CN105585902A - Waterborne UV curing spraying printing ink and preparation method thereof - Google Patents
Waterborne UV curing spraying printing ink and preparation method thereof Download PDFInfo
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- CN105585902A CN105585902A CN201610100117.6A CN201610100117A CN105585902A CN 105585902 A CN105585902 A CN 105585902A CN 201610100117 A CN201610100117 A CN 201610100117A CN 105585902 A CN105585902 A CN 105585902A
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- 238000005507 spraying Methods 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000007639 printing Methods 0.000 title abstract description 10
- 238000003848 UV Light-Curing Methods 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 74
- 239000000919 ceramic Substances 0.000 claims abstract description 25
- 239000000049 pigment Substances 0.000 claims abstract description 16
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000006184 cosolvent Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 23
- 239000002270 dispersing agent Substances 0.000 claims description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims description 12
- 239000003899 bactericide agent Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 229920000058 polyacrylate Polymers 0.000 claims description 11
- 230000010148 water-pollination Effects 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 150000003254 radicals Chemical class 0.000 claims description 6
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000001768 cations Chemical group 0.000 claims description 4
- 125000003010 ionic group Chemical group 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- USEGQPUGEPSVQL-UHFFFAOYSA-N [Pr].[Zr] Chemical compound [Pr].[Zr] USEGQPUGEPSVQL-UHFFFAOYSA-N 0.000 claims description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims 1
- PTNGTIMIEJADLN-UHFFFAOYSA-N ethene;2-hydroxyacetic acid Chemical compound C=C.OCC(O)=O PTNGTIMIEJADLN-UHFFFAOYSA-N 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 11
- 239000003085 diluting agent Substances 0.000 abstract description 9
- 238000000016 photochemical curing Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 239000002085 irritant Substances 0.000 abstract 1
- 231100000021 irritant Toxicity 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 14
- 239000003002 pH adjusting agent Substances 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- 238000007641 inkjet printing Methods 0.000 description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004056 anthraquinones Chemical class 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses waterborne UV curing spraying printing ink and a preparation method thereof and belongs to the technical field of printing ink production. The waterborne UV curing spraying printing ink comprises the following components in parts by weight: 40-60 parts of waterborne epoxy acrylate, 1-4 parts of a water soluble photoinitiator, 15-35 parts of ceramic pigment, 3-8 parts of a cosolvent, 2-20 parts of a hyperdispersant, 0.5-5 parts of a coupling agent and 8-25 parts of water. The waterborne UV curing spraying printing ink disclosed by the invention combines advantages of waterborne and traditional oil-based ink UV photocuring technologies, water is utilized for replacing a reactive diluent in an oily UV curing system, cost is reduced, the problem that the reactive diluent is toxic, irritant and the like is solved, and system viscosity can be regulated more easily.
Description
Technical field
The present invention relates to Printing ink producing technical field, relate in particular to a kind of water-based UV and solidify spraying ink and system thereofPreparation Method.
Background technology
From China in 2009 introduces First ink-jet printer, ceramic ink jet printing technology starts fast at homeHail exhibition. With respect to traditional screen printing and roller printing ceramic printing technology, ceramic ink jet printing technologyRealized contactless unsettled printing, pattern and color are limited by equipment and process no longer, preparation flow letterSingle, prepared product image resolution ratio is high, and third dimension is strong. But in prior art, the pottery that market is generalCeramic ink water is generally solvent type ink, needs, with adding a large amount of organic solvents, to be unfavorable for the health of production operatorAnd contaminated environment, along with the reinforcement gradually of people's environmental consciousness and the gradual perfection of relevant laws and regulations, researchExploitation high-performance, low pollution or even free of contamination ceramic printing technology are the development of ceramic ink jet printing technologyInexorable trend.
Chinese patent application " a kind of UV photocuring ceramic ink jet ink and the side for ceramic surface printing thereofMethod " a kind of UV light-curable ink that is applied to ceramic ink jet technical field disclosed. UV light-curable inkBy UV-irradiation, exciting light initator produces free radical, causes oligomer and reactive diluent crosslinked solidChange into film. It is fast, energy-conservation etc. excellent that traditional oiliness UV curing system has low or VOC free, solidification ratePoint, but skin and the eyes of many reactive diluent compositions to people in its formula have stronger spread effect,Affect the healthy of operator, and price is more expensive.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of environment amenable ceramic ink jet printing that is applied toThe water-based UV of technical field solidifies spraying ink:
A kind of water-based UV solidifies spraying ink, it is characterized in that, comprises following parts by weight of component:
Preferably, described water-soluble light trigger is selected from the free radical type water of introducing hydrophily anionic groupDissolubility light trigger, or the free radical type water-soluble light trigger of introducing hydrophily cation group, or introduceThe free radical type water-soluble light trigger of hydrophily non-ionic group.
