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CN104072881B - A kind of thermoplasticity fretting map vibration-absorptive material and preparation method thereof - Google Patents

A kind of thermoplasticity fretting map vibration-absorptive material and preparation method thereof Download PDF

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Publication number
CN104072881B
CN104072881B CN201310103357.8A CN201310103357A CN104072881B CN 104072881 B CN104072881 B CN 104072881B CN 201310103357 A CN201310103357 A CN 201310103357A CN 104072881 B CN104072881 B CN 104072881B
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parts
foaming
thermoplastic
temperature
absorbing material
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CN104072881A (en
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杨桂生
郭学林
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Nanjing Qingyan New Material Research Institute Co ltd
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CHUZHOU GEMEITE TECHNOLOGY CO LTD
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/76—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76498—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76531—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76551—Time
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/14—Copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
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  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明属于高分子材料加工技术领域，涉及一种热塑性微发泡减震材料及其制备方法。该减震材料由包含以下重量份的组分制成：聚丙烯80～100份，热塑性弹性体50～80份，填料8～15份，抗氧剂1～2份，粘度调节剂12～25份，发泡母粒10～18份，分散剂0.8～1.5份。本发明的热塑性微发泡减震材料采用热塑性弹性体和粘度调节剂复合改性聚丙烯，达到同时增韧、增强的目的，并添加发泡母粒进行注塑发泡，发泡均匀、产品表面的美观。本发明配方简单原料易得，成本低廉；制备方法操作简单，工艺条件易控制，运行成本低，生产效率高，产品性能好；产品可在包装、建筑、汽车工业、航天航空工业以及运动器材等行业有着广泛的应用。The invention belongs to the technical field of polymer material processing, and relates to a thermoplastic micro-foaming shock-absorbing material and a preparation method thereof. The shock-absorbing material is made of the following components by weight: 80-100 parts of polypropylene, 50-80 parts of thermoplastic elastomer, 8-15 parts of filler, 1-2 parts of antioxidant, and 12-25 parts of viscosity regulator. 10-18 parts of foam masterbatch, 0.8-1.5 parts of dispersant. The thermoplastic micro-foaming shock-absorbing material of the present invention adopts thermoplastic elastomer and viscosity modifier to compound modified polypropylene to achieve the purpose of simultaneously toughening and strengthening, and adds foaming masterbatch for injection foaming, and the foaming is uniform and the product surface beautiful. The invention has simple formula, easy access to raw materials, and low cost; the preparation method is simple to operate, the process conditions are easy to control, the operating cost is low, the production efficiency is high, and the product performance is good; the product can be used in packaging, construction, automobile industry, aerospace industry, and sports equipment, etc. industry has a wide range of applications.

Description

A kind of thermoplasticity fretting map vibration-absorptive material and preparation method thereof
Technical field
The invention belongs to processing of high molecular material technical field, is related to a kind of thermoplasticity fretting map vibration-absorptive material and its preparation Method.
Background technology
Micro-foaming material refers to using polymeric material as matrix, wherein containing abscess-size from micro- to tens less than one micron The porous polymer material of rice.Foamed plastics prepared by conventional physically or chemically foaming is because its aperture is larger, generally not Belong to this category, compared with the millimetre-sized abscess of general foamed plastics, the abscess of fretting map polymer is much smaller, and abscess Density is much greater, thus referred to as fretting map polymeric material.Fretting map thermoplastic elastomer (TPE) has good mechanical property because of it Energy, excellent heat resistance, resistant to chemical media, weatherability and resistance to ag(e)ing have been applied to the field of shock absorption of high-speed railway, But being prepared with chemical blowing process for being commonly used does not have independent bubble in pure foamed thermoplastic elastomers, bubble compared with Greatly and remain that chemical substance, its mechanical property etc. is unstable, the needs of high ferro damping can't be fully met.It is existing Rubber blanket, EVA pads, TPU pads have been difficult the damping requirement for meeting growing high-speed railway, and service life is also short；And work Though engineering plastics cause its damping effect poor with higher-strength but the pliability of itself and dynamic mechanical.
