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CN103964705A - Method for preparing multifunctional automobile glass window film - Google Patents

Method for preparing multifunctional automobile glass window film Download PDF

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Publication number
CN103964705A
CN103964705A CN201410196337.4A CN201410196337A CN103964705A CN 103964705 A CN103964705 A CN 103964705A CN 201410196337 A CN201410196337 A CN 201410196337A CN 103964705 A CN103964705 A CN 103964705A
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CN
China
Prior art keywords
film
layer
pet
automobile
tin
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Pending
Application number
CN201410196337.4A
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Chinese (zh)
Inventor
白永平
邵志敏
丁丽萍
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Wuxi Haite New Material Research Institute Co Ltd
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Wuxi Haite New Material Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority to CN201410196337.4A priority Critical patent/CN103964705A/en
Publication of CN103964705A publication Critical patent/CN103964705A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a method for preparing a multifunctional automobile glass window film. The method comprises the whole process of preparing specific components of the glass window film into the glass window film by using a specific method. In such a mode, by adopting the method for preparing the multifunctional automobile glass window film, the automobile glass window not only has various characteristics of explosion resistance, abrasion resistance, ultraviolet resistance, privacy, glare resistance, thermal insulation, sun blocking and the like, but also automobile owners can select and manufacture exclusive automobile window films according to personality and favor of self, and thus requirements of people can be better met.

