CN105088405A - Mothproof down feather composite spinning material and preparation method thereof - Google Patents
Mothproof down feather composite spinning material and preparation method thereof Download PDFInfo
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- CN105088405A CN105088405A CN201510459659.8A CN201510459659A CN105088405A CN 105088405 A CN105088405 A CN 105088405A CN 201510459659 A CN201510459659 A CN 201510459659A CN 105088405 A CN105088405 A CN 105088405A
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- feather
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- mothproof
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- spinning material
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- 210000003746 feather Anatomy 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 title claims abstract description 33
- 238000009987 spinning Methods 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 239000004743 Polypropylene Substances 0.000 claims abstract description 13
- -1 polypropylene Polymers 0.000 claims abstract description 13
- 229920001155 polypropylene Polymers 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 7
- 244000144977 poultry Species 0.000 claims abstract description 7
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960000490 permethrin Drugs 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- 210000002268 wool Anatomy 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 230000001954 sterilising effect Effects 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 102000011782 Keratins Human genes 0.000 claims description 6
- 108010076876 Keratins Proteins 0.000 claims description 6
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- 229960000583 acetic acid Drugs 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000004332 deodorization Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000012362 glacial acetic acid Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 230000002269 spontaneous effect Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 229920001661 Chitosan Polymers 0.000 abstract description 4
- 241000934067 Acarus Species 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 230000002147 killing effect Effects 0.000 abstract 1
- 238000005517 mercerization Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000004753 textile Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003519 biomedical and dental material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a mothproof down feather composite spinning material and a preparation method thereof. The spinning material is characterized by comprising, by weight, 40-60 parts of poultry feathers, 14-17 parts of down feathers, 1-3 parts of silane coupling agent KH550, 1-2 parts of nano-silica, 1-2 parts of nano-silver, 14-20 parts of chitosan, 30-50 parts of polypropylene, 3-5 parts of mercerized wool fibers, 0.2-0.4 part of permethrin, 0.5-1 part of stearic acid and an appropriate amount of water. Under the interaction of the added mercerized wool fibers, permethrin and stearic acid, the antibacterial property, bactericidal property, mothproof property, acarus killing property and other properties of the spinning material are greatly improved, and the surface mercerization property of the spinning material is improved as well. The preparation process is simple, the material source is wide, and the prepared spinning material has excellent properties and great use value and promotion value.
Description
Technical field
The present invention relates to textile material technical field, be specifically related to a kind of mothproof eider down composite spinning material and preparation method thereof.
Background technology
In textile industry, only have Isotactic polypropylene can be used to produce textile fabric, this is because Isotactic polypropylene fiber has higher degree of crystallinity and the degree of orientation, regularity is better.Therefore Isotactic polypropylene fiber is widely used as sewing thread, bandage, textile bags and bio-medical material.But because Isotactic polypropylene fiber lacks dyeability, limit its application in textile garment field.Eider down is a kind of natural protein fibre material, except a small amount of for making warming packing material in clothes and bedding and in the composite as except reinforcing material, major part just simple processing process is used as feed or adopts the methods such as fermentation to degrade, and causes a large amount of wastes.When fiber made separately by eider down, fragility is large, tensile strength is low, is not suitable for making coat, is only suitable for being filled in inside clothes obtaining very strong warmth retention property, because eider down content in feather is very few, usually only account for 20 ~ 25%, use cost is too high, feather fiber is not utilized very well, very unfortunately.The present invention utilizes discarded feather to be degraded into keratin solution, then with the chitosan solution blend spinning of modification, compatibility is good, recycling Isotactic polypropylene fills feather fiber, reduce the consumption of feather, gain in weight, and improve the performance of the aspects such as the intensity of fiber, modulus, heat resistance, chemical resistance and anti-corrosive properties, develop novel weaving face fabric, facilitate society and expanding economy.
