CN104098304B - Light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof - Google Patents
Light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof Download PDFInfo
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- CN104098304B CN104098304B CN201410272064.7A CN201410272064A CN104098304B CN 104098304 B CN104098304 B CN 104098304B CN 201410272064 A CN201410272064 A CN 201410272064A CN 104098304 B CN104098304 B CN 104098304B
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- making slag
- slag powder
- powder
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- 239000000843 powder Substances 0.000 title claims abstract description 35
- 239000002893 slag Substances 0.000 title claims abstract description 21
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 title claims abstract description 19
- 239000010436 fluorite Substances 0.000 title claims abstract description 19
- 238000009628 steelmaking Methods 0.000 title claims abstract description 19
- 238000005192 partition Methods 0.000 title claims abstract description 15
- 230000001413 cellular effect Effects 0.000 title claims abstract description 13
- 150000001875 compounds Chemical class 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- -1 polyethylene Polymers 0.000 claims abstract description 14
- 229920000876 geopolymer Polymers 0.000 claims abstract description 10
- 239000004816 latex Substances 0.000 claims abstract description 10
- 229920000126 latex Polymers 0.000 claims abstract description 10
- 235000014360 Punica granatum Nutrition 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 244000144730 Amygdalus persica Species 0.000 claims abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 7
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 235000006040 Prunus persica var persica Nutrition 0.000 claims abstract description 7
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 7
- 239000004568 cement Substances 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 238000004537 pulping Methods 0.000 claims description 3
- 230000003252 repetitive effect Effects 0.000 claims description 3
- 238000005201 scrubbing Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 3
- 229940056729 sodium sulfate anhydrous Drugs 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 229940095064 tartrate Drugs 0.000 claims description 3
- 244000294611 Punica granatum Species 0.000 claims 2
- 241000219991 Lythraceae Species 0.000 abstract description 7
- 238000009413 insulation Methods 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 3
- 239000000796 flavoring agent Substances 0.000 abstract description 2
- 235000019634 flavors Nutrition 0.000 abstract description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 239000002956 ash Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses the light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound, it is characterized in that, be made up of the raw material of following weight part: cement 9-14, polyethylene fibre 11-15, geopolymer 13-18, NS-780 redispersable latex powder 10-13, steel-making slag powder 19-24, dicumyl peroxide 1-2, fluorite mine tailing 17-19, oyster shell whiting 13-16, polypropylene fiber 1-4, Pomegranate Leaf 15-19, peach gum 4-7, auxiliary agent 3-6, suitable quantity of water; The present invention will add in starting material after the pyroprocessing such as fluorite mine tailing, steel-making slag powder, Pomegranate Leaf, can the obnoxious flavour such as formaldehyde, PM2.5 particle in absorbed air, and obtained partition plate has lightweight, the feature such as intensity is high, insulation, sound insulation, fire prevention.
Description
Technical field
The present invention relates to building material field, be specifically related to light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof.
Background technology
Light cellular partition board is made up of various industrial waste residues such as innoxious phosphogypsum, lightweight slag, flyash, through a kind of novel energy-conserving walling material of frequency conversion steam pressurized maintenance, the walling that it is a kind of external form as the cassette ceiling, but there is male and female falcon groove on its both sides, only sheet material need be erected during installation, male and female falcon is coated after a small amount of filleting mortar assembled.It has the advantages such as quality is light, intensity is high, multiple environmental protection, heat insulating, sound insulation, breathing damping, fire prevention, rapid construction, reduction body of wall cost, so enjoy favor in architecture indoor finishing field, but shortcomings such as the light cellular partition board ultimate compression strength used in the market is low, tensile strength is weak, anti-cracking performance and hanging ability is not good, production cost is high, sound-insulating weak effect.
Summary of the invention
Object of the present invention is just to provide light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of light cellular partition board of fluorite mine tailing/steel-making slag powder compound, it is characterized in that, be made up of the raw material of following weight part: cement 9-14, polyethylene fibre 11-15, geopolymer 13-18, NS-780 redispersable latex powder 10-13, steel-making slag powder 19-24, dicumyl peroxide 1-2, fluorite mine tailing 17-19, oyster shell whiting 13-16, polypropylene fiber 1-4, Pomegranate Leaf 15-19, peach gum 4-7, auxiliary agent 3-6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 6-9, Sodium sulfate anhydrous.min(99) 2-5, magnesium chloride 3-5, magnesium oxide 2-4, polyvinyl alcohol 0.2-0.5, Starso 0.03-0.07, sodium aluminate 0.05-0.6, tartrate 0.8-2.1, organosilicon crylic acid latex 2.1-4.3, 2-imidazolidone 0.04-0.09, silicon carbide 1-3, accelerant CZ 0.03-0.05, Syzygium aromaticum stem oil 1.2-3.2, its preparation method to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter is at 2-5mm, dry and get final product.