Description

The preparation method of multi-purpose vehicle(MPV) adhering film to glass
Technical field
The present invention relates to automobile adhesive film field, particularly relate to a kind of preparation method of multi-purpose vehicle(MPV) adhering film to glass.
Background technology
Along with the develop rapidly that China's economic is built, the generally raising of living standards of the people, automobile is just striding forward the family of ordinary people with unprecedented paces, and consequent automobile adhesive film market also will expand rapidly in China.
Automobile adhesive film (Auto foil) is exactly on vehicle front-rear windshield glass, side window glass and skylight, to stick thin film shape object.The situation such as hurt sb.'s feelings that the effect that it mainly should possess is shielding of ultraviolet, intercept part heat and prevent that the unexpected explosion of glass from causing occurs, and simultaneously according to the single plane fluoroscopy performance of solar film, reaches the object of protection individual privacy.In addition, it also can reduce the damage that article in car and personnel cause because of uviolizing, reach the effect of saving fuel oil consumption in some aspect, but the automobile adhesive film on market far can not reach above-mentioned requirement now, and, can not design and customize according to user's hobby, so the automobile adhesive film that people need to meet the demands more.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of preparation method of multi-purpose vehicle(MPV) adhering film to glass, has diverse in function, the advantage such as easy to use, simultaneously application and universal on have market outlook widely.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is:
A kind of preparation method of multi-purpose vehicle(MPV) adhering film to glass is provided, and its step comprises:
Diphenylmethanediisocyanate and polyphenyl polymethylene polyisocyanates are mixed according to the mass ratio of 3-5:1-3, form wearing-resistant layer, the hardness of wearing-resistant layer need be more than or equal to 4H;
The PET polyester of high strength, high-clarity is carried out to melting, then make PET sheet with extrusion molding, then make clear PET film through two-way stretch;
Automobile film sole pigment is coated with and is located at the front of clear PET film uniformly, and dry;
Before automobile film sole pigment parches completely, then take another layer of PET film, be attached on automobile film sole pigment, compacting makes coloured PET base film layer after drying;
Wearing-resistant layer is plated in to the reverse side of coloured PET base film layer;
By vacuum vapour deposition or vacuum magnetic-control sputtering method, will there is the nano level metal layer of high reflectance to be attached to the front of coloured PET base film layer to infrared rays;
Get again a clear PET film, be attached on nano level metal layer;
Tin-antiomony oxide powder is attached on nano level metal layer, forms tin-antiomony oxide layer;
Polyurethane adhesive is spread upon on tin-antiomony oxide layer uniformly;
Separately get a clear PET film, utilize polyurethane adhesive to be arranged on tin-antiomony oxide powder bed;
Diphenylmethanediisocyanate, polyphenyl polymethylene polyisocyanates and extraordinary UV light absorber are mixed, make UV absorption layer;
Utilize ultraviolet light source and ultraviolet luxmeter to detect the ultraviolet absorption ability of UV absorption layer;
UV absorption layer is attached on described tin-antiomony oxide powder;
The smart extracting solution of transparent acrylic ester adhesive, extraordinary UV light absorber and natural phant is mixed, make installation glue-line;
Glue-line brushing will be installed on UV absorption layer;
PET release film is sticked on and installed on glue-line, form final automobile adhesive film.
In a preferred embodiment of the present invention, concrete composition and the quality proportioning of described UV absorption layer are: diphenylmethanediisocyanate 10-20 part, polyphenyl polymethylene polyisocyanates 10-15 part and extraordinary UV light absorber 1-3 part.
In a preferred embodiment of the present invention, described nano level metal layer comprises one or more in aluminium, silver, nickel, gold and copper.
In a preferred embodiment of the present invention, concrete composition and the quality proportioning of described installation glue-line are: smart extracting solution 1-3 part of acrylic ester adhesive 80-100 part, extraordinary UV light absorber 10-20 part and natural phant.
In a preferred embodiment of the present invention, described natural phant comprises one or more in rose, orange peel, flores aurantii, lavandula angustifolia, pomegranate, jasmine, camellia, peach blossom, oriental cherry, apricot flower, Chinese herbaceous peony, silk tree, plum blossom, tree peony, peppermint, natsudaidai, amber, Wen Bai, jacinthe, cdear, oranges and tangerines, Caulis Miscanthis floriduli, flag flower, Fructus Citri Sarcodactylis, lemon, the lily of the valley, Semen Myristicae, lotus, cedar, piper nigrum, pink pepper, strawberry, grane ambra, santal, cape jasmine, vanilla, pine, ginger, apple, Chinese cassia tree and honey peach.
The invention has the beneficial effects as follows: the preparation method who the invention provides a kind of multi-purpose vehicle(MPV) adhering film to glass, not only can allow automobile adhesive film there is the various features such as more outstanding explosion-proof, resistance to abrasion, antiultraviolet, privacy, anti-dazzle and heat insulation sun, but also can be according to car owner's oneself individual character and hobby, select and make own exclusive automobile adhesive film, more meet the present demand of people.
Embodiment
To the technical scheme in the embodiment of the present invention be clearly and completely described below, obviously, described embodiment is only a part of embodiment of the present invention, instead of whole embodiment.Based on the embodiment in the present invention, those of ordinary skill in the art, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A preparation method for multi-purpose vehicle(MPV) adhering film to glass, its step comprises:
Diphenylmethanediisocyanate and polyphenyl polymethylene polyisocyanates are mixed according to the mass ratio of 3-5:1-3, form wearing-resistant layer, the hardness of wearing-resistant layer need be more than or equal to 4H, in configuration wearing-resistant layer, also need to add auxiliary agent to improve formation efficiency and the quality of wearing-resistant layer, auxiliary agent comprises the strong solvent of ether alcohol class superpolymer, as propandiol butyl ether, 1-Methoxy-2-propyl acetate etc., when selecting auxiliary agent, the product that preferably boiling point is greater than 320 DEG C, because boiling point is high, environmental-protecting performance is superior, compatibility is good, volatility is low, easily absorbed by latex particle, can form excellent continuous film,
The PET polyester of high strength, high-clarity is carried out to melting, then make PET sheet with extrusion molding, then make clear PET film through two-way stretch;
Automobile film sole pigment is coated with and is located at the front of clear PET film uniformly, and dry, automobile film sole pigment can weaken the see-through of film, and the people that this sample car is seen outward does not just see in car, retains privacy and safety;
Before automobile film sole pigment parches completely, then take another layer of PET film, be attached on automobile film sole pigment, compacting makes coloured PET base film layer after drying, because automobile film sole pigment is clipped in PET film the inside, oxidation stain can be prevented, the work-ing life of film can be effectively extended;
Wearing-resistant layer is plated in to the reverse side of coloured PET base film layer, so just can allows car mould have the very good anti-breakdown function of resistance to tearing;
By vacuum vapour deposition or vacuum magnetic-control sputtering method, will there is the nano level metal layer of high reflectance to be attached to the front of coloured PET base film layer to infrared rays;
Get again a clear PET film, be attached on nano level metal layer, described nano level metal layer comprises aluminium, silver, nickel, one or more in gold and copper, the perveance of metal is higher, penetration depth is more shallow, reflectivity is higher, these metal levels can be optionally by the various thermal energy sourcies in sunlight, comprise infrared rays, ultraviolet ray and visible ray heat energy reflect back, after coordinating again color on film to the absorption of sun heat radiation, secondary outwards discharges again, along with outdoor air flowing is taken away a part of heat, thereby effectively play heat insulation effect, but because the reflectivity of each metal is not identical, and the wavelength of the radiation that in use receives of car film is not identical yet, so need to use different metals,
Tin-antiomony oxide powder is attached on nano level metal layer, form tin-antiomony oxide layer, described tin-antiomony oxide can conduct electricity, there is good dispersiveness, resistance to activity, thermoplasticity, wear resistance and security, can effectively increase the static electricity resistance of car film and heat insulation effect, can replace tin-antiomony oxide with nano indium tin metal oxide in addition, it has good electroconductibility and the transparency, can cut off harmful electron radiation, ultraviolet ray and far infrared rays, therefore, indium tin oxide is sprayed on glass conventionally, in plastics and electronic display, as transparent conductive film, reduce harmful electron radiation and ultraviolet simultaneously, infrared rays,
Polyurethane adhesive is spread upon on tin-antiomony oxide layer uniformly;
Separately get a clear PET film, utilize polyurethane adhesive to be arranged on tin-antiomony oxide powder bed;
Diphenylmethanediisocyanate, polyphenyl polymethylene polyisocyanates and extraordinary UV light absorber are mixed, make UV absorption layer,, can intercept 99% ultraviolet ray, reduce radiation;
Utilize ultraviolet light source and ultraviolet luxmeter to detect the ultraviolet absorption ability of UV absorption layer;
UV absorption layer is attached on described tin-antiomony oxide powder;
The smart extracting solution of transparent acrylic ester adhesive, extraordinary UV light absorber and natural phant is mixed, make installation glue-line;
Glue-line brushing will be installed on UV absorption layer; PET release film is sticked on and installed on glue-line, form final automobile adhesive film.
Concrete composition and the quality proportioning of described UV absorption layer are: diphenylmethanediisocyanate 10-20 part, polyphenyl polymethylene polyisocyanates 10-15 part and extraordinary UV light absorber 1-3 part.
Concrete composition and the quality proportioning of described installation glue-line are: smart extracting solution 1-3 part of acrylic ester adhesive 80-100 part, extraordinary UV light absorber 10-20 part and natural phant, like this can be in improving adhesive capacity, ensure the transparency of glue, and can allow like this fragrance of car film with plant, both strengthened the binding property of glue, and can, according to the hobby customization of oneself, strengthen the individual character of car film.
Described natural phant comprises rose, orange peel, flores aurantii, lavandula angustifolia, pomegranate, jasmine, camellia, peach blossom, oriental cherry, apricot flower, Chinese herbaceous peony, silk tree, plum blossom, tree peony, peppermint, natsudaidai, amber, Wen Bai, jacinthe, cdear, oranges and tangerines, Caulis Miscanthis floriduli, flag flower, Fructus Citri Sarcodactylis, lemon, the lily of the valley, Semen Myristicae, lotus, cedar, piper nigrum, pink pepper, strawberry, grane ambra, santal, cape jasmine, vanilla, pine, ginger, apple, one or more in Chinese cassia tree and honey peach.
The preparation method's of multi-purpose vehicle(MPV) adhering film to glass of the present invention beneficial effect is: not only can allow automobile adhesive film have the various features such as more outstanding explosion-proof, resistance to abrasion, antiultraviolet, privacy, anti-dazzle and heat insulation sun, but also can be according to car owner's oneself individual character and hobby, select and make own exclusive automobile adhesive film, more meet the present demand of people.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (5)

