CN102942841B - Transparent thermal insulation coating material system for glass substrate - Google Patents
Transparent thermal insulation coating material system for glass substrate Download PDFInfo
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- CN102942841B CN102942841B CN201210411426.7A CN201210411426A CN102942841B CN 102942841 B CN102942841 B CN 102942841B CN 201210411426 A CN201210411426 A CN 201210411426A CN 102942841 B CN102942841 B CN 102942841B
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- acid ester
- propyl
- titanic acid
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- 238000000576 coating method Methods 0.000 title claims abstract description 65
- 239000011248 coating agent Substances 0.000 title claims abstract description 57
- 239000011521 glass Substances 0.000 title claims abstract description 39
- 238000009413 insulation Methods 0.000 title abstract description 11
- 239000000758 substrate Substances 0.000 title abstract description 8
- 239000000463 material Substances 0.000 title abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003701 inert diluent Substances 0.000 claims abstract description 5
- -1 isophthaloyl titanic acid ester Chemical class 0.000 claims description 55
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 28
- 150000002148 esters Chemical class 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 5
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 4
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims description 4
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- FHLPGTXWCFQMIU-UHFFFAOYSA-N [4-[2-(4-prop-2-enoyloxyphenyl)propan-2-yl]phenyl] prop-2-enoate Chemical compound C=1C=C(OC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OC(=O)C=C)C=C1 FHLPGTXWCFQMIU-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 4
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical group COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 4
- QEWYKACRFQMRMB-UHFFFAOYSA-N monofluoroacetic acid Natural products OC(=O)CF QEWYKACRFQMRMB-UHFFFAOYSA-N 0.000 claims description 4
- 229910000077 silane Inorganic materials 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 3
- XLXOGJYARRBRPZ-UHFFFAOYSA-N [2,3-di(prop-2-enoyloxy)-3-propoxypropyl] prop-2-enoate Chemical compound CCCOC(OC(=O)C=C)C(OC(=O)C=C)COC(=O)C=C XLXOGJYARRBRPZ-UHFFFAOYSA-N 0.000 claims description 3
- ZOJPTQRKWVDKTP-UHFFFAOYSA-N decane methanol prop-2-enoic acid Chemical compound C(C=C)(=O)O.C(C=C)(=O)O.CO.CO.CCCCCCCCCC ZOJPTQRKWVDKTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- PCLLJCFJFOBGDE-UHFFFAOYSA-N (5-bromo-2-chlorophenyl)methanamine Chemical compound NCC1=CC(Br)=CC=C1Cl PCLLJCFJFOBGDE-UHFFFAOYSA-N 0.000 claims description 2
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 claims description 2
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims description 2
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 claims description 2
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 2
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 claims description 2
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 claims description 2
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 claims description 2
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- LNLPZVVOYZTUNG-UHFFFAOYSA-N benzyl(ethenyl)silicon Chemical compound C=C[Si]CC1=CC=CC=C1 LNLPZVVOYZTUNG-UHFFFAOYSA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 125000004386 diacrylate group Chemical group 0.000 claims description 2
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 claims description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 claims description 2
- 229960003493 octyltriethoxysilane Drugs 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 2
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- MLFKNHZGOMNRBN-UHFFFAOYSA-N C(C)OCCOC(=CC)CC Chemical group C(C)OCCOC(=CC)CC MLFKNHZGOMNRBN-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000843 powder Substances 0.000 abstract description 4
- 239000002002 slurry Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 20
- 239000006185 dispersion Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 238000000016 photochemical curing Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 239000011858 nanopowder Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical group CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000009998 heat setting Methods 0.000 description 2
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pent-2-ene Chemical group CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 description 2
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000001883 metal evaporation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention discloses a transparent thermal insulation coating material system for a glass substrate. The coating material system is a double layer coating material system formed by a separately-prepared primary coating and a separately-prepared surface coating, wherein the surface coating is coated on the primary coating, the primary coating comprises the following components, by mass, 0.05-3 parts of a silicane coupling agent or a titanate coupling agent, 0.2-5 parts of a hydrolysis catalyst, and 95-99 parts of a solvent, and the surface coating comprises the following components, by mass, 50-80 parts of a light curable resin, 5-35 parts of an active diluent, 1-8 parts of a photoinitiator, 5-35 parts of an antimony tin oxide nanometer thermal insulation powder slurry or an indium tin oxide nanometer thermal insulation powder slurry, 100-140 parts of an inert diluent, and 0.01-0.15 part of a leveling agent. With the coating material system, a film can be formed through a conventional film forming method, and the film layer can be cured within a few seconds after ultraviolet light irradiation. In addition, the coating material system has characteristics of high hardness, excellent adhesion and excellent water resistance.
