CN104982436A - Insecticidal composition containing niclosamide and neonicotinoid pesticide - Google Patents
Insecticidal composition containing niclosamide and neonicotinoid pesticide Download PDFInfo
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- CN104982436A CN104982436A CN201510416179.3A CN201510416179A CN104982436A CN 104982436 A CN104982436 A CN 104982436A CN 201510416179 A CN201510416179 A CN 201510416179A CN 104982436 A CN104982436 A CN 104982436A
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- China
- Prior art keywords
- niclosamide
- pesticide
- fertilizer
- insecticide
- sodium
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- RJMUSRYZPJIFPJ-UHFFFAOYSA-N niclosamide Chemical compound OC1=CC=C(Cl)C=C1C(=O)NC1=CC=C([N+]([O-])=O)C=C1Cl RJMUSRYZPJIFPJ-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229960001920 niclosamide Drugs 0.000 title claims abstract description 67
- 239000000575 pesticide Substances 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 230000000749 insecticidal effect Effects 0.000 title abstract description 10
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 claims abstract description 20
- 229940079888 nitenpyram Drugs 0.000 claims abstract description 20
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000005888 Clothianidin Substances 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 239000003337 fertilizer Substances 0.000 claims description 45
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 claims description 25
- 229930014345 anabasine Natural products 0.000 claims description 25
- 230000000361 pesticidal effect Effects 0.000 claims description 22
- 239000002917 insecticide Substances 0.000 claims description 19
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 claims description 18
- 239000004480 active ingredient Substances 0.000 claims description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000011573 trace mineral Substances 0.000 claims description 10
- 235000013619 trace mineral Nutrition 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 7
- -1 polyoxyethylene Polymers 0.000 claims description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 6
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 6
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 4
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- NVTRPRFAWJGJAJ-UHFFFAOYSA-L EDTA monocalcium salt Chemical compound [Ca+2].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O NVTRPRFAWJGJAJ-UHFFFAOYSA-L 0.000 claims description 3
- FGXXEEGTUFLZCQ-UHFFFAOYSA-N [Na].[Na].[Mn].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN Chemical compound [Na].[Na].[Mn].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.NCCN FGXXEEGTUFLZCQ-UHFFFAOYSA-N 0.000 claims description 3
- ZJKUNLIROZVUOJ-UHFFFAOYSA-N [Na].[Zn].C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.C(CN)N Chemical compound [Na].[Zn].C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.C(C)(=O)O.C(CN)N ZJKUNLIROZVUOJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 3
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 3
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- 235000015393 sodium molybdate Nutrition 0.000 claims description 3
- 239000011684 sodium molybdate Substances 0.000 claims description 3
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 3
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- ATSGLBOJGVTHHC-UHFFFAOYSA-N bis(ethane-1,2-diamine)copper(2+) Chemical compound [Cu+2].NCCN.NCCN ATSGLBOJGVTHHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 235000013877 carbamide Nutrition 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 2
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 2
- 235000019797 dipotassium phosphate Nutrition 0.000 claims description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000004021 humic acid Substances 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- 235000007079 manganese sulphate Nutrition 0.000 claims description 2
- 239000011702 manganese sulphate Substances 0.000 claims description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 239000001508 potassium citrate Substances 0.000 claims description 2
- 229960002635 potassium citrate Drugs 0.000 claims description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 2
- 235000011082 potassium citrates Nutrition 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- NEUOBESLMIKJSB-UHFFFAOYSA-J tetrasodium;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O NEUOBESLMIKJSB-UHFFFAOYSA-J 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 235000009529 zinc sulphate Nutrition 0.000 claims description 2
- 239000011686 zinc sulphate Substances 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 13
- 235000009566 rice Nutrition 0.000 abstract description 13
- 241000426497 Chilo suppressalis Species 0.000 abstract description 9
