CN104610656A - High and low temperature resin material for plastic coating (impregnating) of steel wire ropes - Google Patents
High and low temperature resin material for plastic coating (impregnating) of steel wire ropes Download PDFInfo
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- CN104610656A CN104610656A CN201510046482.9A CN201510046482A CN104610656A CN 104610656 A CN104610656 A CN 104610656A CN 201510046482 A CN201510046482 A CN 201510046482A CN 104610656 A CN104610656 A CN 104610656A
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- low temperature
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- steel wire
- temperature resin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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Abstract
Description
技术领域technical field
本发明属于树脂材料技术领域,涉及一种钢丝绳包注塑用高低温树脂材料。The invention belongs to the technical field of resin materials, and relates to a high-low temperature resin material for injection molding of steel wire rope bags.
背景技术Background technique
近年来,为提高钢丝绳使用寿命,在露天矿山、工程机械类钢丝绳制造过程中,包(注)塑钢丝绳研发及制造得到了行业科技人员较大的关注。对于钢丝绳制造行业来讲,国内钢丝绳技术发展已经相当成熟,而包(注)塑所用树脂的性能,一直是制约该类钢丝绳发展的一个瓶颈。作为钢丝绳包(注)塑树脂,其性能应满足以下三点:一是在较宽的温度范围内具有良好的使用性能,即高低温性能优良,二是具有良好的抗冲击性能,三是具有良好的强韧性。目前大多数钢丝绳包(注)塑所使用的树脂使用性能仅满足0℃以上,因此行业内急需一种具有高低温优良性能的树脂。In recent years, in order to improve the service life of steel wire ropes, in the manufacturing process of steel wire ropes for open-pit mines and construction machinery, the research and development and manufacture of plastic-coated (injection) steel wire ropes have attracted greater attention from industry scientists. For the steel wire rope manufacturing industry, the development of domestic steel wire rope technology has been quite mature, and the performance of the resin used for wrapping (injection) molding has always been a bottleneck restricting the development of this type of steel wire rope. As a steel wire rope (injection) plastic resin, its performance should meet the following three points: first, it has good performance in a wide temperature range, that is, it has excellent high and low temperature performance; second, it has good impact resistance; third, it has Good toughness. At present, most of the resins used in wire rope wrapping (injection) molding can only meet the performance above 0°C, so a resin with excellent high and low temperature performance is urgently needed in the industry.
发明内容Contents of the invention
本发明目的是提供一种钢丝绳包注塑用高低温树脂材料,解决了现有技术中钢丝绳包(注)塑所使用的树脂使用性能仅满足0℃以上,不能满足高低温使用性能的问题。The object of the present invention is to provide a high and low temperature resin material for steel wire rope wrapping injection molding, which solves the problem in the prior art that the performance of the resin used in the steel wire rope wrapping (injection) molding only satisfies above 0°C and cannot meet the high and low temperature performance.
本发明所采用的技术方案是,一种钢丝绳包注塑用高低温树脂材料,按其质量百分比计算,由以下三种组分组成:The technical solution adopted in the present invention is that a high and low temperature resin material for injection molding of steel wire rope bags is composed of the following three components according to its mass percentage:
聚丙烯为60%~75%,Polypropylene is 60% to 75%,
乙烯/α烯烃共聚弹性体为15%~30%,Ethylene/α-olefin copolymerized elastomer is 15% to 30%,
聚乙烯为4%~10%,Polyethylene is 4% to 10%,
三种组分的质量合计为100%。The mass of the three components adds up to 100%.
本发明的钢丝绳包塑用高低温树脂,其特征还在于:The high and low temperature resin for steel wire rope plastic coating of the present invention is also characterized in that:
聚丙烯和低压高密度聚乙烯均选用颗粒状,乙烯/α烯烃共聚弹性体选用颗粒状半透明晶体。Both polypropylene and low-pressure high-density polyethylene are granular, and ethylene/α-olefin copolymer elastomers are granular translucent crystals.
本发明的有益效果是,使用温度为-45℃~30℃,具有良好的高低温性能,尤其是低温韧性良好。根据用户使用要求不同,通过在A组分中添加不同比例的B和C两种化学产品后,可分别提供耐高低温性能通用配方、高低温耐磨抗挤压性能树脂配方、高低温抗冲击性能、高韧性配方,使树脂能够更好的适应各种恶劣环境,增大包(注)塑钢丝绳的使用领域。The beneficial effect of the invention is that the service temperature is -45°C to 30°C, and it has good high and low temperature performance, especially good low temperature toughness. According to the different requirements of users, by adding different proportions of B and C two chemical products in component A, it can provide general formula for high and low temperature resistance, resin formula for high and low temperature wear resistance and extrusion resistance, and high and low temperature impact resistance. The high performance and high toughness formula enable the resin to better adapt to various harsh environments and increase the application field of plastic-coated (injection) steel wire ropes.
具体实施方式Detailed ways
下面结合具体实施方式对本发明进行详细说明。The present invention will be described in detail below in combination with specific embodiments.
本发明的钢丝绳包注塑用高低温树脂材料,按其质量百分比计算,由以下三种组分组成:The high and low temperature resin material for injection molding of the steel wire rope bag of the present invention is composed of the following three components according to its mass percentage:
A组分:聚丙烯(简称PP)为60%~75%,A component: polypropylene (referred to as PP) is 60% to 75%,
B组分:乙烯/α烯烃共聚弹性体(简称POE)为15%~30%,Component B: Ethylene/α-olefin copolymerized elastomer (referred to as POE) is 15% to 30%,
C组分:低压高密度的聚乙烯(简称PE)为4%~10%,Component C: 4% to 10% of low-pressure high-density polyethylene (referred to as PE),
PP、POE、PE三种组分公开销售,质量合计为100%。The three components of PP, POE and PE are sold publicly, and the total quality is 100%.