Described geopolymer is the novel inorganic silicon-aluminum gelatinized material a kind of structure with the network-like bonded structure of space three-dimensional, does not adopt " two mills one burn " calcining process of consumption of natural resource and the energy, substantially do not discharge CO in preparation technology
2.The raw material sources of geopolymer is extensive, easy to prepare, energy consumption is little, has higher mechanical property and very excellent resistance to elevated temperatures simultaneously, breaches the use range of traditional portland and alkali slag cement.The present invention, by geopolymer replacing partial cement, not only can be reduced cost energy-conserving and environment-protective, and can not weaken the pectisation of cement again.
The preparation method of the light cellular partition board of described a kind of fluorite mine tailing/steel-making slag powder compound, is characterized in that comprising the following steps:
(1) send in charring furnace by Pomegranate Leaf, at 485-605 DEG C, charing process 3-4 hour, takes out, is ground into powder, and the powder to gained makes it seethe spray form peach gum under condition in air blast, then adds NS-780 redispersable latex powder stirring and evenly mixing;
(2) get the hydrochloric acid soln that geopolymer puts into 8-12% and soak 4-5 hour, filter and take out, use clear water repetitive scrubbing, dry, be added to the water, meanwhile, add oyster shell whiting, grinding obtains slurry;
(3) steel-making slag powder, fluorite mine tailing are calcined at 600-828 DEG C after 3-6 hour and take out, pulverize, add polyethylene fibre, polypropylene fiber stirs 5-10 minute;
(4) step (1), (2), (3) reaction mass and other leftover materials are pulverized add suitable quantity of water stirring and evenly mixing and obtain slip, obtained slurry is added wall slab squeezing former is shaping, cutting, natural curing, to obtain final product.
The present invention has following beneficial effect: the present invention will add in starting material after the pyroprocessing such as fluorite mine tailing, steel-making slag powder, Pomegranate Leaf, can the obnoxious flavour such as formaldehyde, PM2.5 particle in absorbed air, obtained partition plate has lightweight, the feature such as intensity is high, insulation, sound insulation, fire prevention.
Embodiment
The light cellular partition board of described a kind of fluorite mine tailing/steel-making slag powder compound, it is characterized in that, be made up of the raw material of following weight part: cement 9, polyethylene fibre 11, geopolymer 13, NS-780 redispersable latex powder 10, steel-making slag powder 19, dicumyl peroxide 1, fluorite mine tailing 17, oyster shell whiting 16, polypropylene fiber 1, Pomegranate Leaf 17, peach gum 4, auxiliary agent 3, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 6, Sodium sulfate anhydrous.min(99) 2, magnesium chloride 3, magnesium oxide 4, polyvinyl alcohol 0.2, Starso 0.03, sodium aluminate 0.4, tartrate 1.8, organosilicon crylic acid latex 2.1,2-imidazolidone 0.04, silicon carbide 1, accelerant CZ 0.03, Syzygium aromaticum stem oil 2.2, its preparation method to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter, at 2-5mm, is dried and be get final product.
Making method comprises the following steps:
(1) send in charring furnace by Pomegranate Leaf, at 485-605 DEG C, charing process 3-4 hour, takes out, is ground into powder, and the powder to gained makes it seethe spray form peach gum under condition in air blast, then adds NS-780 redispersable latex powder stirring and evenly mixing;
(2) get the hydrochloric acid soln that geopolymer puts into 8-12% and soak 4-5 hour, filter and take out, use clear water repetitive scrubbing, dry, be added to the water, meanwhile, add oyster shell whiting, grinding obtains slurry;
(3) steel-making slag powder, fluorite mine tailing are calcined at 600-828 DEG C after 3-6 hour and take out, pulverize, add polyethylene fibre, polypropylene fiber stirs 5-10 minute;
(4) step (1), (2), (3) reaction mass and other leftover materials are pulverized add suitable quantity of water stirring and evenly mixing and obtain slip, obtained slurry is added wall slab squeezing former is shaping, cutting, natural curing, to obtain final product.
The technical indicator of being processed the light cellular partition board obtained by above-described embodiment is as follows:
(1) unit weight: 523kg/m
3;
(2) ultimate compression strength: 4.78MPa;
(3) high temperature resistant, flat appearance is smooth.