- 241001498622 Cixius wagneri Species 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 241000534460 Ampullaria Species 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000005941 Thiamethoxam Substances 0.000 abstract 1
- 230000003111 delayed effect Effects 0.000 abstract 1
- 230000012865 response to insecticide Effects 0.000 abstract 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 49
- 231100000419 toxicity Toxicity 0.000 description 34
- 230000001988 toxicity Effects 0.000 description 34
- 239000000843 powder Substances 0.000 description 24
- 238000012360 testing method Methods 0.000 description 16
- 230000002195 synergetic effect Effects 0.000 description 13
- 241000209094 Oryza Species 0.000 description 12
- 241000570011 Pomacea canaliculata Species 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 9
- 241001556089 Nilaparvata lugens Species 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 230000009471 action Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 5
- 241001414720 Cicadellidae Species 0.000 description 4
- 230000008485 antagonism Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 210000002784 stomach Anatomy 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- 241001124076 Aphididae Species 0.000 description 3
- 241000254173 Coleoptera Species 0.000 description 3
- 241000255925 Diptera Species 0.000 description 3
- 241001414989 Thysanoptera Species 0.000 description 3
- 239000000642 acaricide Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000000205 computational method Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000009615 deamination Effects 0.000 description 2
- 238000006481 deamination reaction Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229960002715 nicotine Drugs 0.000 description 2
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- FNRMMDCDHWCQTH-UHFFFAOYSA-N 2-chloropyridine;3-chloropyridine;4-chloropyridine Chemical compound ClC1=CC=NC=C1.ClC1=CC=CN=C1.ClC1=CC=CC=N1 FNRMMDCDHWCQTH-UHFFFAOYSA-N 0.000 description 1
- KLEYVGWAORGTIT-UHFFFAOYSA-N 2-chlorothiazole Chemical compound ClC1=NC=CS1 KLEYVGWAORGTIT-UHFFFAOYSA-N 0.000 description 1
- XYCDHXSQODHSLG-UHFFFAOYSA-N 4-chloro-2-[(2-chloro-4-nitrophenyl)carbamoyl]phenolate;2-hydroxyethylazanium Chemical compound NCCO.OC1=CC=C(Cl)C=C1C(=O)NC1=CC=C([N+]([O-])=O)C=C1Cl XYCDHXSQODHSLG-UHFFFAOYSA-N 0.000 description 1
- 241001600407 Aphis <genus> Species 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 1
- 241000754688 Cercaria Species 0.000 description 1
- 208000034657 Convalescence Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 241000565674 Oncomelania hupensis Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241001442514 Schistosomatidae Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 102000015296 acetylcholine-gated cation-selective channel activity proteins Human genes 0.000 description 1
- 108040006409 acetylcholine-gated cation-selective channel activity proteins Proteins 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 231100000194 ovacidal Toxicity 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention belongs to the field of pesticide application technologies, in particular to an insecticidal composition containing niclosamide and a neonicotinoid pesticide. The insecticidal composition is a binary compound which is compounded by taking the niclosamide and the neonicotinoid pesticide as effective components; the mass ratio of the niclosamide and the neonicotinoid pesticide is (1 to 50) to (50 to 1), and the neonicotinoid pesticide is any one of nitenpyram, clothianidin, thiamethoxam and dinotefuran. The insecticidal composition provided by the invention has the remarkable effects for controlling ampullaria gigas, plant hopper and chilo suppressalis of rice. The insecticidal composition has the advantages that the synergism is obvious, the pesticide dose is reduced, the controlling cost is lowered, the insecticide resistance is delayed and the environmental pollution is reduced.
Description
Technical field
The invention belongs to pesticides application technical field, relate to a kind of composition pesticide, specifically a kind of Pesticidal combination containing niclosamide and anabasine pesticide.
Background technology
Niclosamide ethanolamine salt (abbreviation niclosamide), also makes spiral shell kill, hundred spiral shells kills, niclosamide, are amides compound, be a kind of strong invertebrate poison, have stomach poison function, have strong killing action to spiral shell ovum, blood fluke cercaria etc.Effect is rapid, lasting medicine.Product has 50% and 70% wetting powder, and 25% missible oil, there is production in Sichuan Prov. Chemical Industry Research & Design Academy.Paddy rice Pomacea canaliculata can be prevented and treated, Killing Oncomelania Hupensis, agriculturally also can be used for preventing and treating slug.