Description
Technical field
The present invention relates to a kind of coating of glass baseplate, specifically refer to a kind of transparent heat insulating dope system for glass baseplate.
Technical background
Transparent heat-insulated coating is generally coated in transparent glass surface, can strong absorption UV-light, through most of visible ray, higher reflectivity is had near infrared ray, thus to the internal space that it is gone along with sb. to guard him, as in indoor, car etc., reach the object of heat-insulating and energy-saving, in today that power supply growing tension and environmental pollution increase the weight of, there is important economy and social benefit.
Early stage transparent heat-insulated coating is at metallic films such as glass surface evaporation one or more layers such as gold and silver, copper, tin, chromium, titaniums by vapour deposition process.This plated film heat-insulating and energy-saving successful, but high to visible reflectance, be applied on curtain wall for high rise building glass and can cause so-called " light pollution " problem.In addition, vapour deposition process facility investment is large, and production energy consumption is high, can not site operation.
By metal evaporation in polyester film surface, then evaporation face laminating on another strata ester film, then coat wearing layer and install glue make transparent heat-insulated pad pasting, be directly attached to glass surface during construction.Adopt this method can not only improve building energy-saving effect, can also improve building glass security, be comparatively feasible technique means simultaneously at present in existing building glass energy-saving improvement project.But it is expensive that shortcoming is it, easily scratches, be mainly used on high-grade hotel, senior office building and vehicle glass at present, common building be difficult to big area and use.
Nano transparent insulating coating is a kind of high-tech product grown up in recent years.It is that transparent conductive oxide (TCO) the nano-powder Homogeneous phase mixing such as ITO, ATO by having heat insulating function are in transparent base resin, and add the auxiliary agents such as certain stablizer, flow agent, the obtained transparent heat insulating dope with certain stably stored phase, be coated on during construction on glass, make transparent heat insulation diaphragm through solvent evaporates or curing reaction.The preparation of nano transparent insulating coating focuses on the selection of transparent base film-forming resin.Different according to selected resin membrane formation mechanism, nano transparent insulating coating can be divided into volatilization, thermofixation and photocuring three kinds.
The resin of solvent type heat insulation coating is mainly organic solvent type and aqueous dispersion type.Atmospheric pollution can be caused, not environmentally during solvent-based system film forming; And aqueous dispersion film forming speed is slow, become film hardness low, not scratch resistance.Thermofixation thermal insulating coating becomes film hardness high adhesive force good, excellent combination property, and shortcoming is that heating energy consumption is higher, is difficult to carry out site operation.
Application number is the effect of heat insulation test set that patent document discloses a kind of nano transparent heat-insulation composite coating and this coating thereof of 200410014672.4, coating is by urethane resin, polyorganosiloxane resin, polyacrylic resin, nano-indium stannum oxide (ITO) powder, nano antimony tin oxide (ATO) powder, the composition such as coatings additive(s) and thinner.The features such as this coating has, transparent, and shielding infrared rays is heat insulation.But coating surface hardness described in this patent documentation is inadequate, and be H, sticking power is poor, is 3 grades.
Application number is the nano transparent heat-insulation composite coating that patent document discloses a kind of ultraviolet light polymerization of 201110092748.5.But product paint coatings hardness deficiency (2H) of this patent application, for providing coating adhesion and water resistance aspect data.
Photocuring thermal insulating coating can under ultraviolet light irradiation, film-forming within the room temperature lower several seconds, and curing speed is fast, is both applicable to factory lines technical process, again can site operation, and energy consumption is low.But light solidifying coating internal stress is large, and hardness height then sticking power declines greatly; Then coating hardness is inadequate to ensure sticking power.In addition, the water tolerance of current light solidifying coating is inadequate.These factors greatly limit its marketization application.
