CN105585899A - Water-based UV-curing ceramic spraying ink and preparation method thereof - Google Patents
Water-based UV-curing ceramic spraying ink and preparation method thereof Download PDFInfo
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- CN105585899A CN105585899A CN201610100158.5A CN201610100158A CN105585899A CN 105585899 A CN105585899 A CN 105585899A CN 201610100158 A CN201610100158 A CN 201610100158A CN 105585899 A CN105585899 A CN 105585899A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 239000000919 ceramic Substances 0.000 title claims abstract description 56
- 238000005507 spraying Methods 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000003848 UV Light-Curing Methods 0.000 title abstract description 6
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 239000007822 coupling agent Substances 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229920002635 polyurethane Polymers 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 239000006184 cosolvent Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 23
- 239000002270 dispersing agent Substances 0.000 claims description 22
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000003002 pH adjusting agent Substances 0.000 claims description 11
- 229920000058 polyacrylate Polymers 0.000 claims description 11
- 230000010148 water-pollination Effects 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 9
- 230000000844 anti-bacterial effect Effects 0.000 claims description 8
- 239000003899 bactericide agent Substances 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 150000003254 radicals Chemical class 0.000 claims description 7
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 4
- 150000001768 cations Chemical group 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 125000003010 ionic group Chemical group 0.000 claims description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- USEGQPUGEPSVQL-UHFFFAOYSA-N [Pr].[Zr] Chemical compound [Pr].[Zr] USEGQPUGEPSVQL-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 abstract description 9
- 238000000016 photochemical curing Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 230000007794 irritation Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000007639 printing Methods 0.000 description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 4
- 238000007641 inkjet printing Methods 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004056 anthraquinones Chemical class 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 241000534944 Thia Species 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a water-based UV-curing ceramic spraying ink and a preparation method thereof, relating to the technical field of ink production. The water-based UV-curing ceramic spraying ink comprises the following components in parts by weight: 40-60 parts of water-based polyurethane acrylate, 1-4 parts of water-soluble photoinitiator, 15-35 parts of ceramic pigment, 3-8 parts of cosolvent, 2-20 parts of hyperdispersant, 0.5-5 parts of coupling agent and 8-25 parts of water. The water-based UV-curing ceramic spraying ink combines the advantages in the water-based and traditional oil-based UV-photocuring techniques; water is used instead of the reactive diluent in the oil-based UV-curing system, thereby lowering the cost, and solving the problems of toxicity, irritation and the like in the reactive diluent; and the viscosity of the system can be regulated more easily.
Description
Technical field
The present invention relates to Printing ink producing technical field, relate in particular to a kind of water-based UV solidify ceramic spraying ink andIts preparation method.
Background technology
From China in 2009 introduces First ink-jet printer, ceramic ink jet printing technology starts fast at homeHail exhibition. With respect to traditional screen printing and roller printing ceramic printing technology, ceramic ink jet printing technologyRealized contactless unsettled printing, pattern and color are limited by equipment and process no longer, preparation flow letterSingle, prepared product image resolution ratio is high, and third dimension is strong. But in prior art, the pottery that market is generalCeramic ink water is generally solvent type ink, needs, with adding a large amount of organic solvents, to be unfavorable for the health of production operatorAnd contaminated environment, along with the reinforcement gradually of people's environmental consciousness and the gradual perfection of relevant laws and regulations, researchExploitation high-performance, low pollution or even free of contamination ceramic printing technology are the development of ceramic ink jet printing technologyInexorable trend.
Chinese patent application " a kind of UV photocuring ceramic ink jet ink and the side for ceramic surface printing thereofMethod " a kind of UV light-curable ink that is applied to ceramic ink jet technical field disclosed. UV light-curable inkBy UV-irradiation, exciting light initator produces free radical, causes oligomer and reactive diluent crosslinked solidChange into film. It is fast, energy-conservation etc. excellent that traditional oiliness UV curing system has low or VOC free, solidification ratePoint, but skin and the eyes of many reactive diluent compositions to people in its formula have stronger spread effect,Affect the healthy of operator, and price is more expensive.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of environment amenable ceramic ink jet printing that is applied toThe water-based UV of technical field solidifies ceramic spraying ink:
A kind of water-based UV solidifies ceramic spraying ink, it is characterized in that, comprises following parts by weight of component:
Preferably, described water-soluble light trigger is selected from the free radical type water of introducing hydrophily anionic groupDissolubility light trigger, or the free radical type water-soluble light trigger of introducing hydrophily cation group, or introduceThe free radical type water-soluble light trigger of hydrophily non-ionic group.