Nitenpyram (nitenpyram), nicotimine class is another novel product that Japan develops after Imidacloprid, pyridine worm miaow.Have that remarkable interior absorption, osmosis, insecticidal spectrum are wide, safety is without poisoning.That control sucking pest is as the regeneration product of trialeurodes vaporariorum, aphid, pear sucker, leafhopper, thrips.
Clothianidin is a kind of insecticide in anabasine, is the novel pesticide of a class highly effective and safe, high selectivity, and its effect is similar with nAChR, have tag, stomach toxicity and systemic activity.To be mainly used on paddy rice, vegetables, fruit tree and other crops anti-ly eliminating aphis, leafhopper, thrips, the Semiptera such as plant hopper, coleoptera, diptera and some Lepidoptera class pest insecticide, have efficient, wide spectrum, consumption are few, toxicity is low, the drug effect lasting period long, to crop without poisoning, use safety and conventional pesticide without advantages such as cross resistances, having remarkable interior suction and osmosis, is the another kind of alternative high-toxic organic phosphorus agricultural chemicals.Its novel structure, special, performance is more excellent compared with traditional nicotinic insecticide, and likely become international large-scale insecticide variety.
Diacloden is a kind of second generation nicotinoids high-efficient low toxicity insecticide of brand new, has stomach toxicity, tags and systemic activity to insect, for foliar spray and soil root irrigation.Rapidly by interior suction after its dispenser, and be transmitted to each position of plant, to sucking pest as aphid, plant hopper, leafhopper, aleyrodid etc. have good preventive effect.
The nicotinic insecticide that MTI-446 (dinotefuran) is researched and developed for Mitsui company.The chemical constitution of itself and existing nicotinic insecticide is far from each other, and its tetrahydrofuran base instead of former chloro-pyridine base, chloro-thiazole base, not containing halogen.Meanwhile, also different with nicotine at aspect of performance, so current people are referred to as " furans nicotine ".This medicament has the features such as tag, strong, the quick-acting height of absorption in stomach toxicity and root, long 3-4 week lasting period (theoretical lasting effect 43 days), insecticidal spectrum are wide, and have excellent preventive effect to sucking insect, and namely show very high insecticidal activity at very low dosage.Be mainly used in the aphid in the various crop such as control wheat, paddy rice, cotton, vegetables, fruit tree, tobacco leaf, leafhopper, plant hopper, thrips, aleyrodid and resistant strain thereof, have efficiently coleoptera, diptera and Lepidoptera, diptera, beetle order and total wing order insect simultaneously, and have efficiently sanitary insect pests such as blattaria, termite, houseflies.
Being carried out by the pesticide active ingredient of the different mechanism of action composite is the one mode effectively efficiently developed pesticide new product at present and prevent and treat resistance damage by disease and insect.Different pesticide active ingredient carry out composite after, three kinds of type of action can be shown: summation action, synergistic effect and antagonism.Usually, only have by a large amount of tests just can learn different pesticide active ingredient composite after type of action.The Recompounded pesticide of screening tool synergistic effect, can significantly improve control efficiency, reduce Pesticide use amount, reduce cost accounting, and can also expanding prevention compose, delaying the generation of damage by disease and insect resistance, is one of important means of current integrated pest prevention and control.
Inventor is tested and field control effectiveness test by a large amount of indoor biometrics, and filter out the Pesticidal combination of niclosamide and anabasine pesticide, said composition has synergistic effect within the specific limits.
Up to now, the Pesticidal combination being active ingredient with niclosamide and anabasine pesticide, there is not yet relevant report at home and abroad.
Summary of the invention
The invention provides a kind of Pesticidal combination containing niclosamide and anabasine pesticide, the advantage that said composition tool improves control efficiency, expansion insecticidal spectrum, delaying drug resistance generation, minimizing pesticide dosage and reduces costs.