Summary of the invention
The object of the invention is to the deficiency for existing glass transparent insulating coating and defect, provide a kind of transparent heat insulating dope system for glass baseplate, this coating system has high rigidity, excellent sticking power and water tolerance.
Above-mentioned purpose of the present invention realizes by following technical solution: a kind of transparent heat insulating dope system for glass baseplate, it is characterized in that: described coating system is be coated with by the primary coat prepared separately and face the two-layer coating systems formed, face is coated in primary coat, wherein, in described primary coat each component and mass fraction proportioning as follows: silane coupling agent or titanate coupling agent 0.05 ~ 3 part, hydrolyst 0.2 ~ 5 part, solvent 95 ~ 99 parts; Described face is painted with ultraviolet curable coating, face be coated with in each component and mass fraction proportioning as follows: light-cured resin 50 ~ 80 parts, reactive thinner 5 ~ 35 parts, light trigger 1 ~ 8 part, tin-antiomony oxide or tin indium oxide nano heat-insulating powdery pulp 5 ~ 35 parts, inert diluent 100 ~ 140 parts, flow agent 0.01 ~ 0.15 part.
Primary coat of the present invention is silane or the titanate coupling agent alcoholic solution of activation, and its effect is by inorganic substrate and has machine side to be coated with system by being wound around link between chemical bond or molecular chain, improves sticking power and the water tolerance of whole coating system; It is photo-cured coating that face is coated with, and is wherein added with ATO or the ITO nano-powder playing heat insulating function, and the Main Function that face is coated with is the dispersion bearing substrate as heat insulating function nano-powder, for whole coating system provides high surface hardness.
In the present invention, described silane coupling agent or titanate coupling agent need be hydrolyzed in advance, and described hydrolyst is the one in hydrochloric acid, phosphoric acid, acetic acid, oxalic acid, butyric acid, methylene-succinic acid, toxilic acid.
In the present invention, described silane coupling agent is γ-aminopropyl triethoxysilane, γ-glycydoxy Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, gamma-mercaptopropyltriethoxysilane, γ-mercaptopropyl trimethoxysilane, vinyltriethoxysilane, vinyltrimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-methacryloyloxypropyl methyl dimethoxysilane, octadecyl trimethoxysilane, octyltri-ethoxysilane, γ-chloropropyl triethoxysilane, γ-r-chloropropyl trimethoxyl silane, 3-(2, 3-epoxy third oxygen) propyl trimethoxy silicane, 3-(2, 3-epoxy third oxygen) propyl-triethoxysilicane, one or more in cationic vinyl benzyl silane.
In the present invention, described titanate coupling agent is sec.-propyl three isophthaloyl titanic acid ester, sec.-propyl dodecyl benzene sulfonyl titanic acid ester, sec.-propyl three (dioctylphyrophosphoric acid ester) titanic acid ester, two (dioctyl phosphito ester) titanic acid ester of tetra isopropyl, two [two (dodecyl) phosphorous acid ester] titanic acid ester of four octyl groups, four (2,2 two allyl oxygen methyl isophthalic acid-butyl) two [two (tridecyl) phosphorous acid ester] titanic acid ester, two (dioctylphyrophosphoric acid ester) fluoroacetic acid ester titanic acid ester, two (dioctylphyrophosphoric acid ester) ethylene titanic acid ester, sec.-propyl three decoyl titanic acid ester, sec.-propyl dimethacrylate iso stearate titanic acid ester, sec.-propyl iso stearate two acryloyl titanic acid ester, sec.-propyl three (dioctyl phosphoric acid ester) titanic acid ester, sec.-propyl three cumyl phenyl titanic acid ester, sec.-propyl three (N-aminoethyl-aminoethyl) titanic acid ester, dicumylphenyl fluoroacetic acid ester titanic acid ester, distearyl ethylene titanic acid ester, sec.-propyl three (methacryloyl) titanic acid ester, one in sec.-propyl three acryloyl titanic acid ester.
In the present invention, primary coat solvent for use is a kind of in deionized water, ethanol and Virahol or their mixture.