The content of the invention
The defects of it is an object of the invention to overcome prior art provide a kind of thermoplasticity fretting map vibration-absorptive material and Its preparation method.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of thermoplasticity fretting map vibration-absorptive material, is made up of the component comprising following parts by weight：
Described polypropylene is selected from COPP, and its melt index is 1.5~3g/10min.
Described thermoplastic elastomer (TPE) is selected from thermoplastic polyester elastomer（TPEE）, thermoplasticity EPDM dynamic vulcanization bullet Property body（TPV）Or thermoplastic styrene class elastomer（TPS）In one or more；Wherein, thermoplastic polyester elastomer （TPEE）Formed by terephthalic acid (TPA) Isosorbide-5-Nitrae butanediol and the copolymerization of poly- butanol, thermoplasticity EPDM dynamic vulcanization elastomer（TPV） It is dispersed in polypropylene plastics matrix and is formed by ethylene propylene diene rubber particulate, thermoplastic styrene class elastomer（TPS）For fourth two The copolymer of alkene or isoprene and styrene block type.
One or more of the described filler in titanium dioxide, mica, talcum powder or silica.
Described antioxidant be selected from thio-2 acid octadecyl ester, [β-（3,5 di-t-butyl 4- hydroxy-phenies）Propionic acid] season penta Four alcohol esters, dilauryl thiodipropionate or 4,4 '-thio（6- tertiary butyl -3- methylphenols）In one or more.
Described viscosity modifier is selected from low density polyethylene (LDPE), acrylonitrile-butadiene-styrene terpolymer or second One or more in alkene-acetate ethylene copolymer.
One or more of the described dispersant in oleic acid, Tissuemat E or stearic acid.
Described foaming master batch is made up of the component comprising following parts by weight：
Described foaming agent is azodicarbonamide.
Described nucleator is talcum powder.
Described cladding is ethylene-vinyl acetate copolymer.
Described foaming master batch vector resin is low density polyethylene (LDPE).
A kind of preparation method of above-mentioned thermoplasticity fretting map vibration-absorptive material, comprises the following steps：
（1）Prepare foaming master batch：15~25 parts of foaming agent, 45~60 parts of nucleator, 30~45 parts of cladding, foaming is female After grain 100 parts of addition homogenizers of vector resin are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Extrusion temperature Spend for 140~150 DEG C, screw speed 40r/min；
（2）Prepare base-material：By 80~100 parts of polypropylene, 50~80 parts of thermoplastic elastomer (TPE), 8~15 parts of filler, antioxidant 1~2 part, 12~25 parts of viscosity modifier, 0.8~1.5 part of addition mixer high speed of dispersant is stirred 5~8min, so After be added to double screw extruder and be granulated；Rotating speed is 180~240r/min, and temperature is set as 180~190 DEG C, and water cooling is drawn Bar pelletizing is into base-material；
（3）Injection foaming：The base-material prepared in step 2 is taken, then adds 10~18 parts of foaming master batch to be mixed to join injector Hopper injection foaming obtains product.
Described step（1）Middle double screw extruder diameter 76mm, draw ratio 40；
Described step（3）The concrete technology of middle injection foaming is：Injector drying temperature is 80~90 DEG C, injection pressure For 55~65MPa, injection time is 1~2 second, and barrel zone temperature is 185~195 DEG C, 190~200 DEG C, 175~185 DEG C respectively, Nozzle temperature is 185~195 DEG C, and mold temperature is 20~30 DEG C.
The prescription of fretting map vibration-absorptive material provided by the invention is simple, raw material is easy to get, cost is cheap, and the items of product It is functional.The shaped article of the present invention is the closed pore fretting map elastomeric article that aperture is tens microns, and its smooth in appearance is put down It is whole, there is the advantages of independent bubble, foaming is smaller, without chemical residue.The shaped article of the present invention can loss of weight simultaneously 10%-40%, when being hit, the energy of absorption can increase 3-5 times, can be passivated original crack tip, so as to improve material The toughness of material and endurance life-span, the requirement such as mechanical property, elasticity, kinetic energy absorption of high ferro shock-absorption backing plate needs can be met.
