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CN105504972A - Waterborne UV cured ceramic printing ink and preparation method thereof - Google Patents

Waterborne UV cured ceramic printing ink and preparation method thereof Download PDF

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Publication number
CN105504972A
CN105504972A CN201610099215.2A CN201610099215A CN105504972A CN 105504972 A CN105504972 A CN 105504972A CN 201610099215 A CN201610099215 A CN 201610099215A CN 105504972 A CN105504972 A CN 105504972A
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water
borne
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ceramic ink
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谭海林
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses waterborne UV cured ceramic printing ink and a preparation method thereof and relates to the technical field of printing ink production. The waterborne UV cured ceramic printing ink comprises, by weight, 40-60 parts of waterborne acrylated acrylic oligomer, 1-4 parts of water-soluble photoinitiator, 15-35 parts of ceramic pigment, 3-8 parts of cosolvent, 2-20 parts of hyperdispersant, 0.5-5 parts of coupling agent and 8-25 parts of water. The waterborne UV cured ceramic printing ink combines the advantages of waterborne and conventional oily printing ink UV photocuring technology, and water is used to replace an active diluent in an oily UV curing system, so that cost is lowered, the problem that the active diluent is toxic and irritative is solved, and system viscosity is easier to adjust.

Description

A kind of water-borne UV-curing ceramic ink and preparation method thereof
Technical field
The present invention relates to Printing ink producing technical field, particularly relate to a kind of water-borne UV-curing ceramic ink and preparation method thereof.
Background technology
From China in 2009 introduces First ink-jet printer, ceramic ink jet printing technology starts fast development at home.Relative to traditional screen printing and roller printing ceramic printing technology, ceramic ink jet printing technology achieves contactless unsettled printing, and pattern and color no longer limit by equipment and process, and preparation flow is simple, obtained product image resolution ratio is high, and stereoscopic sensation is strong.But in prior art, the general ceramic ink in market is generally solvent type ink, need with adding a large amount of organic solvent, be unfavorable for the health of production operator and contaminate environment, along with the gradual perfection of reinforcement and the relevant laws and regulations gradually of people's environmental consciousness, research and development high-performance, low stain or even free of contamination ceramic printing technology are the inexorable trends of ceramic ink jet printing technology development.
Chinese patent application " a kind of UV photocuring ceramic ink jet ink and the method for ceramic surface printing thereof " discloses a kind of UV light-curable ink being applied to ceramic ink jet technical field.UV light-curable ink is by UV-irradiation, and exciting light initiator produces free radical, causes oligopolymer and reactive thinner crosslinking curing film forming.Traditional oiliness UV curing system has the advantages such as low or VOC free, solidification rate be fast, energy-conservation, but the many reactive thinner compositions in its formula have stronger hormesis to the skin of people and eyes, affect the healthy of operator, and price is more expensive.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of environment amenable water-borne UV-curing ceramic ink being applied to ceramic ink jet printing technology:
A kind of water-borne UV-curing ceramic ink, is characterized in that, comprise following parts by weight of component:
Preferably, described water-soluble light trigger is selected from the free radical type water-soluble light trigger introducing hydrophilic anions group, or introduce the free radical type water-soluble light trigger of hydrophilic cationic group, or introduce the free radical type water-soluble light trigger of hydrophilic nonionic group.
Further, described hydrophilic anions group is sulfonic group or carboxyl; Described hydrophilic cationic group is quaternary ammonium salt; Described hydrophilic nonionic group is alkoxyl group hydroxyl.
Preferably, water-soluble light trigger can be selected from one or more in the hydrogen-abstraction light initiation system that water-based benzoin derivatives, water-based acetophenone derivs, water-based alpha-alcohol ketone derivative, water-based α-cracking type light initiation system such as amido ketone derivatives, water-based acylphosphine oxide or water-based benzophenone derivates, water-based thia anthracyclinone derivatives, water-based anthraquinone derivative and reactive amines combine.
Preferably, described ceramic pigment is selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
Preferably, described hyper-dispersant is selected from polyacrylate(s) hyper-dispersant; Described coupling agent is selected from the one in silane coupling agent or titanate coupling agent; Described solubility promoter is selected from least one in ethylene glycol, propylene glycol, Virahol, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, ethylene glycol monobutyl ether.
Further, described water-borne UV-curing ceramic ink also comprises auxiliary agent 1 ~ 4 part, and described auxiliary agent is selected from least two kinds in flow agent, defoamer, anti-settling agent, sterilant or pH adjusting agent.