Further, described hydrophily anionic group is sulfonic group or carboxyl; Described hydrophily cation radicalGroup is quaternary ammonium salt; Described hydrophily non-ionic group is alkoxyl hydroxyl.
Preferably, water-soluble light trigger can be selected from water-based benzoin derivatives, water-based acetophenone derivs,The cracking type light such as water-based alpha-alcohol ketone derivative, water-based α-amido ketone derivatives, water-based acylphosphine oxideInitiator system or water-based benzophenone derivates, water-based thia anthracyclinone derivatives, water-based anthraquinone derivative and workProperty amine combination hydrogen-abstraction light initiation system in one or more.
Preferably, described ceramic pigment is selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
Preferably, described hyper-dispersant is selected from polyacrylate hyper-dispersant; Described coupling agent is selected from siliconOne in alkane coupling agent or titanate coupling agent; Described cosolvent is selected from ethylene glycol, propane diols, isopropylAt least one in alcohol, glycol monoethyl ether, diethylene glycol monomethyl ether, ethylene glycol monobutyl ether.
Further, the curing ceramic spraying ink of described water-based UV also comprises 1～4 part of auxiliary agent, described auxiliary agentBe selected from least two kinds in levelling agent, defoamer, anti-settling agent, bactericide or pH adjusting agent.
Above-mentioned water-based UV solidifies the preparation method of ceramic spraying ink, comprises the following steps:
A) prepare mill base: under high-speed stirred, in the mixed liquor of cosolvent and water, add hyper-dispersant, stirHyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirred is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add aqueous polyurethane acrylate and couplingAgent, mixes, then adds auxiliary agent to stir, and finally adds water-soluble light trigger high-speed stirred, fillsDivide and mix;
C) prepare ink: premixed liquid is ground to ceramic pigment particle diameter < 1 μ m, obtains water-based UV and solidify potteryPorcelain spraying ink.
Skin and the eyes of reactive diluent composition in tradition ink UV technology to people have stronger stimulationEffect, affect the healthy of operator, and price is more expensive. Water-based UV of the present invention solidifies ceramic sprayingInk combines the advantage of water-based and traditional oil-based ink UV photocuring technology, fortune water consumption substitution oiliness UVReactive diluent in curing system, has reduced cost, has solved that reactive diluent is toxic, excitant etc.Problem. On the other hand, because reactive diluent has toxicity, must control its use amount, addition mistakeWhen large, the problem of product retrogradation is also relatively difficult to resolve certainly, and with respect to reactive diluent, the viscosity of water is lower,Can well control viscosity and the mobility of ink, make ink in the time of printing, show good performance.
Detailed description of the invention
In order to more fully understand technology contents of the present invention, below in conjunction with specific embodiment to technology of the present inventionScheme is further introduced and explanation.
Embodiment 1
By weight, the diethylene glycol monomethyl ether of 3 parts is added in the water of 10 parts, be mixed into diethylene glycol listThe methyl ether aqueous solution; Under high-speed stirred to the polyacrylic acid that adds 4 parts in the aqueous solution of diethylene glycol monomethyl etherEster class hyper-dispersant, stirs hyper-dispersant is fully mixed, and slowly adds the cobalt blue ceramic pigment of 30 parts,High-speed stirred is mixed with into mill base; To preparation mill base in add 50 parts aqueous polyurethane acrylate andThe silane coupler of 0.6 part, mixes, then adds the levelling agent of 0.1 part, the defoamer, 0.2 of 0.1 partPart anti-settling agent, the bactericide of 0.4 part and the pH adjusting agent of 0.6 part stir, finally add 1 partWater-based benzoin derivatives high-speed stirred, is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 2
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 40 parts and the titanate coupling agent of 0.5 part, mixEvenly, then add the levelling agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the sterilization of 0.2 partThe pH adjusting agent of agent and 0.2 part stirs, and finally adds the water-based alpha-alcohol ketone derivative and 1 of 1 partWater-based α-amido ketone derivatives high-speed stirred of part, is fully mixed with into premixed liquid; Premixed liquid is ground toParticle diameter < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 3
By weight, the ethylene glycol monobutyl ether of the isopropyl alcohol of 3 parts and 3 parts is added in the water of 25 parts, mixBecome the aqueous solution; Under high-speed stirred, to the polyacrylate hyper-dispersant that adds 20 parts in the aqueous solution, stirHyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirred is mixed with intoMill base; In the mill base of preparation, add the aqueous polyurethane acrylate of 60 parts and the titanate coupling agent of 5 parts,Mix, then add the levelling agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent, 0.8 part of 0.8 partThe pH adjusting agent of bactericide and 0.8 part stirs, and finally adds the water-based benzophenone derivates of 4 parts highSpeed stirs, and is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UVSolidify ceramic spraying ink.