Technical scheme provided by the present invention is:
A kind of Pesticidal combination containing niclosamide and anabasine pesticide, described Pesticidal combination is that two yuan of carrying out for active ingredient with niclosamide and anabasine pesticide are composite, the mass ratio of described active ingredient niclosamide and anabasine pesticide is 1:50-50:1, and described anabasine pesticide is any one in Nitenpyram, clothianidin, Diacloden and MTI-446.
As preferably, described niclosamide and the Pesticidal combination of anabasine pesticide, the mass ratio of described active ingredient niclosamide and anabasine pesticide is 1:30-30:1.
Present invention also offers a kind of insecticide fertilizer, described insecticide fertilizer comprises following component by weight percentage: containing Pesticidal combination 0.1-50%, macroelement fertilizer 15-50%, trace element fertilizer 1-15%, auxiliary agent 3-15%, surfactant 3-15%, the adsorbent 0.5-2% of niclosamide and anabasine pesticide, carrier supplies 100%.
As preferably, described macroelement fertilizer is at least one in ammonium sulfate, ammonium chloride, ammonium dihydrogen phosphate (ADP), urea, potassium dihydrogen phosphate, potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate; Described trace element fertilizer is at least one in sodium molybdate, four water ammonium molybdates, zinc sulphate, manganese sulphate, copper sulphate, ferrous sulfate, boric acid, four water eight Boratexes, ethylenediamine tetra-acetic acid zinc sodium, calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or cupric ethylene diamine tetraacetate sodium.
As preferably, described auxiliary agent is at least one in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate or sodium butylnaphthalenesulfonate; Described surfactant is at least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene or naphthalenesulfonate formaldehyde condensation compound; Described adsorbent is white carbon.
As preferably, described carrier is at least one in kaolin, diatomite, nacrite or humic acid.
As preferably, the formulation of described insecticide fertilizer is granule or pulvis.
Pesticidal combination of the present invention and containing this Pesticidal combination medicine fertilizer have good control efficiency to various agricultural insects such as paddy rice Pomacea canaliculata, plant hopper, striped rice borer.
Compared with prior art, the invention has the beneficial effects as follows:
(1) Pesticidal combination of the present invention is after two kinds of active ingredients are composite, has obvious synergistic effect, improves control efficiency.
(2) between Pesticidal combination of the present invention two kinds of active ingredients without cross resistance, thus composite rear use can the producing and developing of delaying drug resistance.
(3) Pesticidal combination of the present invention can reduce the usage amount of agricultural chemicals, reduces cost accounting, reduces environmental pollution, thus alleviates the pressure to environment.
(4) insecticide fertilizer product preparation process of the present invention is simple, and condition is easily controlled, and is suitable for suitability for industrialized production.
Embodiment
The present invention is described in detail its beneficial effect in conjunction with specific embodiments.
One, indoor virulence test measures
(1) niclosamide and anabasine pesticide combine the indoor virulence test to paddy rice Pomacea canaliculata
1. experiment material: test medicine adopts 95% niclosamide, the former medicine of 95% Nitenpyram, the former medicine of 95% clothianidin, the former medicine of 95% Diacloden and the former medicine of 95% MTI-446; Examination worm is the Pomacea canaliculata taked from rice field.
2. test method: each single dose and Mixed Pharmacy arrange 5 different concentration respectively, often 3 repetitions are established in process, make blank with clear water (deamination water).
3. operating procedure: being poured into by 100mL liquid respectively in beaker and to be settled to 200mL, 3 bags, the spiral shell bag of 30 Pomacea canaliculatas put into by every beaker, and the liquid degree of depth exceeds spiral shell bag 2-3cm, establishes clear water (deamination water) to contrast simultaneously.After spiral shell bag immerses liquid, respectively take out 1 bag after 24h, 48h and 72h, dry after clear water is cleaned, with hammering method qualification Pomacea canaliculata death and survival number after 72h convalescence raises.
4. computational methods: analyze test data with DPS statistical analysis software, calculate the LC50 of each medicament, evaluate the ovicidal trait of each medicament.And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T1154.13-2008 miticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80< co-toxicity coefficient (CTC) <120 shows as summation action.
