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CN103928345B - Ion implanting forms the UMOSFET preparation method of N-type heavy doping drift layer table top - Google Patents

Ion implanting forms the UMOSFET preparation method of N-type heavy doping drift layer table top Download PDF

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CN103928345B
CN103928345B CN201410166460.1A CN201410166460A CN103928345B CN 103928345 B CN103928345 B CN 103928345B CN 201410166460 A CN201410166460 A CN 201410166460A CN 103928345 B CN103928345 B CN 103928345B
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CN103928345A (en
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汤晓燕
蒋明伟
宋庆文
张艺蒙
贾仁需
王悦湖
张玉明
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    • H10D12/00Bipolar devices controlled by the field effect, e.g. insulated-gate bipolar transistors [IGBT]
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    • H01L21/0445Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
    • H01L21/0455Making n or p doped regions or layers, e.g. using diffusion
    • H01L21/046Making n or p doped regions or layers, e.g. using diffusion using ion implantation
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Abstract

本发明涉及一种离子注入形成N型重掺杂漂移层台面的UMOSFET器件制备方法,外延生长N型漂移区;离子注入形成N+阱;N+阱刻蚀为台面;外延生长P‑外延层;外延生长N+源区层;刻蚀成槽;刻蚀形成源区;氧化形成槽栅;淀积多晶硅;开接触孔:制备钝化层,开电极接触孔;制备电极:蒸发金属,制备电极。本发明通过离子注入和刻蚀工艺提高了带有N型漂移层台面的碳化硅UMOSFET器件中的N型漂移区台面的掺杂浓度,降低了该器件的导通电阻。

The invention relates to a method for preparing a UMOSFET device by ion implantation to form an N-type heavily doped drift layer mesa. The N-type drift region is epitaxially grown; the ion implantation forms an N+ well; the N+ well is etched into a mesa; the epitaxially grows a P-epitaxial layer; Grow N+ source region layer; etch into groove; etch to form source region; oxidize to form groove gate; deposit polysilicon; open contact hole: prepare passivation layer, open electrode contact hole; prepare electrode: evaporate metal, prepare electrode. The invention improves the doping concentration of the N-type drift region mesa in the silicon carbide UMOSFET device with the N-type drift layer mesa through the ion implantation and etching process, and reduces the on-resistance of the device.

Description

离子注入形成N型重掺杂漂移层台面的UMOSFET制备方法UMOSFET preparation method for forming N-type heavily doped drift layer mesa by ion implantation

技术领域technical field

本发明涉及微电子技术领域,尤其涉及一种离子注入形成N型重掺杂漂移层台面的碳化硅UMOSFET器件制备方法。The invention relates to the technical field of microelectronics, in particular to a method for preparing a silicon carbide UMOSFET device for forming an N-type heavily doped drift layer mesa by ion implantation.

背景技术Background technique

第三代半导体材料碳化硅具有宽带隙,高临界击穿电场,高电子饱和漂移速度和较高的热导率等优良的物理和化学性质,在高温,高压,大功率半导体器件中具有很大优势。The third-generation semiconductor material silicon carbide has excellent physical and chemical properties such as wide band gap, high critical breakdown electric field, high electron saturation drift velocity and high thermal conductivity, and has great potential in high temperature, high pressure and high power semiconductor devices. Advantage.

功率MOSFET作为开关,其正向导通电阻和反向击穿电压是一对矛盾关系,而纵向结构的UMOSFET消除了寄生积累层电阻和JFET电阻,所以UMOSFET在这方面和横向结构的MOSFET相比具有一定的优势。As a switch, the power MOSFET has a contradictory relationship between its forward conduction resistance and reverse breakdown voltage, while the UMOSFET of the vertical structure eliminates the parasitic accumulation layer resistance and JFET resistance, so the UMOSFET has an advantage compared with the MOSFET of the horizontal structure in this respect. Certain advantages.

