CN106634321A - Scratch-proof anti-abrasion heat insulating film of car front windshield and preparation method of scratch-proof anti-abrasion heat insulating film - Google Patents
Scratch-proof anti-abrasion heat insulating film of car front windshield and preparation method of scratch-proof anti-abrasion heat insulating film Download PDFInfo
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- CN106634321A CN106634321A CN201610841934.7A CN201610841934A CN106634321A CN 106634321 A CN106634321 A CN 106634321A CN 201610841934 A CN201610841934 A CN 201610841934A CN 106634321 A CN106634321 A CN 106634321A
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- scratch resistant
- isolation film
- thermal isolation
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- 238000002360 preparation method Methods 0.000 title claims abstract description 35
- 238000005299 abrasion Methods 0.000 title abstract 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 24
- 238000000576 coating method Methods 0.000 claims abstract description 24
- 239000002131 composite material Substances 0.000 claims abstract description 21
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002270 dispersing agent Substances 0.000 claims abstract description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920000180 alkyd Polymers 0.000 claims abstract description 17
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 17
- 239000010703 silicon Substances 0.000 claims abstract description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000080 wetting agent Substances 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 16
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- -1 alcohol ester Chemical class 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052731 fluorine Inorganic materials 0.000 claims abstract 2
- 239000011737 fluorine Substances 0.000 claims abstract 2
- 230000003678 scratch resistant effect Effects 0.000 claims description 61
- 238000002955 isolation Methods 0.000 claims description 49
- 239000011521 glass Substances 0.000 claims description 36
- 239000002002 slurry Substances 0.000 claims description 21
- 239000006255 coating slurry Substances 0.000 claims description 20
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 17
- 239000012528 membrane Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000013530 defoamer Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 238000005507 spraying Methods 0.000 claims description 15
- 239000004576 sand Substances 0.000 claims description 14
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- YJKHMSPWWGBKTN-UHFFFAOYSA-N 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)F YJKHMSPWWGBKTN-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- ODPUKHWKHYKMRK-UHFFFAOYSA-N cerium;nitric acid Chemical compound [Ce].O[N+]([O-])=O ODPUKHWKHYKMRK-UHFFFAOYSA-N 0.000 claims 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 229940124543 ultraviolet light absorber Drugs 0.000 claims 1
- 238000002834 transmittance Methods 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 1
- 239000011858 nanopowder Substances 0.000 description 15
- 238000009413 insulation Methods 0.000 description 9
- 238000000227 grinding Methods 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 229940070721 polyacrylate Drugs 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000005340 laminated glass Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a scratch-proof anti-abrasion heat insulating film of a car front windshield and a preparation method of the scratch-proof anti-abrasion heat insulating film. The heat insulating film comprises a transparent film substrate, a heat insulating coating and a scratch-proof anti-abrasion coating, wherein the heat insulating coating is prepared from the following components in parts by weight: 50 to 80 parts of polyacrylic resin, 3 to 6 parts of nano titanium oxide, 1 to 2 parts of nano CeO2/La2O3 composite material, 0.5 to 1 part of ultraviolet absorbent, 0.08 to 0.5 part of dispersing agent, 0.5 to 1 part of flatting agent, and 0.8 to 1.2 parts of film forming aid. The scratch-proof anti-abrasion coating is prepared from the following components in parts by weight: 40 to 60 parts of water-based alkyd resin, 5 to 15 parts of fluorine-containing acrylate, 0.6 to 1 part of alcohol ester, 1 to 3 parts of wetting agent, 2 to 3 parts of curing agent, and 1 to 1.5 parts of organic silicon defoaming agent. The invention also discloses a preparation method of the heat insulating film. The heat insulating film is not only good in heat insulating property, but also excellent in scratch-proof ant-abrasion performance, and good in light transmittance.
Description
Technical field：
The present invention relates to heat-insulated technical field of membrane, is specifically related to a kind of scratch resistant wear-resisting shield glass heat-insulated
Film.
Background technology：
Automobile has become the indispensable vehicles in people's daily life.For the daylighting realized, automobile making
Used in substantial amounts of glass, especially front windshield, be even more all made by large-area glass, to provide for driver
Good sight line, it is ensured that traffic safety, windshield is generally laminated glass.But common laminated glass sunlight transmissivity
Height, ultraviolet light, infrared light barrier are poor, and in hot summer, strong sunlight irradiation causes vehicle interior temperature to raise, car facilities
Aging speed is accelerated, and affects the environment by bus of human pilot, increased the consumption of air-conditioning electric energy.