5. result of the test (referring to table 1-3)
Table 1 niclosamide and Nitenpyram are to the indoor joint toxicity measuring of paddy rice Pomacea canaliculata
Table 2 niclosamide and clothianidin are to the indoor joint toxicity measuring of paddy rice Pomacea canaliculata
Table 3 niclosamide and Diacloden are to the indoor joint toxicity measuring of paddy rice Pomacea canaliculata
Table 4 niclosamide and MTI-446 are to the indoor joint toxicity measuring of paddy rice Pomacea canaliculata
As can be seen from table 1-4: in this Pesticidal combination, the mass ratio of niclosamide and anabasine pesticide Nitenpyram, clothianidin, Diacloden, MTI-446 is within the scope of 1:50-50:1, co-toxicity coefficient is all greater than 120, and namely the biologically active of said composition to paddy rice Pomacea canaliculata all shows as synergistic effect; Especially its mass ratio is within the scope of 1:30-30:1, and co-toxicity coefficient is all more than 130, and synergistic effect is more obvious.
(2) niclosamide and anabasine pesticide combine the indoor virulence test to Brown Planthopper
1. experiment material: test medicine adopts 95% niclosamide, the former medicine of 95% Nitenpyram, the former medicine of 95% clothianidin, the former medicine of 95% Diacloden and the former medicine of 95% MTI-446; Examination worm is the brown planthopper gathered from rice field, and in indoor feeding to the 5th generation.
2. test method: adopt glass-tube medicine embrane method, each single dose is become the concentration that 5 different with Mixed Pharmacy acetone diluted, with 0.5mL pipette correct amount taking liquid 0.5mL, adding capacity is in the teat glass of 20mL, be positioned on testing stand and also constantly rolled, acetone is volatilized, medicament forms medicine film at glass-tube inwall, only to add the glass tube of acetone film forming in contrast, often 3 repetitions are established in process, in each glass tube, consistent brown planthopper adult 30 is grown in access, mouth of pipe spun yarn net seals and places towards having a down dip 35 °, check dead after process 5h, borer population amount alive.
3. computational methods: analyze test data with DPS statistical analysis software, calculate the LC50 of each medicament, evaluate the acaricidal activity of each medicament.And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T1154.13-2008 miticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80< co-toxicity coefficient (CTC) <120 shows as summation action.
5. result of the test (referring to table 5-8)
Table 5 niclosamide and Nitenpyram are to the indoor joint toxicity measuring of brown planthopper
Table 6 niclosamide and clothianidin are to the indoor joint toxicity measuring of brown planthopper
Table 7 niclosamide and Diacloden are to the indoor joint toxicity measuring of brown planthopper
Table 8 niclosamide and MTI-446 are to the indoor joint toxicity measuring of brown planthopper
As can be seen from table 5-8: in this Pesticidal combination, the mass ratio of niclosamide and anabasine pesticide Nitenpyram, clothianidin, Diacloden, MTI-446 is within the scope of 1:50-50:1, co-toxicity coefficient is all greater than 120, and namely the biologically active of said composition to Brown Planthopper all shows as synergistic effect; Especially its mass ratio is within the scope of 1:30-30:1, and co-toxicity coefficient is all more than 130, and synergistic effect is more obvious.
(3) niclosamide and anabasine pesticide combine the indoor virulence test to rice-stem borer
1. experiment material: test medicine adopts 95% niclosamide, the former medicine of 95% Nitenpyram, the former medicine of 95% clothianidin, the former medicine of 95% Diacloden and the former medicine of 95% MTI-446; Examination worm is striped rice borer 2-4 instar larvae.
2. test method: adopt dip method, concrete operations are with reference to People's Republic of China (PRC) agricultural industry criteria NY/T 1154.7-2006.
3. computational methods: analyze test data with DPS statistical analysis software, calculate the LC50 of each medicament, evaluate the insecticidal activity of each medicament.And the co-toxicity coefficient (CTC value) of mixture is calculated according to the abundant method of Sun Yun.