In the present invention, described primary coat is added with beta-dicarbonyl compound methyl aceto acetate or the methyl ethyl diketone that mass fraction is 0.1 ~ 5, in order to the hydrolysate of stable silane or titanate coupling agent.
In the present invention, described inert diluent is ethanol, in order to adjust coating application performance, also plays froth breaking effect simultaneously.
In the present invention, described light-cured resin is epoxy acrylic resin, one or more in polyester chloride acrylic ester or multifunctional polyurethane acrylic resin.
In the present invention, described reactive thinner is hydroxyethyl methylacrylate, 2(2-ethoxy ethoxy) ethyl propylene acid esters, two diacrylates of Poly-propylene glycols, tripropylene glycol diacrylate, propylene glycol diacrylate, hexanediyl ester, glycerol triacrylate, propoxy-glycerol triacrylate, propoxy-neopentylglycol diacrylate, tri methylol triacrylate, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, cyclohexane dimethanol diacrylate, alkoxide cyclohexane dimethanol diacrylate, bisphenol a diacrylate, alkoxylated bisphenol A diacrylate, tricyclic decane Dimethanol Diacrylate, one or more in three (2-hydroxyethyl) tricarbimide triacrylate.
In the present invention; described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2; 4; 6, one or more in-trimethylbenzoy-dipheny phosphorus oxide, 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone, 2-dimethylamino-2-benzyl-1-[4-(4-morpholinyl) phenyl]-1-butanone, isopropyl thioxanthone, active ammonia.
In the present invention, described flow agent adopts the flow agent of existing routine, as adopted lower molecular weight silicone resin, model is as BYK307, BYK310, BYK333, BYK344, BYK300 etc. or adopt acrylic ester oligomer, and model is as any one in BYK354, BYK356, BYK381, BYK390 etc.
Compared with prior art, coating system of the present invention comprises the two-layer coating systems of quick-dry type primary coat and photocuring face painting compound, be coated with photocuring face with crossing quick-dry type primary coat cooperation, the instantaneous solidification, the energy consumption that make it both to remain photo-cured coating are low, feature flexibly of constructing, solve again the problem that light solidifying coating hardness and sticking power are difficult to take into account simultaneously, substantially increase its water tolerance simultaneously, make the properties of prepared transparent heat-insulated coating all can meet practical application request.The primary coat easy construction of this coating system, after applying, 1 ~ 2min can from dry, and coat-thickness is 0.1 ~ 1 μm; After photocuring face is coated with and applies after the levelling drying of 3 ~ 5min, ultraviolet lighting several seconds and curable, thickness is 7 ~ 20 μm.The Double-layered transparent thermal isolation film obtained sticking power on glass can reach 0 ~ 1 grade, and hardness is 4 ~ 6H, and the one week rete that soaks under room temperature is non-foaming, does not come off.After film, glass visible ray average transmittances is higher than 70%, and infrared rays rejection rate can reach 75%, and effect of heat insulation is remarkable, room temp can be reduced the highest 7 ° of C, not affect indoor lighting again simultaneously.
Embodiment
The invention will be further described below to provide specific embodiment.Embodiment is only the detailed description to implementation process of the present invention, does not have any restriction to the scope of the invention.
Embodiment 1
A kind of transparent heat insulating dope system for glass baseplate, this coating system is be coated with by the primary coat prepared separately and face the two-layer coating systems formed, face is coated in primary coat and forms duplex coating, wherein, prepared by primary coat: in stirred vessel, add 987g 95% successively ethanol and 10g acetic acid, drip 3g γ-methacryloxypropyl trimethoxy silane after stirring, dropwise rear continuation stirring 30 minutes.
Face is coated with preparation: in stirring tank, add Epocryl 4.69kg successively, polyester chloride acrylic ester 0.35kg, propoxy-neopentylglycol diacrylate 1.4kg, 2(2-ethoxy ethoxy) ethyl propylene acid esters 0.35kg, light trigger 2-hydroxy-2-methyl-1-phenyl-1-acetone 0.21kg, adds the tin-antiomony oxide nanoparticle alcohol dispersion liquid 2.0kg of 30wt% solid content, flow agent BYK356 10g again after stirring, 95% ethanol 11kg, last stirring at low speed 1 hour.