The preparation method of above-mentioned water-borne UV-curing ceramic ink, comprises the following steps:
A) prepare mill base: in the mixed solution of solubility promoter and water, add hyper-dispersant under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirring is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add water soluble acrylic acid esterification polyacrylic ester and coupling agent, mix, then add auxiliary agent and stir, finally add water-soluble light trigger high-speed stirring, fully mix;
C) ink is prepared: premixed liquid is ground to ceramic pigment particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Reactive thinner composition in tradition ink UV technology has stronger hormesis to the skin of people and eyes, affect the healthy of operator, and price is more expensive.Water-borne UV-curing ceramic ink of the present invention combines the advantage of water-based and conventional oil-based ink UV photocuring technology, and the reactive thinner in fortune water consumption substitution oiliness UV curing system, reduces cost, solve the problems such as reactive thinner is toxic, pungency.On the other hand, because reactive thinner has toxicity, its usage quantity must be controlled, when add-on is excessive, the problem of product retrogradation also compares to be difficult to resolve determines, and relative to reactive thinner, the viscosity of water is lower, viscosity and the mobility of ink can well being controlled, making ink show good performance when printing.
Embodiment
In order to more fully understand technology contents of the present invention, below in conjunction with specific embodiment technical scheme of the present invention being introduced further and illustrating.
Embodiment 1
By weight, the diethylene glycol monomethyl ether of 6 parts is added in the water of 12 parts, be mixed into the diethylene glycol monomethyl ether aqueous solution; In the aqueous solution of diethylene glycol monomethyl ether, add the polyacrylate(s) hyper-dispersant of 4 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the yellow ceramic pigment of praseodymium zirconium of 35 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the silane coupling agent of 0.7 part is added in the mill base of preparation, mix, add again the flow agent of 0.1 part, the defoamer of 0.1 part, the anti-settling agent of 0.1 part, the sterilant of 0.1 part and 0.5 part pH adjusting agent stir, the water-based acylphosphine oxide speed finally adding 1 part stirs, and is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains yellow water-borne UV-curing ceramic ink.
Embodiment 2
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into aqueous glycol solution; In aqueous glycol solution, add the polyacrylate(s) hyper-dispersant of 2 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt blue ceramic pigment of 15 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the titanate coupling agent of 0.5 part is added in the mill base of preparation, mix, add again the flow agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the sterilant of 0.2 part and 0.2 part pH adjusting agent stir, finally add the water-based alpha-alcohol ketone derivative of 1 part and the water-based α-amido ketone derivatives high-speed stirring of 1 part, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 3
By weight, the ethylene glycol monobutyl ether of the Virahol of 3 parts and 3 parts is added in the water of 25 parts, is mixed into the aqueous solution; In the aqueous solution, add the polyacrylate(s) hyper-dispersant of 20 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 60 parts and the titanate coupling agent of 5 parts is added in the mill base of preparation, mix, add again the flow agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent of 0.8 part, the sterilant of 0.8 part and 0.8 part pH adjusting agent stir, finally add the water-based benzophenone derivates high-speed stirring of 4 parts, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 4
By weight, the diethylene glycol monomethyl ether of 5 parts is added in the water of 15 parts, be mixed into the diethylene glycol monomethyl ether aqueous solution; In the diethylene glycol monomethyl ether aqueous solution, add the polyacrylate(s) hyper-dispersant of 8 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt blue ceramic pigment of 20 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 45 parts and the titanate coupling agent of 2 parts is added in the mill base of preparation, mix, add again the flow agent of 0.4 part, the defoamer of 0.4 part, the anti-settling agent of 0.1 part and 0.2 part sterilant stir, finally add the water-based acylphosphine oxide high-speed stirring of 2 parts, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 5
By weight, the Virahol of 6 parts is added in the water of 20 parts, be mixed into isopropanol water solution; In isopropanol water solution, add the polyacrylate(s) hyper-dispersant of 2 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt black ceramic pigment of 25 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 55 parts and the silane coupling agent of 4.5 parts is added in the mill base of preparation, mix, add again the flow agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the sterilant of 0.4 part and 0.5 part pH adjusting agent stir, finally add the water-based acetophenone derivs of 1.5 parts and the water-based thia anthracyclinone derivatives high-speed stirring of 1.5 parts, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 6