Embodiment 4
By weight, the diethylene glycol monomethyl ether of 5 parts is added in the water of 15 parts, be mixed into diethylene glycol listThe methyl ether aqueous solution; Under high-speed stirred to the polyacrylate that adds 8 parts in the diethylene glycol monomethyl ether aqueous solutionClass hyper-dispersant, stirs hyper-dispersant is fully mixed, and slowly adds the cobalt blue ceramic pigment of 20 parts, heightSpeed is uniformly mixed and is prepared into mill base; In the mill base of preparation, add the aqueous polyurethane acrylate and 2 of 45 partsThe titanate coupling agent of part, mixes, then adds the levelling agent of 0.4 part, the defoamer, 0.1 of 0.4 partThe anti-settling agent of part and the bactericide of 0.2 part stir, and finally add the water-based acylphosphine oxide of 2 parts highSpeed stirs, and is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UVSolidify ceramic spraying ink.
Embodiment 5
By weight, the isopropyl alcohol of 6 parts is added in the water of 20 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt black ceramic pigment of 25 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 55 parts and the silane coupler of 4.5 parts, mix allEven, then add the levelling agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the bactericide of 0.4 partAnd the pH adjusting agent of 0.5 part stirs, finally add the water-based acetophenone derivs of 1.5 parts and 1.5 partsWater-based thia anthracyclinone derivatives high-speed stirred, be fully mixed with into premixed liquid; Premixed liquid is ground to grainFootpath < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 6
By weight, the isopropyl alcohol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 40 parts and the titanate coupling agent of 0.5 part, mixEvenly, then add the levelling agent of 0.2 part, the defoamer of 0.1 part, the anti-settling agent of 0.3 part, the sterilization of 0.2 partThe pH adjusting agent of agent and 0.2 part stirs, and finally adds the water-based alpha-alcohol ketone derivative and 1 of 3 partsWater-based α-amido ketone derivatives high-speed stirred of part, is fully mixed with into premixed liquid; Premixed liquid is ground toParticle diameter < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 7
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 40 parts and the titanate coupling agent of 0.5 part, mixEvenly, then add the levelling agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the sterilization of 0.2 partThe pH adjusting agent of agent and 0.2 part stirs, and finally adds the water-based anthraquinone derivative hydrogen-abstraction light of 3 parts to drawSend out agent and reactive amines and press the mixture high-speed stirred of 1:1 combination, be fully mixed with into premixed liquid; By premixLiquid is ground to particle diameter < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 8
By weight, the isopropyl alcohol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 2 parts in isopropanol water solution, stir and make oversubscriptionPowder fully mixes, and slowly adds the cobalt blue ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 40 parts and the titanate coupling agent of 0.5 part, mixEvenly, then add the levelling agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the sterilization of 0.4 partThe pH adjusting agent of agent and 0.5 part stirs, and finally adds the water-based anthraquinone derivative hydrogen-abstraction light of 3 parts to drawSend out agent and reactive amines and press the mixture of 1:1 combination, be fully mixed with into premixed liquid; Premixed liquid is ground toParticle diameter < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
Embodiment 9
By weight, the ethylene glycol monobutyl ether of the isopropyl alcohol of 3 parts and 3 parts is added in the water of 25 parts, mixBecome the aqueous solution; Under high-speed stirred, to the polyacrylate hyper-dispersant that adds 20 parts in the aqueous solution, stirHyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirred is mixed with intoMill base; In the mill base of preparation, add the aqueous polyurethane acrylate of 60 parts and the titanate coupling agent of 5 parts,Mix, then add the levelling agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent, 0.8 part of 0.8 partThe pH adjusting agent of bactericide and 0.8 part stirs, finally add 4 parts water-based benzophenone derivates withWater-based alpha-alcohol ketone derivative is pressed the mixture high-speed stirred of 1:1 combination, is fully mixed with into premixed liquid;Premixed liquid is ground to particle diameter < 1 μ m, obtains water-based UV and solidify ceramic spraying ink.
Embodiment 10
By weight, the ethylene glycol of 2 parts is added in the water of 15 parts, be mixed into glycol water; At heightUnder speed stirs, to the polyacrylate hyper-dispersant that adds 15 parts in glycol water, stir and make oversubscriptionPowder fully mixes, and slowly adds the reddish brown ceramic pigment of 15 parts, and high-speed stirred is mixed with into mill base; ToIn the mill base of preparation, add the aqueous polyurethane acrylate of 40 parts and the silane coupler of 0.5 part, mix allEven, then add the levelling agent of 0.6 part, the defoamer of 0.6 part, the anti-settling agent of 0.6 part, the bactericide of 0.6 partAnd the pH adjusting agent of 0.6 part stirs, finally add the water-based alpha-alcohol ketone derivative of 1 part and 1 partWater-based α-amido ketone derivatives high-speed stirred, be fully mixed with into premixed liquid; Premixed liquid is ground to grainFootpath < 1 μ m, obtains water-based UV and solidifies ceramic spraying ink.