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50) × 100.
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B.
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
According to the NY/T1154.13-2008 miticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80< co-toxicity coefficient (CTC) <120 shows as summation action.
5. result of the test (referring to table 9-12)
Table 9 niclosamide and Nitenpyram are to the indoor joint toxicity measuring of striped rice borer
Table 10 niclosamide and clothianidin are to the indoor joint toxicity measuring of striped rice borer
Table 11 niclosamide and Diacloden are to the indoor joint toxicity measuring of striped rice borer
Table 12 niclosamide and MTI-446 are to the indoor joint toxicity measuring of striped rice borer
As can be seen from table 9-12: in this Pesticidal combination, the mass ratio of niclosamide and anabasine pesticide Nitenpyram, clothianidin, Diacloden, MTI-446 is within the scope of 1:50-50:1, co-toxicity coefficient is all greater than 120, and namely the biologically active of this Pesticidal combination to rice-stem borer all shows as synergistic effect; Especially its mass ratio is within the scope of 1:30-30:1, and co-toxicity coefficient is all more than 130, and synergistic effect is more obvious.
Two, insecticide fertilizer prepares embodiment
eXAMPLE l:0.2% niclosamide Nitenpyram granular pesticide fertilizer, its formula is as follows:
Preparation method is: first niclosamide, the former medicine of Nitenpyram and auxiliary agent lauryl sodium sulfate and the abundant mixing and stirring of surfactant fatty alcohol-polyoxyethylene ether are obtained female powder, obtained female powder and ammonium sulfate, potassium dihydrogen phosphate, four water eight Boratexes, ethylenediamine tetra-acetic acid zinc sodium, four water ammonium molybdates, white carbon and kaolin is carried out granulation in fluidized bed prilling mode and namely obtains 0.2% niclosamide Nitenpyram granular pesticide fertilizer.
embodiment 2:5.5% niclosamide clothianidin granular pesticide fertilizer, its formula is as follows:
Preparation method is: first niclosamide, the former medicine of clothianidin and auxiliary agent sodium lignin sulfonate and the abundant mixing and stirring of surfactant alkylphenol polyoxyethylene are obtained female powder, obtained female powder and ammonium dihydrogen phosphate (ADP), potassium nitrate, boric acid, ethylenediamine tetra-acetic acid manganese disodium, sodium molybdate, calcium disodium edathamil, white carbon and diatomite is carried out granulation in fluidized bed prilling mode and namely obtains 5.5% niclosamide clothianidin granular pesticide fertilizer.
embodiment 3: 35% niclosamide Diacloden granular pesticide fertilizer, its formula is as follows:
Preparation method is: first niclosamide, the former medicine of Diacloden, auxiliary agent calcium lignosulfonate and surface-active agent alkylphenol polyoxyethylene are fully mixed into female powder, obtained female powder and macroelement fertilizer, trace element fertilizer, white carbon and diatomite is carried out granulation in fluidized bed prilling mode and namely obtains 35% niclosamide Diacloden granular pesticide fertilizer.
embodiment 4:20% niclosamide MTI-446 granular pesticide fertilizer, its formula is as follows:
Preparation method is: first niclosamide, the former medicine of MTI-446, auxiliary agent calcium lignosulfonate and surface-active agent naphthalenesulfonate formaldehyde condensation compound are fully mixed into female powder, obtained female powder and macroelement fertilizer, trace element fertilizer, white carbon, diatomite is carried out granulation in fluidized bed prilling mode and namely obtains 20% niclosamide MTI-446 granular pesticide fertilizer.
embodiment 5:30% niclosamide Nitenpyram powder-type medicine is fertile, and its formula is as follows:
Preparation method is: first obtain female powder by niclosamide, the former medicine of Nitenpyram, auxiliary agent lauryl sodium sulfate and the abundant mixing and stirring of surface-active agent alkylphenol polyoxyethylene, obtained female powder and macroelement fertilizer, trace element fertilizer and carrier is carried out combination drying and pulverize namely obtaining 30% niclosamide Nitenpyram powder medicine fertilizer.
