condensation product 6%, wetting and penetrating agent F 5%, ammonium sulfate 2.5%, diatomite add to 100%, make 65% fluorine pyridine worm amine nitrile Tsumacide water dispersible granule.
Example 2112% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspending agent
Fluorine pyridine worm amine nitrile 6%, meta-tolyl-N-methylcarbamate (MTMC) 6%, alkylnaphthalene sulfonate 8%, soapberry powder 7%, xanthans 1.8%, C
8～10Aliphatic alcohols 0.1%, glycerine 1.5%, deionized water add to 100%, the mixed 12% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspending agent that gets.
Example 2248% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspending agent
Fluorine pyridine worm amine nitrile 8%, meta-tolyl-N-methylcarbamate (MTMC) 40%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, lauryl sodium sulfate 5%, silicone compound 0.5%, phenolic resins 1.2%, polyethylene glycol 2.1%, deionized water add to 100%, the mixed 48% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspending agent that gets.
Example 2325% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion
Fluorine pyridine worm amine nitrile 10%, meta-tolyl-N-methylcarbamate (MTMC) 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, Nekal BX 4%, sodium phosphate trimer 1.3%, 600# phosphate 6%, diethylene glycol (DEG) 1.5%, silicone compound 0.2%, water add to 100%, through the mixed 25% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion that gets.
Example 2430% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion
Fluorine pyridine worm amine nitrile 5%, meta-tolyl-N-methylcarbamate (MTMC) 25%, aliphatic amine polyoxyethylene are phonetic 8%, soapberry powder 6%, methylcellulose 1.7%, agricultural newborn 400#7%, propane diols 1.3%, C
10～20Saturated fat acids 0.5%, water add to 100%, through the mixed 30% fluorine pyridine worm amine nitrile meta-tolyl-N-methylcarbamate (MTMC) suspension emulsion that gets.
Example 2550% fluorine pyridine worm amine nitrile Bassa wetting powder
Fluorine pyridine worm amine nitrile 10%, Bassa 40%, lignosulfonates 7%, wetting and penetrating agent F 6%, attapulgite add to 100%, make 50% fluorine pyridine worm amine nitrile Bassa wetting powder.
Example 2660% fluorine pyridine worm amine nitrile Bassa wetting powder
Fluorine pyridine worm amine nitrile 6%, Bassa 54%, polyoxyethylene carboxylate 6%, lauryl sodium sulfate 5%, kaolin add to 100%, make 60% fluorine pyridine worm amine nitrile Bassa wetting powder.
Example 2760% fluorine pyridine worm amine nitrile Bassa water dispersible granules
Fluorine pyridine worm amine nitrile 10%, Bassa 50%, alkyl benzene sulfonate calcium salt 9%, spaonin powder 6%, aluminium chloride 2%, diatomite add to 100%, make 60% fluorine pyridine worm amine nitrile Bassa water dispersible granules.
Example 2880% fluorine pyridine worm amine nitrile Bassa water dispersible granules
Fluorine pyridine worm amine nitrile 20%, Bassa 60%, polycarboxylate 7%, soapberry powder 5%, sodium carbonate 1.6%, bentonite add to 100%, make 80% fluorine pyridine worm amine nitrile Bassa water dispersible granules.
Example 2922% fluorine pyridine worm amine nitrile Bassa suspending agent
Fluorine pyridine worm amine nitrile 10%, Bassa 12%, ester polyoxyethylene are phonetic 6%, tea is withered 3%, xanthans 1.8%, propane diols 1.1%, C
10～20Saturated fat acids 0.1%, deionized water add to 100%, the mixed 22% fluorine pyridine worm amine nitrile Bassa suspending agent that gets.
Example 3040% fluorine pyridine worm amine nitrile Bassa suspending agent
Fluorine pyridine worm amine nitrile 20%, Bassa 20%, polyoxyethylene carboxylate 8%, wetting and penetrating agent F 7%, silicone oil 0.2%, PAA 1.4%, glycerine 1.6%, deionized water add to 100%, the mixed 40% fluorine pyridine worm amine nitrile Bassa suspending agent that gets.
Example 3120% fluorine pyridine worm amine nitrile Bassa suspension emulsion
Fluorine pyridine worm amine nitrile 5%, Bassa 15%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, Nekal BX 4%, C
8～10Aliphatic alcohols 0.5%, sodium alginate 1.3%, agricultural newborn 500#8%, triethylene glycol 1.7%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 20% fluorine pyridine worm amine nitrile Bassa suspension emulsion.
