CN104072032B - A kind of raw material light cellular partition board containing coal gangue and preparation method thereof - Google Patents
A kind of raw material light cellular partition board containing coal gangue and preparation method thereof Download PDFInfo
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- CN104072032B CN104072032B CN201410226896.5A CN201410226896A CN104072032B CN 104072032 B CN104072032 B CN 104072032B CN 201410226896 A CN201410226896 A CN 201410226896A CN 104072032 B CN104072032 B CN 104072032B
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- coal gangue
- raw material
- partition board
- auxiliary agent
- flyash
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- 239000003245 coal Substances 0.000 title claims abstract description 17
- 239000002994 raw material Substances 0.000 title claims abstract description 17
- 238000005192 partition Methods 0.000 title claims abstract description 14
- 230000001413 cellular effect Effects 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002699 waste material Substances 0.000 claims abstract description 10
- 239000010881 fly ash Substances 0.000 claims abstract description 9
- 229920000876 geopolymer Polymers 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 239000004568 cement Substances 0.000 claims abstract description 7
- 229920002209 Crumb rubber Polymers 0.000 claims abstract description 6
- 235000003222 Helianthus annuus Nutrition 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000391 magnesium silicate Substances 0.000 claims abstract description 6
- 229910052919 magnesium silicate Inorganic materials 0.000 claims abstract description 6
- 235000019792 magnesium silicate Nutrition 0.000 claims abstract description 6
- 239000002689 soil Substances 0.000 claims abstract description 6
- 239000002383 tung oil Substances 0.000 claims abstract description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 4
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 4
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 4
- 244000020551 Helianthus annuus Species 0.000 claims abstract 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 5
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002956 ash Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 238000004537 pulping Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 3
- 229940056729 sodium sulfate anhydrous Drugs 0.000 claims description 3
- 229940095064 tartrate Drugs 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000009413 insulation Methods 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract description 2
- 241000208818 Helianthus Species 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000003252 repetitive effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses the light cellular partition board that a kind of raw material contains coal gangue, it is characterized in that, be made up of the raw material of following weight part: cement 9-13, geopolymer 12-15, waste Crumb rubber 11-13, flyash 19-26, coal gangue 18-24, sawdust 17-20, Evening Tide soil 13-16, Sodium hexametaphosphate 99 0.6-1.4, fibrous magnesium silicate 4-8, ACRYLIC EMULSION 8-10, dicumyl peroxide 1-2, tung oil 3-5, floral disc of sunflower into 17-20, auxiliary agent 3-6, suitable quantity of water; Flyash, coal gangue, sawdust the like waste add in starting material by the present invention, achieve the recycling economy effect turned waste into wealth, and obtained partition plate has the advantages such as unit weight is light, intensity is high, shock resistance is good, waterproof sound insulation.
Description
Technical field
The present invention relates to building material field, be specifically related to a kind of raw material light cellular partition board containing coal gangue and preparation method thereof.
Background technology
Light cellular partition board is made up of various industrial waste residues such as innoxious phosphogypsum, lightweight slag, flyash, through a kind of novel energy-conserving walling material of frequency conversion steam pressurized maintenance, the walling that it is a kind of external form as the cassette ceiling, but there is male and female falcon groove on its both sides, only sheet material need be erected during installation, male and female falcon is coated after a small amount of filleting mortar assembled.It has the advantages such as quality is light, intensity is high, multiple environmental protection, heat insulating, sound insulation, breathing damping, fire prevention, rapid construction, reduction body of wall cost, so enjoy favor in architecture indoor finishing field, but shortcomings such as the light cellular partition board ultimate compression strength used in the market is low, tensile strength is weak, anti-cracking performance and hanging ability is not good, production cost is high, sound-insulating weak effect.
