CN105494344A - Synergistic insecticidal composition containing propargite and spinosad and application thereof - Google Patents
Synergistic insecticidal composition containing propargite and spinosad and application thereof Download PDFInfo
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- CN105494344A CN105494344A CN201511019620.0A CN201511019620A CN105494344A CN 105494344 A CN105494344 A CN 105494344A CN 201511019620 A CN201511019620 A CN 201511019620A CN 105494344 A CN105494344 A CN 105494344A
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- propargite
- multiple killing
- killing teichomycin
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- insecticidal compositions
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a synergistic insecticidal composition containing propargite and spinosad and application thereof. The insecticidal composition takes the propargite and the spinosad as main effective components, wherein the weight ratio of the propargite to the spinosad is (1:60) to (60:1). The composition provided by the invention can be used for preventing and controlling a plurality of types of injurious insects and has a remarkable synergistic effect; an insecticidal spectrum is expanded; the synergistic insecticidal composition has relatively high activity on a plurality of types of lepidoptera, diptera and thysanoptera injurious insects on rice, wheat, cotton, fruit trees and vegetables; the dosage of a pesticide is reduced and the residual amount of the pesticide on crops is reduced so that the environmental pollution is alleviated; the synergistic insecticidal composition is safe to human and livestock and has good environment compatibility; and the injurious insects do not easily have pesticide resistance. The composition can be prepared into missible oil, emulsion in water, micro-emulsion, a suspending agent, wettable powder or water dispersible granules.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of be principle active component Pesticidal combination and the application thereof of propargite and multiple killing teichomycin.
Background technology
Propargite (Propargite), molecular formula: C
19h
26o
4s, chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl propine-2-base sulfite.Structural formula is:
Propargite is broad spectrum activity, efficient, low toxicity miticide, has and tags and stomach poison function, without infiltration and systemic action.If to children mite with to become mite effective, ovicidal effect is poor.Can effectively preventing and treating apple-tree, cotton, cucumber, grape, corn, soybean, spider mite kind insect on tomato and vegetables.
Multiple killing teichomycin (Spinosad), structural formula:
It is a kind of macrolides Nuisanceless high-efficient biological insecticides extracted in sugared many born of the same parents bacterium (Saccharopolysporaspinosa) zymotic fluid of thorn that multiple killing teichomycin has another name called pleocidin (Spinosad).It has stronger interior suction, tags and stomach poison function, and its mode of action is novel, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Can effectively preventing Lepidoptera, diptera and Thysanoptera, also well can prevent and treat in coleoptera and orthoptera that some takes food the pest species of blade in a large number, poor to the control efficiency of sucking pest and mite class, therefore can use composite with mite class.
Containing the insecticide variety of single component often existing defects in agricultural chemicals control of insect: use is easily developed immunity to drugs continuously, and insecticidal spectrum is narrow, and can not provide comprehensive protection for crop, peasant's drug cost is high.Being combined in and can overcoming above-mentioned shortcoming to a certain extent to a certain extent by two kinds or various active component in the coming year.There is two kinds of synergistic effect or the combination mixture of two or more active component, can preventive effect be improved, reduce active ingredient ground dosage, cost-saving, slow down pest resistance and to occur and can expanding prevention spectrum, play that many worms are double to be controlled, reduce the use cost of peasant.
Summary of the invention
The object of the invention is to for above-mentioned various problem, in order to overcome and delay pesticide resistance to existing agricultural chemicals, expand insecticidal spectrum, strengthen drug effect, reduce drug cost, thus provide a kind of prevent and treat various crop Lepidoptera, diptera, thrips and the insect pest of mite class Pesticidal combination.
A further object of the invention is to provide the purposes of this Pesticidal combination.
Measure of the present invention is realized by following measures.
Containing a Synergistic insecticidal compositions for propargite and multiple killing teichomycin, this Synergistic insecticidal compositions is with propargite and multiple killing teichomycin for principle active component, and wherein, the weight ratio of propargite and multiple killing teichomycin is 1:60 ~ 60:1.
