CN101760110A - Ultraviolet curing nano transparent heat-insulation composite coating - Google Patents
Ultraviolet curing nano transparent heat-insulation composite coating Download PDFInfo
- Publication number
- CN101760110A CN101760110A CN 201010110050 CN201010110050A CN101760110A CN 101760110 A CN101760110 A CN 101760110A CN 201010110050 CN201010110050 CN 201010110050 CN 201010110050 A CN201010110050 A CN 201010110050A CN 101760110 A CN101760110 A CN 101760110A
- Authority
- CN
- China
- Prior art keywords
- nano
- coating
- transparent heat
- composite coating
- insulation composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 68
- 239000011248 coating agent Substances 0.000 title claims abstract description 64
- 238000009413 insulation Methods 0.000 title claims abstract description 25
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 238000000016 photochemical curing Methods 0.000 claims description 11
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000005543 nano-size silicon particle Substances 0.000 claims description 10
- 239000002086 nanomaterial Substances 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 229920002635 polyurethane Polymers 0.000 claims description 10
- -1 hexanediyl ester Chemical class 0.000 claims description 9
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000003822 epoxy resin Substances 0.000 claims description 7
- 229920000647 polyepoxide Polymers 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 5
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000012747 synergistic agent Substances 0.000 claims description 5
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 4
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 claims description 3
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- YTLYLLTVENPWFT-UPHRSURJSA-N (Z)-3-aminoacrylic acid Chemical compound N\C=C/C(O)=O YTLYLLTVENPWFT-UPHRSURJSA-N 0.000 claims 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 24
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 10
- 230000032683 aging Effects 0.000 abstract description 5
- 230000005855 radiation Effects 0.000 abstract description 4
- 238000011109 contamination Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 2
- 238000012216 screening Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 15
- 239000003973 paint Substances 0.000 description 11
- 238000001723 curing Methods 0.000 description 10
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 9
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 9
- 238000010276 construction Methods 0.000 description 8
- 229920003180 amino resin Polymers 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000004223 radioprotective effect Effects 0.000 description 2
- 238000007613 slurry method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an ultraviolet curing nano transparent heat-insulation composite coating belonging to the field of ultraviolet curing coatings and containing the following substances in percentage by weight: 30-75 percent of oilopolymer, 0.01-15 percent of photosensitive curing agent and 10-55 percent of activated monomer, as well as 0.1-15 percent of stannic oxide. The transparent heat-insulation coating can be prepared in 1 minute under ultraviolet irradiation at room temperature, and the curing speed is high and the cost is low. The coating has selectivity to a solar spectrum, and a coating film which is about 5-70 micrometers is formed on the material surface. When the coating is used for glass, the visible light transmissivity of the glass is still higher than 75 percent, and the infrared thermal screening factor is higher than 70 percent, thereby not only keeping the transparency of the original glass, but also effectively isolating the infrared thermal radiation of sunlight. The coating has good ageing resistance, contamination resistance, anti-static performance, anti-dazzle performance, radiation protection, quick curing, environmental protection and the like.
Description
Technical field
The present invention relates to a kind of ultraviolet-curing paint, specifically, is a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization.
Background technology
Nano transparent heat-insulation composite coating is the high-tech energy-saving coatings that development in recent years is got up.This coating is to utilize the shielding properties of nano material to the infrared rays excellence, selects good coating system for use, makes the nano transparent heat-insulation composite coating of making have strong adhesion, transparent, shielding infrared rays, heat insulation, characteristics such as environmental protection.According to surveying and determination, the coating that scribbles this coating can make the testee tow sides temperature difference reach 9 degrees centigrade, and energy-efficient performance is very superior.This coating is used for glass to prevent ultrared transmission, effectively cuts down the consumption of energy, have crucial meaning.
