CN105557760A - Synergistic insecticidal composition containing propargite and tetranactin, and application thereof - Google Patents
Synergistic insecticidal composition containing propargite and tetranactin, and application thereof Download PDFInfo
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- CN105557760A CN105557760A CN201511022608.5A CN201511022608A CN105557760A CN 105557760 A CN105557760 A CN 105557760A CN 201511022608 A CN201511022608 A CN 201511022608A CN 105557760 A CN105557760 A CN 105557760A
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- tetranactin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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Abstract
The invention discloses a synergistic insecticidal composition containing propargite and tetranactin, and a use thereof. The c insecticidal composition adopts propargite and tetranactin as main effective components, wherein a weight ratio of propargite to tetranactin is 1:60-60:1. The composition can prevent and control various pests, has an obvious synergistic effect, enlarges the insecticidal spectrum, has high activity on diamondback moths, prodenia litura, rice hoppers, Chilo suppressalis and mites on fruit trees, tea leaves and flowers, and has the advantages of reduction of the pesticide consumption, reduction of the residual quantity of pesticides on crops, mitigation of the environment pollution, safety to humans and animals, good environmental compatibility, and difficult pesticide resistance of the pests. The composition can be processed to prepare a missible oil, an emulsion in water, a micro-emulsion, a suspension, a wettable pulvis or a water dispersible granule.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of be principle active component Pesticidal combination and the application thereof of propargite and tetranactin.
Background technology
Propargite (Propargite), molecular formula: C
19h
26o
4s, chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl propine-2-base sulfite.Structural formula is:
Propargite is broad spectrum activity, efficient, low toxicity miticide, has and tags and stomach poison function, without infiltration and systemic action.If to children mite with to become mite effective, ovicidal effect is poor.Can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn, soybean, spider mite kind insect on tomato and vegetables.
Tetranactin (tetranactin), tetranactin is by from the one large Fourth Ring lactone antibiotic extracted in streptomyces aureus (Streptomycesaureus) thalline, has stronger acaricidal activity, can kill adult, also can ovicidal; Low to person poultry toxicity, plant not easily produces poisoning; Not easily resistance is produced to responsive mite class; Do not pollute the environment; Can be used in combination with various insecticide, bactericide, but the young fruit period to cucumber, pears, brassicaceous vegetable easily produces poisoning.Be applicable to prevent and treat the mite class in apple, tea, flowers and other crops.
Containing the miticide kind of single component often existing defects in agrochemical damage acarid control: use is easily developed immunity to drugs continuously, it is narrow to kill mite spectrum, and can not provide comprehensive protection for crop, peasant's drug cost is high.Being combined in and can overcoming above-mentioned shortcoming to a certain extent to a certain extent by two kinds or various active component in the coming year.There is two kinds of synergistic effect or the combination mixture of two or more active component, can preventive effect be improved, reduce active ingredient ground dosage, cost-saving, slow down harmful mite resistance and to occur and can expanding prevention spectrum, play that many mites are double to be controlled, reduce the use cost of peasant.
Summary of the invention
The object of the invention is to for above-mentioned various problem, in order to overcome and delay pesticide resistance to existing agricultural chemicals, expand and kill mite spectrum, strengthen drug effect, reduce drug cost, thus provide a kind of Pesticidal combination preventing and treating various crop mite class disease.
A further object of the invention is to provide the purposes of this Pesticidal combination.
Measure of the present invention is realized by following measures.
Containing a Synergistic insecticidal compositions for propargite and tetranactin, this Synergistic insecticidal compositions is with propargite and tetranactin for principle active component, and wherein, the weight ratio of propargite and tetranactin is 1:60 ~ 60:1.
Described Pesticidal combination, wherein the more excellent weight ratio of propargite and tetranactin is 1:50 ~ 30:1.Preferably the weight ratio of propargite and tetranactin is 1:20 ~ 20:1 further, then the weight ratio of further preferably propargite and tetranactin is 1:1 ~ 10, and most preferably the weight ratio of propargite and tetranactin is 1:5 ~ 10.The weight ratio of propargite and tetranactin can also be 1:10,1:5,1:10,1:2,1:3,1:1.
Described Pesticidal combination, wherein the weight ratio of propargite and the shared preparations of tetranactin two kinds of active principles accumulation is 0.5% ~ 90%, preferably 1 ~ 60%.
Described Pesticidal combination, with propargite and tetranactin for principle active component (active component) and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.The formulation that can be processed into is missible oil, suspending agent, aqueous emulsion, microemulsion, pulvis, wetting powder, dispersible oil-suspending agent and water dispersible granules etc.Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other agriculturally known auxiliary material can be alone or and use.
The described Synergistic insecticidal compositions containing propargite and tetranactin is applied in the insecticide for the preparation of the mite pest prevented and treated on Lepidoptera, Homoptera and fruit tree, flowers, tea tree.Described lepidoptera pest is prodenia litura, diamond-back moth, striped rice borer, and homoptera pest is rice fulgorid, and mite pest is citrus red mite, tetranychid, Panonychus citri, Tetranychus cinnabarinus.
