CN104005264B - 造纸用表面施胶剂以及涂布该施胶剂得到的纸张 - Google Patents

造纸用表面施胶剂以及涂布该施胶剂得到的纸张 Download PDF

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Publication number: CN104005264B
Authority: CN; China
Prior art keywords: sizing agent; paper making; surface sizing; paper; starch
Prior art date: 2013-02-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

CN201410035991.7A

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English (en)

Chinese (zh)

Other versions

CN104005264A (zh

Inventor

原口刚士

佐藤辉彰

须田雅彦

大野健

大野健一

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Arakawa Chemical Industries Ltd

Original Assignee

Arakawa Chemical Industries Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2013-02-22

Filing date

2014-01-24

Publication date

2016-08-17

2014-01-24 Application filed by Arakawa Chemical Industries Ltd filed Critical Arakawa Chemical Industries Ltd

2014-08-27 Publication of CN104005264A publication Critical patent/CN104005264A/zh

2016-08-17 Application granted granted Critical

2016-08-17 Publication of CN104005264B publication Critical patent/CN104005264B/zh

Status Active legal-status Critical Current

2034-01-24 Anticipated expiration legal-status Critical

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238000004513 sizing Methods 0.000 title claims abstract description 77
239000003795 chemical substances by application Substances 0.000 claims abstract description 75
239000000178 monomer Substances 0.000 claims abstract description 49
229920002472 Starch Polymers 0.000 claims abstract description 44
239000008107 starch Substances 0.000 claims abstract description 44
235000019698 starch Nutrition 0.000 claims abstract description 44
239000000203 mixture Substances 0.000 claims abstract description 38
239000000839 emulsion Substances 0.000 claims abstract description 31
229920000642 polymer Polymers 0.000 claims abstract description 30
239000003505 polymerization initiator Substances 0.000 claims abstract description 20
238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 9
-1 (methyl) n-butyl Chemical group 0.000 claims description 38
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 18
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
239000002245 particle Substances 0.000 claims description 12
239000007787 solid Substances 0.000 claims description 11
150000002978 peroxides Chemical class 0.000 claims description 10
CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
229910052782 aluminium Inorganic materials 0.000 claims description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
150000003839 salts Chemical class 0.000 claims description 8
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
239000000470 constituent Substances 0.000 claims description 7
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
239000002253 acid Substances 0.000 claims description 5
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
235000019394 potassium persulphate Nutrition 0.000 claims description 4
239000011593 sulfur Substances 0.000 claims description 4
229910052717 sulfur Inorganic materials 0.000 claims description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
239000010949 copper Substances 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
150000002148 esters Chemical class 0.000 claims description 2
229910000358 iron sulfate Inorganic materials 0.000 claims description 2
239000000126 substance Substances 0.000 claims description 2
150000001399 aluminium compounds Chemical class 0.000 claims 1
150000004968 peroxymonosulfuric acids Chemical class 0.000 claims 1
229920006395 saturated elastomer Polymers 0.000 claims 1
238000000576 coating method Methods 0.000 abstract description 26
230000005587 bubbling Effects 0.000 abstract description 3
239000000123 paper Substances 0.000 description 83
239000011248 coating agent Substances 0.000 description 20
238000000034 method Methods 0.000 description 19
238000004519 manufacturing process Methods 0.000 description 10
239000012530 fluid Substances 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000000047 product Substances 0.000 description 8
229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
229920001577 copolymer Polymers 0.000 description 7
230000008569 process Effects 0.000 description 7
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
229910001870 ammonium persulfate Inorganic materials 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
125000002091 cationic group Chemical group 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000007788 liquid Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
238000003786 synthesis reaction Methods 0.000 description 6
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 5
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
239000004815 dispersion polymer Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
238000012360 testing method Methods 0.000 description 4
235000004258 Cordia alliodora Nutrition 0.000 description 3
244000085692 Cordia alliodora Species 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
229920000881 Modified starch Polymers 0.000 description 3
239000000654 additive Substances 0.000 description 3
239000011111 cardboard Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000003750 conditioning effect Effects 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical group CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
239000003995 emulsifying agent Substances 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
238000005187 foaming Methods 0.000 description 3
229910000359 iron(II) sulfate Inorganic materials 0.000 description 3
239000000463 material Substances 0.000 description 3
235000019426 modified starch Nutrition 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
210000000582 semen Anatomy 0.000 description 3
239000001117 sulphuric acid Substances 0.000 description 3
235000011149 sulphuric acid Nutrition 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 2
MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
239000004368 Modified starch Substances 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
229920001131 Pulp (paper) Polymers 0.000 description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical group CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
125000005037 alkyl phenyl group Chemical group 0.000 description 2
125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
238000000149 argon plasma sintering Methods 0.000 description 2
XTPLQANXHDDXIH-UHFFFAOYSA-N azanium;1,1-dioxo-1,2-benzothiazol-3-olate Chemical compound N.C1=CC=C2C(=O)NS(=O)(=O)C2=C1 XTPLQANXHDDXIH-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
230000033228 biological regulation Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000011093 chipboard Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical group CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
239000013530 defoamer Substances 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 2
NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
229920000578 graft copolymer Polymers 0.000 description 2
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WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
239000003999 initiator Substances 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
229920001223 polyethylene glycol Polymers 0.000 description 2
239000003755 preservative agent Substances 0.000 description 2
230000002335 preservative effect Effects 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical group ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
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IAXXETNIOYFMLW-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) 2-methylprop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C(=C)C)CC1C2(C)C IAXXETNIOYFMLW-UHFFFAOYSA-N 0.000 description 1
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XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
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IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 1
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102000013142 Amylases Human genes 0.000 description 1
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LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
240000000163 Cycas revoluta Species 0.000 description 1
235000008601 Cycas revoluta Nutrition 0.000 description 1
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206010020466 Hunger Diseases 0.000 description 1
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
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SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
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WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
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238000005660 chlorination reaction Methods 0.000 description 1
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125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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JP6566204B2 (ja) *	2014-09-30	2019-08-28	荒川化学工業株式会社	製紙用添加剤および該添加剤を用いて得られる紙
CN104452469A (zh) *	2014-11-13	2015-03-25	苏州誉之铖贸易有限责任公司	一种礼品包装用香型包装材料
CN104497721B (zh) *	2014-12-02	2017-02-22	周宏亮	一种离型剂及其离型纸和离型膜
CN105038488B (zh) *	2015-08-04	2017-07-14	上海维凯光电新材料有限公司	具备高耐擦性能的胶印转移涂料及其制备方法
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CN110644283A (zh) *	2018-06-27	2020-01-03	玖龙纸业(重庆)有限公司	一种用于包装纸的表面施胶剂及其制备方法
JP6760344B2 (ja)	2018-09-18	2020-09-23	栗田工業株式会社	製紙用表面サイズ剤
JP7156089B2 (ja) *	2019-03-01	2022-10-19	荒川化学工業株式会社	製紙用表面サイズ剤、塗工紙
CN110541302B (zh) *	2019-09-06	2022-12-13	天津科技大学	一种纸基材料表面改性的方法
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4855343A (en) *	1986-08-14	1989-08-08	Basf Aktiengesellschaft	Paper size based on finely divided aqueous dispersions
CN101851877A (zh) *	2009-03-31	2010-10-06	荒川化学工业株式会社	造纸用表面涂布液以及纸张
CN102656192A (zh) *	2009-10-02	2012-09-05	巴斯夫欧洲公司	含淀粉的细碎聚合物分散体、其生产方法及其在造纸中作为施胶剂的用途