At present, the domestic research that has many people to carry out this respect.CN101029206 invents a kind of thermal-insulating external-wall coating of nano-composite water and preparation method thereof, the CN1903958 disclosure of the Invention a kind of synthesized polyurethane glass heat insulating paint and preparation method thereof, the CN1357590 disclosure of the Invention a kind of preparation method of inorganic antistatic water suspensoid, the CN1446862 disclosure of the Invention a kind of nano antimony-doped tindioxide water paste and preparation method thereof, the CN101164946 invention relates to a kind of preparation method of thermal insulation spraying agent for glass, the CN101205419 disclosure of the Invention a kind of Yb-doped nano aqueous ATO heat-proof slurry and preparation method thereof, the CN101219859 disclosure of the Invention nano-oiliness ATO heat-insulating slurry and preparation method and application thereof, the CN1542062 disclosure of the Invention a kind of nano antimony-doped tindioxide (ATO) polar organic slurry, the CN1864834 disclosure of the Invention a kind of brilliant aqueous dispersions of transparent conductive nano and preparation method thereof of high-solid level of non-additive long-term stability, the CN1884409 disclosure of the Invention a kind of nanometer antimony-doped stannic oxide antistatic coating and preparation method thereof, the CN101186781 disclosure of the Invention a kind of water transparent heat insulation paint and preparation method thereof.CN1249321 invents a kind of radioresistant insulating water paint that is applied to skin or metallic surface.CN101289281 invents a kind of high transparent organic silicon resin glass thermal insulating coating.CN101362630 invents a kind of insulating mold coating of transparent glass of acrylic resin modified preparation.The CN101550312 disclosure of the Invention a kind of synthetic alkyd resin glass transparent insulating coating and preparation method thereof.More than these coating all have the characteristics that visible light transmissivity is very high, the infrared light transmitance is very low.But, they or water-borne coatings or do not adopt the oil paint of ultraviolet light polymerization technology, set time is long, the contaminate environment if oiliness system (paint) also needs to expend than multi-solvent.
UV-light (UV) is coating material solidified to be to obtain flourish new high-tech industry over past ten years at home, and nanotechnology is the 21st century focus competitively studied of countries in the world.Come the nano transparent heat-insulation composite coating of modified ultraviolet curing with nanotechnology, not only can make the upgrading of UV coating products, and can impel UV coating to expand to high-tech sector fields such as (as aerospace, electronic materials).
UV solidifies the rapid polymerization reaction that is often referred to the solvent-free aqueous chemical material of UV-light (UV) radiation and takes place, zero release in production and environment for use and zero waste treatment, adopt this technology to significantly reduce volatile organic matter (VOC) and enter environment, avoid producing the Greenhouse effect even more serious thus, and under irradiation of sunlight, form oxide compound and photo-chemical smog than carbonic acid gas.This promotes the whole ecological system to keep circulation to have very important significance for the protection environment.
At present, the domestic report that a lot of nano composite dopes are arranged relates to multiple products such as car paint, building coating, antibiotic paint, UV be coating material solidified.In paint field, nanometer grade silica, titanium dioxide, zinc oxide, alchlor particle are often used as the auxiliary agent of coating, in order to the rheological of improving coating, improve adhesive force of coatings, hardness of film, smooth finish and do aging resistance.According to the literature, nano titanium oxide and nano silicon also have antibiotic, antirust, decompose foreign odor and multiple function such as antifouling.With containing the 0.5%--4.0% nano titanium oxide, can be used for preparing permanent seal cooling external application Clear paint as a kind of good ultraviolet money absorption agent.The adding of nano silicon can improve curing speed, hardness of film, sticking power and cryogenic thermostability that the nano transparent heat-insulation composite coating of ultraviolet light polymerization is filmed.
Summary of the invention
1. invent the technical problem that will solve
At the existing problem of existing nano transparent heat-insulation composite coating performance, the invention provides a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, wherein comprise ATO powder body material (stannic oxide and weisspiessglanz), make its cost far below being the coating that material is developed with the tin indium oxide, also be lower than the thermal isolation film that adopts usually now.Can have functions such as excellent ageing-resistant, anti-contamination is self-cleaning, anti-electrostatic, anti-dazzle, radioprotective, quick solidifying.
