CN104041505A - Fluopicolide-containing bactericidal composition - Google Patents
Fluopicolide-containing bactericidal composition Download PDFInfo
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- CN104041505A CN104041505A CN201410071405.4A CN201410071405A CN104041505A CN 104041505 A CN104041505 A CN 104041505A CN 201410071405 A CN201410071405 A CN 201410071405A CN 104041505 A CN104041505 A CN 104041505A
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Abstract
The invention belongs to the field of plant protection and relates to a fluopicolide-containing bactericidal composition. The fluopicolide-containing bactericidal composition comprises an effective dose of active ingredients A and B for synergism. The active ingredient A is fluopicolide and the active ingredient B contains one of a sulfur-type bactericidal component, an amide-type bactericidal component, an imidazole-type bactericidal component, an oxazole-type bactericidal component, a pyrimidine-type bactericidal component and a biological source-type bactericidal component. The fluopicolide-containing bactericidal composition can produce good synergism in a certain matching range, improves disease-resistant effects, prevents and treats a plurality of diseases in agricultural production, reduces use frequency and a use cost and delays pathogen resistance to a single agent.
Description
Technical field
The present invention relates to the bactericidal composition that contains fluopicolide, belong to bactericide field, composition is used for preventing and treating downy mildew, late blight, rice blast, powdery mildew, banded sclerotial blight, gray mold, anthracnose, leaf spot, scab etc.
Background technology
Fluopicolide, English common name flupicolide, chemical name 2, the chloro-N-of 6-bis-(the chloro-5-trifluoromethyl-2-of 3-picolyl) benzamide, molecular formula is C
14h
8cl
3f
3n
2o.Fluopicolide is mainly used in preventing and treating Oomycete disease as downy mildew, epidemic disease etc., in addition rice blast, powdery mildew, gray mold is had to certain preventive effect.For improving preventive effect, Reasonable Protection medicament, delaying the control efficiency of germ to the drug-fast generation of new medicament and raising medicament, be necessary to carry out rational composition research.Inventor, by the research to the composite effect of fluopicolide, has found some beyond thought effects.
Summary of the invention
The object of the present invention is to provide the bactericidal composition that contains fluopicolide, it is that the sterilization component of two kinds of different structures, the different mechanisms of action is carried out composite, be expanding prevention spectrum and the effective way that improves drug effect, the more important thing is and avoid or delay the generation of disease to new composition resistance.The object of the invention is to realize by following measures.
The invention provides a kind of bactericidal composition that contains fluopicolide, it is characterized in that A and two kinds of active components of B that said composition comprises effective dose, wherein A is fluopicolide, B is selected from sulfur-bearing class sterilization component zineb, Carbatene, ambam, carbendazim, S-Ethyl ethylthio sulfonate, Propineb, tpn, thiophanate-methyl, tmtd, asomate, captan, folpet, sulfonat, one in fenaminosulf, or be selected from amide-type sterilization component dimethomorph, zoxamide, efficient metalaxyl, one in efficient M 9834, or be selected from imidazoles sterilization component cyazofamid, Fenamidone, Prochloraz, a kind of in pefurazoate, or be selected from the one in oxazole class sterilization Cheng Fen famoxadone, or be selected from the phonetic phenol of miazines sterilization component second, cyprodinil, fluorine mepanipyrim, one in mepanipyrim, or be selected from biogenic substances sterilization component jinggangmeisu, kasugarnycin, polyoxin, one in Zhongshengmycin.
Preferably, in above-mentioned bactericidal composition, component A is fluopicolide, and B component is selected from the one in zineb, Carbatene, ambam, carbendazim, S-Ethyl ethylthio sulfonate, dimethomorph, cyazofamid, Fenamidone, Prochloraz, famoxadone, the phonetic phenol of second, cyprodinil, jinggangmeisu, kasugarnycin, polyoxin.
In above-mentioned bactericidal composition, preferred, the ratio of quality and the number of copies of A, B two components is 1:50-50:1, preferred, and mass fraction is than being 1:20-10:1.