At present, it is general using the patch thermal isolation film on windshield apron for vehicle glass is in terms of sun heat radiation is blocked
Method, existing Heat insulation type adhering film mainly has 3 classes, i.e. dyeing film, common metal film and spectrum film.Wherein dyeing film is by blend of colors
In polyester piece or it is coated on polyester piece surface, the film is cheap, but effect of heat insulation is limited, and resistance to ag(e)ing is not also good.Commonly
Metal film realizes heat-insulated, but the film reflective " too strong " by light reflection, can cause light pollution, affects driver to sentence road conditions
It is disconnected, can also allow the radio signals such as mobile phone, GPS to weaken, so as to cause potential safety hazard.Spectrum film is in PET using magnetron sputtering
Deposit 5～9 layers of noble metal on plastic sheeting to be prepared from, high definition, heat-proof quality is excellent, but complicated process of preparation, price
It is expensive.Most of Heat insulation type adhering film colors are deeper, are only applicable to automobile side block and wind shield glass wind shield, are not suitable for automobile front windshield glass
Glass, so as to weaken the effect of heat insulation of car load.In recent years, glass is developed rapidly with transparent heat insulating dope, coating Jing
Drying and forming-film after spraying, blade coating, the transparency is good, is that solution automobile wind shield glass is heat-insulated there is provided new approach.
Chinese patent (201110044636.2) discloses a kind of nano ceramics heat insulating membrane, and it includes thermal isolation film main body, every
Hotting mask main body includes at least two-layer composite film, and one layer is thermal insulation layer, and thermal insulation layer adopts the nano ceramics of nano ceramic material
Thermal insulation layer, thermal insulation layer outside is provided with scratch-resistant layer, and scratch-resistant layer is the outermost layer of thermal isolation film main body, and the anti-scratch performance of the thermal isolation film is good, every
Hot property is excellent, but its translucent effect is bad.
The content of the invention：
It is an object of the invention to provide a kind of scratch resistant wear-resisting shield glass thermal isolation film, its scratch resistant wearability is good,
Long service life, light transmission is good, and heat-proof quality is excellent.
It is a further object to provide the preparation method of the shield glass thermal isolation film.
For achieving the above object, the present invention is employed the following technical solutions：
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
Polyacrylate resin 50-80 parts,
Nano-titanium oxide 3-6 parts,
Ceria nanopowder/La2O3Composite 1-2 parts,
Ultra-violet absorber 0.5-1 parts,
Dispersant 0.08-0.5 parts,
Levelling agent 0.5-1 parts, coalescents 0.8-1.2 parts；
The scratch resistant wear-resistant coating, in parts by weight, including following components：
Water soluble alkyd resin 40-60 parts,
Fluorinated acrylate 5-15 parts,
Alcohol ester-12 0.6-1 parts, wetting agent 1-3 parts,
Curing agent 2-3 parts, organic silicon defoamer 1-1.5 parts.
As the preferred of above-mentioned technical proposal, the heat insulating coat, in parts by weight, including following components：
75 parts of polyacrylate resin,
4.5 parts of nano-titanium oxide,
Ceria nanopowder/La2O31 part of composite,
0.7 part of ultra-violet absorber,
0.26 part of dispersant,
0.6 part of levelling agent, 1 part of coalescents；
The scratch resistant wear-resistant coating, in parts by weight, including following components：
50 parts of water soluble alkyd resin,
11 parts of fluorinated acrylate,
0.75 part of alcohol ester-12,2 parts of wetting agent,
2 parts of curing agent, 1 part of organic silicon defoamer.
As the preferred of above-mentioned technical proposal, the ceria nanopowder/La2O3Composite is added by cerous nitrate, lanthanum nitrate
The dissolving dehydration in the stearic acid of melting, obtains light yellow gel, sinters at being subsequently placed in 450-470 DEG C in Muffle furnace, then
Carry out heat treatment to be obtained.
Used as the preferred of above-mentioned technical proposal, the cerous nitrate, lanthanum nitrate, stearic mol ratio are 1：(2.5-3)：6.