Example 3242% fluorine pyridine worm amine nitrile Bassa suspension emulsion
Fluorine pyridine worm amine nitrile 6%, Bassa 36%, alkylphenol-polyethenoxy are phonetic 8%, spaonin powder 6%, silicone compound 0.3%, polyvinylpyrrolidone 1.2%, AEO series 6%, ethylene glycol 1.5%, water add to 100%, the aforementioned formula material is mixed, promptly make 42% fluorine pyridine worm amine nitrile Bassa suspension emulsion.
Example 3360% fluorine pyridine worm amine nitrile Mobucin wetting powder
Fluorine pyridine worm amine nitrile 10%, Mobucin 50%, the phonetic formaldehyde condensation products sulphate 9% of alkylphenol-polyethenoxy, wetting and penetrating agent F 5%, kaolin add to 100%, make 60% fluorine pyridine worm amine nitrile Mobucin wetting powder.
Example 3470% fluorine pyridine worm amine nitrile Mobucin wetting powder
Fluorine pyridine worm amine nitrile 7%, Mobucin 63%, polycarboxylate 6%, neopelex 4%, bentonite add to 100%, make 70% fluorine pyridine worm amine nitrile Mobucin wetting powder.
Example 3564% fluorine pyridine worm amine nitrile Mobucin water dispersible granules
Fluorine pyridine worm amine nitrile 8%, Mobucin 56%, alkyl benzene sulfonate calcium salt 8%, spaonin powder 7%, ammonium sulfate 1.7%, diatomite add to 100%, make 64% fluorine pyridine worm amine nitrile Mobucin water dispersible granules.
Example 3675% fluorine pyridine worm amine nitrile Mobucin water dispersible granules
Fluorine pyridine worm amine nitrile 20%, Mobucin 55%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, lauryl sodium sulfate 5%, sodium carbonate 1.4%, kaolin add to 100%, make 75% fluorine pyridine worm amine nitrile Mobucin water dispersible granules.
Example 3724% fluorine pyridine worm amine nitrile Mobucin suspending agent
Fluorine pyridine worm amine nitrile 4%, Mobucin 20%, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy thing 8%, silkworm excrement 5%, polyvinylpyrrolidone 1%, propane diols 2%, silicone compound 0.4%, deionized water add to 100%, the mixed 24% fluorine pyridine worm amine nitrile Mobucin suspending agent that gets.
Example 3836% fluorine pyridine worm amine nitrile Mobucin suspending agent
Fluorine pyridine worm amine nitrile 18%, Mobucin 18%, aryl phenol polyoxyethylene succinate sulfonate 6%, tea are withered 4%, silicone oil 0.3%, phenolic resins 1.3%, ethylene glycol 1.6%, deionized water add to 100%, mixed 36% fluorine pyridine worm amine nitrile Mobucin suspending agent.
Example 3930% fluorine pyridine worm amine nitrile Mobucin suspension emulsion
Fluorine pyridine worm amine nitrile 10%, Mobucin 20%, alkyl benzene sulfonate calcium salt 8%, soapberry powder 6%, C
10～20Saturated fat acids 0.5%, polyvinyl alcohol 1.2%, tween series 8%, polyethylene glycol 1.7%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 30% fluorine pyridine worm amine nitrile Mobucin suspension emulsion.
Example 4042% fluorine pyridine worm amine nitrile Mobucin suspension emulsion
Fluorine pyridine worm amine nitrile 12%, Mobucin 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, lauryl sodium sulfate 5%, C
8～10Aliphatic alcohols 0.2%, white dextrin 1.4%, 600# phosphate 6%, ethylene glycol 1.6%, water add to 100%, and the aforementioned formula material is mixed, and promptly make 42% fluorine pyridine worm amine nitrile Mobucin suspension emulsion.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent of fluorine pyridine worm amine nitrile effective active composition B is diluted to five series concentration during test, places beaker standby respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament soaked in the soup that configures behind the 5s take out, dry naturally, put into insect box, connect then, under 25 ℃ of conditions, raise for examination 3 instar larvaes, every processing repeats for 3 times, every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (with fluorine pyridine worm amine nitrile is the standard medicament, and its toxicity index is 100):
TI * the P of the theoretical toxicity index (TTI) of M=fluorine pyridine worm amine nitrile
Fluorine pyridine worm amine nitrileTI * P of+effective active composition B
Effective active composition B
In the formula: M is the mixture of different proportionings
P
Effective active composition BBe effective active composition B shared ratio in composition
P
Fluorine pyridine worm amine nitrileBe fluorine pyridine worm amine nitrile shared ratio in composition
A is selected from fluorine pyridine worm amine nitrile;
B is selected from a kind of in carbaryl, indenes worm prestige, meta-tolyl-N-methylcarbamate (MTMC), Bassa, the Mobucin.