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19806745A1 (de) *	1998-02-18	1999-08-19	Bayer Ag	Feinteilige Polymerdispersionen zur Papierleimung
US6114417A (en) *	1998-10-16	2000-09-05	Cytec Technology Corp.	Paper sizing agents and methods
JP5136862B2 (ja) *	2009-01-27	2013-02-06	荒川化学工業株式会社	製紙用表面サイズ剤、製紙用表面サイズ剤を含有する塗工液ならびにこれらを用いて得られる紙
JP5879041B2 (ja) *	2011-03-29	2016-03-08	ハリマ化成株式会社	カチオン性表面サイズ剤の製造方法およびその方法で得られるサイズ剤

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4855343A (en) *	1986-08-14	1989-08-08	Basf Aktiengesellschaft	Paper size based on finely divided aqueous dispersions
CN101851877A (zh) *	2009-03-31	2010-10-06	荒川化学工业株式会社	造纸用表面涂布液以及纸张
CN102656192A (zh) *	2009-10-02	2012-09-05	巴斯夫欧洲公司	含淀粉的细碎聚合物分散体、其生产方法及其在造纸中作为施胶剂的用途

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Publication	Publication Date	Title
CN104005264B (zh)	2016-08-17	造纸用表面施胶剂以及涂布该施胶剂得到的纸张
CA1303765C (en)	1992-06-16	Sizing agents for paper based on finely divided aqueous dispersions
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JP6805251B2 (ja)	2020-12-23	微細なカチオン性水性ポリマー分散液、その製造方法、およびその使用
CN101787664A (zh)	2010-07-28	造纸用表面施胶剂、含有造纸用表面施胶剂的涂布液以及使用它们得到的纸张
CN103410050B (zh)	2015-11-25	表面施胶剂乳液及其制备方法和应用
MX2011001884A (es)	2011-05-10	Dispersion de polimero.
CN102261015A (zh)	2011-11-30	造纸用表面施胶剂、表面施胶涂布液和纸
US11242423B2 (en)	2022-02-08	Surface sizing composition, method of production, and use thereof
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KR102496601B1 (ko)	2023-02-06	제지용 표면 사이즈제
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WO2016098006A1 (en)	2016-06-23	Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and the use thereof
JP2007002360A (ja)	2007-01-11	製紙用表面サイズ剤および印刷用紙
JP4400202B2 (ja)	2010-01-20	製紙用表面サイズ剤
JP6721866B2 (ja)	2020-07-15	製紙用表面サイズ剤、製紙用表面サイズ剤の製造方法及び表面塗工紙

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