In above-mentioned bactericidal composition, preferred, the quality sum of A component and B component accounts for the 1-80% of bactericidal composition gross mass percentage.
Above-mentioned composition of the present invention can be made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion, aqueous emulsion, for spraying, filling root, seed dressing etc.
The present invention also finds, above-mentioned composition of the present invention has good control efficiency to cucumber downy mildew, tomato late blight, rice blast, wheat powdery mildew, rice sheath blight disease, and synergistic effect is obvious.
The present invention also provides the purposes of above-mentioned composition for controlling plant diseases, the fungus-caused downy mildew of disease amphitrichous bacterium subphylum of suitable control, late blight, peronospora tabacina etc., the fungus-caused rice blast of Fungi Imperfecti, banded sclerotial blight, gray mold, scab etc., the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot etc., rust, smut etc. that Basidiomycotina causes.Therefore, the present invention also comprises the purposes of multiple fungal disease on above-mentioned composition control plant.
In the purposes of above-mentioned composition of the present invention, described plant is preferably cucumber, tomato, paddy rice, wheat, watermelon, apple, grape, oranges and tangerines, pears, lichee, flowers, lawn etc.
Beneficial effect of the present invention is:
1, synergistic effect is obvious: composition shows good synergistic effect in certain ratio range, has improved the protection effect of composition.
2, expanding prevention spectrum: composition can be prevented and treated the multiple diseases in agricultural production.
3, reduce use cost: because compositely thering is the preventive effect of raising, control spectrum increases, and has reduced access times, has reduced use cost;
4, delay pesticide resistance: the composition of two kinds of different mechanism of action is composite, pathogen is difficult for developing immunity to drugs, and delays pathogen to the drug-fast generation of single dose.
Embodiment
Following examples are to further illustrate of the present invention, but the present invention is not confined to composition and purposes in present embodiment.
Embodiment 1 is containing the control efficiency of fluopicolide composition to cucumber downy mildew
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When test, cucumber plant, substantially in 4 leaf phases, is investigated downy mildew incidence before the 1st medicine.Carried out cucumber downy mildew pot experiment with fluopicolide composition, and established corresponding single dose and blank, adopted the conventional conventional spray of manual sprayer, every medicament sprays 10 strains, and the 7-10d after 1 time that sprays sprays 1 time again.10-14d investigation after the 2nd dispenser, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-10% of whole leaf area;
5 grades: the connected area of scab accounts for the 11%-20% of whole leaf area;
7 grades: the connected area of scab accounts for the 21%-50% of whole leaf area;
9 grades: the connected area of scab accounts for the more than 51% of whole leaf area;
Theoretical preventive effect (%)=x+y-xy
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect taking actual preventive effect as synergistic effect.The results are shown in Table 1.
Table 1 is containing the control efficiency of fluopicolide composition to cucumber downy mildew
By fluopicolide composition, the potted plant test of cucumber downy mildew is found, the composition of composition, fluopicolide and the Fenamidone of composition, fluopicolide and the cyazofamid of composition, fluopicolide and the dimethomorph of composition, fluopicolide and the S-Ethyl ethylthio sulfonate of composition, fluopicolide and the carbendazim of composition, fluopicolide and the ambam of composition, fluopicolide and the Carbatene of fluopicolide and zineb, fluopicolide Yu the composition of famoxadone to the effect of cucumber downy mildew all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of fluopicolide and above-mentioned Fungicidal compounds is synergy to cucumber downy mildew.