Described Pesticidal combination, wherein the more excellent weight ratio of propargite and multiple killing teichomycin is 1:50 ~ 30:1.Preferably the weight ratio of propargite and multiple killing teichomycin is 1:20 ~ 20:1 further, then the weight ratio of further preferably propargite and multiple killing teichomycin is 1:1 ~ 10, and most preferably the weight ratio of propargite and multiple killing teichomycin is 1:5 ~ 10.The weight ratio of propargite and multiple killing teichomycin can also be 1:10,1:5,1:10,1:2,1:3,1:1.
Described Pesticidal combination, wherein the weight ratio of propargite and the shared preparations of multiple killing teichomycin two kinds of active principles accumulation is 0.5% ~ 90%, preferably 1 ~ 60%.
Described Pesticidal combination, with propargite and multiple killing teichomycin for principle active component (active component) and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.The formulation that can be processed into is missible oil, suspending agent, aqueous emulsion, microemulsion, pulvis, wetting powder, dispersible oil-suspending agent and water dispersible granules etc.Described auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other agriculturally known auxiliary material can be alone or and use.
The above-mentioned Synergistic insecticidal compositions containing propargite and multiple killing teichomycin is applied in for the preparation of the insecticide preventing and treating Lepidoptera, diptera and Thysanoptera and mite class on paddy rice, wheat, cotton, fruit tree, vegetables, tea tree.This insecticide is used in particular for control diamond-back moth, beet armyworm, two spotted spider mite, tetranychid, Panonychus citri.
Synergistic insecticidal compositions antagonism mite pest of the present invention has significant preventive effect, especially has good preventive effect for the easy various pests producing resistance such as tetranychid, two spotted spider mite, Panonychus citri; And suppress insect produce the pesticide resistance of unitary agent (propargite or multiple killing teichomycin) and can diamond-back moth etc. be prevented and treated simultaneously.
Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1), compared with single dose, the control of said composition to insect has notable synergistic, and control efficiency significantly improves; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously, reduce control recruitment cost; By the described insecticidal materials prepared containing the Synergistic insecticidal compositions of propargite and multiple killing teichomycin prevent and treat mite roughly the same time, can lepidoptera pest be prevented and treated again, have good preventive effect to diamond-back moth, beet armyworm especially, reach the effect that a medicine is controlled more.(3) alternative high-toxic pesticide, and significantly reduce field dosage, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) compared with propargite single dose, produce and use cost reduction; (6) insect is suppressed to strengthen the resistance of agricultural chemicals.
Embodiment
Embodiments of the invention are the methods adopting indoor bioassay and field trial to combine.First by indoor bioassay, the co-toxicity coefficient after clear and definite two kinds of medicaments are composite by a certain percentage; On this basis, then carry out field trial.
Embodiment 1:
Propargite and multiple killing teichomycin different ratio co-toxicity
Take propargite, multiple killing teichomycin employing conventional formulation method is mixed with by different proportion the propargite multiple killing teichomycin suspending agent that principle active component weight percentage is 30%.Concrete ratio is in table 1.
Adopt dipping slide to measure propargite and multiple killing teichomycin and composite sample thereof to the virulence of citrus red mite, often process repetition 3 times, every concentration process 30, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
: table 1 propargite, multiple killing teichomycin and composite sample thereof are to the toxicity test of citrus red mite and co-toxicity coefficient
Embodiment 2:
Take propargite, multiple killing teichomycin employing conventional formulation method is mixed with by different proportion the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 30%.Concrete ratio is in table 2.
Test method is first soaked method that leaf connects worm again and is measured propargite and multiple killing teichomycin and composite sample thereof to the virulence of vegetables diamond-back moth, often processes repetition 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 2 propargite, multiple killing teichomycin and composite sample thereof are to the toxicity test of vegetables diamond-back moth and co-toxicity coefficient
Embodiment 3
Take propargite, multiple killing teichomycin employing conventional formulation method is mixed with by different proportion the propargite multiple killing teichomycin suspending agent that principle active component weight percentage is 30%.Concrete ratio is in table 3.
Test method is first soaked method that leaf connects worm again and is measured propargite and multiple killing teichomycin and composite sample thereof to the virulence of wild cabbage Liriomyza, often processes repetition 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 3 propargite, multiple killing teichomycin and composite sample thereof are to the toxicity test of wild cabbage Liriomyza and co-toxicity coefficient
Embodiment 4
Take propargite, multiple killing teichomycin employing conventional formulation method is mixed with by different proportion the propargite spinosad aqueous emulsion that principle active component weight percentage is 30%.Concrete ratio is in table 4.