Beneficial effects of the present invention：
Compared with prior art, thermoplasticity fretting map vibration-absorptive material of the invention is adjusted using thermoplastic elastomer (TPE) and viscosity Agent composite modified polypropylene, because viscosity modifier makes that thermoplastic elastomer (TPE) and the filler mobility in polypropylene is easy to control, boundary Face is compatible good, reaches while toughness reinforcing, the purpose of enhancing, and the resistance to ag(e)ing and Anti- tarnishing of material are improved by adding antioxidant Property, and add foaming master batch and carry out injection foaming, uniform in foaming, the size of foam bubble and U.S. of product surface can be easily controlled See；
The foaming master batch of the present invention overcomes powdery foaming agent and is easy to fly upward, influences measuring accuracy and working environment is defended simultaneously The defects of raw, suitable size, evengranular master batch is made in foaming agent, have high gas-forming property, good dispersiveness and with tree The good compatibility of fat, the porous, expanded material structure that the closed pore gas-solid of standard is combined is easily formed, adds thermoplastic plastic Melt flows and melt diffusion, improves melt strength, and when being hit, the energy of absorption rises to five times, can make original The crack tip passivation come, so as to improve the toughness of material and fatigue durability.
In addition, preparation method provided by the invention is simple to operate, process conditions are easy to control, good product performance, steady quality.
Embodiment
With reference to specific embodiment, the present invention is further illustrated.GB is used in following examples（National standard）Determine material Properties, unless otherwise instructed, the number of component is parts by weight.In addition, polypropylene is selected from altogether in the following example Poly- polypropylene, its melt index are 1.5~3g/10min.
Embodiment 1
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows：
（1）Prepare foaming master batch：By 18 parts of azodicarbonamide, 50 parts of talcum powder, ethylene-vinyl acetate copolymer 30 Part, after 100 parts of addition homogenizers of low density polyethylene (LDPE) are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Squeeze It is 140~145 DEG C to go out temperature, screw speed 40r/min；
（2）Prepare base-material：By 100 parts of polypropylene, thermoplasticity EPDM dynamic vulcanization elastomer（TPV）50 parts, titanium white 15 parts of powder, 1.2 parts of thio-2 acid octadecyl ester, 12 parts of low density polyethylene (LDPE), 1.3 parts of addition mixer high speeds of Tissuemat E are stirred Mixing 5min is mixed, double screw extruder is then added to and is granulated；Rotating speed is 210r/min, and temperature is set as 180~185 DEG C, water cooling bracing pelletizing is into base-material；
（3）Injection foaming：Above-mentioned gained base-material is taken, then adds 15 parts of foaming master batch to be mixed to join injector hopper injection hair Steep to obtain product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 58MPa, and injection time is 1 second, and barrel zone temperature is 185~190 DEG C, 190~195 DEG C, 175~180 DEG C respectively, nozzle Temperature is 185~190 DEG C, and mold temperature is 20~25 DEG C.The test of its properties sees attached list 1.
Embodiment 2
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows：
（1）Prepare foaming master batch：By 15 parts of azodicarbonamide, 45 parts of talcum powder, ethylene-vinyl acetate copolymer 35 Part, after 100 parts of addition homogenizers of low density polyethylene (LDPE) are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Squeeze It is 140~145 DEG C to go out temperature, screw speed 40r/min；
（2）Prepare base-material：By 90 parts of polypropylene, thermoplastic styrene class elastomer（TPS）65 parts, 4 parts of mica and talcum 4 parts of powder, 4,4 '-thio（6- tertiary butyl -3- methylphenols）1.0 parts, 18 parts of ethylene-vinyl acetate copolymer, 0.8 part of stearic acid Add mixer high speed and be stirred 8min, be then added to double screw extruder and be granulated；Rotating speed is 180r/min, temperature Degree is set as 185~190 DEG C, and water cooling bracing pelletizing is into base-material；
（3）Injection foaming：Above-mentioned gained base-material is taken, then adds 10 parts of foaming master batch to be mixed to join injector hopper injection hair Steep to obtain product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 55MPa, and injection time is 2 seconds, and barrel zone temperature is 185~190 DEG C, 195~200 DEG C, 180~185 DEG C respectively, nozzle Temperature is 190~195 DEG C, and mold temperature is 25~30 DEG C.The test of its properties sees attached list 1.