1. a preparation method for multi-purpose vehicle(MPV) adhering film to glass, is characterized in that, step comprises:
Diphenylmethanediisocyanate and polyphenyl polymethylene polyisocyanates are mixed according to the mass ratio of 3-5:1-3, form wearing-resistant layer, the hardness of wearing-resistant layer need be more than or equal to 4H;
The PET polyester of high strength, high-clarity is carried out to melting, then make PET sheet with extrusion molding, then make clear PET film through two-way stretch;
Automobile film sole pigment is coated with and is located at the front of clear PET film uniformly, and dry;
Before automobile film sole pigment parches completely, then take another layer of PET film, be attached on automobile film sole pigment, compacting makes coloured PET base film layer after drying;
Wearing-resistant layer is plated in to the reverse side of coloured PET base film layer;
By vacuum vapour deposition or vacuum magnetic-control sputtering method, will there is the nano level metal layer of high reflectance to be attached to the front of coloured PET base film layer to infrared rays;
Get again a clear PET film, be attached on nano level metal layer;
Tin-antiomony oxide powder is attached on nano level metal layer, forms tin-antiomony oxide layer;
Polyurethane adhesive is spread upon on tin-antiomony oxide layer uniformly;
Separately get a clear PET film, utilize polyurethane adhesive to be arranged on tin-antiomony oxide powder bed;
Diphenylmethanediisocyanate, polyphenyl polymethylene polyisocyanates and extraordinary UV light absorber are mixed, make UV absorption layer;
Utilize ultraviolet light source and ultraviolet luxmeter to detect the ultraviolet absorption ability of UV absorption layer;
UV absorption layer is attached on described tin-antiomony oxide powder;
The smart extracting solution of transparent acrylic ester adhesive, extraordinary UV light absorber and natural phant is mixed, make installation glue-line;
Glue-line brushing will be installed on UV absorption layer;
PET release film is sticked on and installed on glue-line, form final automobile adhesive film.
2. the preparation method of multi-purpose vehicle(MPV) adhering film to glass according to claim 1, it is characterized in that, concrete composition and the quality proportioning of described UV absorption layer are: diphenylmethanediisocyanate 10-20 part, polyphenyl polymethylene polyisocyanates 10-15 part and extraordinary UV light absorber 1-3 part.
3. the preparation method of multi-purpose vehicle(MPV) adhering film to glass according to claim 1, is characterized in that, described nano level metal layer comprises one or more in aluminium, silver, nickel, gold and copper.
4. the preparation method of multi-purpose vehicle(MPV) adhering film to glass according to claim 1, it is characterized in that, concrete composition and the quality proportioning of described installation glue-line are: smart extracting solution 1-3 part of acrylic ester adhesive 80-100 part, extraordinary UV light absorber 10-20 part and natural phant.
5. the preparation method of multi-purpose vehicle(MPV) adhering film to glass according to claim 1, it is characterized in that, described natural phant comprises rose, orange peel, flores aurantii, lavandula angustifolia, pomegranate, jasmine, camellia, peach blossom, oriental cherry, apricot flower, Chinese herbaceous peony, silk tree, plum blossom, tree peony, peppermint, natsudaidai, amber, Wen Bai, jacinthe, cdear, oranges and tangerines, Caulis Miscanthis floriduli, flag flower, Fructus Citri Sarcodactylis, lemon, the lily of the valley, Semen Myristicae, lotus, cedar, piper nigrum, pink pepper, strawberry, grane ambra, santal, cape jasmine, vanilla, pine, ginger, apple, one or more in Chinese cassia tree and honey peach.
CN201410196337.4A 2014-05-12 2014-05-12 Method for preparing multifunctional automobile glass window film Pending CN103964705A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410196337.4A CN103964705A (en) 2014-05-12 2014-05-12 Method for preparing multifunctional automobile glass window film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410196337.4A CN103964705A (en) 2014-05-12 2014-05-12 Method for preparing multifunctional automobile glass window film