By weight, the Virahol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; In isopropanol water solution, add the polyacrylate(s) hyper-dispersant of 2 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt blue ceramic pigment of 15 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the titanate coupling agent of 0.5 part is added in the mill base of preparation, mix, add again the flow agent of 0.2 part, the defoamer of 0.1 part, the anti-settling agent of 0.3 part, the sterilant of 0.2 part and 0.2 part pH adjusting agent stir, finally add the water-based alpha-alcohol ketone derivative of 3 parts and the water-based α-amido ketone derivatives high-speed stirring of 1 part, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 7
By weight, the ethylene glycol of 3 parts is added in the water of 8 parts, be mixed into aqueous glycol solution; In aqueous glycol solution, add the polyacrylate(s) hyper-dispersant of 2 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt blue ceramic pigment of 15 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the titanate coupling agent of 0.5 part is added in the mill base of preparation, mix, add again the flow agent of 0.2 part, the defoamer of 0.2 part, the anti-settling agent of 0.2 part, the sterilant of 0.2 part and 0.2 part pH adjusting agent stir, finally add the mixture high-speed stirring that the water-based anthraquinone derivative hydrogen-capture-type light initiator of 3 parts and reactive amines combine by 1:1, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 8
By weight, the Virahol of 3 parts is added in the water of 8 parts, be mixed into isopropanol water solution; In isopropanol water solution, add the polyacrylate(s) hyper-dispersant of 2 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the cobalt blue ceramic pigment of 15 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the titanate coupling agent of 0.5 part is added in the mill base of preparation, mix, add again the flow agent of 0.1 part, the defoamer of 0.2 part, the anti-settling agent of 0.3 part, the sterilant of 0.4 part and 0.5 part pH adjusting agent stir, finally add the mixture that the water-based anthraquinone derivative hydrogen-capture-type light initiator of 3 parts and reactive amines combine by 1:1, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 9
By weight, the ethylene glycol monobutyl ether of the Virahol of 3 parts and 3 parts is added in the water of 25 parts, is mixed into the aqueous solution; In the aqueous solution, add the polyacrylate(s) hyper-dispersant of 20 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 35 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 60 parts and the titanate coupling agent of 5 parts is added in the mill base of preparation, mix, add again the flow agent of 0.8 part, the defoamer of 0.8 part, the anti-settling agent of 0.8 part, the sterilant of 0.8 part and 0.8 part pH adjusting agent stir, finally add the mixture high-speed stirring that the water-based benzophenone derivates of 4 parts and water-based alpha-alcohol ketone derivative combine by 1:1, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 10
By weight, the ethylene glycol of 2 parts is added in the water of 15 parts, be mixed into aqueous glycol solution; In aqueous glycol solution, add the polyacrylate(s) hyper-dispersant of 15 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 15 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 40 parts and the silane coupling agent of 0.5 part is added in the mill base of preparation, mix, add again the flow agent of 0.6 part, the defoamer of 0.6 part, the anti-settling agent of 0.6 part, the sterilant of 0.6 part and 0.6 part pH adjusting agent stir, finally add the water-based alpha-alcohol ketone derivative of 1 part and the water-based α-amido ketone derivatives high-speed stirring of 1 part, be fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
Embodiment 11
By weight, the ethylene glycol monobutyl ether of 4 parts is added in the water of 8 parts, be mixed into the ethylene glycol monobutyl ether aqueous solution; In the aqueous solution of ethylene glycol monobutyl ether, add the polyacrylate(s) hyper-dispersant of 3 parts under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add the reddish brown ceramic pigment of 25 parts, high-speed stirring is mixed with into mill base; The water soluble acrylic acid esterification polyacrylic ester of 60 parts and the silane coupling agent of 0.7 part is added in the mill base of preparation, mix, add again the flow agent of 0.1 part, the defoamer of 0.1 part, the anti-settling agent of 0.2 part, the sterilant of 0.4 part and 0.5 part pH adjusting agent stir, water-based α-amido the ketone derivatives finally adding 0.4 part is high, the water-based thia anthracyclinone derivatives of 0.5 part, the reactive amines high-speed stirring of 0.1 part, is fully mixed with into premixed liquid; Premixed liquid is ground to particle diameter < 1 μm, obtains brown water-borne UV-curing ceramic ink.
The above only further illustrates technology contents of the present invention with embodiment, so that reader is easier to understand, but does not represent embodiments of the present invention and is only limitted to this, and any technology done according to the present invention extends or recreation, all by protection of the present invention.