Embodiment 3
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows：
（1）Prepare foaming master batch：By 20 parts of azodicarbonamide, 60 parts of talcum powder, ethylene-vinyl acetate copolymer 45 Part, after 100 parts of addition homogenizers of low density polyethylene (LDPE) are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Squeeze It is 145~150 DEG C to go out temperature, screw speed 40r/min；
（2）Prepare base-material：By 80 parts of polypropylene, thermoplastic polyester elastomer（TPEE）70 parts, 12 parts of titanium dioxide, [β-（3, 5 di-t-butyl 4- hydroxy-phenies）Propionic acid] 1.5 parts of pentaerythritol ester, 20 parts of ethylene-vinyl acetate copolymer, Tissuemat E 1.2 Part addition mixer high speed is stirred 6min, is then added to double screw extruder and is granulated；Rotating speed is 240r/min, Temperature is set as 185~190 DEG C, and water cooling bracing pelletizing is into base-material；
（3）Injection foaming：Above-mentioned gained base-material is taken, then adds 18 parts of foaming master batch to be mixed to join injector hopper injection hair Steep to obtain product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 65MPa, and injection time is 1 second, and barrel zone temperature is 190~195 DEG C, 190~195 DEG C, 180~185 DEG C respectively, nozzle Temperature is 185~190 DEG C, and mold temperature is 25~30 DEG C.The test of its properties sees attached list 1.
Embodiment 4
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows：
（1）Prepare foaming master batch：By 25 parts of azodicarbonamide, 55 parts of talcum powder, ethylene-vinyl acetate copolymer 40 Part, after 100 parts of addition homogenizers of low density polyethylene (LDPE) are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Squeeze It is 145~150 DEG C to go out temperature, screw speed 40r/min；
（2）Prepare base-material：By 90 parts of polypropylene, thermoplastic polyester elastomer（TPEE）80 parts, 0 part of silica 1,4, 4 '-thio（6- tertiary butyl -3- methylphenols）1.2 parts, 25 parts of low density polyethylene (LDPE) is high in 1.5 parts of addition mixers of stearic acid Speed is stirred 8min, is then added to double screw extruder and is granulated；Rotating speed is 210r/min, temperature is set as 180~ 185 DEG C, water cooling bracing pelletizing is into base-material；
（3）Injection foaming：Above-mentioned gained base-material is taken, then adds 15 parts of foaming master batch to be mixed to join injector hopper injection hair Steep to obtain product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 62MPa, and injection time is 1.5 seconds, and barrel zone temperature is 185~190 DEG C, 190~195 DEG C, 175~180 DEG C respectively, spray Mouth temperature is 185~190 DEG C, and mold temperature is 20~25 DEG C.The test of its properties sees attached list 1.
Comparative example 1
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows（Thermoplastic elastomer (TPE) is not added with, remaining step With embodiment 3）：
（1）Prepare foaming master batch：By 20 parts of azodicarbonamide, 60 parts of talcum powder, ethylene-vinyl acetate copolymer 45 Part, after 100 parts of addition homogenizers of low density polyethylene (LDPE) are sufficiently mixed uniformly, are extruded, be granulated using double screw extruder；Squeeze It is 145~150 DEG C to go out temperature, screw speed 40r/min；
（2）Prepare base-material：By 80 parts of polypropylene, 12 parts of titanium dioxide, [β-（3,5 di-t-butyl 4- hydroxy-phenies）Propionic acid] 1.5 parts of pentaerythritol ester, 20 parts of ethylene-vinyl acetate copolymer, 1.2 parts of addition mixer high speeds of Tissuemat E are stirred 6min, it is then added to double screw extruder and is granulated；Rotating speed is 240r/min, and temperature is set as 185~190 DEG C, water cooling Tie rod pelletizing is into base-material；
（3）Injection foaming：Above-mentioned gained base-material is taken, then adds 18 parts of foaming master batch to be mixed to join injector hopper injection hair Steep to obtain product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 65MPa, and injection time is 1 second, and barrel zone temperature is 190~195 DEG C, 190~195 DEG C, 180~185 DEG C respectively, nozzle Temperature is 185~190 DEG C, and mold temperature is 25~30 DEG C.The test of its properties sees attached list 1.