Claims (2)
1. the light cellular partition board of fluorite mine tailing/steel-making slag powder compound, it is characterized in that, be made up of the raw material of following weight part: cement 9-14, polyethylene fibre 11-15, geopolymer 13-18, NS-780 redispersable latex powder 10-13, steel-making slag powder 19-24, dicumyl peroxide 1-2, fluorite mine tailing 17-19, oyster shell whiting 13-16, polypropylene fiber 1-4, Pomegranate Leaf 15-19, peach gum 4-7, auxiliary agent 3-6, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 6-9, Sodium sulfate anhydrous.min(99) 2-5, magnesium chloride 3-5, magnesium oxide 2-4, polyvinyl alcohol 0.2-0.5, Starso 0.03-0.07, sodium aluminate 0.05-0.6, tartrate 0.8-2.1, organosilicon crylic acid latex 2.1-4.3, 2-imidazolidone 0.04-0.09, silicon carbide 1-3, accelerant CZ 0.03-0.05, Syzygium aromaticum stem oil 1.2-3.2, its preparation method to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter is at 2-5mm, dry and get final product.
2. the making method of the light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound according to claim 1, is characterized in that comprising the following steps:
(1) send in charring furnace by Pomegranate Leaf, at 485-605 DEG C, charing process 3-4 hour, takes out, is ground into powder, and the powder to gained makes it seethe spray form peach gum under condition in air blast, then adds NS-780 redispersable latex powder stirring and evenly mixing;
(2) get the hydrochloric acid soln that geopolymer puts into 8-12% and soak 4-5 hour, filter and take out, use clear water repetitive scrubbing, dry, be added to the water, meanwhile, add oyster shell whiting, grinding obtains slurry;
(3) steel-making slag powder, fluorite mine tailing are calcined at 600-828 DEG C after 3-6 hour and take out, pulverize, add polyethylene fibre, polypropylene fiber stirs 5-10 minute;
(4) step (1), (2), (3) reaction mass and other leftover materials are pulverized add suitable quantity of water stirring and evenly mixing and obtain slip, obtained slurry is added wall slab squeezing former is shaping, cutting, natural curing, to obtain final product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272064.7A CN104098304B (en) | 2014-06-18 | 2014-06-18 | Light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410272064.7A CN104098304B (en) | 2014-06-18 | 2014-06-18 | Light cellular partition board of a kind of fluorite mine tailing/steel-making slag powder compound and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104098304A CN104098304A (en) | 2014-10-15 |
| CN104098304B true CN104098304B (en) | 2016-03-23 |
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| CN106083129B (en) * | 2016-06-12 | 2019-02-01 | 浙江孚瓯科技有限公司 | The preparation method and products thereof of light stone imitation body heat insulation veneer |
| CN106083014A (en) * | 2016-06-12 | 2016-11-09 | 浙江孚瓯科技有限公司 | Preparation method of foaming building stones roof heat insulation brick and products thereof |
| CN106083008A (en) * | 2016-06-12 | 2016-11-09 | 浙江孚瓯科技有限公司 | Preparation method of lightweight cloud stone ceiling board and products thereof |
| CN106083178A (en) * | 2016-06-12 | 2016-11-09 | 浙江孚瓯科技有限公司 | Preparation method of insulation and decoration dividing plate and products thereof |
| CN106083170A (en) * | 2016-06-12 | 2016-11-09 | 浙江孚瓯科技有限公司 | Preparation method of foaming colored stone heat insulating decorative board and products thereof |
| CN108178576A (en) * | 2017-12-30 | 2018-06-19 | 孙祎 | The preparation method of ceramic tile is imitated in a kind of resistance to compression |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054578A (en) * | 1991-01-11 | 1991-09-18 | 宋纯德 | The manufacture method of jade magnesium silicate marble kitchen sink surface |
| WO2011158109A1 (en) * | 2010-06-18 | 2011-12-22 | Cemex Research Group Ag | Clinker and method for preparing a hydraulic cement with low co2 emission and high resistance |
| CN103774777A (en) * | 2013-12-20 | 2014-05-07 | 汪超 | Assembly type skeleton multi-ribbed beam-plate composite structure big plate |
-
2014
- 2014-06-18 CN CN201410272064.7A patent/CN104098304B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054578A (en) * | 1991-01-11 | 1991-09-18 | 宋纯德 | The manufacture method of jade magnesium silicate marble kitchen sink surface |
| WO2011158109A1 (en) * | 2010-06-18 | 2011-12-22 | Cemex Research Group Ag | Clinker and method for preparing a hydraulic cement with low co2 emission and high resistance |
| CN103774777A (en) * | 2013-12-20 | 2014-05-07 | 汪超 | Assembly type skeleton multi-ribbed beam-plate composite structure big plate |
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| CN104098304A (en) | 2014-10-15 |
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