CN104068022A - Bactericide composition containing fluopicolide and ethylicin - Google Patents
Bactericide composition containing fluopicolide and ethylicin Download PDFInfo
- Publication number
- CN104068022A CN104068022A CN201410326814.4A CN201410326814A CN104068022A CN 104068022 A CN104068022 A CN 104068022A CN 201410326814 A CN201410326814 A CN 201410326814A CN 104068022 A CN104068022 A CN 104068022A
- Authority
- CN
- China
- Prior art keywords
- fluopicolide
- ethyl ethylthio
- ethylthio sulfonate
- bactericidal composition
- sulfonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OICGFSUWXCJLCO-UHFFFAOYSA-N 1-ethylsulfonylsulfanylethane Chemical compound CCSS(=O)(=O)CC OICGFSUWXCJLCO-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000005782 Fluopicolide Substances 0.000 title claims abstract description 52
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- 239000003899 bactericide agent Substances 0.000 title abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 7
- 229920000877 Melamine resin Polymers 0.000 claims description 7
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- -1 polyoxy ethyl ether Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical group OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 6
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 4
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 239000007859 condensation product Substances 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920006324 polyoxymethylene Polymers 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- 239000003814 drug Substances 0.000 abstract description 8
- 229940079593 drug Drugs 0.000 abstract description 3
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 231100000086 high toxicity Toxicity 0.000 abstract 1
- 230000005923 long-lasting effect Effects 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 235000002566 Capsicum Nutrition 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 241000208293 Capsicum Species 0.000 description 6
- 239000006002 Pepper Substances 0.000 description 6
- 241000722363 Piper Species 0.000 description 6
- 235000016761 Piper aduncum Nutrition 0.000 description 6
- 235000017804 Piper guineense Nutrition 0.000 description 6
- 235000008184 Piper nigrum Nutrition 0.000 description 6
- 239000001390 capsicum minimum Substances 0.000 description 6
- 235000012055 fruits and vegetables Nutrition 0.000 description 4
- 239000000575 pesticide Substances 0.000 description 3
- 235000016623 Fragaria vesca Nutrition 0.000 description 2
- 240000009088 Fragaria x ananassa Species 0.000 description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000003641 microbiacidal effect Effects 0.000 description 2
- 229940124561 microbicide Drugs 0.000 description 2
- 239000002855 microbicide agent Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000005802 Mancozeb Substances 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericide composition containing fluopicolide and ethylicin. The composition comprises the fluopicolide and the ethylicin; the weight ratio of the fluopicolide to the ethylicin is (1:10)-(10:1). An actual test shows that the bactericide disclosed by the invention has an obvious effect for preventing and treating anthracnose of fruit trees and vegetable crops. The bactericide composition can replace part of medium and high-toxicity bactericides, so that the drug using amount is reduced, the environment pollution is alleviated, and residues of agricultural products are reduced. The bactericide composition can delay the drug resistance of the anthracnose to the single bactericide and has the advantage of long lasting period; compared with the single medicament, the bactericide composition has the advantage that the cost can be lowered.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of microbicide compositions that contains fluopicolide and S-Ethyl ethylthio sulfonate of preventing and treating fruit and vegetable anthracnose.
Background technology
Anthracnose is the Major Diseases of the fruits and vegetables such as capsicum, capsicum, strawberry, grape; continuous expansion along with Greenhouse area; in recent years; the fruit and vegetable anthracnose Occurrence degrees such as capsicum, capsicum, strawberry rise year by year; become the large evil that fruits and vegetables are produced; morbidity seriously causes a large amount of decayed fruits often, and loss can reach 40%-60%.In production, the medicament of such disease of control be take thiophanate-methyl, tpn, mancozeb etc. as main, and pesticide resistance has appearred in use all the year round.
Summary of the invention
Goal of the invention: technical problem to be solved by this invention has been to provide a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing.
Technical scheme: for solving the problems of the technologies described above, the invention provides a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing, described composition comprises fluopicolide and S-Ethyl ethylthio sulfonate, and described fluopicolide and S-Ethyl ethylthio sulfonate weight ratio are 1:10-10:1.
Wherein, above-mentioned bactericidal composition also comprises auxiliary agent and filler, and described fluopicolide and S-Ethyl ethylthio sulfonate account for 5%～60% of bactericidal composition gross weight, and auxiliary agent accounts for 5%～30% of bactericidal composition gross weight, and all the other are filler.
Wherein, above-mentioned auxiliary agent is lauryl sodium sulfate, ethoxylated dodecyl alcohol, lignosulfonates, sulfonic acid polyformaldehyde condensation product, polyethylene glycol, ammonium sulfate, sodium carboxymethylcellulose, dimethylbenzene, 1-METHYLPYRROLIDONE, alkyl benzene calcium sulfonate, phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether, ethylene glycol, silicone compound, pulls open one or more in powder, xanthans.