Synergistic insecticidal compositions antagonism mite pest of the present invention has significant preventive effect, especially has good preventive effect for the easy various pests producing resistance such as tetranychid, two spotted spider mite, Panonychus citri; And suppress insect produce the pesticide resistance of unitary agent (propargite or tetranactin) and Lepidoptera, homoptera pest can be prevented and treated simultaneously.
Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1), compared with single dose, the control of said composition to insect has notable synergistic, and control efficiency significantly improves; (2) one medicines are controlled more, and a dispenser can prevent and treat multiple harmful mite simultaneously, reduce control recruitment cost; By the described miticide prepared containing the Synergistic insecticidal compositions of propargite and tetranactin prevent and treat mite roughly the same time, Lepidoptera, homoptera pest can be suppressed again, there is good preventive effect to rice fulgorid, beet armyworm and prodenia litura especially, reach the effect that a medicine is controlled more.(3) alternative high-toxic pesticide, and significantly reduce field dosage, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compared with propargite single dose, produce and use cost reduction; (6) insect is suppressed to strengthen the resistance of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods adopting indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1
Take propargite, tetranactin employing conventional formulation method is mixed with by different proportion the propargite tetranactin suspending agent that principle active component weight percentage is 30%.Concrete ratio is in table 1.
Adopt dip-slide method to measure propargite and tetranactin and composite sample thereof to the virulence of citrus red mite, often process repetition 3 times, every concentration process 30, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
: table 1 propargite, tetranactin and composite sample thereof are to the toxicity test of citrus red mite and co-toxicity coefficient
Embodiment 2
Take propargite, tetranactin employing conventional formulation method is mixed with by different proportion the propargite tetranactin missible oil that principle active component weight percentage is 30%.Concrete ratio is in table 2.
Test method employing leaf butterfly spray-on process (with reference to " NY/T1154.13-2008 farm-chemical indoor determination test rule insecticide. the 13rd part: leaf butterfly spray-on process ") measure propargite and tetranactin and composite sample thereof to the virulence of Tetranychus cinnabarinus, often process repetition 3 times, use LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 propargite, tetranactin and composite sample thereof are to the toxicity test of Tetranychus cinnabarinus and co-toxicity coefficient
Embodiment 3
Take 5g propargite, 20g tetranactin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite tetranactin missible oil that principle active component weight percentage is 25%.
Adopt embodiment 3 sample product to carry out the field trial of control in field citrus red mite, contrast medicament is 57% propargite EC and 16% tetranactin EC, and concrete consumption is in table 3, every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 3:
Table 3 example 3 sample is to the field test results of citrus red mite
Example 3 pairs of citrus red mites have fabulous quick-acting as can be seen from Table 3, and the lasting period is long, good at variable rate technology, are the outstanding medicaments of control citrus red mite.
Embodiment 4
Adopt embodiment 3 sample product to carry out the field trial of control in field Tetranychus cinnabarinus, contrast medicament is 57% propargite EC and 16% tetranactin EC, and concrete consumption is in table 4, and every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, and result of the test is in table 4:
Table 4 example 3 sample is to the field test results of Tetranychus cinnabarinus
Example 3 sample has fabulous effect to Tetranychus cinnabarinus as can be seen from Table 4, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing Tetranychus cinnabarinus.
Embodiment 5
Take propargite, tetranactin employing conventional formulation method is mixed with by different proportion the propargite tetranactin aqueous emulsion that principle active component weight percentage is 30%.Concrete ratio is in table 5.
Test method is first soaked method that leaf connects worm again and is measured propargite and tetranactin and composite sample thereof to the virulence of cabbage caterpillar, often processes repetition 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 5 propargite, tetranactin and composite sample thereof are to the toxicity test of cabbage caterpillar and co-toxicity coefficient
Embodiment 6
Take propargite, tetranactin employing conventional formulation method is mixed with by different proportion the propargite tetranactin aqueous emulsion that principle active component weight percentage is 30%.Concrete ratio is in table 6.
Test method feed adds malicious method and measures propargite and tetranactin and composite sample thereof to the virulence of cotten aphid, often processes repetition 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 6 propargite, tetranactin and composite sample thereof are to the toxicity test of cotten aphid and co-toxicity coefficient
Embodiment 7
Adopt embodiment 3 sample product to carry out the field trial of control in field cabbage caterpillar, contrast medicament is 57% propargite EC and 16% tetranactin EC, and concrete consumption is in table 7, and every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, and result of the test is in table 7:
Table 7 example 3 sample is to the field test results of cabbage caterpillar
Embodiment 8
Adopt embodiment 3 sample product to carry out the field trial of control in field cotton aphid, contrast medicament is 57% propargite EC and 16% tetranactin EC, and concrete consumption is in table 8, and every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, and result of the test is in table 8:
Table 8 example 3 sample is to the field test results of cotten aphid
Embodiment 9:
Take 0.2g propargite, 20g tetranactin, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, forms the propargite tetranactin wetting powder that principle active component weight percentage is 20.2%.