Test method feed adds malicious method and measures propargite and multiple killing teichomycin and composite sample thereof to the virulence of melon thrips, often processes repetition 3 times, uses LC
50value is pressed the abundant method of Sun Yun and is calculated co-toxicity coefficient:
Table 4 propargite, multiple killing teichomycin and composite sample thereof are to the toxicity test of melon thrips and co-toxicity coefficient
Embodiment 5:
Take 5g propargite, 20g multiple killing teichomycin, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 25%.
Adopt embodiment 5 sample product to carry out the field trial of control in field citrus red mite, contrast medicament is 57% propargite EC and 2.5% multiple killing teichomycin SC, and concrete consumption is in table 5, every mu of water consumption is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 5:
Table 5 example 5 sample is to the field test results of citrus red mite
Example 5 pairs of citrus red mites have fabulous quick-acting as can be seen from Table 5, and the lasting period is long, good at variable rate technology, are the outstanding medicaments of control citrus red mite.
Embodiment 6:
Adopt embodiment 5 sample product to carry out the field trial of control in field vegetables diamond-back moth, contrast medicament is 57% propargite EC and 2.5% multiple killing teichomycin SC, and concrete consumption is in table 6, every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 6:
Table 6 example 5 sample is to the field test results of vegetables diamond-back moth
Example 5 sample has fabulous effect to vegetables diamond-back moth as can be seen from Table 6, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing vegetables diamond-back moth.
Measure through indoor synergism test and show: all have significant synergistic insecticidal action by propargite and multiple killing teichomycin built agent to citrus red mite and vegetables diamond-back moth; Field control effectiveness test equally also shows that the insecticidal effect of all built agent of the present invention to citrus red mite and vegetables diamond-back moth is all significantly higher than the effect of corresponding single dose agricultural chemicals.
Embodiment 7
Adopt embodiment 5 sample product to carry out the field trial of control in field wild cabbage Liriomyza, contrast medicament is 57% propargite EC and 2.5% multiple killing teichomycin SC, and concrete consumption is in table 7, every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 7:
Table 7 example 5 sample is to the field test results of wild cabbage Liriomyza
Example 5 sample has fabulous effect to wild cabbage Liriomyza as can be seen from Table 7, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing wild cabbage Liriomyza.
Embodiment 8
Adopt embodiment 5 sample product to carry out the field trial of control in field melon thrips, contrast medicament is 57% propargite EC and 2.5% multiple killing teichomycin SC, and concrete consumption is in table 8, every mu of use water is 30kg, looks into 3 days after medicine, 7 days, 14 days, 28 days results, result of the test is in table 8:
Table 8 example 5 sample is to the field test results of melon thrips
Example 5 sample has fabulous effect to melon thrips as can be seen from Table 8, and the lasting period is long, good at variable rate technology, is the outstanding medicament preventing melon thrips.
Embodiment 9:
Take 0.2g propargite, 20g multiple killing teichomycin, lignin 10g, Negel 2g, add to 100g with kaolin, above raw material is mixed in micronizer, forms the propargite multiple killing teichomycin wetting powder that principle active component weight percentage is 20.2%.
Embodiment 10:
Take 78g propargite, 0.5g multiple killing teichomycin, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, dimethylbenzene adds to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 78.5%.
Embodiment 11:
Take 2g propargite, 10g multiple killing teichomycin, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, the dimethylbenzene of n-butanol 3g, 30g and the pyrrolidones of 20g, the xanthans of 0.1g, all the other supply 100g with water, n-butanol and water-soluble solution form aqueous phase, and all the other component mix and blends form oil phase, slowly aqueous phase is added in oil phase and go under clipper effect, and continue shearing 10 ~ 30 minutes, form the propargite spinosad aqueous emulsion that principle active component weight percentage is 12%.
Embodiment 12:
Take 10g propargite, 30g multiple killing teichomycin, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, the solvent xylene of 30g and the pyrrolidones of 15g, all the other complement to 100g with water, former medicine, solvent, emulsifier, cosolvent mix and blend form homogeneous phase transparent solution, then slowly add water and stir and form clear solution, be the propargite spinosad microemulsion that principle active component weight percentage is 40%.