Comparative example 2
In the present embodiment thermoplasticity fretting map vibration-absorptive material prepare it is as follows（Foaming master batch is not prepared, and remaining step is the same as real Apply example 4）：
（1）Prepare base-material：By 90 parts of polypropylene, thermoplastic polyester elastomer（TPEE）80 parts, 0 part of silica 1,4, 4 '-thio（6- tertiary butyl -3- methylphenols）1.2 parts, 25 parts of low density polyethylene (LDPE) is high in 1.5 parts of addition mixers of stearic acid Speed is stirred 8min, is then added to double screw extruder and is granulated；Rotating speed is 210r/min, temperature is set as 180~ 185 DEG C, water cooling bracing pelletizing is into base-material；
（2）Injection foaming：Above-mentioned gained base-material is taken, then adds 15 parts of foaming agent azodicarbonamide to be mixed to join injector Hopper injection foaming obtains product.
Double screw extruder diameter 76mm described above, draw ratio 40；Injector drying temperature is 80~90 DEG C, injection Pressure is 62MPa, and injection time is 1.5 seconds, and barrel zone temperature is 185~190 DEG C, 190~195 DEG C, 175~180 DEG C respectively, spray Mouth temperature is 185~190 DEG C, and mold temperature is 20~25 DEG C.The test of its properties sees attached list 1.
Table 1
It can be seen that by each item data in table 1, the combination property of embodiment 3,4 is preferable, and embodiment 1~4 is with thermoplastic elastomehc The change of property body and viscosity modifier, elongation at break and impact strength etc. significantly increase, compression set and oil resistivity body Product expansion rate diminishes, and tensile strength varies less；By the contrast of comparative example 1 and embodiment 3, thermoplastic elastic is not added in discovery Its impact strength of thermoplasticity fretting map vibration-absorptive material and elongation at break of body decline a lot, and compression set is also deteriorated；It is logical The contrast of comparative example 2 and embodiment 4 is crossed, finds not adding the permanent change of its compression of the thermoplasticity fretting map vibration-absorptive material of foaming master batch Shape and oil resistivity cubical expansivity become big, and impact strength also diminishes, and performance reduces.
The above-mentioned description to embodiment is understood that for ease of those skilled in the art and using this hair It is bright.Person skilled in the art obviously easily can make various modifications to these embodiments, and described herein General Principle is applied in other embodiment without by performing creative labour.Therefore, the invention is not restricted to implementation here Example, for those skilled in the art according to the announcement of the present invention, not departing from improvement that scope made and modification all should be Within protection scope of the present invention.

Claims (9)

1.一种热塑性微发泡减震材料，其特征在于：由以下重量份的组分制成：1. A thermoplastic micro-foam shock-absorbing material, characterized in that: it is made of the following components by weight: 所述的聚丙烯选自共聚聚丙烯，其熔融指数为3g/10min；Described polypropylene is selected from copolymerized polypropylene, and its melt index is 3g/10min; 所述的热塑性弹性体选自热塑性聚酯弹性体、热塑性三元乙丙动态硫化弹性体或热塑性苯乙烯类弹性体中的一种以上；其中，热塑性聚酯弹性体由对苯二甲酸、1,4丁二醇及聚丁醇共聚而成，热塑性三元乙丙动态硫化弹性体由三元乙丙橡胶微粒分散在聚丙烯塑料基体中形成，热塑性苯乙烯类弹性体为丁二烯或异戊二烯与苯乙烯嵌段型的共聚物；Described thermoplastic elastomer is selected from more than one in thermoplastic polyester elastomer, thermoplastic EPDM dynamic vulcanization elastomer or thermoplastic