Application Example two:
For trying insect: cotton aphid.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining fluorine pyridine worm amine nitrile, carbaryl and the two different proportioning mixture through preliminary experiment.
The different proportionings with carbaryl of table 1 fluorine pyridine worm amine nitrile are to the toxicity test of cotton aphid
As shown in Table 1, the proportioning of fluorine pyridine worm amine nitrile and the composite control cotton aphid of carbaryl 50: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when fluorine pyridine worm amine nitrile and carbaryl was at 1: 1 to 1: 9, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine pyridine worm amine nitrile and carbaryl weight ratio are 1: 5 wherein, and synergistic effect is the most obvious.
Application Example three:
For trying insect: the wild cabbage beet armyworm.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining fluorine pyridine worm amine nitrile, indenes worm prestige and the two different proportioning mixture through preliminary experiment.
Table 2 fluorine pyridine worm amine nitrile and the toxicity test of the different proportionings of indenes worm prestige to the wild cabbage beet armyworm
As shown in Table 2, the proportioning of fluorine pyridine worm amine nitrile and the composite control wild cabbage of indenes worm prestige beet armyworm 50: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when fluorine pyridine worm amine nitrile and indenes worm prestige was at 6: 1 to 1: 6, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine pyridine worm amine nitrile and indenes worm prestige weight ratio are 1: 1 wherein, and synergistic effect is the most obvious.
Application Example four:
For trying insect: rice hoppers.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining fluorine pyridine worm amine nitrile, meta-tolyl-N-methylcarbamate (MTMC) and the two different proportioning mixture through preliminary experiment.
The different proportionings with meta-tolyl-N-methylcarbamate (MTMC) of table 3 fluorine pyridine worm amine nitrile are to the toxicity test of rice hoppers
As shown in Table 3, fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) be composite prevents and treats the proportioning 50: 1 to 1: 80 o'clock of rice hoppers, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) was at 1: 1 to 1: 9, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) weight ratio are 1: 5 wherein, and synergistic effect is the most obvious.
Application Example five:
For trying insect: rice-leaf hopper.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining fluorine pyridine worm amine nitrile, Bassa and the two different proportioning mixture through preliminary experiment.
The different proportionings with Bassa of table 4 fluorine pyridine worm amine nitrile are to the toxicity test of rice-leaf hopper
As shown in Table 4, the proportioning of fluorine pyridine worm amine nitrile and fenobucarb composite control rice-leaf hopper 50: 1 to 1: 80 o'clock, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when fluorine pyridine worm amine nitrile and Bassa was at 1: 1 to 1: 9, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine pyridine worm amine nitrile and Bassa weight ratio are 1: 5 wherein, and synergistic effect is the most obvious.
Application Example six:
For trying insect: rice hoppers.
Test medicine provides by Shanxi Thompson Biological Technology Co., Ltd..
Experimental scheme: effective lethal concentration scope of determining fluorine pyridine worm amine nitrile, Mobucin and the two different proportioning mixture through preliminary experiment.
The different proportionings with Mobucin of table 5 fluorine pyridine worm amine nitrile are to the toxicity test of rice hoppers
As shown in Table 5, fluorine pyridine worm amine nitrile and Mobucin be composite prevents and treats the proportioning 50: 1 to 1: 80 o'clock of rice hoppers, co-toxicity coefficient is all greater than 120, illustrating that both were mixed in the scope at 50: 1 to 1: 80 all shows synergistic effect, when saying that especially proportioning when fluorine pyridine worm amine nitrile and Mobucin was at 1: 1 to 1: 9, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when fluorine pyridine worm amine nitrile and Mobucin weight ratio are 1: 5 wherein, and synergistic effect is the most obvious.