Wherein, above-mentioned filler is one or more in kaolin, diatomite or aluminium-magnesium silicate.
Wherein, the formulation of above-mentioned bactericidal composition is a kind of in water dispersible granules, wetting powder or aqueous emulsion.
Beneficial effect: compared with prior art, the present invention has the following advantages:
1, compare this kind with single dose anthracnose is had to obvious synergistic effect, can significantly improve control efficiency;
2, high poisoning microbial inoculum in can Substitute For Partial, reduces dosage, reduces the residual of environmental pollution and agricultural product;
3, can delay the pesticide resistance of anthracnose to single bactericide;
4, have advantages of that the lasting period is long, compare with single medicament, can reduce costs.
Embodiment
Embodiment 1:55% fluopicolide S-Ethyl ethylthio sulfonate water dispersible granules
5g fluopicolide, 50g S-Ethyl ethylthio sulfonate, 4g lauryl sodium sulfate, 2g ethoxylated dodecyl alcohol, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation product (NNO), 2g polyethylene glycol, 4g ammonium sulfate, 10g sodium carboxymethylcellulose, kaolin are mended to 100g, make 55% fluopicolide S-Ethyl ethylthio sulfonate water dispersible granules.
Embodiment 2 55% fluopicolide S-Ethyl ethylthio sulfonate water dispersible granules
50g fluopicolide, 5g S-Ethyl ethylthio sulfonate, 4g lauryl sodium sulfate, 2g ethoxylated dodecyl alcohol, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation product (NNO), 2g polyethylene glycol, 4g ammonium sulfate, 10g sodium carboxymethylcellulose, kaolin are mended to 100g, make 55% fluopicolide S-Ethyl ethylthio sulfonate water dispersible granules.
According to the formula of embodiment 1,2, active ingredient fluopicolide, S-Ethyl ethylthio sulfonate, auxiliary agent, filler are mixed, after stirring, through pulverizing, obtain female powder, then granulation, dry, sieve, can make fluopicolide S-Ethyl ethylthio sulfonate water dispersible granules.
Embodiment 3:50% fluopicolide S-Ethyl ethylthio sulfonate wetting powder
25g fluopicolide, 25g S-Ethyl ethylthio sulfonate, 4g lauryl sodium sulfate, 4g sodium lignin sulfonate, 2g pull open powder (BX), diatomite is supplied 100g.Make 50% fluopicolide S-Ethyl ethylthio sulfonate wetting powder.
Embodiment 4:60% fluopicolide S-Ethyl ethylthio sulfonate wetting powder
20g fluopicolide, 40g S-Ethyl ethylthio sulfonate, 6g lauryl sodium sulfate, 5g sodium lignin sulfonate, 4g pull open powder (BX), diatomite is supplied 100g.Make 60% fluopicolide S-Ethyl ethylthio sulfonate wetting powder.
Formula according to embodiment 3,4, is added together fluopicolide, S-Ethyl ethylthio sulfonate, auxiliary agent, filler, and after air-flow crushing, in cone-type mixer, mix and blend is 30 minutes, can make fluopicolide S-Ethyl ethylthio sulfonate wetting powder.
Embodiment 5:30% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion
10g fluopicolide, 20g S-Ethyl ethylthio sulfonate, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthans, 0.8g aluminium-magnesium silicate, water are mended to 100g, make 30% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion.
Embodiment 6:20% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion
16g fluopicolide, 4g S-Ethyl ethylthio sulfonate, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthans, 0.8g aluminium-magnesium silicate, water are mended to 100g, make 20% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion.
According to the formula of embodiment 5,6, fluopicolide, S-Ethyl ethylthio sulfonate, solvent xylene and 1-METHYLPYRROLIDONE, emulsifier alkyl benzene calcium sulfonate and phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether are added together, be dissolved into even oil phase; Water, antifreeze ethylene glycol, thickener xanthans, defoamer silicone compound are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, can make fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion.
Embodiment 7:5% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion
1g fluopicolide, 4g S-Ethyl ethylthio sulfonate, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthans, 0.8g aluminium-magnesium silicate, water are mended to 100g, make 5% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion.
According to the formula of embodiment 7, fluopicolide, S-Ethyl ethylthio sulfonate, solvent xylene and 1-METHYLPYRROLIDONE, emulsifier alkyl benzene calcium sulfonate and phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether are added together, be dissolved into even oil phase; Water, antifreeze ethylene glycol, thickener xanthans, defoamer silicone compound are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, can make 5% fluopicolide S-Ethyl ethylthio sulfonate aqueous emulsion.