Embodiment: adopt spraying coating process method first to apply primary coat at the glass substrate surface of cleaning, drying at room temperature applies face again and is coated with after 3 ~ 5 minutes, dry levelling was about 15s with 3000W ultraviolet light irradiation after 5 minutes makes face be coated with solidification.Gained solidified coating sticking power is 0 grade, and surface hardness is 4H, to be at room temperature soaked in water 7 days coatings non-foaming, do not come off.After film, glass visible ray average transmittances is 73%, infrared barrier rate 79%, the highest room temp can be reduced by 5 ° of C.
Embodiment 2
For a transparent heat insulating dope system for glass baseplate, comprise face and be coated with and primary coat, wherein, prepared by primary coat: in stirred vessel, add 990g deionized water, drip 10g γ-aminopropyl triethoxysilane under stirring state, dropwise rear continuation stirring 1 hour, ageing 24 hours under room temperature.
Face is coated with preparation: in stirring tank, add six functional polyurethanes acrylate tree 4.9kg successively, tripropylene glycol diacrylate 1.4kg, hydroxyethyl methylacrylate 0.49kg, light trigger 2-hydroxy-2-methyl-1-phenyl-1-acetone 0.21kg, the tin indium oxide nanoparticle alcohol dispersion liquid 1.8kg of 30wt% solid content is added again after stirring, flow agent BYK 354 10g, 95% ethanol 11.2kg, last stirring at low speed 1 hour.
Embodiment: adopt roller painting first to apply primary coat at the glass substrate surface of cleaning, drying at room temperature applies face again and is coated with after 10 ~ 20 minutes, dry levelling was about 15s with 3000W ultraviolet light irradiation after 5 minutes makes face be coated with solidification.Gained solidified coating sticking power is 0 grade, and surface hardness is 5H, to be at room temperature soaked in water 7 days coatings non-foaming, do not come off.After film, glass visible ray average transmittances is 77%, infrared barrier rate 82%, the highest room temp can be reduced by 7 ° of C.
Embodiment 3
A kind of transparent heat insulating dope system for glass baseplate, comprise face to be coated with and primary coat, wherein, prepared by primary coat: in stirred vessel, add 99% ethanol 780g, methyl ethyl diketone 10g, drip the homogeneous mixture be made up of 10g sec.-propyl dimethacrylate iso stearate titanic acid ester, 0.4g concentrated hydrochloric acid, 200g99% ethanol under stirring state, dropwise rear continuation stirring 1 hour, ageing 12 hours under room temperature.
Face is coated with preparation: in stirring tank, add six functional polyurethanes acrylate tree 4.2kg successively, tripropylene glycol diacrylate 1.4kg, hexanediyl ester 0.7kg, propoxy-glycerol triacrylate 0.3kg, hydroxyethyl methylacrylate 0.3kg, light trigger isopropyl thioxanthone 0.14kg, active ammonia 0.21kg, the tin indium oxide nanoparticle alcohol dispersion liquid 1.8kg of 30wt% solid content is added again after stirring, flow agent BYK30710g, 95% ethanol 11.2kg, last stirring at low speed 1 hour.
Embodiment: adopt roller painting first to apply primary coat at the glass substrate surface of cleaning, drying at room temperature applies face again and is coated with after 3 ~ 5 minutes, dry levelling was about 15s with 3000W ultraviolet light irradiation after 5 minutes makes face be coated with solidification.Gained solidified coating sticking power is 1 grade, and surface hardness is 4H, to be at room temperature soaked in water 7 days coatings non-foaming, do not come off.After film, glass visible ray average transmittances is 76%, infrared barrier rate 80%, the highest room temp can be reduced by 7 ° of C.
Embodiment 4
A kind of transparent heat insulating dope system for glass baseplate, comprise face to be coated with and primary coat, wherein, prepared by primary coat: in stirred vessel, add 987g 95% successively ethanol and 5g toxilic acid, drip 1g γ-methacryloxypropyl trimethoxy silane and 2g γ-glycydoxy Trimethoxy silane after stirring, dropwise rear continuation stirring 30 minutes.