Publications (1)

Publication Number Publication Date
CN103964705A true CN103964705A (en) 2014-08-06

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104417000A (en) * 2014-10-30 2015-03-18 孟凡伟 Car explosion-proof membrane and preparation method thereof
CN104760374A (en) * 2015-03-25 2015-07-08 超膜国际环保科技有限公司 Ceramic magnetic-control film for glass and preparation method thereof
CN106113740A (en) * 2016-08-25 2016-11-16 许月珍 A kind of vehicle body protecting film structure with heat insulating function
CN107022317A (en) * 2017-03-27 2017-08-08 苏州威仕薄膜科技有限公司 A kind of glass for vehicle window PET rupture pressure discs and preparation method thereof
CN107057596A (en) * 2017-03-27 2017-08-18 苏州威仕薄膜科技有限公司 A kind of colored safety diaphragm for building and preparation method thereof
CN107685515A (en) * 2017-09-19 2018-02-13 海安浩驰科技有限公司 Fenestrated membrane and preparation method thereof
CN108807576A (en) * 2018-05-24 2018-11-13 同济大学 A kind of solar energy vehicle window pad pasting
CN109288180A (en) * 2018-11-13 2019-02-01 吉林大学 self-heating hat
CN110682656A (en) * 2019-10-24 2020-01-14 优玖(苏州)信息科技有限公司 Automobile glass film pasting method
CN110760274A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Nano metal heat insulation film with low light reflection rate and low light transmittance and preparation method thereof
US10921492B2 (en) 2018-01-09 2021-02-16 Corning Incorporated Coated articles with light-altering features and methods for the production thereof
US11940593B2 (en) 2020-07-09 2024-03-26 Corning Incorporated Display articles with diffractive, antiglare surfaces and methods of making the same
US12195384B2 (en) 2013-05-07 2025-01-14 Corning Incorporated Scratch-resistant laminates with retained optical properties