Embodiment 10:
Take 78g propargite, 0.5g tetranactin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene adds to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite tetranactin missible oil that principle active component weight percentage is 78.5%.
Embodiment 11:
Take 2g propargite, 10g tetranactin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, the dimethylbenzene of n-butanol 3g, 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other supply 100g with water, n-butanol and water-soluble solution form aqueous phase, and all the other component mix and blends form oil phase, slowly aqueous phase is added in oil phase and go under clipper effect, and continue shearing 10 ~ 30 minutes, form the propargite tetranactin aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 12:
Take 10g propargite, 30g tetranactin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other complement to 100g with water, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add water and stir and form clear solution, be the propargite tetranactin microemulsion that principle active component weight percentage is 40%.
Embodiment 13:
Take 4g propargite, 4g tetranactin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite tetranactin missible oil that principle active component weight percentage is 8%.
Embodiment 14:
Take 3g propargite, 30g tetranactin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g with water, forms the propargite tetranactin suspending agent that principle active component weight percentage is 33% under the effect of sand mill.
Embodiment 15:
Take 5g propargite, 60g tetranactin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite tetranactin missible oil that principle active component weight percentage is 65%.
Embodiment 16:
Take 45g propargite, 5g tetranactin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, forms by the method for water dispersion granule the propargite tetranactin water dispersible granules that principle active component weight percentage is 50% by above raw material.
Embodiment 17:
Take 25g propargite, 25g tetranactin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite tetranactin missible oil that principle active component weight percentage is 50%.
Claims (10)
1., containing a Synergistic insecticidal compositions for propargite and tetranactin, it is characterized in that this Synergistic insecticidal compositions with propargite and tetranactin for principle active component, wherein, the weight ratio of propargite and tetranactin is 1:60 ~ 60:1.
2. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 1, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of tetranactin are 1:50 ~ 30:1.
3. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 2, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of tetranactin are 1:20 ~ 20:1.
4. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 3, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of tetranactin are 1:1 ~ 10.
5. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 4, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of tetranactin are 1:5 ~ 10.
6. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 1, both its feature propargite and the tetranactin weight percentage in this Synergistic insecticidal compositions is 0.5% ~ 90%.
7. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 1, is characterized in that with propargite and tetranactin for principle active component and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.
8. the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 7, is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent, water dispersion granule.
9. the application of the Synergistic insecticidal compositions containing propargite and tetranactin according to claim 1 in the insecticide for the preparation of the mite pest prevented and treated on Lepidoptera, Homoptera and fruit tree, flowers, tea tree.
10. application according to claim 9, it is characterized in that described lepidoptera pest is prodenia litura, diamond-back moth, striped rice borer, homoptera pest is rice fulgorid, and mite pest is citrus red mite, tetranychid, Panonychus citri, Tetranychus cinnabarinus.
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| CN201511022608.5A CN105557760B (en) | 2015-12-29 | 2015-12-29 | A kind of Synergistic insecticidal compositions and its application containing propargite and tetranactin |
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| CN201511022608.5A CN105557760B (en) | 2015-12-29 | 2015-12-29 | A kind of Synergistic insecticidal compositions and its application containing propargite and tetranactin |
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| CN105557760A true CN105557760A (en) | 2016-05-11 |
| CN105557760B CN105557760B (en) | 2018-07-17 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112514919A (en) * | 2020-11-26 | 2021-03-19 | 赞皇县龙堂苑农业科技有限责任公司 | Compound agent of verticillium lecanii and propargite |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3272854A (en) * | 1963-07-18 | 1966-09-13 | Us Rubber Co | Cycloaliphatic sulfite esters |
| US6297374B1 (en) * | 1985-02-04 | 2001-10-02 | Nihon Bayer Agrochem K.K. | Nitroimino-nitromethylene—azole or-azine heterocyclic compounds, insecticidal compositions containing them, and insecticidal methods of using them |
| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
-
2015
- 2015-12-29 CN CN201511022608.5A patent/CN105557760B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3272854A (en) * | 1963-07-18 | 1966-09-13 | Us Rubber Co | Cycloaliphatic sulfite esters |
| US6297374B1 (en) * | 1985-02-04 | 2001-10-02 | Nihon Bayer Agrochem K.K. | Nitroimino-nitromethylene—azole or-azine heterocyclic compounds, insecticidal compositions containing them, and insecticidal methods of using them |
| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112514919A (en) * | 2020-11-26 | 2021-03-19 | 赞皇县龙堂苑农业科技有限责任公司 | Compound agent of verticillium lecanii and propargite |
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| CN105557760B (en) | 2018-07-17 |
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