Face is coated with preparation: in stirring tank, add Epocryl 4.69kg successively, 6 functional polyurethanes acrylic resin 0.35kg, tricyclic decane Dimethanol Diacrylate 1.4kg, three (2-hydroxyethyl) tricarbimide triacrylate 0.35kg, light trigger isopropyl thioxanthone 0.1kg, active ammonia 0.15kg, 2-hydroxy-2-methyl-1-phenyl-1-acetone 0.1kg, the tin-antiomony oxide nanoparticle alcohol dispersion liquid 2.0kg of 30wt% solid content is added again after stirring, flow agent BYK333 10g, 95% ethanol 11kg, last stirring at low speed 1 hour.
Embodiment: adopt spraying coating process method first to apply primary coat at the glass substrate surface of cleaning, drying at room temperature applies face again and is coated with after 3 ~ 5 minutes, dry levelling was about 15s with 3000W ultraviolet light irradiation after 5 minutes makes face be coated with solidification.Gained solidified coating sticking power is 0 grade, and surface hardness is 6H, to be at room temperature soaked in water 7 days coatings non-foaming, do not come off.After film, glass visible ray average transmittances is 73%, infrared barrier rate 79%, the highest room temp can be reduced by 5 ° of C.
Claims (9)
1. the transparent heat insulating dope system for glass baseplate, it is characterized in that: described coating system is be coated with by the primary coat prepared separately and face the two-layer coating systems formed, face is coated in primary coat, wherein, in described primary coat each component and mass fraction proportioning as follows: silane coupling agent or titanate coupling agent 0.05 ~ 3 part, hydrolyst 0.2 ~ 5 part, solvent 95 ~ 99 parts; Described face is painted with ultraviolet curable coating, face be coated with in each component and mass fraction proportioning as follows: light-cured resin 50 ~ 80 parts, reactive thinner 5 ~ 35 parts, light trigger 1 ~ 8 part, tin-antiomony oxide or tin indium oxide nano heat-insulating powdery pulp 5 ~ 35 parts, inert diluent 100 ~ 140 parts, flow agent 0.01 ~ 0.15 part.
2. the transparent heat insulating dope system for glass baseplate according to claim 1, it is characterized in that: described silane coupling agent or titanate coupling agent need be hydrolyzed in advance, described hydrolyst is the one in hydrochloric acid, phosphoric acid, acetic acid, oxalic acid, butyric acid, methylene-succinic acid, toxilic acid.
3. the transparent heat insulating dope system for glass baseplate according to claim 1, it is characterized in that: described silane coupling agent is γ-aminopropyl triethoxysilane, γ-glycydoxy Trimethoxy silane, γ-methacryloxypropyl trimethoxy silane, gamma-mercaptopropyltriethoxysilane, γ-mercaptopropyl trimethoxysilane, vinyltriethoxysilane, vinyltrimethoxy silane, vinyl three ('beta '-methoxy oxyethyl group) silane, γ-methacryloyloxypropyl methyl dimethoxysilane, octadecyl trimethoxysilane, octyltri-ethoxysilane, γ-chloropropyl triethoxysilane, γ-r-chloropropyl trimethoxyl silane, 3-(2, 3-epoxy third oxygen) propyl trimethoxy silicane, 3-(2, 3-epoxy third oxygen) propyl-triethoxysilicane, one or more in cationic vinyl benzyl silane.
4. the transparent heat insulating dope system for glass baseplate according to claim 1, is characterized in that: described titanate coupling agent is sec.-propyl three isophthaloyl titanic acid ester, sec.-propyl dodecyl benzene sulfonyl titanic acid ester, sec.-propyl three (dioctylphyrophosphoric acid ester) titanic acid ester, two (dioctyl phosphito ester) titanic acid ester of tetra isopropyl, two [two (dodecyl) phosphorous acid ester] titanic acid ester of four octyl groups, four (2,2 two allyl oxygen methyl isophthalic acid-butyl) two [two (tridecyl) phosphorous acid ester] titanic acid ester, two (dioctylphyrophosphoric acid ester) fluoroacetic acid ester titanic acid ester, two (dioctylphyrophosphoric acid ester) ethylene titanic acid ester, sec.-propyl three decoyl titanic acid ester, sec.-propyl dimethacrylate iso stearate titanic acid ester, sec.-propyl iso stearate two acryloyl titanic acid ester, sec.-propyl three (dioctyl phosphoric acid ester) titanic acid ester, sec.-propyl three cumyl phenyl titanic acid ester, sec.-propyl three (N-aminoethyl-aminoethyl) titanic acid ester, dicumylphenyl fluoroacetic acid ester titanic acid ester, distearyl ethylene titanic acid ester, sec.-propyl three (methacryloyl) titanic acid ester, one in sec.-propyl three acryloyl titanic acid ester.