Embodiment 2 is containing the control efficiency of fluopicolide composition to tomato late blight
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When test, tomato plant, substantially in 4 leaf phases, is investigated late blight incidence before the 1st medicine.Carried out tomato late blight pot experiment with fluopicolide composition, and established corresponding single dose and blank, adopted the conventional conventional spray of manual sprayer, every medicament sprays 10 strains, and the 7-10d after 1 time that sprays sprays 1 time again.10-14d investigation after the 2nd dispenser, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-10% of whole leaf area;
5 grades: the connected area of scab accounts for the 11%-20% of whole leaf area;
7 grades: the connected area of scab accounts for the 21%-50% of whole leaf area;
9 grades: the connected area of scab accounts for the more than 51% of whole leaf area;
Theoretical preventive effect (%)=x+y-xy
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect taking actual preventive effect as synergistic effect.The results are shown in Table 2.
The control efficiency of table 2 fluopicolide composition to tomato late blight
By fluopicolide composition, the potted plant test of tomato late blight is found, the composition of composition, fluopicolide and the cyazofamid of composition, fluopicolide and the dimethomorph of composition, fluopicolide and the S-Ethyl ethylthio sulfonate of composition, fluopicolide and the carbendazim of composition, fluopicolide and the ambam of composition, fluopicolide and the Carbatene of fluopicolide and zineb, fluopicolide Yu the composition of famoxadone to the effect of tomato late blight all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of fluopicolide and above-mentioned Fungicidal compounds is synergy to tomato late blight.
Embodiment 3 is containing the control efficiency of fluopicolide composition to rice blast
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When mensuration, first liquid medicine jet is imposed on to pot rice plant, then inoculate pathogen, moisturizing is cultivated after 24h, is placed in greenhouse and cultivates, and measures the percentage that plant leaf surface infects after certain hour.Use Abbot formula, convert percentage to preventive effect.
Theoretical preventive effect (%)=x+y-xy
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect taking actual preventive effect as synergistic effect.The results are shown in Table 3.
Table 3 is containing the control efficiency of fluopicolide composition to rice blast
By potted plant test, as seen from Table 3, the composition of the composition of the composition of the composition of the composition of the composition of fluopicolide and carbendazim, fluopicolide and S-Ethyl ethylthio sulfonate, fluopicolide and jinggangmeisu, fluopicolide and kasugarnycin, fluopicolide and polyoxin, fluopicolide and Prochloraz to the effect of rice blast all higher than composition theoretical preventive effect.Obviously, the composite of fluopicolide and above-mentioned Fungicidal compounds is synergy to rice blast.
Embodiment 4 contains fluopicolide composition to wheat powdery mildew field trial
Carried out wheat powdery mildew field trial with composition, and established corresponding single dose and blank, every medicament is established community 30m
2.Adopt the conventional conventional spray of knapsack sprayer, test is booting and each spray 1 time of flowering initial stage, 7～10d before medicine and after the 2nd dispenser, every processing is by 5 samplings, every 50 strains, whole blades are investigated in every strain, and the total number of sheets of record investigation, the sick number of sheets, calculate disease index and preventive effect according to following stage division.
Blade staging:
0 grade: anosis
1 grade: the connected area of scab accounts for below 1% of whole leaf area;
3 grades: the connected area of scab accounts for the 1%-5% of whole leaf area;
5 grades: the connected area of scab accounts for the 6%-25% of whole leaf area;
7 grades: the connected area of scab accounts for the 26%-50% of whole leaf area;
9 grades: the connected area of scab accounts for the more than 51% of whole leaf area;
Theoretical preventive effect (%)=x+y-xy
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect taking actual preventive effect as synergistic effect.Bactericidal composition containing fluopicolide the results are shown in Table 4 to the control efficiency of wheat powdery mildew.
Table 4 contains the bactericidal composition of fluopicolide to wheat powdery mildew field effect
By fluopicolide composition, wheat powdery mildew test is found, the composition of composition, fluopicolide and the Fenamidone of composition, fluopicolide and the polyoxin of composition, fluopicolide and the cyprodinil of composition, fluopicolide and the phonetic phenol of second of composition, fluopicolide and the S-Ethyl ethylthio sulfonate of fluopicolide and carbendazim, fluopicolide Yu the composition of famoxadone to the effect of wheat powdery mildew all higher than the theoretical preventive effect of correspondent composition.Obviously, the composition of fluopicolide and above-mentioned Fungicidal compounds is synergy to wheat powdery mildew.