Used as the preferred of above-mentioned technical proposal, the temperature of the heat treatment is 680-720 DEG C, and heat treatment time is 2-3h.
Used as the preferred of above-mentioned technical proposal, the ultra-violet absorber is the mixture of UV-531 and UVP-327, the two
Mass ratio is (0.3-0.6)：1.
Used as the preferred of above-mentioned technical proposal, the dispersant is polyacrylamide, fatty acid polyethylene glycol ester, dodecane
One or more mixing in base sodium sulphate, neopelex.
Used as the preferred of above-mentioned technical proposal, the curing agent is the one kind in isocyanates, modified amine compound.
Used as the preferred of above-mentioned technical proposal, the fluorinated acrylate is Hexafluorobutyl mathacrylate, metering system
Sour 2,2,2- trifluoro ethyl esters, dodecafluoroheptyl methacrylate, dodecafluorhe-ptylacrylate, the trifluoro monooctyl ester of methacrylic acid ten,
One or more mixing in perluorooctyl acrylate.
A kind of preparation method of scratch resistant wear-resisting shield glass thermal isolation film, comprises the following steps：
(1) preparation of heat insulating coat slurry：
By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultra-violet absorber, dispersant, levelling agent and film forming are helped
Agent is well mixed, and in being placed in sand mill, under 3000-5000r/min 12-20h is ground, and is subsequently adding polyacrylate resin, after
Continuous grinding 5-10h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：
Water soluble alkyd resin, fluorinated acrylate and alcohol ester-12 are well mixed, in being placed in sand mill, 3000-
10-15h is ground under 5000r/min, wetting agent, curing agent, organic silicon defoamer is subsequently adding, continues to grind 3-6h, be obtained anti-
Scrape wear-resistant coating slurry；
(3) preparation of thermal isolation film：
Obtained heat insulating coat slurry is coated uniformly on transparent membrane substrate initially with spraying or the method brushed,
1-3h is dried at 80-150 DEG C, heat insulating coat is obtained, then using spraying or the method brushed by obtained scratch resistant wear-resistant coating
Slurry is uniformly coated at heat insulating coat surface, 75-120 DEG C and solidifies 1-3h, obtains shield glass thermal isolation film.
Compared with prior art, the present invention has advantages below：
(1) present invention adds appropriate ceria nanopowder/La in heat insulating coat2O3Composite, it can effectively absorb 800-
The near infrared light of 4500nm, so as to effectively increase the near infrared ray rejection rate of thermal isolation film；
(2) present invention using the mixture of UV-531 and UVP-327 as ultra-violet absorber, and rationally control the two it
Between consumption, it has good compatibility with fluoropolymer resin so that the ultraviolet isolating rate of obtained thermal isolation film reaches
More than 95%；
(3) the obtained thermal isolation film good heat-insulation effect of the present invention, light transmission is excellent, strong with the adhesive force of matrix, is difficult to take off
Fall, scratch resistant anti-wear performance is good, and consistency of performance, preparation method is simple, low cost.
Specific embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
50 parts of polyacrylate resin, 3 parts of nano-titanium oxide,
Ceria nanopowder/La2O31 part of composite,
0.5 part of ultra-violet absorber, 0.08 part of dispersant,
0.5 part of levelling agent, 0.8 part of coalescents.
The scratch resistant wear-resistant coating, in parts by weight, including following components：
40 parts of water soluble alkyd resin, 5 parts of fluorinated acrylate,
0.6 part of alcohol ester-12,1 part of wetting agent,
2 parts of curing agent, 1 part of organic silicon defoamer；
Its preparation method is comprised the following steps：
(1) preparation of heat insulating coat slurry：By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultraviolet radiation absorption
Agent, dispersant, levelling agent and coalescents are well mixed, and in being placed in sand mill, under 3000r/min 12h are ground, and are subsequently adding poly-
Acrylate, continues to grind 5h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：By the mixing of water soluble alkyd resin, fluorinated acrylate and alcohol ester-12
Uniformly, it is placed in sand mill, under 3000r/min 10h is ground, be subsequently adding wetting agent, curing agent, organic silicon defoamer, continues
Grinding 3h, is obtained scratch resistant wear-resistant coating slurry；
(3) preparation of thermal isolation film：Obtained heat insulating coat slurry is uniformly coated initially with spraying or the method brushed
On transparent membrane substrate, 1h is dried at 80 DEG C, obtains heat insulating coat, then will be obtained anti-using spraying or the method brushed
Scrape wear-resistant coating slurry and be uniformly coated in heat insulating coat surface, at 75 DEG C 1h is solidified, obtain shield glass thermal isolation film.
