CN104650683A - 一种环保型防火涂料及其制备方法 - Google Patents
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- 239000011248 coating agent Substances 0.000 title claims abstract description 22
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000004114 Ammonium polyphosphate Substances 0.000 claims abstract description 9
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 9
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 9
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims abstract description 9
- 229920001276 ammonium polyphosphate Polymers 0.000 claims abstract description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 9
- 239000001205 polyphosphate Substances 0.000 claims abstract description 9
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 9
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 claims abstract description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 7
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 7
- 239000008116 calcium stearate Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 9
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 229910052736 halogen Inorganic materials 0.000 abstract description 3
- 150000002367 halogens Chemical class 0.000 abstract description 3
- 230000018044 dehydration Effects 0.000 abstract description 2
- 238000006297 dehydration reaction Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 abstract 2
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 229910052901 montmorillonite Inorganic materials 0.000 abstract 1
- 239000000779 smoke Substances 0.000 abstract 1
- 239000011684 sodium molybdate Substances 0.000 abstract 1
- 235000015393 sodium molybdate Nutrition 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
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Abstract
本发明公开了一种环保型防火涂料及其制备方法。本发明的一种环保型防火涂料，其组分按质量百分数配比为：聚丙烯酸酯乳液20%～40%、三聚氰胺聚磷酸盐10%～20%、聚磷酸铵2%～8%、纳米硼酸锌2%～8%、季戊四醇15%～20%、钼酸钠2%～6%、氢氧化镁2%～15%、蒙脱土2%～15%、铝钛复合偶联剂0.1%～1%、硬酯酸钙0.1%～1%。本发明的有益效果是，本发明以聚丙烯酸酯乳液作为成膜剂、三聚氰胺聚磷酸盐为脱水发泡剂、聚磷酸铵和纳米硼酸锌为阻燃剂，并添加其它适量助剂，使制得的物料具有很好的阻燃、抑烟、防腐、耐热、高粘结强度、耐老化等性能，而且不含有卤素成份，无卤、无毒和满足环保要求。
Description
技术领域
本发明涉及防火涂料技术领域，具体地说是一种环保型防火涂料及其制备方法。
背景技术
防火涂料是用于可燃性基材表面，能降低被涂材料表面的可燃性、阻滞火灾的迅速蔓延，用以提高被涂材料耐火极限的一种特种涂料。随着科学技术的发展以及工业大型化、建筑高层化的需要，防火涂料的应用也越来越广泛，人们对其要求也越来越高，低成本、高性能、耐老化、环保性好的防火涂料成为社会日益关注的课题，而且代表着防火涂料的一种新的发展方向，具有很好的应用前景和意义。
发明内容
本发明的目的在于提供一种低成本、高性能、耐老化和使用效果好的环保型防火涂料及其制备方法。
本发明解决其技术问题所采用的技术方案是：一种环保型防火涂料，其组分按质量百分数配比为：聚丙烯酸酯乳液20%～40%、三聚氰胺聚磷酸盐10%～20%、聚磷酸铵2%～8%、纳米硼酸锌2%～8%、季戊四醇15%～20%、钼酸钠2%～6%、氢氧化镁2%～15%、蒙脱土2%～15%、铝钛复合偶联剂0.1%～1%、硬酯酸钙0.1%～1%。