Embodiment 5 is containing the control efficiency of fluopicolide composition to rice sheath blight disease
Single compound or composition are prepared into the mother liquor of 1000mg/L with organic solvent dissolution.According to biological activity determination trial test, a certain amount of above-mentioned mother liquor is diluted with 0.1% Tween 80, be mixed with the concentration needing.When mensuration, first liquid medicine jet is imposed on to pot rice plant, then inoculate pathogen, moisturizing is cultivated after 24h, is placed in greenhouse and cultivates, and measures the percentage that plant leaf surface infects after certain hour.Use Abbot formula, convert percentage to preventive effect.
Theoretical preventive effect (%)=x+y-xy
X is the preventive effect of the active component A of working concentration while being a, and y is the preventive effect of the active component B of working concentration while being b.Relatively theoretical effect and actual effect, evaluates the synergy of composition, while being greater than theoretical preventive effect taking actual preventive effect as synergistic effect.The results are shown in Table 5.
Table 5 is containing the control efficiency of fluopicolide composition to rice sheath blight disease
By potted plant test, as seen from Table 5, the composition of composition, fluopicolide and the cyprodinil of the composition of the composition of the composition of the composition of fluopicolide and jinggangmeisu, fluopicolide and kasugarnycin, fluopicolide and polyoxin, fluopicolide and Prochloraz, fluopicolide and the phonetic phenol of second to the effect of rice sheath blight disease all higher than composition theoretical preventive effect.Obviously, the composite of fluopicolide and above-mentioned Fungicidal compounds is synergy to banded sclerotial blight.
Claims (6)
1. a bactericidal composition that contains fluopicolide, it is characterized in that A and two kinds of active components of B that said composition comprises effective dose, wherein A is fluopicolide, B is selected from sulfur-bearing class sterilization component zineb, Carbatene, ambam, carbendazim, S-Ethyl ethylthio sulfonate, Propineb, tpn, thiophanate-methyl, tmtd, asomate, captan, folpet, sulfonat, one in fenaminosulf, or be selected from amide-type sterilization component dimethomorph, zoxamide, efficient metalaxyl, one in efficient M 9834, or be selected from imidazoles sterilization component cyazofamid, Fenamidone, Prochloraz, a kind of in pefurazoate, or be selected from the one in oxazole class sterilization Cheng Fen famoxadone, or be selected from the phonetic phenol of miazines sterilization component second, cyprodinil, fluorine mepanipyrim, one in mepanipyrim, or be selected from biogenic substances sterilization component jinggangmeisu, kasugarnycin, polyoxin, one in Zhongshengmycin, A, the ratio of quality and the number of copies of B two components is 1:50-50:1.
2. composition according to claim 1, B component is selected from the one in zineb, Carbatene, ambam, carbendazim, S-Ethyl ethylthio sulfonate, dimethomorph, cyazofamid, Fenamidone, Prochloraz, famoxadone, the phonetic phenol of second, cyprodinil, jinggangmeisu, kasugarnycin, polyoxin, and the ratio of quality and the number of copies of A, B two components is 1:20-10:1.
3. composition according to claim 1 and 2, wherein the quality sum of A component and B component accounts for the 1-80% of bactericidal composition gross mass percentage.
4. composition according to claim 3, said composition is made into suspending agent, wetting powder, water dispersible granules, aqua, microemulsion or aqueous emulsion, for spraying, filling root or seed dressing.
5. bactericidal composition claimed in claim 4 is for the purposes of controlling plant diseases, wherein disease is the fungus-caused downy mildew of Mastigomycotina, late blight, peronospora tabacina etc., the fungus-caused rice blast of Fungi Imperfecti, gray mold, scab etc., the fungus-caused powdery mildew of Ascomycotina, anthracnose, leaf spot etc., rust, smut etc. that Basidiomycotina causes.