styrene-based elastomer; Wherein, thermoplastic polyester elastomer is made of terephthalic acid, 1 ,4 butanediol and polybutanol are copolymerized, thermoplastic EPDM dynamic vulcanized elastomer is formed by dispersing EPDM rubber particles in polypropylene plastic matrix, thermoplastic styrene elastomer is butadiene or iso Pentadiene and styrene block copolymers; 所述的粘度调节剂选自低密度聚乙烯、丙烯腈-丁二烯-苯乙烯三元共聚物或乙烯-醋酸乙烯共聚物中的一种以上；The viscosity regulator is selected from more than one of low-density polyethylene, acrylonitrile-butadiene-styrene terpolymer or ethylene-vinyl acetate copolymer; 所述的发泡母粒由以下重量份的组分制成：Described foam masterbatch is made up of the following components by weight: 所述的包覆体为乙烯-醋酸乙烯共聚物；The coating is ethylene-vinyl acetate copolymer; 所述的热塑性微发泡减震材料的制备方法包括以下步骤：The preparation method of described thermoplastic microfoam shock-absorbing material comprises the following steps: (1)制备发泡母粒：将发泡剂15～25份，成核剂45～60份，包覆体30～45份，发泡母粒载体树脂100份加入高速搅拌机充分混合均匀后，利用双螺杆挤出机挤出、造粒；挤出温度为140～150℃，螺杆转速为40r/min；(1) Preparation of foaming masterbatch: add 15-25 parts of foaming agent, 45-60 parts of nucleating agent, 30-45 parts of coating body, and 100 parts of foaming masterbatch carrier resin into a high-speed mixer and mix well, Use a twin-screw extruder to extrude and granulate; the extrusion temperature is 140-150°C, and the screw speed is 40r/min; (2)制备基料：将聚丙烯80～100份，热塑性弹性体50～80份，填料8～15份，抗氧剂1～2份，粘度调节剂12～25份，分散剂0.8～1.5份加入搅拌机中高速搅拌混合5～8min，然后加入到双螺杆挤出机进行造粒；转速为180～240r/min，温度设定为180～190℃，水冷拉条切粒成基料；(2) Preparation of base material: 80-100 parts of polypropylene, 50-80 parts of thermoplastic elastomer, 8-15 parts of filler, 1-2 parts of antioxidant, 12-25 parts of viscosity modifier, 0.8-1.5 parts of dispersant Add one part to the mixer and mix at high speed for 5-8 minutes, then add to the twin-screw extruder for granulation; the speed is 180-240r/min, the temperature is set at 180-190°C, and the water-cooled strands are cut into pellets; (3)注塑发泡：取步骤(2)中制备的基料，再加发泡母粒10～18份混合加入到注射机料斗注塑发泡得到热塑性微发泡减震材料；(3) Injection molding and foaming: take the base material prepared in step (2), add 10 to 18 parts of foam masterbatch, mix and add to the hopper of the injection machine for injection molding and foaming to obtain a thermoplastic micro-foaming shock-absorbing material; 所述的步骤(3)中注塑发泡的具体工艺参数为：注射机的干燥温度为80～90℃，注射的压力为55～65MPa，注射的时间为1～2秒，机筒的温度分别是185～195℃、190～200℃、175～185℃，喷嘴的温度为185～195℃，模具的温度为20～30℃。The specific process parameters of injection foaming in the step (3) are: the drying temperature of the injection machine is 80-90° C., the injection pressure is 55-65 MPa, the injection time is 1-2 seconds, and the temperature of the barrel is respectively It is 185-195°C, 190-200°C, 175-185°C, the temperature of the nozzle is 185-195°C, and the temperature of the mold is 20-30°C. 2.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的填料选自钛白粉、云母、滑石粉或二氧化硅中的一种以上。2. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: said filler is selected from at least one of titanium dioxide, mica, talcum powder or silicon dioxide. 3.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的抗氧剂选自硫代二丙酸十八酯、硫代二丙酸二月桂酯或4,4’-硫代双(6-叔丁基-3-甲基苯酚)中的一种以上。3. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: said antioxidant is selected from stearyl thiodipropionate, dilauryl thiodipropionate or 4,4 One or more kinds of '-thiobis(6-tert-butyl-3-methylphenol). 4.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的分散剂选自油酸、聚乙烯蜡或硬脂酸中的一种以上。4. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: said dispersant is selected from one or more of oleic acid, polyethylene wax or stearic acid. 5.