Further, described hydrophily anionic group is sulfonic group or carboxyl; Described hydrophily cation radicalGroup is quaternary ammonium salt; Described hydrophily non-ionic group is alkoxyl hydroxyl.
Preferably, water-soluble light trigger can be selected from water-based benzoin derivatives, water-based acetophenone derivs,The cracking type light such as water-based alpha-alcohol ketone derivative, water-based α-amido ketone derivatives, water-based acylphosphine oxideInitiator system or water-based benzophenone derivates, water-based thia anthracyclinone derivatives, water-based anthraquinone derivative and workProperty amine combination hydrogen-abstraction light initiation system in one or more.
Preferably, described ceramic pigment is selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
Preferably, described hyper-dispersant is selected from polyacrylate hyper-dispersant; Described coupling agent is selected from siliconOne in alkane coupling agent or titanate coupling agent; Described cosolvent is selected from ethylene glycol, propane diols, isopropylAt least one in alcohol, glycol monoethyl ether, diethylene glycol monomethyl ether, ethylene glycol monobutyl ether.
Further, described water-based UV solidifies spraying ink and also comprises 1～4 part of auxiliary agent, and described auxiliary agent is selected fromIn levelling agent, defoamer, anti-settling agent, bactericide or pH adjusting agent at least two kinds.
Above-mentioned water-based UV solidifies the preparation method of spraying ink, comprises the following steps:
A) prepare mill base: under high-speed stirred, in the mixed liquor of cosolvent and water, add hyper-dispersant, stirHyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirred is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add waterborne epoxy acrylate and coupling agent,Mix, then add auxiliary agent to stir, finally add water-soluble light trigger high-speed stirred, fully mixedClose;
C) prepare ink: premixed liquid is ground to ceramic pigment particle diameter < 1 μ m, obtains water-based UV and solidify sprayInking.
Skin and the eyes of reactive diluent composition in tradition ink UV technology to people have stronger stimulationEffect, affect the healthy of operator, and price is more expensive. Water-based UV of the present invention solidifies spraying inkCombine the advantage of water-based and traditional oil-based ink UV photocuring technology, fortune water consumption substitution oiliness UV solidifiesReactive diluent in system, has reduced cost, has solved the problems such as reactive diluent is toxic, excitant.On the other hand, because reactive diluent has toxicity, must control its use amount, when addition is excessive,The problem of product retrogradation is also relatively difficult to resolve certainly, and with respect to reactive diluent, the viscosity of water is lower, can be veryViscosity and the mobility of good control ink, make ink in the time of printing, show good performance.
Detailed description of the invention
In order to more fully understand technology contents of the present invention, below in conjunction with specific embodiment to technology of the present inventionScheme is further introduced and explanation.
Embodiment 1
By weight, the diethylene glycol monomethyl ether of 5 parts is added in the water of 12 parts, be mixed into diethylene glycol listThe methyl ether aqueous solution; Under high-speed stirred to the polyacrylic acid that adds 11 parts in the aqueous solution of diethylene glycol monomethyl etherEster class hyper-dispersant, stirs hyper-dispersant is fully mixed, and slowly adds the yellow ceramic pigment of praseodymium zirconium of 25 parts,High-speed stirred is mixed with into mill base; To preparation mill base in add 50 parts waterborne epoxy acrylate andThe silane coupler of 2.5 parts, mixes, then adds the levelling agent of 0.5 part, the defoamer, 0.5 of 0.5 partAnti-settling agent, the bactericide of 0.5 part and the pH adjusting agent of 0.5 part of part stir, and finally add 2.5 partsWater-based benzoin derivatives high-speed stirred, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter< 1 μ m, obtains water-based UV and solidifies spraying ink.
Embodiment 2
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 40 parts and the titanate coupling agent of 0.5 part, mix allEven, then add the levelling agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the bactericide of 0.2 partAnd the pH adjusting agent of 0.2 part stirs, finally add the water-based alpha-alcohol ketone derivative of 1 part and 1 partWater-based α-amido ketone derivatives high-speed stirred, be fully mixed with into premixed liquid; Premixed liquid is ground to grainFootpath < 1 μ m, obtains water-based UV and solidifies spraying ink.
Embodiment 3
By weight, the ethylene glycol monobutyl ether of the isopropyl alcohol of 3 parts and 3 parts is added in the water of 25 parts, mixBecome the aqueous solution; Under high-speed stirred, to the polyacrylate hyper-dispersant that adds 20 parts in the aqueous solution, stirHyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirred is mixed with intoMill base; In the mill base of preparation, add the waterborne epoxy acrylate of 60 parts and the titanate coupling agent of 5 parts,Mix, then add the levelling agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent, 0.8 part of 0.8 partThe pH adjusting agent of bactericide and 0.8 part stirs, and finally adds the water-based benzophenone derivates of 4 parts highSpeed stirs, and is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UVSolidify spraying ink.
