CN105941459A - Synergistic insecticidal composition containing cyantraniliprole and clothianidin and application thereof - Google Patents
Synergistic insecticidal composition containing cyantraniliprole and clothianidin and application thereof Download PDFInfo
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- CN105941459A CN105941459A CN201610451336.9A CN201610451336A CN105941459A CN 105941459 A CN105941459 A CN 105941459A CN 201610451336 A CN201610451336 A CN 201610451336A CN 105941459 A CN105941459 A CN 105941459A
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- clothianidin
- insect amide
- cyanogen insect
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
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- General Health & Medical Sciences (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a synergistic insecticidal composition containing cyantraniliprole and clothianidin and application thereof. In the insecticidal composition, cyantraniliprole and clothianidin are main active ingredients, wherein the weight ratio of the cyantraniliprole to clothianidin is (1-60):(1-60). The insecticidal composition has the functions of expanding the control spectrum and improving effect and can reduce the application cost and can be prepared into missible oil, wettable powder, microemulsion, emulsion in water, suspending agent and water dispersible granules and is used for controlling multiple pests of lepidoptera, hemiptera, hymenoptera, coleoptera and the like.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with bromine cyanogen insect amide and clothianidin the Insecticidal combinations as principle active component
Thing and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is that E.I.Du Pont Company's second filial generation ryania that success is developed after chlorantraniliprole is subject to
Body inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has more efficient, is suitable for
Crop is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Clothianidin (Clothianidin), chemical name: E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-nitroguanidine；
Chemical molecular formula: C6H8ClN5O2S；Structural formula:
Clothianidin belongs to anabasine insecticide, is that a kind of activity is high, has interior absorption, tags and the broad spectrum disinfestation of stomach poison function
Agent.Shi Wu field company after Nitenpyram (nitenpyram), another nicotinic insecticide of discovery, belong to the second filial generation.Make
It it is the nAChR combining and being positioned at neural post-synapse by mechanism.It is applicable to foliar spray, soil treatment effect, table
Revealing preferable quick-acting, the lasting period was at about 7 days.It is mainly used in Oryza sativa L., vegetable, fruit tree and other crop, preventing and treating half
Wing mesh, coleoptera, Diptera and some lepidoptera pest.
Insecticide variety containing single component often existing defects in pesticide Pest control: use is easily developed immunity to drugs continuously,
Insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of clothianidin, said composition can be used for preventing
Agricultural pests are planted by Zhiduo County, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, beet armyworm
With Brown Planthopper etc., a drug can be reached and prevent and treat the effect of dissimilar insect.
The Synergistic insecticidal compositions that it is a further object of the present invention to provide brominated cyanogen insect amide and clothianidin prevents and treats resistance squama wing in preparation
Application in the insecticidal materials of one or more insects in mesh, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of clothianidin, it with bromine cyanogen insect amide with clothianidin for mainly effectively becoming
Point, wherein, the weight ratio of bromine cyanogen insect amide and clothianidin is 1～60:1～60.Preferably bromine cyanogen insect amide and the weight ratio of clothianidin
Being 1～40:1～40, the weight ratio of further preferred bromine cyanogen insect amide and clothianidin is 1～30:1～30.Most preferably bromine cyanogen worm acyl
The weight ratio of amine and clothianidin is 10:1.
In some preferred technical schemes: bromine cyanogen insect amide and clothianidin can 1:30,1:29,1:28,1:27,1:26,
1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、
1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、
10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、
25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、
These ratios of 4:5 select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of clothianidin of the present invention, bromine cyanogen insect amide and both clothianidins are in this increasing
Weight percentage in effect Pesticidal combination is 2%～80%, and preferably 8%～60%, optimum is 20%～40%.
The Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and clothianidin is with bromine cyanogen insect amide and clothianidin as principle active component
(active component) and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.The preferred powder of dosage form, wettable
Property powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene blocked
Compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, anti-
Freeze agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or also
With.
Above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of clothianidin preparation preventing and treating Lepidoptera, Semiptera, Hymenoptera or
Application in the insecticidal materials of one or more insects in coleoptera.Especially at preparation preventing and treating planthopper or the insecticidal materials of snout moths larva
In application effect notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll worm, Radix Betae
Noctuid, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect；And suppress insect to unitary agent (bromine
Cyanogen insect amide or clothianidin) Drug resistance produce and simultaneously can prevent and treat Hemipteran pest such as Brown Planthopper etc..