Application Example seven fluorine pyridine worm amine nitriles and carbaryl and the composite control cotton aphid test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 50% fluorine pyridine worm amine nitrile water dispersible granules (commercial), 25% carbaryl wetting powder (commercial).
Investigation cotton aphid insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 6 fluorine pyridine worm amine nitrile, carbaryl and the composite control cotton aphid test of pesticide effectiveness thereof
As can be seen from Table 6, can effectively prevent and treat cotton aphid after fluorine pyridine worm amine nitrile and carbaryl are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example octafluoro pyridine worm amine nitrile and indenes worm prestige and the composite control wild cabbage beet armyworm test of pesticide effectiveness thereof
This experimental establishment is in Ningcheng County, Chifeng City, the Inner Mongol, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 50% fluorine pyridine worm amine nitrile water dispersible granules (commercial), 150 grams per liter indenes worm prestige suspending agents (commercial).
Investigation wild cabbage beet armyworm insect pest index in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 7 fluorine pyridine worm amine nitrile, indenes worm prestige and the composite control wild cabbage beet armyworm test of pesticide effectiveness thereof
As can be seen from Table 7, can effectively prevent and treat the wild cabbage beet armyworm after fluorine pyridine worm amine nitrile and indenes worm prestige are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example nine fluorine pyridine worm amine nitriles and meta-tolyl-N-methylcarbamate (MTMC) and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Yingtan Yujiang County, Jiangxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 50% fluorine pyridine worm amine nitrile water dispersible granules (commercial), 25% meta-tolyl-N-methylcarbamate (MTMC) wetting powder (commercial).
Investigation rice hoppers insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 8 fluorine pyridine worm amine nitrile, meta-tolyl-N-methylcarbamate (MTMC) and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 8, can effectively prevent and treat rice hoppers after fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example ten fluorine pyridine worm amine nitriles and Bassa and the composite control rice-leaf hopper test of pesticide effectiveness thereof
This experimental establishment is in Chuzhou City Fengyang County, Anhui Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 50% fluorine pyridine worm amine nitrile water dispersible granules (commercial), 20% Bassa missible oil (commercial).
Investigation rice-leaf hopper insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 9 fluorine pyridine worm amine nitrile, Bassa and the composite control rice-leaf hopper test of pesticide effectiveness thereof
As can be seen from Table 9, can effectively prevent and treat rice-leaf hopper behind fluorine pyridine worm amine nitrile and the fenobucarb composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Application Example 11 fluorine pyridine worm amine nitriles and Mobucin and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Ankang City Ziyang County, Shaanxi Province, and test medicine is researched and developed, provided by Shanxi Thompson Biological Technology Co., Ltd., contrast medicament 50% fluorine pyridine worm amine nitrile water dispersible granules (commercial), 20% Mobucin missible oil (commercial).
Investigation rice hoppers insect pest index before the medicine in the their early stage dispenser, was investigated the insect pest indexes in 24 hours, 72 hours after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 10 fluorine pyridine worm amine nitrile, Mobucin and the composite rice hoppers test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 10, can effectively prevent and treat rice hoppers after fluorine pyridine worm amine nitrile and Mobucin are composite, control efficiency all is better than the preventive effect of single agent.In the test scope of medication, the target crop is had no adverse effects.
Claims (6)
1. Pesticidal combination that contains fluorine pyridine worm amine nitrile and carbamates, comprise effective active component, auxiliary agent and filler, it is characterized in that: active component A, B percentage by weight are 1～50%: 1～80%, described active component A is selected from fluorine pyridine worm amine nitrile, and active component B is selected from a kind of in carbaryl, indenes worm prestige, meta-tolyl-N-methylcarbamate (MTMC), Bassa, the Mobucin.
2. the Pesticidal combination that contains fluorine pyridine worm amine nitrile according to claim 1 is characterized in that: the percentage by weight of A, two kinds of active components of B is 1～40%: 1～60%.
3. the Pesticidal combination that contains fluorine pyridine worm amine nitrile according to claim 2, it is characterized in that: the percentage by weight of fluorine pyridine worm amine nitrile and carbaryl is 5～20%: 5～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and indenes worm prestige is 5～20%: 5～20%;
The percentage by weight of fluorine pyridine worm amine nitrile and meta-tolyl-N-methylcarbamate (MTMC) is 5～20%: 1～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and Bassa is 5～20%: 5～40%;
The percentage by weight of fluorine pyridine worm amine nitrile and Mobucin is 5～20%: 5～40%.