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的发泡剂为偶氮二甲酰胺。5. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: the foaming agent is azodicarbonamide. 6.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的成核剂为滑石粉。6. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: the nucleating agent is talcum powder. 7.根据权利要求1所述的热塑性微发泡减震材料，其特征在于：所述的发泡母粒载体树脂为低密度聚乙烯。7. The thermoplastic micro-foamed shock-absorbing material according to claim 1, characterized in that: the carrier resin of the foamed masterbatch is low-density polyethylene. 8.一种根据权利要求1-7任一项所述的热塑性微发泡减震材料的制备方法，其特征在于：包括以下步骤：8. A preparation method according to any one of claims 1-7, characterized in that: comprising the following steps: (1)制备发泡母粒：将发泡剂15～25份，成核剂45～60份，包覆体30～45份，发泡母粒载体树脂100份加入高速搅拌机充分混合均匀后，利用双螺杆挤出机挤出、造粒；挤出温度为140～150℃，螺杆转速为40r/min；(1) Preparation of foaming masterbatch: add 15-25 parts of foaming agent, 45-60 parts of nucleating agent, 30-45 parts of coating body, and 100 parts of foaming masterbatch carrier resin into a high-speed mixer and mix well, Use a twin-screw extruder to extrude and granulate; the extrusion temperature is 140-150°C, and the screw speed is 40r/min; (2)制备基料：将聚丙烯80～100份，热塑性弹性体50～80份，填料8～15份，抗氧剂1～2份，粘度调节剂12～25份，分散剂0.8～1.5份加入搅拌机中高速搅拌混合5～8min，然后加入到双螺杆挤出机进行造粒；转速为180～240r/min，温度设定为180～190℃，水冷拉条切粒成基料；(2) Preparation of base material: 80-100 parts of polypropylene, 50-80 parts of thermoplastic elastomer, 8-15 parts of filler, 1-2 parts of antioxidant, 12-25 parts of viscosity modifier, 0.8-1.5 parts of dispersant Add one part to the mixer and mix at high speed for 5-8 minutes, then add to the twin-screw extruder for granulation; the speed is 180-240r/min, the temperature is set at 180-190°C, and the water-cooled strands are cut into pellets; (3)注塑发泡：取步骤(2)中制备的基料，再加发泡母粒10～18份混合加入到注射机料斗注塑发泡得到热塑性微发泡减震材料；(3) Injection molding foaming: take the base material prepared in step (2), add 10 to 18 parts of foaming masterbatch, mix and add to the hopper of the injection machine for injection molding foaming to obtain a thermoplastic micro-foaming shock-absorbing material; 所述的步骤(3)中注塑发泡的具体工艺参数为：注射机的干燥温度为80～90℃，注射的压力为55～65MPa，注射的时间为1～2秒，机筒的温度分别是185～195℃、190～200℃、175～185℃，喷嘴的温度为185～195℃，模具的温度为20～30℃。The specific process parameters of injection foaming in the step (3) are: the drying temperature of the injection machine is 80-90° C., the injection pressure is 55-65 MPa, the injection time is 1-2 seconds, and the temperature of the barrel is respectively It is 185-195°C, 190-200°C, 175-185°C, the temperature of the nozzle is 185-195°C, and the temperature of the mold is 20-30°C. 9.根据权利要求8所述的制备方法，其特征在于：所述的步骤(1)中双螺杆挤出机的直径为76mm，长径比为40：1。9. The preparation method according to claim 8, characterized in that: in the step (1), the diameter of the twin-screw extruder is 76 mm, and the aspect ratio is 40:1.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN105235126B (en) * 2015-09-02 2017-05-17 江苏科技大学 Method for producing super-stretchable propene polymer (PP)/low-density polyethylene (LDPE) microporous product in ordinary injection machine
CN105885240A (en) * 2016-04-25 2016-08-24 中山诗兰姆汽车零部件有限公司 Microcellular foaming composite material and preparation method thereof
CN106189103A (en) * 2016-08-24 2016-12-07 深圳市传佳新材料有限公司 A kind of thermoplastic polyester elastomer expanded beads and preparation method
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US10508184B2 (en) 2016-12-29 2019-12-17 Exxonmobil Chemical Patents Inc. Foaming agent masterbatches for foaming thermoplastic vulcanizates