2. technical scheme
A kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, comprise the following material of weight percent content: oligomer 30～75%, photo-curing agent 0.01～15% and reactive monomer 10～55%, it also contains weight percent is 0.1～15% tin-antiomony oxide (ATO).
Above-mentioned reactive monomer (photosensitive diluent) is pentaerythritol triacrylate (PETA), Viscoat 295 (TMPTA), ethoxylated trimethylolpropane triacrylate (EO-TMPTA), propoxylation Viscoat 295 (PO-TMPTA), hexanediyl ester (HDDA), tripropylene glycol diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), butyl acrylate, a kind of or several materials in Isooctyl acrylate monomer and the vinylformic acid norbornene ester, they account for, and the composition by weight number is 10-55% in the coating.Photo-curing agent (photoinitiator) is a benzophenone, 1173 and the Irgacure819,651,907,2959 of Belgian UCB. S.A. (BE) Bruxelles Belgium.The photo-curing synergistic agent is the vinylformic acid tertiary ammonium salt, and it accounts for, and composition by weight is 0-15% in the coating.Flow agent and defoamer respectively account in the coating composition by weight and are 0.01-5%.Dispersion moisture agent accounts for that composition by weight is 0.01-5% in the coating.Nano material comprises that described nano material is nano silicon, zirconium dioxide, titanium dioxide, aluminum oxide, and weight percent is in 10%.Described tin-antiomony oxide (ATO) is a nano material.
Oligomer is the main component of decision coating physicals, to the many important performance of material, has a significant impact as rigidity, viscosity, curing speed, sticking power, anti-old power performance.Contain epoxy group(ing), hydroxyl isopolarity group in the acrylic acid epoxy resin molecule to by sticking material very strong sticking power being arranged, film forming matter rigidity is big, and is ageing-resistant, hardness big but weathering resistance is bad.N and urethano are arranged in the acroleic acid polyurethane molecule, unoccupied orbital is arranged on the N, snappiness is good, and is helpful to improving the coating snappiness.Acrylic-amino resin, cost is low, and viscosity is low, and curing speed is fast.Polyester acrylate and organosilicon-modified acrylate then sticking power are good.
Use because the viscosity of oligomer, is difficult to normal construction generally all than higher, so must add thinner, and this thinner is a kind of photosensitive diluent, promptly has in dilution function before solidifying and the solidification process to participate in the solidified function.The UV paint thinner mainly comprises pentaerythritol triacrylate (PETA), Viscoat 295 (TMPTA), ethoxylated trimethylolpropane triacrylate (EO-TMPTA), propoxylation Viscoat 295 (PO-TMPTA), hexanediyl ester (HDDA), tripropylene glycol diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), butyl acrylate, Isooctyl acrylate monomer and vinylformic acid norbornene ester.Thinner contains one～three activated double bonds, under photosensitizers and uviolizing crosslinking reaction takes place, and forms the build network structure.The used photosensitive diluent of the present invention is water white transparency, odorlessness liquid.
The photo-curing agent in prescription consumption seldom, adopt among the present invention benzophenone, 1173 and the Irgacure819,651,907 of Belgian UCB. S.A. (BE) Bruxelles Belgium, 2959 etc. be the photo-curing agent.It is fast to have curing speed, and stability is high, is difficult for advantages such as yellowing during curing.
The present invention adopts the photo-curing synergistic agent, and contained tertiary amine groups has the effect of free epoxy group(ing) in the curing system, accelerates curing speed under ultraviolet ray.
Flow agent and photosensitive resin consistency are good, and the coating levelling is effective after adding.
The foam of coating system is eliminated or suppressed to defoamer.
Dispersion moisture agent accounts for that composition by weight is 0.01-5% in the coating, plays the dispersion moistening nano-powder.
