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CN104845465A - 一种安全无污染的防火涂料 - Google Patents

一种安全无污染的防火涂料 Download PDF

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CN104845465A
CN104845465A CN201510197883.4A CN201510197883A CN104845465A CN 104845465 A CN104845465 A CN 104845465A CN 201510197883 A CN201510197883 A CN 201510197883A CN 104845465 A CN104845465 A CN 104845465A
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parts
fire retardant
magnesium hydroxide
dioxide
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何益庆
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Tongling Xiangyun Fire Fighting Technology Co Ltd
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Abstract

本发明公开了一种安全无污染的防火涂料，所述安全无污染的防火涂料，由以下重量份的原料制成：丙烯酸树脂15～25份、聚磷酸按10～20份、硼酸锌2～4份、二氧化硅2～5份、钦白粉3～5份、氢氧化镁2～5份、二氧化钦2～5份、硼砂2～5份、氮化硅纤维3～10份、水5～10份、丙酮2～5份、膨胀石墨3～20份、玻璃纤维3～6份、二季戊四醇2～5份、阻燃剂3～5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。本发明提供的安全无污染的防火涂料，耐水性强，与材料结合紧密，粘结强度高，不会遇水脱落，不会释放有毒有害气体，安全无污染；阻燃剂的配方合理、成本低廉，阻燃效果好。

Description

一种安全无污染的防火涂料
技术领域
本发明涉及防火产品领域，具体是一种安全无污染的防火涂料。
背景技术
防火涂料是用于可燃性基材表面，能降低被涂材料表面的可燃性、阻滞火灾的迅速蔓延，用以提高被涂材料耐火极限的一种特种涂料。防火涂料本身具有难燃性或不燃性，使被保护基材不直接与空气接触，延迟物体着火和减少燃烧的速度，提高材料的耐火能力，减缓火焰蔓延传播速度，或在一定时间内能阻止燃烧。
溶剂型防火材料会在配制和施工中大量使用有机溶剂，对环境和操作人员均存在很大危害。水性防火涂料相对来说环保绿色，符合环境友好型涂料的发展方向，但水性防火涂料存在粘结强度低、耐水性差的缺点，时间长了以后容易脱落。
目前，公知的很多日常用品包括家具、地板、壁纸等，其在为生活带来实用、美观、时尚的同时，亦存在着很多的隐患；燃烧时产生大量的有害气体，不仅对人们的身体健康安全带来不利，同时也破坏了周边的生态环境。虽然阻燃剂被广泛的用于生活的各个方面，但对物品进行阻燃处理时，仍存在新的技术问题。
发明内容
一种安全无污染的防火涂料，由以下重量份的原料制成：丙烯酸树脂15～25份、聚磷酸按10～20份、硼酸锌2～4份、二氧化硅2～5份、钦白粉3～5份、氢氧化镁2～5份、二氧化钦2～5份、硼砂2～5份、氮化硅纤维3～10份、水5～10份、丙酮2～5份、膨胀石墨3～20份、玻璃纤维3～6份、二季戊四醇2～5份、阻燃剂3～5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
作为进一步的方案，由以下重量份的原料制成：丙烯酸树脂15份、聚磷酸按10份、硼酸锌2份、二氧化硅2份、钦白粉3份、氢氧化镁2份、二氧化钦2份、硼砂2份、氮化硅纤维3份、水5份、丙酮2份、膨胀石墨3份、玻璃纤维3份、二季戊四醇2份、阻燃剂3份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
作为进一步的方案，由以下重量份的原料制成：丙烯酸树脂20份、聚磷酸按15份、硼酸锌3份、二氧化硅3份、钦白粉4份、氢氧化镁4份、二氧化钦4份、硼砂4份、氮化硅纤维8份、水8份、丙酮4份、膨胀石墨17份、玻璃纤维3份、二季戊四醇2份、阻燃剂4份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
作为进一步的方案，由以下重量份的原料制成：丙烯酸树脂25份、聚磷酸按20份、硼酸锌4份、二氧化硅5份、钦白粉5份、氢氧化镁5份、二氧化钦5份、硼砂5份、氮化硅纤维10份、水10份、丙酮5份、膨胀石墨20份、玻璃纤维6份、二季戊四醇5份、阻燃剂5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
本发明在制备时，按照配方组分比例将聚磷酸按、硼酸锌、二氧化硅、钦白粉、氢氧化镁、二氧化认、硼砂和水在搅拌釜中混合均匀，高速研磨，研至细度为100目左右时即可。然后将膨胀石墨、玻璃纤维、二季戊四醇、氮化硅纤维、阻燃剂一起加入，再搅拌均匀，高速搅拌分散后即得本发明。
与现有技术相比，本发明的有益效果是：本发明提供的安全无污染的防火涂料，耐水性强，与材料结合紧密，粘结强度高，不会遇水脱落；为水性涂料，仅使用少量溶剂，不会释放有毒有害气体，安全无污染。阻燃剂的配方合理、成本低廉，阻燃效果好。
具体实施方式
下面将结合本发明实施例，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1
本发明实施例中，一种安全无污染的防火涂料，由以下重量份的原料制成：丙烯酸树脂15份、聚磷酸按10份、硼酸锌2份、二氧化硅2份、钦白粉3份、氢氧化镁2份、二氧化钦2份、硼砂2份、氮化硅纤维3份、水5份、丙酮2份、膨胀石墨3份、玻璃纤维3份、二季戊四醇2份、阻燃剂3份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
将原料按比例称量好，按照配方组分比例将聚磷酸按、硼酸锌、二氧化硅、钦白粉、氢氧化镁、二氧化饮、硼砂和水在搅拌釜中混合均匀，高速研磨，研至细度为100目左右时即可。然后将膨胀石墨、玻璃纤维、二季戊四醇、氮化硅纤维、阻燃剂一起加入，再搅拌均匀，高速搅拌分散后即得本发明。
实施例2
本发明实施例中，一种安全无污染的防火涂料，由以下重量份的原料制成：丙烯酸树脂20份、聚磷酸按15份、硼酸锌3份、二氧化硅3份、钦白粉4份、氢氧化镁4份、二氧化钦4份、硼砂4份、氮化硅纤维8份、水8份、丙酮4份、膨胀石墨17份、玻璃纤维3份、二季戊四醇2份、阻燃剂4份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
制备方法同实施例1。
实施例3
本发明实施例中，一种安全无污染的防火涂料，由以下重量份的原料制成：丙烯酸树脂25份、聚磷酸按20份、硼酸锌4份、二氧化硅5份、钦白粉5份、氢氧化镁5份、二氧化钦5份、硼砂5份、氮化硅纤维10份、水10份、丙酮5份、膨胀石墨20份、玻璃纤维6份、二季戊四醇5份、阻燃剂5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
制备方法同实施例1。
对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。
此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。