Embodiment 2
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
80 parts of polyacrylate resin, 6 parts of nano-titanium oxide,
Ceria nanopowder/La2O32 parts of composite,
1 part of ultra-violet absorber, 0.5 part of dispersant,
1 part of levelling agent, 1.2 parts of coalescents.
The scratch resistant wear-resistant coating, in parts by weight, including following components：
60 parts of water soluble alkyd resin, 15 parts of fluorinated acrylate,
1 part of alcohol ester-12,3 parts of wetting agent,
3 parts of curing agent, 1.5 parts of organic silicon defoamer；
Its preparation method is comprised the following steps：
(1) preparation of heat insulating coat slurry：By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultraviolet radiation absorption
Agent, dispersant, levelling agent and coalescents are well mixed, and in being placed in sand mill, under 5000r/min 20h are ground, and are subsequently adding poly-
Acrylate, continues to grind 10h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：By the mixing of water soluble alkyd resin, fluorinated acrylate and alcohol ester-12
Uniformly, it is placed in sand mill, under 5000r/min 15h is ground, be subsequently adding wetting agent, curing agent, organic silicon defoamer, continues
Grinding 6h, is obtained scratch resistant wear-resistant coating slurry；
(3) preparation of thermal isolation film：Obtained heat insulating coat slurry is uniformly coated initially with spraying or the method brushed
On transparent membrane substrate, 3h is dried at 150 DEG C, obtains heat insulating coat, then will be obtained using spraying or the method brushed
Scratch resistant wear-resistant coating slurry is uniformly coated in heat insulating coat surface, and at 120 DEG C 3h is solidified, and obtains shield glass heat-insulated
Film.
Embodiment 3
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
55 parts of polyacrylate resin, 4 parts of nano-titanium oxide,
Ceria nanopowder/La2O31.2 parts of composite,
0.6 part of ultra-violet absorber, 0.12 part of dispersant,
0.6 part of levelling agent, 0.9 part of coalescents.
The scratch resistant wear-resistant coating, in parts by weight, including following components：
45 parts of water soluble alkyd resin, 7 parts of fluorinated acrylate,
0.7 part of alcohol ester-12,1.5 parts of wetting agent,
2.3 parts of curing agent, 1.1 parts of organic silicon defoamer；
Its preparation method is comprised the following steps：
(1) preparation of heat insulating coat slurry：By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultraviolet radiation absorption
Agent, dispersant, levelling agent and coalescents are well mixed, and in being placed in sand mill, under 3500r/min 14h are ground, and are subsequently adding poly-
Acrylate, continues to grind 6h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：By the mixing of water soluble alkyd resin, fluorinated acrylate and alcohol ester-12
Uniformly, it is placed in sand mill, under 3500r/min 11h is ground, be subsequently adding wetting agent, curing agent, organic silicon defoamer, continues
Grinding 4h, is obtained scratch resistant wear-resistant coating slurry；
(3) preparation of thermal isolation film：Obtained heat insulating coat slurry is uniformly coated initially with spraying or the method brushed
On transparent membrane substrate, 1.5h is dried at 100 DEG C, obtains heat insulating coat, then will be obtained using spraying or the method brushed
Scratch resistant wear-resistant coating slurry be uniformly coated in heat insulating coat surface, solidify 1.5h at 85 DEG C, obtain shield glass
Thermal isolation film.
Embodiment 4
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
65 parts of polyacrylate resin, 5 parts of nano-titanium oxide,
Ceria nanopowder/La2O31.4 parts of composite,
0.7 part of ultra-violet absorber, 0.23 part of dispersant,
0.7 part of levelling agent, 1.0 parts of coalescents.