3. beneficial effect
The invention discloses a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, select nano inorganic material for use, can have functions such as excellent ageing-resistant, anti-contamination is self-cleaning, anti-electrostatic, anti-dazzle, radioprotective, quick solidifying, the good prospect of marketing is arranged.This material has selectivity to solar spectrum, form about 5～70 microns filming at glass surface, the visible light transmissivity of glass still is higher than 75%, and the infra-red heat shielding rate is higher than 70%, this has not only kept the transparency of original glass, and can effectively completely cut off the infrared emanation of sunlight.The glass made from this coating has higher visible light transmissivity, and the reflectivity to infrared rays (thermal radiation) is very high simultaneously, has the effect that blocking radiant heat directly sees through.Coating of the present invention at normal temperatures can be made transparent heat insulating dope through UV-irradiation in 1 minute, curing speed is exceedingly fast, and cost is low, environmental protection.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
The main production process of preparation of the present invention is: 55-65 ℃ of control stirring tank, (after 1000～2000rpm), adding residue is again prepared burden, and continues to stir after 1～4 hour to get final product earlier nano material and reactive monomer to be carried out high speed dispersion 1 hour.Following examples are all by this preparation.Following degree is weight percent content.
Embodiment 1
Preparation as stated above, the each component parts by weight are respectively:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Dispersion moisture agent: 2%
Nano silicon: 1%
ATO：2％
HDDA：20％
TPGDA：8％
TMPTA：2％
Butyl acrylate: 15%
Benzophenone: 5%
Irgacure819：5％
1173：4％
Photo-curing synergistic agent: 6%
With the coating that this prescription is produced, adopt spraying method after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 85% of glass, the infra-red heat shielding rate is higher than 71%.
Embodiment 2
Adjust nano material kind and oligomer, various material contents are as follows:.
Polyester acrylic resin: 10%
Acroleic acid polyurethane: 5%
Organosilicon modified crylic acid resin: 25%
Dispersion moisture agent: 2%
Nano silicon: 0.5%
Nano aluminium oxide: 0.5%
ATO：7％
HDDA：10％
TPGDA：8％
TMPTA：2％
Isooctyl acrylate monomer: 10%
Irgacure970：10％
1173：4％
Photo-curing synergistic agent: 6%
With the coating that this prescription is produced, adopt roll coating model after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 80% of glass, infra-red heat shielding rate 87%.
Embodiment 3
Adjust nano material kind and oligomer, various material contents are as follows.
Acroleic acid polyurethane: 25%
Organosilicon modified crylic acid resin: 20%
Dispersion moisture agent: 1.5%
Nano silicon: 0.5%
ATO：5％
PETA：4％
HDDA：8％
TPGDA：8％
E0-TMPTA：5％
Butyl acrylate: 7%
Irgacure970：10％
1173：6％
With the coating that this prescription is produced, adopt roll coating model after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 83% of glass, infra-red heat shielding rate 87%.
Embodiment 4
On the basis of embodiment 1 prescription, adjust, only keep following material:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
ATO：15％
HDDA：30％
1173：15％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are lower than embodiment 1.The visible light transmissivity 78%. of glass
Embodiment 5
On the basis of embodiment 4 prescriptions, adjust, increase nano material:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Nano silicon: 5%
ATO：10％
HDDA：30％
1173：15％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are better than embodiment 4.
Embodiment 6
On the basis of embodiment 4 prescriptions, adjust:
Acrylic-amino resin: 35%
Acroleic acid polyurethane: 20%
Acrylic acid epoxy resin: 20%
Nano silicon: 5%
ATO：5％
HDDA：10％
1173：5％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are better than embodiment 4.
Embodiment 7
On the basis of embodiment 4 prescriptions, adjust:
Acrylic-amino resin: 24%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Nano silicon: 0.89%
ATO：0.1％
HDDA：55％
1173：0.01％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate are not better than embodiment 4.
The content constraints that protection scope of the present invention is not enumerated by the foregoing description.
Claims (9)
1. the nano transparent heat-insulation composite coating of a ultraviolet light polymerization, comprise the following material of weight percent content: oligomer 30～75%, photo-curing agent 0.01～15% and reactive monomer 10～55% is characterized in that: also contain weight percent and be 0.1～15% tin-antiomony oxide.
2. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1 is characterized in that also comprising nano material, wherein nano material is a kind of in nano silicon, nano zirconium dioxide, nano titanium oxide, the nano aluminium oxide or several, and weight percent is in 10%.
3. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 2, it is characterized in that oligomer be contain that two keys can ultraviolet light polymerization resin, mix by a kind of or several materials in acrylic acid epoxy resin, acroleic acid polyurethane, polyester acrylate, organosilicon-modified acrylate and the aminoacrylic acid resin and to form.
4. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 3 is characterized in that reactive monomer is a kind of in pentaerythritol triacrylate, Viscoat 295, ethoxylated trimethylolpropane triacrylate, propoxylation Viscoat 295, hexanediyl ester, tripropylene glycol diacrylate, propylene glycol diacrylate, neopentylglycol diacrylate, butyl acrylate, Isooctyl acrylate monomer and the vinylformic acid norbornene ester or several.
5. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 4 is characterized in that the photo-curing agent is a benzophenone, 1173 or the Irgacure819,651,907 of Belgian UCB. S.A. (BE) Bruxelles Belgium, 2959 a kind of or several.
6. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior defoamer, defoamer is a kind of in silicone antifoam agent, vinyl polymer and the acrylic acid copolymer defoamer or several.
7. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior flow agent, flow agent is a kind of in polysiloxane, vinyl polymer and the acrylate copolymer or several.
8. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior dispersion moisture agent, dispersion moisture agent is a kind of in carboxylic acid, the amide polymer or several.
9. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 15% with interior vinylformic acid tertiary ammonium salt photo-curing synergistic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010110050 CN101760110A (en) | 2010-02-11 | 2010-02-11 | Ultraviolet curing nano transparent heat-insulation composite coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010110050 CN101760110A (en) | 2010-02-11 | 2010-02-11 | Ultraviolet curing nano transparent heat-insulation composite coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101760110A true CN101760110A (en) | 2010-06-30 |
Family
ID=42491493
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010110050 Pending CN101760110A (en) | 2010-02-11 | 2010-02-11 | Ultraviolet curing nano transparent heat-insulation composite coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101760110A (en) |
Cited By (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533091A (en) * | 2010-12-10 | 2012-07-04 | 江南大学 | Transparent heat-insulation ultraviolet (UV) photocuring polyurethane coating capable of being used in building windows and preparation method thereof |
| CN102603208A (en) * | 2012-03-16 | 2012-07-25 | 惠州市长润发涂料有限公司 | Manufacturing method of self-cleaning glass |
| CN102807814A (en) * | 2012-07-26 | 2012-12-05 | 惠州市至上化工有限公司 | Nano silica-modified recoatable ultraviolet (UV) varnish used on plastic and preparation method for varnish |
| CN102942841A (en) * | 2012-05-30 | 2013-02-27 | 刘志钊 | Transparent thermal insulation coating material system for glass substrate |
| CN103351677A (en) * | 2013-07-11 | 2013-10-16 | 苏江林 | Paint for preparing antiglare, antistatic and antifouling coating, coating and preparation method of coating |
| CN103450795A (en) * | 2013-09-17 | 2013-12-18 | 成都优品涂料有限公司 | Ultraviolet-curing fireproof flame-retardant wood paint and preparation method thereof |
| CN103788797A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | A kind of antibacterial ultraviolet photocuring coating and preparation method thereof |