Embodiment 13:
Take 4g propargite, 4g multiple killing teichomycin, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, dimethylbenzene to 100g.The method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 8%.
Embodiment 14:
Take 3g propargite, 30g multiple killing teichomycin, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supplies 100g with water, forms the propargite multiple killing teichomycin suspending agent that principle active component weight percentage is 33% under the effect of sand mill.
Embodiment 15:
Take 5g propargite, 60g multiple killing teichomycin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 65%.
Embodiment 16:
Take 45g propargite, 5g multiple killing teichomycin, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, kaolin 28g, forms by the method for water dispersion granule the propargite spinosad water dispersible granule that principle active component weight percentage is 50% by above raw material.
Embodiment 17:
Take 25g propargite, 25g multiple killing teichomycin, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene to 100g, the method above raw material being prepared routinely missible oil drops in mixing kettle and mixes, and forms the propargite multiple killing teichomycin missible oil that principle active component weight percentage is 50%.
Claims (10)
1., containing a Synergistic insecticidal compositions for propargite and multiple killing teichomycin, it is characterized in that this Synergistic insecticidal compositions with propargite and multiple killing teichomycin for principle active component, wherein, the weight ratio of propargite and multiple killing teichomycin is 1:60 ~ 60:1.
2. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 1, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of multiple killing teichomycin are 1:50 ~ 30:1.
3. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 2, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of multiple killing teichomycin are 1:20 ~ 20:1.
4. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 3, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of multiple killing teichomycin are 1:1 ~ 10.
5. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 4, is characterized in that the effective ingredient propargite of this Pesticidal combination and the weight ratio of multiple killing teichomycin are 1:5 ~ 10.
6. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 1, both its feature propargite and the multiple killing teichomycin weight percentage in this Synergistic insecticidal compositions is 0.5% ~ 90%.
7. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 1, is characterized in that with propargite and multiple killing teichomycin for principle active component and auxiliary agent and/or excipient are processed into any one formulation that agricultural chemicals allows.
8. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 7, is characterized in that described formulation is missible oil, wetting powder, microemulsion, aqueous emulsion, suspending agent, pulvis or water dispersion granule.
9. the Synergistic insecticidal compositions containing propargite and multiple killing teichomycin according to claim 1 is for the preparation of the application prevented and treated in the insecticide of Lepidoptera, diptera and Thysanoptera and mite class on paddy rice, wheat, cotton, fruit tree, vegetables, tea tree.
10. application according to claim 9, is characterized in that Synergistic insecticidal compositions containing propargite and multiple killing teichomycin is for the preparation of the application prevented and treated in the insecticide of diamond-back moth, beet armyworm, two spotted spider mite, tetranychid, Panonychus citri.
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| CN201511019620.0A CN105494344B (en) | 2015-12-29 | 2015-12-29 | A kind of Synergistic insecticidal compositions and its application containing propargite and multiple killing teichomycin |
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Citations (4)
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|---|---|---|---|---|
| US4522825A (en) * | 1982-04-01 | 1985-06-11 | Montedison S.P.A. | Acaricide compositions employing synergistic mixtures of 1-decyloxy-4-(7-oxa-4-octinyl)-oxy-benzene and propargite |
| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
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| CN101489388A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
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2015
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| US4522825A (en) * | 1982-04-01 | 1985-06-11 | Montedison S.P.A. | Acaricide compositions employing synergistic mixtures of 1-decyloxy-4-(7-oxa-4-octinyl)-oxy-benzene and propargite |
| CN1430890A (en) * | 2003-01-29 | 2003-07-23 | 徐建军 | Multiple preparation type pesticide for killing insects and acarids |
| CN101489388A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
| CN101248786A (en) * | 2008-01-26 | 2008-08-27 | 益阳市润慷宝化工有限公司 | Avermectin . Propargite emulsifiable concentrate and method of preparing the same |
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Effective date of registration: 20231214 Address after: Room 710-53, No.116 Suo Street, Jianye District, Nanjing City, Jiangsu Province, 210000 Patentee after: Jiangsu Dingyue Technology Co.,Ltd. Address before: 210002 705, Xingye building, 15 Hubu street, Qinhuai District, Nanjing City, Jiangsu Province Patentee before: Jiangsu Ouyue Biotechnology Co.,Ltd. |
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