The above only further illustrates technology contents of the present invention with embodiment, so that reader is easierUnderstand, but do not represent that embodiments of the present invention only limit to this, any technology of doing according to the present invention extend orRecreation, is all subject to protection of the present invention.
Claims (10)
1. water-based UV solidifies a ceramic spraying ink, it is characterized in that, comprises following parts by weight of component:
2. water-based UV according to claim 1 solidifies ceramic spraying ink, it is characterized in that, described inWater-soluble light trigger be selected from the free radical type water-soluble light trigger of introducing hydrophily anionic group, orIntroduce the free radical type water-soluble light trigger of hydrophily cation group, or introduce hydrophily non-ionic groupFree radical type water-soluble light trigger.
3. water-based UV according to claim 2 solidifies ceramic spraying ink, it is characterized in that, described inHydrophily anionic group is sulfonic group or carboxyl; Described hydrophily cation group is quaternary ammonium salt.
4. water-based UV according to claim 2 solidifies ceramic spraying ink, it is characterized in that, described inHydrophily non-ionic group be alkoxyl hydroxyl.
5. water-based UV according to claim 1 solidifies ceramic spraying ink, it is characterized in that, described inCeramic pigment be selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
6. water-based UV according to claim 1 solidifies ceramic spraying ink, it is characterized in that, described inHyper-dispersant is selected from polyacrylate hyper-dispersant.
7. water-based UV according to claim 1 solidifies ceramic spraying ink, it is characterized in that, described inCoupling agent be selected from the one in silane coupler or titanate coupling agent.
8. water-based UV according to claim 1 solidifies ceramic spraying ink, it is characterized in that, described inCosolvent be selected from ethylene glycol, propane diols, isopropyl alcohol, glycol monoethyl ether, diethylene glycol monomethyl ether, secondAt least one in glycol monobutyl ether.
9. solidify ceramic spraying ink, its feature according to the water-based UV described in claim 1-8 any oneBe, also comprise 1～4 part of auxiliary agent, described auxiliary agent be selected from levelling agent, defoamer, anti-settling agent, bactericide orIn pH adjusting agent at least two kinds.
10. the preparation method that water-based UV solidifies ceramic spraying ink as claimed in claim 9, is characterized in that,Comprise the following steps:
A) prepare mill base: under high-speed stirred, in the mixed liquor of cosolvent and water, add hyper-dispersant, stirHyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirred is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add aqueous polyurethane acrylate and couplingAgent, mixes, then adds auxiliary agent to stir, and finally adds water-soluble light trigger high-speed stirred, fillsDivide and mix;
C) prepare ink: premixed liquid is ground to ceramic pigment particle diameter < 1 μ m, obtains water-based UV and solidify potteryPorcelain spraying ink.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1878814A (en) * | 2004-10-12 | 2006-12-13 | 德古萨公司 | Radiation curable modified, unsaturated, amorphous polyesters |
| CN1898296A (en) * | 2005-01-19 | 2007-01-17 | 德古萨公司 | Aqueous, unsaturated, amorphous polyesters that are modified so as to be radiation curable |
| CN102675967A (en) * | 2012-05-08 | 2012-09-19 | 中山大学 | Water-based ceramic three-dimensional pattern printing ink and preparation method thereof |
| CN103937326A (en) * | 2014-03-14 | 2014-07-23 | 鲁继烈 | Ceramic ink-jet printing ink and its use methods |
-
2016
- 2016-02-23 CN CN201610100158.5A patent/CN105585899A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1878814A (en) * | 2004-10-12 | 2006-12-13 | 德古萨公司 | Radiation curable modified, unsaturated, amorphous polyesters |
| CN1898296A (en) * | 2005-01-19 | 2007-01-17 | 德古萨公司 | Aqueous, unsaturated, amorphous polyesters that are modified so as to be radiation curable |
| CN102675967A (en) * | 2012-05-08 | 2012-09-19 | 中山大学 | Water-based ceramic three-dimensional pattern printing ink and preparation method thereof |
| CN103937326A (en) * | 2014-03-14 | 2014-07-23 | 鲁继烈 | Ceramic ink-jet printing ink and its use methods |
Non-Patent Citations (1)
| Title |
|---|
| 金养智: "《光固化材料性能及应用手册》", 31 July 2010, 化学工业出版社 * |
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