Embodiment 4
By weight, the diethylene glycol monomethyl ether of 5 parts is added in the water of 15 parts, be mixed into diethylene glycol listThe methyl ether aqueous solution; Under high-speed stirred to the polyacrylate that adds 8 parts in the diethylene glycol monomethyl ether aqueous solutionClass hyper-dispersant, stirs hyper-dispersant is fully mixed, and slowly adds the cobalt blue ceramic pigment of 20 parts, heightSpeed is uniformly mixed and is prepared into mill base; In the mill base of preparation, add the waterborne epoxy acrylate and 2 of 45 partsThe titanate coupling agent of part, mixes, then adds the levelling agent of 0.4 part, the defoamer, 0.1 of 0.4 partThe anti-settling agent of part and the bactericide of 0.2 part stir, and finally add the water-based acylphosphine oxide of 2 parts highSpeed stirs, and is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UVSolidify spraying ink.
Embodiment 5
By weight, the isopropyl alcohol of 6 parts is added in the water of 20 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt black ceramic pigment of 25 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 55 parts and the silane coupler of 4.5 parts, mix,Add again the levelling agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the bactericide and 0.5 of 0.4 partThe pH adjusting agent of part stirs, and finally adds the water-based acetophenone derivs of 1.5 parts and the water-based of 1.5 partsThioxanthone derivative high-speed stirred, is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1μ m, obtains water-based UV and solidifies spraying ink.
Embodiment 6
By weight, the isopropyl alcohol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 40 parts and the titanate coupling agent of 0.5 part, mix allEven, then add the levelling agent of 0.2 part, the defoamer of 0.1 part, the anti-settling agent of 0.3 part, the bactericide of 0.2 partAnd the pH adjusting agent of 0.2 part stirs, finally add the water-based alpha-alcohol ketone derivative of 3 parts and 1 partWater-based α-amido ketone derivatives high-speed stirred, be fully mixed with into premixed liquid; Premixed liquid is ground to grainFootpath < 1 μ m, obtains water-based UV and solidifies spraying ink.
Embodiment 7
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 40 parts and the titanate coupling agent of 0.5 part, mix allEven, then add the levelling agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the bactericide of 0.2 partAnd the pH adjusting agent of 0.2 part stirs, finally add the water-based anthraquinone derivative hydrogen-abstraction of 3 parts light-initiatedAgent and reactive amines are pressed the mixture high-speed stirred of 1:1 combination, are fully mixed with into premixed liquid; By premixed liquidBe ground to particle diameter < 1 μ m, obtain water-based UV and solidify spraying ink.
Embodiment 8
By weight, the isopropyl alcohol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 40 parts and the titanate coupling agent of 0.5 part, mix allEven, then add the levelling agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the bactericide of 0.4 partAnd the pH adjusting agent of 0.5 part stirs, finally add the water-based anthraquinone derivative hydrogen-abstraction of 3 parts light-initiatedAgent and reactive amines are pressed the mixture of 1:1 combination, are fully mixed with into premixed liquid; Premixed liquid is ground to grainFootpath < 1 μ m, obtains water-based UV and solidifies spraying ink.
Embodiment 9
By weight, the ethylene glycol monobutyl ether of the isopropyl alcohol of 3 parts and 3 parts is added in the water of 25 parts, mixBecome the aqueous solution; Under high-speed stirred, to the polyacrylate hyper-dispersant that adds 20 parts in the aqueous solution, stirHyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirred is mixed with intoMill base; In the mill base of preparation, add the waterborne epoxy acrylate of 60 parts and the titanate coupling agent of 5 parts,Mix, then add the levelling agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent, 0.8 part of 0.8 partThe pH adjusting agent of bactericide and 0.8 part stirs, finally add 4 parts water-based benzophenone derivates withWater-based alpha-alcohol ketone derivative is pressed the mixture high-speed stirred of 1:1 combination, is fully mixed with into premixed liquid;Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UV and solidify spraying ink.
Embodiment 10
By weight, the ethylene glycol of 2 parts is added in the water of 15 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 15 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the reddish brown ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the waterborne epoxy acrylate of 40 parts and the silane coupler of 0.5 part, mix,Add again the levelling agent of 0.6 part, the defoamer of 0.6 part, the anti-settling agent of 0.6 part, the bactericide and 0.6 of 0.6 partThe pH adjusting agent of part stirs, and finally adds the water-based alpha-alcohol ketone derivative of 1 part and the water-based of 1 partα-amido ketone derivatives high-speed stirred, is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1μ m, obtains water-based UV and solidifies spraying ink.