Summary of the invention
The object of this invention is to provide a kind of mothproof eider down composite spinning material and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the invention is to be realized by following technological means:
A kind of mothproof eider down composite spinning material and preparation method thereof, it is characterized in that, be made up of the raw material of following weight portion: poultry feather 40-60, eider down 14-17, Silane coupling agent KH550 1-3, nano silicon 1-2, Nano Silver 1-2, shitosan 14-20, polypropylene 30-50, mercerized wool fiber 3-5, Permethrin 0.2-0.4, stearic acid 0.5-1, water are appropriate;
A kind of mothproof eider down composite spinning material of the present invention and preparation method thereof, be made up of following concrete steps:
(1) poultry feather and feather stem are separated, use clear water rinsed clean respectively, dry, carry out processed, feather extruding is separated, and feather stem carries out torsion extruding, sterilizing and deodorization under 100-200 ° of C in high-pressure sterilizing pot is added to eider down mixing after again feather and feather stem being cut into mean size, after spontaneous combustion cooling, mixing feather material is placed in alcohol and soaks 4-6 hour, then be neutral post-drying with clear water washing surface, be ground into powder for subsequent use;
(2) Silane coupling agent KH550 appropriate isopropyl alcohol dissolving is placed in reaction vessel, add nano silicon, Nano Silver again, stirring and refluxing 1-3h under 70-90 ° of C, cooling, for subsequent use after suction filtration, washing, drying, again shitosan glacial acetic acid solution is dissolved and make the chitosan-acetic acid solution that content is 3%, then with after NaOH alkalization 2-3h, add above-mentioned mixture for subsequent use, 2-3h is reacted under 40-60 ° of C, cooling, filters, washs, for subsequent use after drying;
(3) material prepared by step (1) and step (2) is used equivalent dissolution with solvents respectively, makes keratin content in feather within the scope of 8-13%, then be mixed and made into composite spinning stoste, carry out after spinning short cut for subsequent use;
(4) polypropylene and all the other remaining material mixing are added to main feeding trough in double screw extruder, the short collodion silk of cutting step (3) obtained again adds at natural exhaust outlet, blending extrusion temperature section is 195 ° of C, 190 ° of C, 190 ° of C, 185 ° of C, 180 ° of C, 165 ° of C, 110 ° of C, obtain composite master batch, composite master batch is carried out spinning.
Advantage of the present invention is: the present invention utilizes discarded feather to carry out dehydration taste removal deodorizing degreasing, the keratin solution of suitable solubility is made by dissolution with solvents, and utilize nano silicon and Nano Silver modification of chitosan, shitosan is had excellent antibacterial, sterilization, the performance that antibacterial and uvioresistant etc. are excellent, the fabric that the present invention utilizes chitosan solution and keratin solution co-blended spinning to obtain has good hygroscopicity, antibiotic property, the features such as biodegradability, and the ABRASION RESISTANCE of material is enhanced again by adding polypropylene, tensile strength, the characteristic of the aspects such as weight, decrease the consumption of feather fiber, add the novelty teabag of feather, the mercerized wool fiber added, Permethrin and stearic acid three interact, facilitate the antibacterial of spinning material greatly, sterilization, mothproof, except characteristics such as mites, and improve the silkiness on spinning material surface, preparation technology of the present invention is simple, material source enriches, the spinning material excellent performance made, there is very strong use value and promotional value.
Detailed description of the invention
A kind of mothproof eider down composite spinning material and preparation method thereof, it is characterized in that, be made up of the raw material of following weight portion (kilogram): poultry feather 60, eider down 16, Silane coupling agent KH550 3, nano silicon 2, Nano Silver 1, shitosan 18, polypropylene 46, mercerized wool fiber 4, Permethrin 0.3, stearic acid 0.8, water are appropriate;
A kind of mothproof eider down composite spinning material of the present invention and preparation method thereof, be made up of following concrete steps:
(1) poultry feather and feather stem are separated, use clear water rinsed clean respectively, dry, carry out processed, feather extruding is separated, and feather stem carries out torsion extruding, sterilizing and deodorization under 150 ° of C in high-pressure sterilizing pot is added to eider down mixing after again feather and feather stem being cut into mean size, after spontaneous combustion cooling, mixing feather material is placed in alcohol to soak 6 hours, then is neutral post-drying with clear water washing surface, be ground into powder for subsequent use;
(2) Silane coupling agent KH550 appropriate isopropyl alcohol dissolving is placed in reaction vessel, add nano silicon, Nano Silver again, stirring and refluxing 3h under 80 ° of C, cooling, for subsequent use after suction filtration, washing, drying, again shitosan glacial acetic acid solution is dissolved and make the chitosan-acetic acid solution that content is 3%, then with after NaOH alkalization 2h, add above-mentioned mixture for subsequent use, 2h is reacted under 50 ° of C, cooling, filters, washs, for subsequent use after drying;
(3) material prepared by step (1) and step (2) is used equivalent dissolution with solvents respectively, makes keratin content in feather in 11% scope, then be mixed and made into composite spinning stoste, carry out after spinning short cut for subsequent use;
(4) polypropylene and all the other remaining material mixing are added to main feeding trough in double screw extruder, the short collodion silk of cutting step (3) obtained again adds at natural exhaust outlet, blending extrusion temperature section is 195 ° of C, 190 ° of C, 190 ° of C, 185 ° of C, 180 ° of C, 165 ° of C, 110 ° of C, obtain composite master batch, composite master batch is carried out spinning.
The eider down composite fibre performance indications parameter using the present invention to prepare is as follows:
Hydroscopicity (%): 12.7;
Regain (%): 4.3;
Extensibility (%): 28.2;
Tensile break strength (N): 5.4.