Claims (4)

1.一种安全无污染的防火涂料，其特征在于，由以下重量份的原料制成：丙烯酸树脂15～25份、聚磷酸按10～20份、硼酸锌2～4份、二氧化硅2～5份、钦白粉3～5份、氢氧化镁2～5份、二氧化钦2～5份、硼砂2～5份、氮化硅纤维3～10份、水5～10份、丙酮2～5份、膨胀石墨3～20份、玻璃纤维3～6份、二季戊四醇2～5份、阻燃剂3～5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
2.根据权利要求1所述的一种安全无污染的防火涂料，其特征在于，由以下重量份的原料制成：丙烯酸树脂15份、聚磷酸按10份、硼酸锌2份、二氧化硅2份、钦白粉3份、氢氧化镁2份、二氧化钦2份、硼砂2份、氮化硅纤维3份、水5份、丙酮2份、膨胀石墨3份、玻璃纤维3份、二季戊四醇2份、阻燃剂3份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
3.根据权利要求1所述的一种安全无污染的防火涂料，其特征在于，由以下重量份的原料制成：丙烯酸树脂20份、聚磷酸按15份、硼酸锌3份、二氧化硅3份、钦白粉4份、氢氧化镁4份、二氧化钦4份、硼砂4份、氮化硅纤维8份、水8份、丙酮4份、膨胀石墨17份、玻璃纤维3份、二季戊四醇2份、阻燃剂4份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
4.根据权利要求1所述的一种安全无污染的防火涂料，其特征在于，由以下重量份的原料制成：丙烯酸树脂25份、聚磷酸按20份、硼酸锌4份、二氧化硅5份、钦白粉5份、氢氧化镁5份、二氧化钦5份、硼砂5份、氮化硅纤维10份、水10份、丙酮5份、膨胀石墨20份、玻璃纤维6份、二季戊四醇5份、阻燃剂5份；阻燃剂的组成为：二氧化锑13％～14％、硫酸胺0.2％～0.3％、氢氧化镁10％～20％、柠檬酸10％～20％，其余为硅藻土。
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