The above only further illustrates technology contents of the present invention with embodiment, so that reader is easierUnderstand, but do not represent that embodiments of the present invention only limit to this, any technology of doing according to the present invention extend orRecreation, is all subject to protection of the present invention.
Claims (10)
1. water-based UV solidifies a spraying ink, it is characterized in that, comprises following parts by weight of component:
2. water-based UV according to claim 1 solidifies spraying ink, it is characterized in that described waterDissolubility light trigger is selected from the free radical type water-soluble light trigger of introducing hydrophily anionic group, or introducesThe free radical type water-soluble light trigger of hydrophily cation group, or introduce hydrophily non-ionic group fromBy fundamental mode water-soluble light trigger.
3. water-based UV according to claim 2 solidifies spraying ink, it is characterized in that, described hydrophilicProperty anionic group is sulfonic group or carboxyl; Described hydrophily cation group is quaternary ammonium salt.
4. water-based UV according to claim 2 solidifies spraying ink, it is characterized in that described parentWater-based non-ionic group is alkoxyl hydroxyl.
5. water-based UV according to claim 1 solidifies spraying ink, it is characterized in that described potteryPorcelain color is selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
6. water-based UV according to claim 1 solidifies spraying ink, it is characterized in that described oversubscriptionPowder is selected from polyacrylate hyper-dispersant.
7. water-based UV according to claim 1 solidifies spraying ink, it is characterized in that described idolConnection agent is selected from the one in silane coupler or titanate coupling agent.
8. water-based UV according to claim 1 solidifies spraying ink, it is characterized in that, described helpsSolvent is selected from ethylene glycol, propane diols, isopropyl alcohol, glycol monoethyl ether, diethylene glycol monomethyl ether, ethylene glycolAt least one in monobutyl ether.
9. solidify spraying ink according to the water-based UV described in claim 1-8 any one, it is characterized in that,Also comprise 1～4 part of auxiliary agent, described auxiliary agent is selected from levelling agent, defoamer, anti-settling agent, bactericide or pH and adjustsSave at least two kinds in agent.
10. the preparation method that water-based UV solidifies spraying ink as claimed in claim 9, is characterized in that, bagDraw together following steps:
A) prepare mill base: under high-speed stirred, in the mixed liquor of cosolvent and water, add hyper-dispersant, stirHyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirred is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add waterborne epoxy acrylate and coupling agent,Mix, then add auxiliary agent to stir, finally add water-soluble light trigger high-speed stirred, fully mixedClose;
C) prepare ink: premixed liquid is ground to ceramic pigment particle diameter < 1 μ m, obtains water-based UV and solidify sprayInking.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610100117.6A CN105585902A (en) | 2016-02-23 | 2016-02-23 | Waterborne UV curing spraying printing ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610100117.6A CN105585902A (en) | 2016-02-23 | 2016-02-23 | Waterborne UV curing spraying printing ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105585902A true CN105585902A (en) | 2016-05-18 |
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| CN201610100117.6A Pending CN105585902A (en) | 2016-02-23 | 2016-02-23 | Waterborne UV curing spraying printing ink and preparation method thereof |
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Cited By (7)
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| CN106189512A (en) * | 2016-09-26 | 2016-12-07 | 济南阿波罗文化用品有限公司 | A kind of aqueous UV ink for inkjet printing and preparation method thereof |
| CN106189508A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of anion water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106189507A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of antibacterial noctilucence water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106189519A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | One can photochromic water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106349814A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区海帝陶瓷原料有限公司 | Antibacterial and antistatic water- borne UV light curing ceramic ink jet ink and preparing method thereof |
| CN106349813A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区海帝陶瓷原料有限公司 | Deodorant aqueous UV light curing ceramics ink-jet ink and preparing method thereof |
| US20190233334A1 (en) * | 2016-06-03 | 2019-08-01 | Basf Se | Production of a photocurable formulation for additive manufacturing |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20190233334A1 (en) * | 2016-06-03 | 2019-08-01 | Basf Se | Production of a photocurable formulation for additive manufacturing |
| CN106189508A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of anion water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106189507A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of antibacterial noctilucence water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106189519A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | One can photochromic water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof |
| CN106349814A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区海帝陶瓷原料有限公司 | Antibacterial and antistatic water- borne UV light curing ceramic ink jet ink and preparing method thereof |
| CN106349813A (en) * | 2016-08-29 | 2017-01-25 | 佛山市高明区海帝陶瓷原料有限公司 | Deodorant aqueous UV light curing ceramics ink-jet ink and preparing method thereof |
| CN106189512A (en) * | 2016-09-26 | 2016-12-07 | 济南阿波罗文化用品有限公司 | A kind of aqueous UV ink for inkjet printing and preparation method thereof |
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Application publication date: 20160518 |