Claims (10)

1. a water-borne UV-curing ceramic ink, is characterized in that, comprises following parts by weight of component:
2. water-borne UV-curing ceramic ink according to claim 1, it is characterized in that, described water-soluble light trigger is selected from the free radical type water-soluble light trigger introducing hydrophilic anions group, or introduce the free radical type water-soluble light trigger of hydrophilic cationic group, or introduce the free radical type water-soluble light trigger of hydrophilic nonionic group.
3. water-borne UV-curing ceramic ink according to claim 2, is characterized in that, described hydrophilic anions group is sulfonic group or carboxyl; Described hydrophilic cationic group is quaternary ammonium salt.
4. water-borne UV-curing ceramic ink according to claim 2, is characterized in that, described hydrophilic nonionic group is alkoxyl group hydroxyl.
5. water-borne UV-curing ceramic ink according to claim 1, is characterized in that, described ceramic pigment is selected from the one in praseodymium zirconium Huang, cobalt blue, reddish brown and cobalt black.
6. water-borne UV-curing ceramic ink according to claim 1, is characterized in that, described hyper-dispersant is selected from polyacrylate(s) hyper-dispersant.
7. water-borne UV-curing ceramic ink according to claim 1, is characterized in that, described coupling agent is selected from the one in silane coupling agent or titanate coupling agent.
8. water-borne UV-curing ceramic ink according to claim 1, is characterized in that, described solubility promoter is selected from least one in ethylene glycol, propylene glycol, Virahol, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, ethylene glycol monobutyl ether.
9. the water-borne UV-curing ceramic ink according to claim 1-8 any one, is characterized in that, also comprise auxiliary agent 1 ~ 4 part, described auxiliary agent is selected from least two kinds in flow agent, defoamer, anti-settling agent, sterilant or pH adjusting agent.
10. the preparation method of water-borne UV-curing ceramic ink as claimed in claim 9, is characterized in that, comprise the following steps:
A) prepare mill base: in the mixed solution of solubility promoter and water, add hyper-dispersant under high velocity agitation, stir and hyper-dispersant is fully mixed, slowly add ceramic pigment, high-speed stirring is to mixing;
B) prepare premixed liquid: in the mill base that a) prepared by step, add water soluble acrylic acid esterification polyacrylic ester and coupling agent, mix, then add auxiliary agent and stir, finally add water-soluble light trigger high-speed stirring, fully mix;
C) ink is prepared: premixed liquid is ground to ceramic pigment particle diameter < 1 μm, obtains water-borne UV-curing ceramic ink.
CN201610099215.2A 2016-02-23 2016-02-23 Waterborne UV cured ceramic printing ink and preparation method thereof Pending CN105504972A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118222A (en) * 2016-08-29 2016-11-16 佛山市高明区海帝陶瓷原料有限公司 A kind of antibacterial aqueous UV photocuring ceramic ink jet ink and preparation method thereof
CN106189506A (en) * 2016-08-29 2016-12-07 佛山市高明区海帝陶瓷原料有限公司 A kind of radioprotective water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof
CN106189504A (en) * 2016-08-29 2016-12-07 佛山市高明区海帝陶瓷原料有限公司 A kind of environment-friendly type aqueous UV photocuring ceramic ink jet ink and preparation method thereof
CN106283670A (en) * 2016-08-29 2017-01-04 徐杭婷 A kind of preparation method of antibiotic finish of the fabric liquid
CN107502044A (en) * 2017-10-11 2017-12-22 广东至远实业集团有限公司 A kind of water-based UV ink of shelf-stable and preparation method thereof
CN111512452A (en) * 2017-10-17 2020-08-07 科迪华公司 Ink composition with high quantum dot concentration for display device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1878814A (en) * 2004-10-12 2006-12-13 德古萨公司 Radiation curable modified, unsaturated, amorphous polyesters
CN1898296A (en) * 2005-01-19 2007-01-17 德古萨公司 Aqueous, unsaturated, amorphous polyesters that are modified so as to be radiation curable
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN103937326A (en) * 2014-03-14 2014-07-23 鲁继烈 Ceramic ink-jet printing ink and its use methods

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1878814A (en) * 2004-10-12 2006-12-13 德古萨公司 Radiation curable modified, unsaturated, amorphous polyesters
CN1898296A (en) * 2005-01-19 2007-01-17 德古萨公司 Aqueous, unsaturated, amorphous polyesters that are modified so as to be radiation curable
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN103937326A (en) * 2014-03-14 2014-07-23 鲁继烈 Ceramic ink-jet printing ink and its use methods

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118222A (en) * 2016-08-29 2016-11-16 佛山市高明区海帝陶瓷原料有限公司 A kind of antibacterial aqueous UV photocuring ceramic ink jet ink and preparation method thereof
CN106189506A (en) * 2016-08-29 2016-12-07 佛山市高明区海帝陶瓷原料有限公司 A kind of radioprotective water-based ultraviolet (UV) curable ceramic ink jet ink and preparation method thereof
CN106189504A (en) * 2016-08-29 2016-12-07 佛山市高明区海帝陶瓷原料有限公司 A kind of environment-friendly type aqueous UV photocuring ceramic ink jet ink and preparation method thereof
CN106283670A (en) * 2016-08-29 2017-01-04 徐杭婷 A kind of preparation method of antibiotic finish of the fabric liquid
CN107502044A (en) * 2017-10-11 2017-12-22 广东至远实业集团有限公司 A kind of water-based UV ink of shelf-stable and preparation method thereof
CN111512452A (en) * 2017-10-17 2020-08-07 科迪华公司 Ink composition with high quantum dot concentration for display device
CN111512452B (en) * 2017-10-17 2023-11-21 科迪华公司 Ink composition with high quantum dot concentration for display devices

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