Summary of the invention
Object of the present invention is just to provide a kind of raw material light cellular partition board containing coal gangue and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of raw material contains the light cellular partition board of coal gangue, it is characterized in that, be made up of the raw material of following weight part: cement 9-13, geopolymer 12-15, waste Crumb rubber 11-13, flyash 19-26, coal gangue 18-24, sawdust 17-20, Evening Tide soil 13-16, Sodium hexametaphosphate 99 0.6-1.4, fibrous magnesium silicate 4-8, ACRYLIC EMULSION 8-10, dicumyl peroxide 1-2, tung oil 3-5, floral disc of sunflower into 17-20, auxiliary agent 3-6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 6-9, Sodium sulfate anhydrous.min(99) 2-5, magnesium chloride 3-5, magnesium oxide 2-4, polyvinyl alcohol 0.2-0.5, Starso 0.03-0.07, sodium aluminate 0.05-0.6, tartrate 0.8-2.1, organosilicon crylic acid latex 2.1-4.3, 2-imidazolidone 0.04-0.09, silicon carbide 1-3, accelerant CZ 0.03-0.05, Syzygium aromaticum stem oil 1.2-3.2, its preparation method to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter is at 2-5mm, dry and get final product.
Described geopolymer is the novel inorganic silicon-aluminum gelatinized material a kind of structure with the network-like bonded structure of space three-dimensional, does not adopt " two mills one burn " calcining process of consumption of natural resource and the energy, substantially do not discharge CO in preparation technology
2.The raw material sources of geopolymer is extensive, easy to prepare, energy consumption is little, has higher mechanical property and very excellent resistance to elevated temperatures simultaneously, breaches the use range of traditional portland and alkali slag cement.The present invention, by geopolymer replacing partial cement, not only can be reduced cost energy-conserving and environment-protective, and can not weaken the pectisation of cement again.
Described a kind of raw material contains the preparation method of the light cellular partition board of coal gangue, it is characterized in that comprising the following steps:
(1) floral disc of sunflower into, sawdust are sent in charring furnace, at 489-605 DEG C, charing process 3-4 hour, takes out, is ground into powder, and the powder to gained makes it seethe spray form tung oil under condition in air blast, then adds fibrous magnesium silicate and stir and make it mixing;
(2) get the hydrochloric acid soln that geopolymer puts into 8-12% and soak 4-5 hour, filter and take out, use clear water repetitive scrubbing, dry, be added to the water, meanwhile, add waste Crumb rubber, river sand, grinding obtains slurry;
(3) flyash, coal gangue, Evening Tide soil are taken out calcine 3-6 hour at 600-828 DEG C after, pulverize, spray ACRYLIC EMULSION to evenly with spraying gun, dry;
(4) step (1), (2), (3) reaction mass and other leftover materials are pulverized add suitable quantity of water stirring and evenly mixing and obtain slip, obtained slurry is added wall slab squeezing former is shaping, cutting, natural curing, to obtain final product.
The present invention has following beneficial effect: flyash, coal gangue, sawdust the like waste add in starting material by the present invention, achieve the recycling economy effect turned waste into wealth, obtained partition plate has the advantages such as unit weight is light, intensity is high, shock resistance is good, waterproof sound insulation.
Embodiment
Described a kind of raw material contains the light cellular partition board of coal gangue, it is characterized in that, be made up of the raw material of following weight part: cement 9, geopolymer 12, waste Crumb rubber 11, flyash 19, coal gangue 24, sawdust 20, Evening Tide soil 15, Sodium hexametaphosphate 99 0.6, fibrous magnesium silicate 4, ACRYLIC EMULSION 10, dicumyl peroxide 1, tung oil 3, floral disc of sunflower into 17, auxiliary agent 6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 8, Sodium sulfate anhydrous.min(99) 2, magnesium chloride 3, magnesium oxide 4, polyvinyl alcohol 0.4, Starso 0.03, sodium aluminate 0.05, tartrate 0.8, organosilicon crylic acid latex 2.1,2-imidazolidone 0.06, silicon carbide 1, accelerant CZ 0.03, Syzygium aromaticum stem oil 1.2, its preparation method to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter, at 2-5mm, is dried and be get final product.
Making method comprises the following steps:
(1) floral disc of sunflower into, sawdust are sent in charring furnace, at 489-605 DEG C, charing process 3-4 hour, takes out, is ground into powder, and the powder to gained makes it seethe spray form tung oil under condition in air blast, then adds fibrous magnesium silicate and stir and make it mixing;
(2) get the hydrochloric acid soln that geopolymer puts into 8-12% and soak 4-5 hour, filter and take out, use clear water repetitive scrubbing, dry, be added to the water, meanwhile, add waste Crumb rubber, river sand, grinding obtains slurry;
(3) flyash, coal gangue, Evening Tide soil are taken out calcine 3-6 hour at 600-828 DEG C after, pulverize, spray ACRYLIC EMULSION to evenly with spraying gun, dry;
(4) step (1), (2), (3) reaction mass and other leftover materials are pulverized add suitable quantity of water stirring and evenly mixing and obtain slip, obtained slurry is added wall slab squeezing former is shaping, cutting, natural curing, to obtain final product.