在本发明以下较佳实施例中,A组分选用颗粒状,B组分选用颗粒状半透明晶体,C组分选用颗粒状。In the following preferred embodiments of the present invention, component A is granular, component B is granular translucent crystals, and component C is granular.
本发明钢丝绳包注塑用高低温树脂材料,按如下步骤制备:The high and low temperature resin material for injection molding of the steel wire rope bag of the present invention is prepared according to the following steps:
第一步:按照上述的比例称量三种组分,并混合搅拌10min~15min;Step 1: Weigh the three components according to the above proportions, and mix and stir for 10 minutes to 15 minutes;
第二步:将混合料在挤塑机中加热,加热温度范围为190℃~220℃;Step 2: Heat the mixture in the extruder, and the heating temperature range is 190°C to 220°C;
第三步:保温1h-2h,确保混合料完全融化;Step 3: Keep warm for 1h-2h to ensure that the mixture is completely melted;
第四步:开启挤塑机,主机螺杆的挤塑速度为3~6转/分;Step 4: Turn on the extruder, and the extrusion speed of the host screw is 3 to 6 rpm;
第五步:将树脂挤出模口(直径为2-5mm的树脂条)用切粒机切成3mm的颗粒,风冷成型,即成。Step 5: Cut the resin extrusion die (resin strip with a diameter of 2-5mm) into 3mm pellets with a pelletizer, and air-cool it to form it.
实施例1Example 1
各组分质量配比为:聚丙烯(PP)64%、乙烯/α烯烃共聚弹性体(POE)30%、低压高密度的聚乙烯(PE)6%,合计为100%。按照上述的制备方法所得的高低温树脂配方满足通用钢丝绳包注塑性能要求。The mass ratio of each component is: polypropylene (PP) 64%, ethylene/alpha olefin copolymerized elastomer (POE) 30%, low-pressure high-density polyethylene (PE) 6%, and the total is 100%. The high and low temperature resin formula obtained according to the above preparation method meets the injection molding performance requirements of general steel wire rope bales.
实施例2Example 2
各组分质量配比为:聚丙烯(PP)70%、乙烯/α烯烃共聚弹性体(POE)26%、低压高密度的聚乙烯(PE)4%,合计为100%。按照上述的制备方法所得的高低温树脂配方满足抗磨损、抗挤压的性能要求。The mass ratio of each component is: 70% of polypropylene (PP), 26% of ethylene/α-olefin copolymerized elastomer (POE), 4% of low-pressure high-density polyethylene (PE), and the total is 100%. The high-low temperature resin formula obtained according to the above-mentioned preparation method meets the performance requirements of wear resistance and extrusion resistance.
实施例3Example 3
各组分质量配比为:聚丙烯(PP)60%、乙烯/α烯烃共聚弹性体(POE)30%、低压高密度的聚乙烯(PE)10%,合计为100%。按照上述的制备方法所得的高低温树脂配方满足抗冲击、高韧性的性能要求。The mass ratio of each component is: 60% of polypropylene (PP), 30% of ethylene/α-olefin copolymerized elastomer (POE), 10% of low-pressure high-density polyethylene (PE), and the total is 100%. The high and low temperature resin formula obtained according to the above preparation method meets the performance requirements of impact resistance and high toughness.
本发明的钢丝绳包注塑用高低温树脂材料,具有良好的耐高/低温性能,解决了现有技术的不足和缺陷,通过在PP中添加另外两个化学组分,使树脂具有了优良的高低温性能,使包(注)塑钢丝绳的性能得到优化,从而进一步扩大了包(注)塑钢丝绳使用领域。The high and low temperature resin material for injection molding of steel wire rope bags of the present invention has good high/low temperature resistance, which solves the deficiencies and defects of the prior art. By adding two other chemical components to PP, the resin has excellent high and low temperature performance. The low-temperature performance optimizes the performance of the plastic-coated (injection) steel wire rope, thereby further expanding the application field of the plastic-coated (injection) steel wire rope.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110359303A (en) * | 2019-06-28 | 2019-10-22 | 咸阳宝石钢管钢绳有限公司 | A kind of compacting stock fills out modeling resistance rotating wire rope and its manufacturing method |
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Patent Citations (9)
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CN1752131A (en) * | 2005-10-09 | 2006-03-29 | 广州市鹿山化工材料有限公司 | Special resin for exhaust pipe of moving air conditioner |
CN102372874A (en) * | 2010-08-19 | 2012-03-14 | 中国石油化工股份有限公司 | Stress whitening resistant and scratch resistant polypropylene composition, and preparation method thereof |
CN102453279A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Polypropylene composition for producing carbonated beverage bottle cap |
CN102532687A (en) * | 2010-12-21 | 2012-07-04 | 上海日之升新技术发展有限公司 | Composite material with low shrinkage rate and preparation method thereof |
CN102070839A (en) * | 2011-01-10 | 2011-05-25 | 广东华盛塑料有限公司 | Modified plastic |
CN102344603A (en) * | 2011-10-24 | 2012-02-08 | 浙江俊尔新材料有限公司 | Rubber and plastic sealing material in stable size at high and low temperatures and preparation method thereof |
CN102532660A (en) * | 2011-12-23 | 2012-07-04 | 常州大学 | Solvent-resistant macromolecular blending material for injection molding |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110359303A (en) * | 2019-06-28 | 2019-10-22 | 咸阳宝石钢管钢绳有限公司 | A kind of compacting stock fills out modeling resistance rotating wire rope and its manufacturing method |
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