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and clothianidin prevent and treat resistance Lepidoptera,
While Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and beet armyworm
There is good preventive effect, reach the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, said composition
Insect has notable synergistic, hence it is evident that improve prevention effect；(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, subtracts
Preventing and treating recruitment cost less；(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and agriculture
Medicine remains；(4) have concurrently quick-acting and long-acting；(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces；(6) press down
The resistance of pesticide is strengthened by insect processed.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor bioassay,
Co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage；On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g clothianidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two
Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight
Percentage composition is the bromine cyanogen insect amide clothianidin cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g clothianidin, lignin 10g, Negel 2g, add to 100g with Kaolin,
Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide thiophene that principle active component weight percentage is 82%
Worm amine wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g clothianidin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the bromine cyanogen insect amide clothianidin cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g clothianidin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g with water, n-butyl alcohol and water-soluble
Solving and form aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase under cutter effect, and
Continue to shear 10～30 minutes, form the bromine cyanogen insect amide clothianidin water and milk that principle active component weight percentage is 62%
Agent.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g clothianidin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and former medicine, solvent, emulsifying agent, cosolvent are mixed
Close stirring and form homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight
Percentage composition is the bromine cyanogen insect amide clothianidin microemulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g clothianidin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two
Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide clothianidin cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g clothianidin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulfate thereof
4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at sand mill
Effect lower form the bromine cyanogen insect amide clothianidin suspending agent that principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g clothianidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide clothianidin cream of 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g clothianidin, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component
Weight percentage is the bromine cyanogen insect amide clothianidin water dispersible granules of 15%.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g clothianidin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide clothianidin cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g clothianidin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two
Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight
Percentage composition is the bromine cyanogen insect amide clothianidin cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, clothianidin employing conventional formulation method is configured to principle active component weight percent by different proportion and contains
Amount is the bromine cyanogen insect amide clothianidin cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure bromine cyanogen insect amide and clothianidin and the compounding sample virulence to cotton boll worm thereof, often process weight
Multiple 3 times, every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, clothianidin and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and clothianidin mixture, cotton boll worm are had potentiation, listed joining in table
Being both greater than 120 than co-toxicity coefficient, therefore bromine cyanogen insect amide and clothianidin mixture have significant synergies.
Weigh bromine cyanogen insect amide, clothianidin employing conventional formulation method is configured to principle active component weight percent by different proportion and contains
Amount is the bromine cyanogen insect amide clothianidin cream of 30%.Concrete ratio is shown in Table 2.
Use rice-stem dipping method to measure bromine cyanogen insect amide and clothianidin and the compounding sample virulence to Brown Planthopper thereof, often process weight
Multiple 3 times, use LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, clothianidin and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation after bromine cyanogen insect amide and clothianidin mixture to Brown Planthopper, listed joining in table
All being much larger than 120 than co-toxicity coefficient, therefore bromine cyanogen insect amide and clothianidin mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen insect amide
EC and 15% clothianidin EC, concrete consumption is shown in Table 3, and every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days results,
Result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, good at variable rate technology
Good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: with clothianidin built agent, cotton boll worm and Brown Planthopper are had by bromine cyanogen insect amide
Significantly synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll worm insecticidal effect equally
It is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (9)
1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for clothianidin, is characterized in that this Synergistic insecticidal compositions is with bromine cyanogen worm
Amide and clothianidin are principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and clothianidin is 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of clothianidin, is characterized in that this parasite killing group
The active ingredient bromine cyanogen insect amide of compound and the weight ratio of clothianidin are 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of clothianidin, is characterized in that this parasite killing group
The active ingredient bromine cyanogen insect amide of compound and the weight ratio of clothianidin are 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of clothianidin, is characterized in that bromine cyanogen worm acyl
Amine and both clothianidins weight percentage in this Synergistic insecticidal compositions are 2%～80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of clothianidin, is characterized in that bromine cyanogen worm acyl
Amine and both clothianidins weight percentage in this Synergistic insecticidal compositions are 8%～60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of clothianidin, is characterized in that this potentiation is killed
With bromine cyanogen insect amide, as principle active component and insecticides adjuvant, excipient are configured on pesticide appointing of permission to worm compositions with clothianidin
A kind of dosage form of meaning.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of clothianidin, is characterized in that described dosage form
It is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and clothianidin is at preparation preventing and treating Lepidoptera, half wing
Application in the insecticidal materials of one or more insects in mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and clothianidin is in system
Application in the insecticidal materials of standby preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN118160734A (en) * | 2022-12-08 | 2024-06-11 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing cyantraniliprole and neonicotinoid insecticide |
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| CN103283764A (en) * | 2012-02-24 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole containing insecticidal composition |
| CN104798805A (en) * | 2015-03-26 | 2015-07-29 | 河北博嘉农业有限公司 | Insecticide composition for corn |
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2016
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Patent Citations (5)
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| JP2013107861A (en) * | 2011-11-24 | 2013-06-06 | Sumitomo Chemical Co Ltd | Pest controlling composition, and method for controlling pest |
| CN103283764A (en) * | 2012-02-24 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole containing insecticidal composition |
| CN102626071A (en) * | 2012-03-29 | 2012-08-08 | 广西田园生化股份有限公司 | Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides |
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| CN118160734A (en) * | 2022-12-08 | 2024-06-11 | 江苏扬农化工股份有限公司 | Sanitary insecticidal composition containing cyantraniliprole and neonicotinoid insecticide |
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