本发明的一种环保型防火涂料的制备方法，包括以下步骤：
（1）按质量百分数配比称取各组分；
（2）、将氢氧化镁、蒙脱土和铝钛复合偶联剂加入筒料温度在80℃～120℃的混合机中，并于转速3000～4500转/分钟下搅拌10～60分钟，冷却至温室，出料待用；
（3）、在反应器中加入聚丙烯酸酯乳液、三聚氰胺聚磷酸盐、聚磷酸铵、纳米硼酸锌、季戊四醇、钼酸钠和硬酯酸钙，并加入步骤（2）得到的物料，使充分研磨搅拌和混合均匀后，出料、并密封包装，即得本发明的一种环保型防火涂料。
本发明的有益效果是，与现有技术相比，本发明以聚丙烯酸酯乳液作为成膜剂、三聚氰胺聚磷酸盐为脱水发泡剂、聚磷酸铵和纳米硼酸锌为阻燃剂，并添加其它适量助剂，使制得的物料具有很好的阻燃、抑烟、防腐、耐热、高粘结强度、耐老化等性能，而且不含有卤素成份，无卤、无毒和满足环保要求；本发明提供的制备方法简单、易工业化和无污染清洁生产，成本也较低，可用于钢结构、混凝土、木材表面的防火涂覆，具有较好的使用效果和广阔的应用前景。
具体实施方式
下面结合具体的优选实施例来进一步说明本发明的技术方案。
一种环保型防火涂料，其组分按质量百分数配比为：聚丙烯酸酯乳液26%、三聚氰胺聚磷酸盐20%、聚磷酸铵5%、纳米硼酸锌8%、季戊四醇15%、钼酸钠6%、氢氧化镁8%、蒙脱土10%、铝钛复合偶联剂1%、硬酯酸钙1%。
其制备方法为：（1）按质量百分数配比称取各组分；（2）、将氢氧化镁、蒙脱土和铝钛复合偶联剂加入筒料温度在80℃～120℃的混合机中，并于转速3000～4500转/分钟下搅拌10～60分钟，冷却至温室，出料待用；（3）、在反应器中加入聚丙烯酸酯乳液、三聚氰胺聚磷酸盐、聚磷酸铵、纳米硼酸锌、季戊四醇、钼酸钠和硬酯酸钙，并加入步骤（2）得到的物料，使充分研磨搅拌和混合均匀后，出料、并密封包装，即得本发明的一种环保型防火涂料。
Claims (2)
1.一种环保型防火涂料，其特征在于，其组分按质量百分数配比为：聚丙烯酸酯乳液20%～40%、三聚氰胺聚磷酸盐10%～20%、聚磷酸铵2%～8%、纳米硼酸锌2%～8%、季戊四醇15%～20%、钼酸钠2%～6%、氢氧化镁2%～15%、蒙脱土2%～15%、铝钛复合偶联剂0.1%～1%、硬酯酸钙0.1%～1%。
2.根据权利要求1所述的一种环保型防火涂料，其特征在于，包括以下步骤：
（1）按质量百分数配比称取各组分；
（2）、将氢氧化镁、蒙脱土和铝钛复合偶联剂加入筒料温度在80℃～120℃的混合机中，并于转速3000～4500转/分钟下搅拌10～60分钟，冷却至温室，出料待用；
（3）、在反应器中加入聚丙烯酸酯乳液、三聚氰胺聚磷酸盐、聚磷酸铵、纳米硼酸锌、季戊四醇、钼酸钠和硬酯酸钙，并加入步骤（2）得到的物料，使充分研磨搅拌和混合均匀后，出料、并密封包装，即得本发明的一种环保型防火涂料。
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987804A (zh) * | 2015-06-30 | 2015-10-21 | 芜湖县双宝建材有限公司 | 一种建筑外墙用防火涂料 |
| CN105907305A (zh) * | 2016-06-28 | 2016-08-31 | 安阳华森纸业有限责任公司 | 阻燃防水涂料的制备方法 |
| CN106700769A (zh) * | 2015-07-31 | 2017-05-24 | 江苏田园新材料股份有限公司 | 一种无卤阻燃涂层胶 |
| CN109762422A (zh) * | 2019-01-12 | 2019-05-17 | 常州凯丽特装饰材料有限公司 | 一种室内装饰材料阻燃涂料的制备方法 |
| CN110256927A (zh) * | 2019-07-05 | 2019-09-20 | 中南大学 | 一种水性膨胀型饰面防火涂料 |
| CN110591154A (zh) * | 2018-06-12 | 2019-12-20 | 淮安市冰青建设工程管理有限公司 | 一种环保型阻燃材料 |
| CN111945437A (zh) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | 一种高阻燃耐腐蚀玻璃纤维套管 |
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| CN104987804A (zh) * | 2015-06-30 | 2015-10-21 | 芜湖县双宝建材有限公司 | 一种建筑外墙用防火涂料 |
| CN106700769A (zh) * | 2015-07-31 | 2017-05-24 | 江苏田园新材料股份有限公司 | 一种无卤阻燃涂层胶 |
| CN105907305A (zh) * | 2016-06-28 | 2016-08-31 | 安阳华森纸业有限责任公司 | 阻燃防水涂料的制备方法 |
| CN110591154A (zh) * | 2018-06-12 | 2019-12-20 | 淮安市冰青建设工程管理有限公司 | 一种环保型阻燃材料 |
| CN109762422A (zh) * | 2019-01-12 | 2019-05-17 | 常州凯丽特装饰材料有限公司 | 一种室内装饰材料阻燃涂料的制备方法 |
| CN110256927A (zh) * | 2019-07-05 | 2019-09-20 | 中南大学 | 一种水性膨胀型饰面防火涂料 |
| CN111945437A (zh) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | 一种高阻燃耐腐蚀玻璃纤维套管 |
| CN111945437B (zh) * | 2020-06-29 | 2023-10-31 | 安徽浩天新型材料有限公司 | 一种高阻燃耐腐蚀玻璃纤维套管 |
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