| CN103865368A (en) * | 2014-03-12 | 2014-06-18 | 河南科技大学 | Nano titanium dioxide anti-bacterial UV (ultraviolet) varnish and preparation method thereof |
| CN104017402A (en) * | 2014-05-23 | 2014-09-03 | 浙江鸿浩科技有限公司 | Flame retardation type exterior coating capable of automatically cleaning |
| CN104164168A (en) * | 2014-08-29 | 2014-11-26 | 广西梧州龙鱼漆业有限公司 | Air-drying acrylic enamel |
| CN104559699A (en) * | 2014-12-11 | 2015-04-29 | 惠州市长润发涂料有限公司 | UV (ultraviolet) matte varnish for roller coating |
| CN104629610A (en) * | 2013-11-07 | 2015-05-20 | 龙海市大华涂料有限公司 | A kind of electrostatic coating UV photocuring polyurethane acrylic coating and preparation method thereof |
| CN104761994A (en) * | 2015-04-10 | 2015-07-08 | 南昌航空大学 | Preparation method of photocuring organic silicon modified epoxy resin paint film |
| CN104774550A (en) * | 2015-02-04 | 2015-07-15 | 绵阳市盛宇新材料有限公司 | A kind of nanometer TiO2/ZnO anti-ultraviolet coating for PC and its preparation method |
| CN105199051A (en) * | 2015-11-02 | 2015-12-30 | 宋介珍 | Transparent organosilicon material and preparation method thereof |
| CN105859956A (en) * | 2016-04-25 | 2016-08-17 | 江苏敦超电子科技有限公司 | Photosensitive resin for solid materials and preparation method thereof |
| CN106281032A (en) * | 2016-08-10 | 2017-01-04 | 太仓市美航涂料有限公司 | A kind of preparation technology of the photo-curing paint of good heat-insulation effect |
| CN106281033A (en) * | 2016-08-10 | 2017-01-04 | 太仓市美航涂料有限公司 | The purple light solidified paint that a kind of effect of heat insulation is outstanding |
| CN106811109A (en) * | 2017-01-10 | 2017-06-09 | 浙江新迪在龙涂料科技有限公司 | A kind of energy-conserving and environment-protective thermal insulation board and preparation method thereof |
| CN107236425A (en) * | 2017-06-23 | 2017-10-10 | 南京工业大学 | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof |
| CN107418442A (en) * | 2017-06-13 | 2017-12-01 | 乾帛新材料科技（上海）有限公司 | A kind of new hydrophilic glass self-cleaning coating and preparation method thereof |
| CN109403478A (en) * | 2018-11-21 | 2019-03-01 | 嘉兴才蛮幕墙材料有限公司 | A kind of production method of environment-friendly type aluminum veneer |
| CN110669400A (en) * | 2019-09-22 | 2020-01-10 | 珠海东胜科技有限公司 | Ultraviolet-curing heat-insulating automobile glass coating and preparation method and application thereof |
| CN111303465A (en) * | 2020-03-20 | 2020-06-19 | 江苏新视客光电科技有限公司 | Efficient polarizing PC anti-glare lens and preparation method thereof |
| CN115612395A (en) * | 2022-11-07 | 2023-01-17 | 江南大学 | Preparation process of a fast-drying fluorine-containing modified UV-cured hyperbranched waterborne polyurethane coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554717A (en) * | 2003-12-26 | 2004-12-15 | �Ͼ���̩���ײ�������˾ | Nano technology modified ultraviolet solidified woodware paint |
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulation glass |
| CN101186781A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | A kind of transparent thermal insulation coating and preparation method thereof |
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
| CN101538443A (en) * | 2008-03-19 | 2009-09-23 | 汤汉良 | Method for preparing automobile finish made of nanometer heat insulation material |
-
2010
- 2010-02-11 CN CN 201010110050 patent/CN101760110A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554717A (en) * | 2003-12-26 | 2004-12-15 | �Ͼ���̩���ײ�������˾ | Nano technology modified ultraviolet solidified woodware paint |
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulation glass |
| CN101186781A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | A kind of transparent thermal insulation coating and preparation method thereof |
| CN101538443A (en) * | 2008-03-19 | 2009-09-23 | 汤汉良 | Method for preparing automobile finish made of nanometer heat insulation material |