embodiment 6: 1% niclosamide clothianidin powder medicine is fertile, and its formula is as follows:
Preparation method is: first by niclosamide, the former medicine of clothianidin, auxiliary agent sodium butylnaphthalenesulfonate and the abundant mix and blend of surfactant alkylphenol polyoxyethylene all female powder, obtained female powder and macroelement fertilizer, trace element fertilizer, carrier are carried out combination drying pulverizing and namely obtain 1% niclosamide clothianidin powder medicine fertilizer.
embodiment 7: 10.1% niclosamide Diacloden powder medicine is fertile, and its formula is as follows:
Preparation method is: by formula first by niclosamide, the former medicine of Diacloden, auxiliary agent and the abundant mix and blend of surfactant all female powder, obtained female powder and macroelement fertilizer, trace element fertilizer, carrier are carried out combination drying and also pulverize and namely obtain 10.1% niclosamide Diacloden powder medicine fertilizer.
embodiment 8:50% niclosamide MTI-446 powder medicine is fertile, and its formula is as follows:
Preparation method is: by formula first by niclosamide, the former medicine of MTI-446, auxiliary agent lauryl sodium sulfate and the abundant mix and blend of surfactant fatty alcohol-polyoxyethylene ether all female powder, obtained female powder and macroelement fertilizer, trace element fertilizer, carrier are carried out combination drying and also pulverize and namely obtain 50% niclosamide MTI-446 powder medicine fertilizer.
The foregoing is only preferred embodiment of the present invention, and be not used to the scope limiting substantial technological content of the present invention, substantial technological content of the present invention is broadly defined in the right of application, any technology that other people complete or method, if with the right of the application define identical, or the replacement of just a kind of equivalence, is all regarded as being covered by among this right.
Claims (7)
1. one kind contains the Pesticidal combination of niclosamide and anabasine pesticide, it is characterized in that: described Pesticidal combination is that two yuan of carrying out for active ingredient with niclosamide and anabasine pesticide are composite, the mass ratio of described active ingredient niclosamide and anabasine pesticide is 1:50-50:1, and described anabasine pesticide is any one in Nitenpyram, clothianidin, Diacloden and MTI-446.
2. the Pesticidal combination of niclosamide according to claim 1 and anabasine pesticide, is characterized in that: the mass ratio of described active ingredient niclosamide and anabasine pesticide is 1:30-30:1.
3. an insecticide fertilizer, it is characterized in that, described insecticide fertilizer comprises following component by weight percentage: the Pesticidal combination 0.1-50% described in claim 1 or 2, macroelement fertilizer 15-50%, trace element fertilizer 1-15%, auxiliary agent 3-15%, surfactant 3-15%, adsorbent 0.5-2%, carrier supplies 100%.
4. insecticide fertilizer according to claim 3, it is characterized in that, described macroelement fertilizer is at least one in ammonium sulfate, ammonium chloride, ammonium dihydrogen phosphate (ADP), urea, potassium dihydrogen phosphate, potassium hydrogen phosphate, potassium chloride, potassium sulfate, potassium nitrate or potassium citrate; Described trace element fertilizer is at least one in sodium molybdate, four water ammonium molybdates, zinc sulphate, manganese sulphate, copper sulphate, ferrous sulfate, boric acid, four water eight Boratexes, ethylenediamine tetra-acetic acid zinc sodium, calcium disodium edathamil, ethylenediamine tetra-acetic acid manganese disodium or cupric ethylene diamine tetraacetate sodium.
5. insecticide fertilizer according to claim 3, is characterized in that, described auxiliary agent is at least one in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate or sodium butylnaphthalenesulfonate; Described surfactant is at least one in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene or naphthalenesulfonate formaldehyde condensation compound; Described adsorbent is white carbon.
6. insecticide fertilizer according to claim 3, is characterized in that, described carrier is at least one in kaolin, diatomite, nacrite or humic acid.
7. insecticide fertilizer according to claim 3, is characterized in that, the formulation of described insecticide fertilizer is granule or pulvis.
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