The technical indicator of being processed the light cellular partition board obtained by above-described embodiment is as follows:
(1) unit weight: 484kg/m
3;
(2) ultimate compression strength: 4.76MPa; (4) high temperature resistant, flat appearance is smooth;
(3) shock resistance: 30kg drop 0.5 meter, flawless.
Claims (1)
1. a raw material contains the light cellular partition board of coal gangue, it is characterized in that, be made up of the raw material of following weight part: cement 9-13, geopolymer 12-15, waste Crumb rubber 11-13, flyash 19-26, coal gangue 18-24, sawdust 17-20, Evening Tide soil 13-16, Sodium hexametaphosphate 99 0.6-1.4, fibrous magnesium silicate 4-8, ACRYLIC EMULSION 8-10, dicumyl peroxide 1-2, tung oil 3-5, floral disc of sunflower into 17-20, auxiliary agent 3-6, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: volcanic ash 6-9, Sodium sulfate anhydrous.min(99) 2-5, magnesium chloride 3-5, magnesium oxide 2-4, polyvinyl alcohol 0.2-0.5, Starso 0.03-0.07, sodium aluminate 0.05-0.6, tartrate 0.8-2.1, organosilicon crylic acid latex 2.1-4.3, 2-imidazolidone 0.04-0.09, silicon carbide 1-3, accelerant CZ 0.03-0.05, Syzygium aromaticum stem oil 1.2-3.2, the preparation method of auxiliary agent to stir adding magnesium oxide powder in 50% magnesium chloride solution to obtain inorganic gel agent, then other leftover materials are pulverized mixing, add suitable quantity of water and stir 30-40 minute pulping, granulation, balling-up particle diameter is at 2-5mm, dry and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410226896.5A CN104072032B (en) | 2014-05-27 | 2014-05-27 | A kind of raw material light cellular partition board containing coal gangue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410226896.5A CN104072032B (en) | 2014-05-27 | 2014-05-27 | A kind of raw material light cellular partition board containing coal gangue and preparation method thereof |
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| Publication Number | Publication Date |
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| CN104072032A CN104072032A (en) | 2014-10-01 |
| CN104072032B true CN104072032B (en) | 2016-04-06 |
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| CN201410226896.5A Active CN104072032B (en) | 2014-05-27 | 2014-05-27 | A kind of raw material light cellular partition board containing coal gangue and preparation method thereof |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104326698B (en) * | 2014-10-16 | 2017-02-08 | 江苏贸隆机械制造有限公司 | Building sound insulation material and preparation method thereof |
| CN109208839A (en) * | 2017-06-29 | 2019-01-15 | 河北卓达建材研究院有限公司 | It copies and takes molding alkali-activated carbonatite gangue decorative plate of outer wall and preparation method thereof |
| CN107935464A (en) * | 2017-10-26 | 2018-04-20 | 连云港职业技术学院 | A kind of New Building Materials and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070221100A1 (en) * | 2006-03-22 | 2007-09-27 | Sanjay Kumar | Process for the preparation of self-glazed geopolymer tile from fly ash and blast furnace slag |
| CN101880141A (en) * | 2010-06-13 | 2010-11-10 | 周远飞 | Wall form integrated board and manufacturing method thereof |
| CN103419271A (en) * | 2012-05-23 | 2013-12-04 | 北京航空航天大学 | Preparation method of calcium silicate board |
-
2014
- 2014-05-27 CN CN201410226896.5A patent/CN104072032B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070221100A1 (en) * | 2006-03-22 | 2007-09-27 | Sanjay Kumar | Process for the preparation of self-glazed geopolymer tile from fly ash and blast furnace slag |
| CN101880141A (en) * | 2010-06-13 | 2010-11-10 | 周远飞 | Wall form integrated board and manufacturing method thereof |
| CN103419271A (en) * | 2012-05-23 | 2013-12-04 | 北京航空航天大学 | Preparation method of calcium silicate board |
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| CN104072032A (en) | 2014-10-01 |
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