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533091A (en) * | 2010-12-10 | 2012-07-04 | 江南大学 | Transparent heat-insulation ultraviolet (UV) photocuring polyurethane coating capable of being used in building windows and preparation method thereof |
| CN102603208A (en) * | 2012-03-16 | 2012-07-25 | 惠州市长润发涂料有限公司 | Manufacturing method of self-cleaning glass |
| CN102603208B (en) * | 2012-03-16 | 2015-04-22 | 惠州市长润发涂料有限公司 | Manufacturing method of self-cleaning glass |
| CN102942841A (en) * | 2012-05-30 | 2013-02-27 | 刘志钊 | Transparent thermal insulation coating material system for glass substrate |
| CN102942841B (en) * | 2012-05-30 | 2015-07-22 | 刘志钊 | Transparent thermal insulation coating material system for glass substrate |
| CN102807814B (en) * | 2012-07-26 | 2015-04-08 | 惠州市至上新材料有限公司 | Nano silica-modified recoatable ultraviolet (UV) varnish used on plastic and preparation method for varnish |
| CN102807814A (en) * | 2012-07-26 | 2012-12-05 | 惠州市至上化工有限公司 | Nano silica-modified recoatable ultraviolet (UV) varnish used on plastic and preparation method for varnish |
| CN103351677A (en) * | 2013-07-11 | 2013-10-16 | 苏江林 | Paint for preparing antiglare, antistatic and antifouling coating, coating and preparation method of coating |
| CN103450795A (en) * | 2013-09-17 | 2013-12-18 | 成都优品涂料有限公司 | Ultraviolet-curing fireproof flame-retardant wood paint and preparation method thereof |
| CN104629610B (en) * | 2013-11-07 | 2017-08-25 | 龙海市大华涂料有限公司 | A kind of electrostatic coating UV photocuring polyurethane acrylic coating and preparation method thereof |
| CN104629610A (en) * | 2013-11-07 | 2015-05-20 | 龙海市大华涂料有限公司 | A kind of electrostatic coating UV photocuring polyurethane acrylic coating and preparation method thereof |
| CN103788797A (en) * | 2014-02-13 | 2014-05-14 | 芜湖市宝艺游乐科技设备有限公司 | A kind of antibacterial ultraviolet photocuring coating and preparation method thereof |
| CN103865368A (en) * | 2014-03-12 | 2014-06-18 | 河南科技大学 | Nano titanium dioxide anti-bacterial UV (ultraviolet) varnish and preparation method thereof |
| CN104017402A (en) * | 2014-05-23 | 2014-09-03 | 浙江鸿浩科技有限公司 | Flame retardation type exterior coating capable of automatically cleaning |
| CN104164168A (en) * | 2014-08-29 | 2014-11-26 | 广西梧州龙鱼漆业有限公司 | Air-drying acrylic enamel |
| CN104559699A (en) * | 2014-12-11 | 2015-04-29 | 惠州市长润发涂料有限公司 | UV (ultraviolet) matte varnish for roller coating |
| CN104774550B (en) * | 2015-02-04 | 2017-05-10 | 绵阳市盛宇新材料有限公司 | Nanometer TiO2/ZnO anti-ultraviolet coating for PC and preparation method thereof |
| CN104774550A (en) * | 2015-02-04 | 2015-07-15 | 绵阳市盛宇新材料有限公司 | A kind of nanometer TiO2/ZnO anti-ultraviolet coating for PC and its preparation method |
| CN104761994A (en) * | 2015-04-10 | 2015-07-08 | 南昌航空大学 | Preparation method of photocuring organic silicon modified epoxy resin paint film |
| CN104761994B (en) * | 2015-04-10 | 2016-11-23 | 南昌航空大学 | A kind of preparation method of photo-curable silicone modified epoxy paint film |
| CN105199051A (en) * | 2015-11-02 | 2015-12-30 | 宋介珍 | Transparent organosilicon material and preparation method thereof |
| CN105859956A (en) * | 2016-04-25 | 2016-08-17 | 江苏敦超电子科技有限公司 | Photosensitive resin for solid materials and preparation method thereof |
| CN106281032A (en) * | 2016-08-10 | 2017-01-04 | 太仓市美航涂料有限公司 | A kind of preparation technology of the photo-curing paint of good heat-insulation effect |
| CN106281033A (en) * | 2016-08-10 | 2017-01-04 | 太仓市美航涂料有限公司 | The purple light solidified paint that a kind of effect of heat insulation is outstanding |
| CN106811109A (en) * | 2017-01-10 | 2017-06-09 | 浙江新迪在龙涂料科技有限公司 | A kind of energy-conserving and environment-protective thermal insulation board and preparation method thereof |
| CN107418442A (en) * | 2017-06-13 | 2017-12-01 | 乾帛新材料科技（上海）有限公司 | A kind of new hydrophilic glass self-cleaning coating and preparation method thereof |