Claims (2)
1. mothproof eider down composite spinning material and preparation method thereof, it is characterized in that, be made up of the raw material of following weight portion: poultry feather 40-60, eider down 14-17, Silane coupling agent KH550 1-3, nano silicon 1-2, Nano Silver 1-2, shitosan 14-20, polypropylene 30-50, mercerized wool fiber 3-5, Permethrin 0.2-0.4, stearic acid 0.5-1, water are appropriate.
2. a kind of mothproof eider down composite spinning material and preparation method thereof according to claim 1, is characterized in that, be made up of following concrete steps:
(1) poultry feather and feather stem are separated, use clear water rinsed clean respectively, dry, carry out processed, feather extruding is separated, and feather stem carries out torsion extruding, sterilizing and deodorization under 100-200 ° of C in high-pressure sterilizing pot is added to eider down mixing after again feather and feather stem being cut into mean size, after spontaneous combustion cooling, mixing feather material is placed in alcohol and soaks 4-6 hour, then be neutral post-drying with clear water washing surface, be ground into powder for subsequent use;
(2) Silane coupling agent KH550 appropriate isopropyl alcohol dissolving is placed in reaction vessel, add nano silicon, Nano Silver again, stirring and refluxing 1-3h under 70-90 ° of C, cooling, for subsequent use after suction filtration, washing, drying, again shitosan glacial acetic acid solution is dissolved and make the chitosan-acetic acid solution that content is 3%, then with after NaOH alkalization 2-3h, add above-mentioned mixture for subsequent use, 2-3h is reacted under 40-60 ° of C, cooling, filters, washs, for subsequent use after drying;
(3) material prepared by step (1) and step (2) is used equivalent dissolution with solvents respectively, makes keratin content in feather within the scope of 8-13%, then be mixed and made into composite spinning stoste, carry out after spinning short cut for subsequent use;
(4) polypropylene and all the other remaining material mixing are added to main feeding trough in double screw extruder, the short collodion silk of cutting step (3) obtained again adds at natural exhaust outlet, blending extrusion temperature section is 195 ° of C, 190 ° of C, 190 ° of C, 185 ° of C, 180 ° of C, 165 ° of C, 110 ° of C, obtain composite master batch, composite master batch is carried out spinning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510459659.8A CN105088405A (en) | 2015-07-31 | 2015-07-31 | Mothproof down feather composite spinning material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510459659.8A CN105088405A (en) | 2015-07-31 | 2015-07-31 | Mothproof down feather composite spinning material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105088405A true CN105088405A (en) | 2015-11-25 |
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| CN201510459659.8A Pending CN105088405A (en) | 2015-07-31 | 2015-07-31 | Mothproof down feather composite spinning material and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435516A (en) * | 2002-12-12 | 2003-08-13 | 内蒙古鄂尔多斯羊绒集团有限责任公司 | Technique for processing regenerated keratin functional fibre |
| CN1912231A (en) * | 2006-08-25 | 2007-02-14 | 江苏欣隆羽绒有限公司 | Antibiotic down and its preparation method |
| CN101611938A (en) * | 2008-06-27 | 2009-12-30 | 凌颖 | A kind of antibacterial down feather and preparation method thereof |
| CN101912634A (en) * | 2010-08-06 | 2010-12-15 | 华南理工大学 | A kind of preparation method of antibacterial biological dressing containing nano-silver/nanometer silicon dioxide |
| CN104195664A (en) * | 2014-08-30 | 2014-12-10 | 安徽一隆羽绒有限公司 | Down feather composite fiber modified by polypropylene fiber and preparation method of down feather composite fiber |
| CN104264277A (en) * | 2014-09-09 | 2015-01-07 | 安徽省含山县富强羽绒制品有限公司 | Mothproof down feather composite fiber and preparation method thereof |
-
2015
- 2015-07-31 CN CN201510459659.8A patent/CN105088405A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435516A (en) * | 2002-12-12 | 2003-08-13 | 内蒙古鄂尔多斯羊绒集团有限责任公司 | Technique for processing regenerated keratin functional fibre |
| CN1912231A (en) * | 2006-08-25 | 2007-02-14 | 江苏欣隆羽绒有限公司 | Antibiotic down and its preparation method |
| CN101611938A (en) * | 2008-06-27 | 2009-12-30 | 凌颖 | A kind of antibacterial down feather and preparation method thereof |
| CN101912634A (en) * | 2010-08-06 | 2010-12-15 | 华南理工大学 | A kind of preparation method of antibacterial biological dressing containing nano-silver/nanometer silicon dioxide |
| CN104195664A (en) * | 2014-08-30 | 2014-12-10 | 安徽一隆羽绒有限公司 | Down feather composite fiber modified by polypropylene fiber and preparation method of down feather composite fiber |
| CN104264277A (en) * | 2014-09-09 | 2015-01-07 | 安徽省含山县富强羽绒制品有限公司 | Mothproof down feather composite fiber and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20151125 |