4. the Pesticidal combination that contains fluorine pyridine worm amine nitrile according to claim 1, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent or suspension emulsion.
5. the fluorine pyridine worm amine nitrile Pesticidal combination that contains according to claim 1 is used to prevent and treat insect on cereal class, vegetables, the cotton.
6. the Pesticidal combination that contains fluorine pyridine worm amine nitrile according to claim 5 is used to prevent and treat cotton bollworm, aphid, rice hoppers, rice-leaf hopper, rice leaf roller and brassicaceous vegetable diamond-back moth, cabbage caterpillar, beet armyworm.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102217634A (en) * | 2011-04-19 | 2011-10-19 | 青岛海利尔药业有限公司 | Insecticidal composition containing sulfoxaflor and pymetozine or indoxacarb |
| CN102217635A (en) * | 2011-05-03 | 2011-10-19 | 青岛海利尔药业有限公司 | Efficient environmentally-friendly pesticide composition containing sulfoxaflor |
| CN102763665A (en) * | 2012-06-30 | 2012-11-07 | 广东中迅农科股份有限公司 | Indoxacarb water dispersible granule and preparation method thereof |
| CN103385251A (en) * | 2012-05-12 | 2013-11-13 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition comprising pyriproxyfen |
| CN103719132A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing sulfoxaflor and carbamates pesticide |
| CN104705333A (en) * | 2015-03-23 | 2015-06-17 | 广东中迅农科股份有限公司 | Pesticide composition containing sodium abietate and sulfoxaflor |
| CN105794828A (en) * | 2014-12-30 | 2016-07-27 | 江苏龙灯化学有限公司 | Insecticidal composition and insect control method |
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| WO2009135613A1 (en) * | 2008-05-07 | 2009-11-12 | Bayer Cropscience Aktiengesellschaft | Synergistic active ingredient combinations |
| WO2010022917A2 (en) * | 2008-08-27 | 2010-03-04 | Bayer Cropscience Ag | Method of controlling soul insects |
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- 2011-03-25 CN CN2011100742012A patent/CN102217632A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009135613A1 (en) * | 2008-05-07 | 2009-11-12 | Bayer Cropscience Aktiengesellschaft | Synergistic active ingredient combinations |
| WO2010022917A2 (en) * | 2008-08-27 | 2010-03-04 | Bayer Cropscience Ag | Method of controlling soul insects |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102217634A (en) * | 2011-04-19 | 2011-10-19 | 青岛海利尔药业有限公司 | Insecticidal composition containing sulfoxaflor and pymetozine or indoxacarb |
| CN102217635A (en) * | 2011-05-03 | 2011-10-19 | 青岛海利尔药业有限公司 | Efficient environmentally-friendly pesticide composition containing sulfoxaflor |
| CN103385251A (en) * | 2012-05-12 | 2013-11-13 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition comprising pyriproxyfen |
| CN103385251B (en) * | 2012-05-12 | 2016-08-10 | 陕西韦尔奇作物保护有限公司 | A kind of Pesticidal combination of pyriproxyfen-containing |
| CN102763665A (en) * | 2012-06-30 | 2012-11-07 | 广东中迅农科股份有限公司 | Indoxacarb water dispersible granule and preparation method thereof |
| CN103719132A (en) * | 2013-12-13 | 2014-04-16 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing sulfoxaflor and carbamates pesticide |
| CN105794828A (en) * | 2014-12-30 | 2016-07-27 | 江苏龙灯化学有限公司 | Insecticidal composition and insect control method |
| CN104705333A (en) * | 2015-03-23 | 2015-06-17 | 广东中迅农科股份有限公司 | Pesticide composition containing sodium abietate and sulfoxaflor |
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Address after: 715500 middle section of North Ring Road, Pucheng County, Shaanxi Applicant after: Shanxi Thompson Biological Technology Co., Ltd. Address before: 710075, C, 15 floor, Jinqiao International Plaza, science and technology road, hi tech Zone, Shaanxi, Xi'an Applicant before: Shanxi Thompson Biological Technology Co., Ltd. |
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Application publication date: 20111019 |