| CN107236425A (en) * | 2017-06-23 | 2017-10-10 | 南京工业大学 | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof |
| CN107236425B (en) * | 2017-06-23 | 2019-12-24 | 南京工业大学 | A self-cleaning UV-cured transparent heat-insulating coating and its preparation method |
| CN109403478A (en) * | 2018-11-21 | 2019-03-01 | 嘉兴才蛮幕墙材料有限公司 | A kind of production method of environment-friendly type aluminum veneer |
| CN110669400A (en) * | 2019-09-22 | 2020-01-10 | 珠海东胜科技有限公司 | Ultraviolet-curing heat-insulating automobile glass coating and preparation method and application thereof |
| CN111303465A (en) * | 2020-03-20 | 2020-06-19 | 江苏新视客光电科技有限公司 | Efficient polarizing PC anti-glare lens and preparation method thereof |
| CN115612395A (en) * | 2022-11-07 | 2023-01-17 | 江南大学 | Preparation process of a fast-drying fluorine-containing modified UV-cured hyperbranched waterborne polyurethane coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101760110A (en) | Ultraviolet curing nano transparent heat-insulation composite coating | |
| CN107236425B (en) | A self-cleaning UV-cured transparent heat-insulating coating and its preparation method | |
| CN102120900A (en) | Ultraviolet curing nano transparent heat-insulating composite coating | |
| CN103224722B (en) | Ultraviolet light polymerization fluorine carbon solar cell backside protecting film coating | |
| CN103319971B (en) | A kind of metallic travel aqueous fluorocarbon coating and preparation method thereof for exterior wall | |
| KR101413219B1 (en) | Resin compositions having insulation effect and antibiotic effect, functional film using the same | |
| CN110964416B (en) | Weather-resistant wear-resistant polyester resin, powder coating and preparation method thereof | |
| CN101885943A (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN102408765B (en) | Ultraviolet ray and electron beam cured heat insulation coating | |
| CN101423677A (en) | Method for preparing transparent and heat insulating water ultraviolet curing coating | |
| CN107267011A (en) | A kind of coating with heat insulating reflecting function and preparation method thereof | |
| CN102816551A (en) | Ultraviolet (UV)-moisture double-curing liquid optical transparent adhesive and preparation method thereof | |
| CN104070734A (en) | A kind of coated glass with high reflectivity and preparation method thereof | |
| CN102863892B (en) | Water-base polyurethane coating for fan blades and preparation method thereof | |
| CN104263204A (en) | Preparation method for carbon nanotube-epoxy resin radiation-resistant coating for steel-based surface of nuclear power station | |
| CN102140251B (en) | Super-hydrophobic transparent film with hydrogen-containing silicone oil condensate as matrix and preparation method thereof | |
| CN105062314B (en) | A kind of high-low temperature resistant UV plastic coatings and preparation method thereof | |
| CN101787238B (en) | Preparation method for high stain-resistant and thermal-insulating type UV curing fluorine coating | |
| CN108752571A (en) | It is a kind of using useless PET plastic bottle as the aqueous polyester resin for coating of primary raw material | |
| CN103897577B (en) | glass coating and preparation method thereof | |
| CN110437711A (en) | A kind of low temperature curing type B68 extinction powder epoxy resin and the preparation method and application thereof | |
| CN104004429A (en) | Normal temperature-curable composite coating based on modified 107 silicone rubber and preparation method thereof | |
| CN106831624A (en) | A kind of lacquer as woodenware finish UV resins and preparation method thereof | |
| CN105859996A (en) | Water-soluble UV resin and preparation method thereof | |
| CN102040872A (en) | Heat-insulating coating with spectral selectivity |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20100630 |