US11192992B2 (en) 2016-12-29 2021-12-07 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates for foaming applications
CN107200919A (en) * 2017-06-23 2017-09-26 苏州润佳工程塑料股份有限公司 A kind of injection grade micro-foaming polypropylene composite material and preparation method thereof
CN107200924A (en) * 2017-07-10 2017-09-26 海南新美特科技有限公司 A kind of technological process of air inlet pipe development ＆ production
CN111615535A (en) 2017-12-06 2020-09-01 埃克森美孚化学专利公司 Low density foamed thermoplastic vulcanizate composition
CN108285578B (en) * 2018-02-09 2020-08-18 郑州大学 A kind of preparation method of PP/ABS micro-foaming material
CN108340532B (en) * 2018-02-09 2020-05-22 江苏科技大学 A kind of product molding method of PP/PC micro-foaming material
CN108641194A (en) * 2018-03-26 2018-10-12 南京聚隆科技股份有限公司 A kind of hollow blow molding fretting map tool box material and preparation method thereof
CN108690267A (en) * 2018-05-29 2018-10-23 芜湖创科新材料科技有限公司 A kind of micro-foaming polypropylene material and preparation method thereof
CN109337153A (en) * 2018-08-09 2019-02-15 南京聚隆科技股份有限公司 A kind of automobile batteries shell cover material and preparation method thereof
CN108929554A (en) * 2018-08-28 2018-12-04 三斯达（江苏）环保科技有限公司 A kind of children's foam pad rubber and its processing method
CN112280177A (en) * 2020-11-03 2021-01-29 罗万象 Method for toughening child plastic seat through micro-foaming
CN113354899A (en) * 2021-06-21 2021-09-07 武汉理工大学 Light micro-foaming polypropylene composite material and preparation method thereof
CN113416363B (en) * 2021-08-02 2023-03-31 无锡会通轻质材料股份有限公司 Sound-suppression and high-resilience foamed polypropylene bead and application thereof
CN113999438A (en) * 2021-09-22 2022-02-01 浙江吉利控股集团有限公司 Damping rubber for chassis and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792554A (en) * 2010-03-12 2010-08-04 株洲时代新材料科技股份有限公司 Micro-foaming polypropylene and preparation method thereof
CN102218879A (en) * 2010-04-18 2011-10-19 黎明 Waste polypropylene-modified foaming plate and manufacturing method thereof
CN102464831A (en) * 2010-11-17 2012-05-23 宝瑞龙高分子材料(天津)有限公司 Micro-foaming thermoplastic elastomer for high-speed rail damping base plate and preparation method thereof
CN102604223A (en) * 2012-03-16 2012-07-25 武汉富蒂亚新型材料有限公司 Polypropylene resin foam concentrate and preparation method thereof
CN102634096A (en) * 2012-03-31 2012-08-15 合肥工业大学 Polypropylene foaming masterbatch and production method thereof
CN102850655A (en) * 2012-09-26 2013-01-02 长城汽车股份有限公司 Low-density automobile back door plate module and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792554A (en) * 2010-03-12 2010-08-04 株洲时代新材料科技股份有限公司 Micro-foaming polypropylene and preparation method thereof
CN102218879A (en) * 2010-04-18 2011-10-19 黎明 Waste polypropylene-modified foaming plate and manufacturing method thereof
CN102464831A (en) * 2010-11-17 2012-05-23 宝瑞龙高分子材料(天津)有限公司 Micro-foaming thermoplastic elastomer for high-speed rail damping base plate and preparation method thereof
CN102604223A (en) * 2012-03-16 2012-07-25 武汉富蒂亚新型材料有限公司 Polypropylene resin foam concentrate and preparation method thereof
CN102634096A (en) * 2012-03-31 2012-08-15 合肥工业大学 Polypropylene foaming masterbatch and production method thereof
CN102850655A (en) * 2012-09-26 2013-01-02 长城汽车股份有限公司 Low-density automobile back door plate module and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7103701B2 (en) 2019-01-16 2022-07-20 コンフォート グリッド テクノロジーズ プライベート リミテッド Gels and cushioning materials based on thermoplastic elastomers and their manufacturing methods

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