The scratch resistant wear-resistant coating, in parts by weight, including following components：
50 parts of water soluble alkyd resin, 9 parts of fluorinated acrylate,
0.8 part of alcohol ester-12,2 parts of wetting agent,
2.6 parts of curing agent, 1.2 parts of organic silicon defoamer；
Its preparation method is comprised the following steps：
(1) preparation of heat insulating coat slurry：By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultraviolet radiation absorption
Agent, dispersant, levelling agent and coalescents are well mixed, and in being placed in sand mill, under 4000r/min 16h are ground, and are subsequently adding poly-
Acrylate, continues to grind 7h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：By the mixing of water soluble alkyd resin, fluorinated acrylate and alcohol ester-12
Uniformly, it is placed in sand mill, under 4000r/min 12h is ground, be subsequently adding wetting agent, curing agent, organic silicon defoamer, continues
Grinding 5h, is obtained scratch resistant wear-resistant coating slurry；
(3) preparation of thermal isolation film：Obtained heat insulating coat slurry is uniformly coated initially with spraying or the method brushed
On transparent membrane substrate, 2h is dried at 120 DEG C, obtains heat insulating coat, then will be obtained using spraying or the method brushed
Scratch resistant wear-resistant coating slurry is uniformly coated in heat insulating coat surface, and at 95 DEG C 2h is solidified, and obtains shield glass heat-insulated
Film.
Embodiment 5
A kind of scratch resistant wear-resisting shield glass thermal isolation film, the thermal isolation film includes transparent membrane substrate, heat insulating coat
And scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
75 parts of polyacrylate resin, 5.5 parts of nano-titanium oxide,
Ceria nanopowder/La2O31.6 parts of composite,
0.8 part of ultra-violet absorber, 0.4 part of dispersant,
0.8 part of levelling agent, 1.1 parts of coalescents.
The scratch resistant wear-resistant coating, in parts by weight, including following components：
55 parts of water soluble alkyd resin, 11 parts of fluorinated acrylate,
0.9 part of alcohol ester-12,2.5 parts of wetting agent,
2.8 parts of curing agent, 1.35 parts of organic silicon defoamer；
Its preparation method is comprised the following steps：
(1) preparation of heat insulating coat slurry：By nano-titanium oxide, ceria nanopowder/La2O3Composite, ultraviolet radiation absorption
Agent, dispersant, levelling agent and coalescents are well mixed, and in being placed in sand mill, under 4500r/min 18h are ground, and are subsequently adding poly-
Acrylate, continues to grind 8h, obtains heat insulating coat slurry；
(2) preparation of scratch resistant wear-resistant coating slurry：By the mixing of water soluble alkyd resin, fluorinated acrylate and alcohol ester-12
Uniformly, it is placed in sand mill, under 4500r/min 14h is ground, be subsequently adding wetting agent, curing agent, organic silicon defoamer, continues
Grinding 5.5h, is obtained scratch resistant wear-resistant coating slurry；
(3) preparation of thermal isolation film：Obtained heat insulating coat slurry is uniformly coated initially with spraying or the method brushed
On transparent membrane substrate, 2.5h is dried at 135 DEG C, obtains heat insulating coat, then will be obtained using spraying or the method brushed
Scratch resistant wear-resistant coating slurry be uniformly coated in heat insulating coat surface, solidify 2.5h at 105 DEG C, obtain shield glass
Thermal isolation film.
Below performance test is carried out to thermal isolation film obtained in the present invention, test result is as shown in table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Ultraviolet isolating rate, % | 96 | 95 | 96 | 98 | 95 |
| Infrared ray rejection rate, % | 90 | 92 | 92 | 95 | 90 |
| Light transmittance, % | 83 | 79 | 82 | 85 | 85 |
| Adhesive force, level | 0 | 0 | 0 | 0 | 0 |
| 6H | 6H | 6H | 5H | 6H |
From the point of view of table 1, the obtained thermal isolation film ultraviolet isolating rate of the present invention reaches more than 95%, and infrared ray rejection rate reaches
More than 90%, light transmittance is on 75%, and adhesive force is strong, and hardness is big, and scratch resistant anti-wear performance is excellent.
Claims (10)
1. a kind of scratch resistant wear-resisting shield glass thermal isolation film, it is characterised in that the thermal isolation film include transparent membrane substrate,
Heat insulating coat and scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including following components：
Polyacrylate resin 50-80 parts,
Nano-titanium oxide 3-6 parts,
Nano Ce O2/La2O3Composite 1-2 parts,
Ultra-violet absorber 0.5-1 parts,
Dispersant 0.08-0.5 parts,
Levelling agent 0.5-1 parts, coalescents 0.8-1.2 parts；
The scratch resistant wear-resistant coating, in parts by weight, including following components：
Water soluble alkyd resin 40-60 parts,
Fluorinated acrylate 5-15 parts,
Alcohol ester-12 0.6-1 parts, wetting agent 1-3 parts,
Curing agent 2-3 parts, organic silicon defoamer 1-1.5 parts.
2. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that the thermal isolation film
Including transparent membrane substrate, heat insulating coat and scratch resistant wear-resistant coating, the heat insulating coat, in parts by weight, including with the following group
Point：
75 parts of polyacrylate resin,
4.5 parts of nano-titanium oxide,
Nano Ce O2/La2O31 part of composite,
0.7 part of ultra-violet absorber,
0.26 part of dispersant,
0.6 part of levelling agent, 1 part of coalescents；
The scratch resistant wear-resistant coating, in parts by weight, including following components：
50 parts of water soluble alkyd resin,
11 parts of fluorinated acrylate,
0.75 part of alcohol ester-12,2 parts of wetting agent,
2 parts of curing agent, 1 part of organic silicon defoamer.
3. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that：The nanometer
CeO2/La2O3Composite is to be added to dissolving dehydration in the stearic acid of melting by cerous nitrate, lanthanum nitrate, obtains light yellow solidifying
Glue, sinters at being subsequently placed in 450-470 DEG C in Muffle furnace, then carries out heat treatment and is obtained.
4. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 3, it is characterised in that：The nitric acid
Cerium, lanthanum nitrate, stearic mol ratio are 1：（2.5-3）：6.
5. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 3, it is characterised in that：At the heat
The temperature of reason is 680-720 DEG C, and heat treatment time is 2-3h.
6. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that：It is described ultraviolet
Light absorbers are the mixture of UV-531 and UVP-327, and the two mass ratio is（0.3-0.6）：1.
7. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that：The dispersion
Agent is one or more in polyacrylamide, fatty acid polyethylene glycol ester, lauryl sodium sulfate, neopelex
Mixing.
8. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that：The solidification
Agent is the one kind in isocyanates, modified amine compound.
9. a kind of scratch resistant wear-resisting shield glass thermal isolation film as claimed in claim 1, it is characterised in that：It is described fluorine-containing
Acrylate be Hexafluorobutyl mathacrylate, methacrylic acid 2,2,2- trifluoro ethyl esters, dodecafluoroheptyl methacrylate, third
One or more mixing in the difluoro heptyl ester of olefin(e) acid ten, the trifluoro monooctyl ester of methacrylic acid ten, perluorooctyl acrylate.
10. the preparation method of a kind of scratch resistant wear-resisting shield glass thermal isolation film as described in claim 1 to 9 is arbitrary,
Characterized in that, comprising the following steps：
（1）The preparation of heat insulating coat slurry：
By nano-titanium oxide, nano Ce O2/La2O3Composite, ultra-violet absorber, dispersant, levelling agent and coalescents are mixed
Close uniform, in being placed in sand mill, under 3000-5000r/min 12-20h is ground, be subsequently adding polyacrylate resin, continue to grind
Mill 5-10h, obtains heat insulating coat slurry；
（2）The preparation of scratch resistant wear-resistant coating slurry：
Water soluble alkyd resin, fluorinated acrylate and alcohol ester-12 are well mixed, in being placed in sand mill, 3000-5000r/
10-15h is ground under min, wetting agent, curing agent, organic silicon defoamer is subsequently adding, continues to grind 3-6h, be obtained scratch resistant wear-resisting
Coating paste；
（3）The preparation of thermal isolation film：
Obtained heat insulating coat slurry is coated uniformly on transparent membrane substrate initially with spraying or the method brushed, 80-
1-3h is dried at 150 DEG C, heat insulating coat is obtained, then using spraying or the method brushed by obtained scratch resistant wear-resistant coating slurry
Uniformly it is coated at heat insulating coat surface, 75-120 DEG C and solidifies 1-3h, obtains shield glass thermal isolation film.
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| CN107033510A (en) * | 2017-05-23 | 2017-08-11 | 句容耀皮节能玻璃科技发展有限公司 | A kind of highly-efficient glass thermal isolation film |
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| CN111280579A (en) * | 2019-03-26 | 2020-06-16 | 深圳光启高端装备技术研发有限公司 | Heat-insulation helmet and preparation method thereof |
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