Implementation of an application example 1: fluopicolide S-Ethyl ethylthio sulfonate control pepper anthracnose
The present invention tests and April 19, by every mu of medication amount of formulation, was watered 60 kilograms and carries out even spraying, and dispenser is 3 times altogether, 7 days, each dispenser interval, and after the 3rd dispenser, investigation result is as table 1.
Table 1 fluopicolide S-Ethyl ethylthio sulfonate control pepper anthracnose field control effectiveness test
As seen from Table 1, the present composition is all remarkable to the control efficiency of pepper anthracnose, than apparently higher than contrast medicament, capsicum is given birth to safety, and bad reaction is not found in field.
Implementation of an application example 2: fluopicolide S-Ethyl ethylthio sulfonate control pepper anthracnose
The present invention tests and May 15, by every mu of medication amount of formulation, was watered 60 kilograms and carries out even spraying, and dispenser is 3 times altogether, 7 days, each dispenser interval, and after the 3rd dispenser, investigation result is as table 1.
Table 2 fluopicolide S-Ethyl ethylthio sulfonate control pepper anthracnose field control effectiveness test
As seen from Table 2, the present composition is all remarkable to the control efficiency of pepper anthracnose, than apparently higher than contrast medicament, capsicum is given birth to safety, and bad reaction is not found in field.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. contain the composite bactericidal composition of fluopicolide and S-Ethyl ethylthio sulfonate, it is characterized in that, described composition comprises fluopicolide and S-Ethyl ethylthio sulfonate, and described fluopicolide and S-Ethyl ethylthio sulfonate weight ratio are 1:10-10:1.
2. a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing according to claim 1, it is characterized in that, described bactericidal composition also comprises auxiliary agent and filler, described fluopicolide and S-Ethyl ethylthio sulfonate account for 5%～60% of bactericidal composition gross weight, auxiliary agent accounts for 5%～30% of bactericidal composition gross weight, and all the other are filler.
3. a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing according to claim 2, it is characterized in that, described auxiliary agent is lauryl sodium sulfate, ethoxylated dodecyl alcohol, lignosulfonates, sulfonic acid polyformaldehyde condensation product, polyethylene glycol, ammonium sulfate, sodium carboxymethylcellulose, dimethylbenzene, 1-METHYLPYRROLIDONE, alkyl benzene calcium sulfonate, phenethyl phenol mela mine-formaldehyde resin polyoxy ethyl ether, ethylene glycol, silicone compound, pulls open one or more in powder, xanthans.
4. a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing according to claim 2, is characterized in that, described filler is one or more in kaolin, diatomite or aluminium-magnesium silicate.
5. a kind of fluopicolide and composite bactericidal composition of S-Ethyl ethylthio sulfonate of containing according to claim 1, is characterized in that, the formulation of described bactericidal composition is a kind of in water dispersible granules, wetting powder or aqueous emulsion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410326814.4A CN104068022B (en) | 2014-07-09 | 2014-07-09 | A kind of microbicide compositions containing fluopicolide and S-Ethyl ethylthio sulfonate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410326814.4A CN104068022B (en) | 2014-07-09 | 2014-07-09 | A kind of microbicide compositions containing fluopicolide and S-Ethyl ethylthio sulfonate |
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| Publication Number | Publication Date |
|---|---|
| CN104068022A true CN104068022A (en) | 2014-10-01 |
| CN104068022B CN104068022B (en) | 2016-04-06 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2494867A1 (en) * | 2011-03-01 | 2012-09-05 | Bayer CropScience AG | Halogen-substituted compounds in combination with fungicides |
| CN103491785A (en) * | 2011-03-23 | 2014-01-01 | 拜耳知识产权有限责任公司 | Active compound combinations |
| CN103548856A (en) * | 2013-11-20 | 2014-02-05 | 骆毛喜 | Compounded bactericide and application thereof |
| CN104041505A (en) * | 2014-03-01 | 2014-09-17 | 海南正业中农高科股份有限公司 | Fluopicolide-containing bactericidal composition |
-
2014
- 2014-07-09 CN CN201410326814.4A patent/CN104068022B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2494867A1 (en) * | 2011-03-01 | 2012-09-05 | Bayer CropScience AG | Halogen-substituted compounds in combination with fungicides |
| CN103491785A (en) * | 2011-03-23 | 2014-01-01 | 拜耳知识产权有限责任公司 | Active compound combinations |
| CN103548856A (en) * | 2013-11-20 | 2014-02-05 | 骆毛喜 | Compounded bactericide and application thereof |
| CN104041505A (en) * | 2014-03-01 | 2014-09-17 | 海南正业中农高科股份有限公司 | Fluopicolide-containing bactericidal composition |
Non-Patent Citations (1)
| Title |
|---|
| 朱卫刚 等: ""新型杀菌剂氟吡菌胺室内杀菌活性"", 《农药》 * |
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