5. the transparent heat insulating dope system for glass baseplate according to claim 1, is characterized in that: primary coat solvent for use is a kind of in deionized water, ethanol and Virahol or their mixture.
6. the transparent heat insulating dope system for glass baseplate according to claim 1, is characterized in that: described inert diluent is ethanol, in order to adjust coating application performance, also plays froth breaking effect simultaneously.
7. the transparent heat insulating dope system for glass baseplate according to claim 1, is characterized in that: described light-cured resin is epoxy acrylic resin, one or more in polyester chloride acrylic ester or multifunctional polyurethane acrylic resin.
8. the transparent heat insulating dope system for glass baseplate according to claim 1, it is characterized in that: described reactive thinner is hydroxyethyl methylacrylate, two (2-ethoxy ethoxy) ethyl propylene acid esters, two diacrylates of Poly-propylene glycols, tripropylene glycol diacrylate, propylene glycol diacrylate, hexanediyl ester, glycerol triacrylate, propoxy-glycerol triacrylate, propoxy-neopentylglycol diacrylate, tri methylol triacrylate, pentaerythritol triacrylate, tetramethylol methane tetraacrylate, cyclohexane dimethanol diacrylate, alkoxide cyclohexane dimethanol diacrylate, bisphenol a diacrylate, alkoxylated bisphenol A diacrylate, tricyclic decane Dimethanol Diacrylate, one or more in three (2-hydroxyethyl) tricarbimide triacrylate.
9. the transparent heat insulating dope system for glass baseplate according to claim 1; it is characterized in that: described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone, 2; 4; 6, one or more in-trimethylbenzoy-dipheny phosphorus oxide, 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone, 2-dimethylamino-2-benzyl-1-[4-(4-morpholinyl) phenyl]-1-butanone, isopropyl thioxanthone, active ammonia.
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| CN103232783B (en) * | 2013-03-29 | 2016-04-27 | 王德全 | A kind of alkali resistance protective system and preparation method thereof |
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| CN104745029A (en) * | 2015-04-07 | 2015-07-01 | 广东雪莱特光电科技股份有限公司 | Bulb housing protective film for LED (light-emitting diode) lamp and preparation method for bulb housing protective film |
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| WO2019065316A1 (en) * | 2017-09-29 | 2019-04-04 | 日本ペイントホールディングス株式会社 | Coating composition and coating film |
| CN108084833A (en) * | 2018-01-25 | 2018-05-29 | 合肥利裕泰玻璃制品有限公司 | A kind of glass heat-insulating coating and preparation method thereof |
| JP7312715B2 (en) * | 2020-03-13 | 2023-07-21 | 双葉電子工業株式会社 | COMPOUND, PHOTOCURABLE COMPOSITION, CURED FILM AND ORGANIC EL DEVICE |
| CN112480814B (en) * | 2020-11-26 | 2022-07-26 | 汪元亮 | Surface treating agent and surface protection method for porous loose material |
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| CN113527934A (en) * | 2021-09-16 | 2021-10-22 | 中熵科技(北京)有限公司 | Electrothermal coating slurry, preparation method and application |
| CN113817404A (en) * | 2021-09-26 | 2021-12-21 | 珠海东胜科技有限公司 | Heat-insulating coating and preparation method thereof, coated product and application |
| CN116496002A (en) * | 2023-03-24 | 2023-07-28 | 台玻太仓工程玻璃有限公司 | A kind of formula, preparation method and application of heat absorbing film |
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