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12195384B2 (en) 2013-05-07 2025-01-14 Corning Incorporated Scratch-resistant laminates with retained optical properties
CN104417000A (en) * 2014-10-30 2015-03-18 孟凡伟 Car explosion-proof membrane and preparation method thereof
CN104760374A (en) * 2015-03-25 2015-07-08 超膜国际环保科技有限公司 Ceramic magnetic-control film for glass and preparation method thereof
CN104760374B (en) * 2015-03-25 2017-07-25 超膜国际环保科技有限公司 It is a kind of for ceramic magnetic control pad pasting of glass and preparation method thereof
CN106113740A (en) * 2016-08-25 2016-11-16 许月珍 A kind of vehicle body protecting film structure with heat insulating function
CN107022317A (en) * 2017-03-27 2017-08-08 苏州威仕薄膜科技有限公司 A kind of glass for vehicle window PET rupture pressure discs and preparation method thereof
CN107057596A (en) * 2017-03-27 2017-08-18 苏州威仕薄膜科技有限公司 A kind of colored safety diaphragm for building and preparation method thereof
CN107685515A (en) * 2017-09-19 2018-02-13 海安浩驰科技有限公司 Fenestrated membrane and preparation method thereof
US10921492B2 (en) 2018-01-09 2021-02-16 Corning Incorporated Coated articles with light-altering features and methods for the production thereof
US12019209B2 (en) 2018-01-09 2024-06-25 Corning Incorporated Coated articles with light-altering features and methods for the production thereof
CN108807576A (en) * 2018-05-24 2018-11-13 同济大学 A kind of solar energy vehicle window pad pasting
CN110760274A (en) * 2018-07-27 2020-02-07 苏州今蓝纳米科技有限公司 Nano metal heat insulation film with low light reflection rate and low light transmittance and preparation method thereof
CN109288180A (en) * 2018-11-13 2019-02-01 吉林大学 self-heating hat
CN110682656B (en) * 2019-10-24 2021-06-29 优玖(苏州)信息科技有限公司 Automobile glass film pasting method
CN110682656A (en) * 2019-10-24 2020-01-14 优玖(苏州)信息科技有限公司 Automobile glass film pasting method
US11940593B2 (en) 2020-07-09 2024-03-26 Corning Incorporated Display articles with diffractive, antiglare surfaces and methods of making the same
US11971519B2 (en) 2020-07-09 2024-04-30 Corning Incorporated Display articles with antiglare surfaces and thin, durable antireflection coatings
US11977206B2 (en) 2020-07-09 2024-05-07 Corning Incorporated Display articles with diffractive, antiglare surfaces and thin, durable antireflection coatings
US12147009B2 (en) 2020-07-09 2024-11-19 Corning Incorporated Textured region to reduce specular reflectance including a low refractive index substrate with higher elevated surfaces and lower elevated surfaces and a high refractive index material disposed on the lower elevated surfaces
US12352924B2 (en) 2020-07-09 2025-07-08 Corning Incorporated Display articles with diffractive, antiglare surfaces and methods of making the same
US12360290B2 (en) 2020-07-09 2025-07-15 Corning Incorporated Display articles with antiglare surfaces and thin, durable antireflection coatings
US12386101B2 (en) 2020-07-09 2025-08-12 Corning Incorporated Textured region of a substrate to reduce specular reflectance incorporating surface features with an elliptical perimeter or segments thereof, and method of making the same

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Application publication date: 20140806