6. purposes according to claim 5, wherein said plant is cucumber, tomato, paddy rice, wheat, watermelon, apple, grape, oranges and tangerines, pears, lichee, flowers, lawn.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103975924A (en) * | 2014-05-24 | 2014-08-13 | 深圳诺普信农化股份有限公司 | Sterilization composition |
| CN103975925A (en) * | 2014-05-24 | 2014-08-13 | 深圳诺普信农化股份有限公司 | Fungicidal composition taking Fluopicolide as main ingredient |
| CN104068022A (en) * | 2014-07-09 | 2014-10-01 | 江苏省绿盾植保农药实验有限公司 | Bactericide composition containing fluopicolide and ethylicin |
| CN105941438A (en) * | 2016-05-26 | 2016-09-21 | 南京华洲药业有限公司 | {0><}0{>Sterilization composition containing fluoride ether bacteria amide and thiophal and application of sterilization composition<0} |
| CN106135210A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of containing Boscalid and the bactericidal composition of fluopicolide and application |
| CN106689164A (en) * | 2016-12-30 | 2017-05-24 | 陕西省蒲城美尔果农化有限责任公司 | Fungicidal composition containing oxine-copper |
| CN107258803A (en) * | 2017-06-19 | 2017-10-20 | 陕西先农生物科技有限公司 | Composition pesticide of containing fluopicolide and Carbatene and preparation method thereof |
| WO2022248683A1 (en) * | 2021-05-27 | 2022-12-01 | Bayer Intellectual Property Gmbh | Plant growth regulator for turfgrass and method for regulating growth of turfgrass |
| CN115943962A (en) * | 2023-01-05 | 2023-04-11 | 河南科技学院 | Bactericidal composition for preventing and treating wheat sharp eyespot |
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2014
- 2014-03-01 CN CN201410071405.4A patent/CN104041505A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103975924A (en) * | 2014-05-24 | 2014-08-13 | 深圳诺普信农化股份有限公司 | Sterilization composition |
| CN103975925A (en) * | 2014-05-24 | 2014-08-13 | 深圳诺普信农化股份有限公司 | Fungicidal composition taking Fluopicolide as main ingredient |
| CN104068022A (en) * | 2014-07-09 | 2014-10-01 | 江苏省绿盾植保农药实验有限公司 | Bactericide composition containing fluopicolide and ethylicin |
| CN104068022B (en) * | 2014-07-09 | 2016-04-06 | 江苏丘陵地区镇江农业科学研究所 | A kind of microbicide compositions containing fluopicolide and S-Ethyl ethylthio sulfonate |
| CN106135210A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of containing Boscalid and the bactericidal composition of fluopicolide and application |
| CN105941438A (en) * | 2016-05-26 | 2016-09-21 | 南京华洲药业有限公司 | {0><}0{>Sterilization composition containing fluoride ether bacteria amide and thiophal and application of sterilization composition<0} |
| CN105941438B (en) * | 2016-05-26 | 2018-08-03 | 南京华洲药业有限公司 | A kind of bactericidal composition and its application of fluorine-containing ether bacterium amide and folpet |
| CN106689164A (en) * | 2016-12-30 | 2017-05-24 | 陕西省蒲城美尔果农化有限责任公司 | Fungicidal composition containing oxine-copper |
| CN107258803A (en) * | 2017-06-19 | 2017-10-20 | 陕西先农生物科技有限公司 | Composition pesticide of containing fluopicolide and Carbatene and preparation method thereof |
| WO2022248683A1 (en) * | 2021-05-27 | 2022-12-01 | Bayer Intellectual Property Gmbh | Plant growth regulator for turfgrass and method for regulating growth of turfgrass |
| CN115943962A (en) * | 2023-01-05 | 2023-04-11 | 河南科技学院 | Bactericidal composition for preventing and treating wheat sharp eyespot |
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Application publication date: 20140917 |