UMOSFET自身也存在缺点,其槽栅拐角处的电场集中效应导致器件提前发生击穿,降低了器件的可靠性。一种能够降低槽栅拐角电场的带有N-漂移层台面的SiC UMOSFET器件已经被发明出来,该器件的P-外延层包裹了槽栅拐角,以SiC PN结界面代替了拐角的SiO2/SiC界面来承受反向电压,提高了器件的可靠性。UMOSFET itself also has disadvantages. The electric field concentration effect at the corner of the groove gate leads to early breakdown of the device, which reduces the reliability of the device. A SiC UMOSFET device with an N-drift layer mesa that can reduce the electric field at the corner of the trench gate has been invented. The P-epitaxial layer of the device wraps the corner of the trench gate, and the SiC PN junction interface replaces the corner SiO 2 / The SiC interface is used to withstand the reverse voltage, which improves the reliability of the device.

但是由于该方案中P-外延层包裹了槽栅拐角,使导电通路在台面处变窄,而且台面处的杂质浓度和漂移层浓度相等,掺杂浓度较低,这都是对导通电阻不利的因素。However, in this scheme, the P-epitaxial layer wraps the corners of the groove gate, which narrows the conductive path at the mesa, and the impurity concentration at the mesa is equal to the concentration of the drift layer, and the doping concentration is low, which is not good for the on-resistance the elements of.

鉴于上述缺陷,本发明创作者经过长时间的研究和实践终于获得了本创作。In view of the above-mentioned defects, the author of the present invention has finally obtained this creation through long-term research and practice.

发明内容Contents of the invention

本发明的目的在于提供一种离子注入形成N型重掺杂漂移层台面的UMOSFET制备方法,用以克服上述技术缺陷。The object of the present invention is to provide a UMOSFET preparation method for forming N-type heavily doped drift layer mesa by ion implantation, so as to overcome the above-mentioned technical defects.

为实现上述目的,本发明提供一种离子注入形成N型重掺杂漂移层台面的UMOSFET制备方法,该具体过程为:In order to achieve the above object, the present invention provides a UMOSFET preparation method for forming an N-type heavily doped drift layer mesa by ion implantation, the specific process is:

步骤a,外延生长N型漂移区:在碳化硅N+衬底样片上外延生长厚度约为12μm~25μm,氮离子掺杂浓度为1×1015cm-3~5×1015cm-3的N型漂移区;Step a, epitaxial growth of N-type drift region: epitaxially grow N on the silicon carbide N+ substrate sample with a thickness of about 12 μm to 25 μm and a nitrogen ion doping concentration of 1×10 15 cm -3 to 5×10 15 cm -3 Type drift zone;

步骤b,离子注入形成N+阱:在N型漂移区中进行离子注入,形成重掺杂的N+阱,N+阱宽度为3μm~4μm,注入杂质为氮离子,深度为0.5μm,掺杂浓度为1×1017cm-3Step b, ion implantation to form an N+ well: perform ion implantation in the N-type drift region to form a heavily doped N+ well, the width of the N+ well is 3 μm to 4 μm, the implanted impurities are nitrogen ions, the depth is 0.5 μm, and the doping concentration is 1×10 17 cm −3 ;

步骤c,N+阱刻蚀为台面:把N+阱刻蚀成一个台面,台面高度和N+阱的深度相等,台面宽度与阱的宽度相等;Step c, etching the N+ well into a mesa: etching the N+ well into a mesa, the height of the mesa is equal to the depth of the N+ well, and the width of the mesa is equal to the width of the well;

步骤d,外延生长P-外延层:在N型漂移区和N+漂移层台面上生长一层P-外延层,厚度为3μm,铝离子掺杂浓度为5×1017cm-3~1×1018cm-3Step d, epitaxially growing a P- epitaxial layer: growing a P- epitaxial layer on the N-type drift region and N+ drift layer mesa, with a thickness of 3 μm and an aluminum ion doping concentration of 5×10 17 cm -3 to 1×10 18 cm -3 ;

步骤e,外延生长N+源区层:在P-外延层上生长一层N+源区层,厚度为0.5μm,掺杂浓度为5×1018cm-3Step e, epitaxially growing an N+ source region layer: growing an N+ source region layer on the P- epitaxial layer with a thickness of 0.5 μm and a doping concentration of 5×10 18 cm −3 ;

步骤f,刻蚀成槽:在N型重掺杂漂移层台面正上方采用ICP刻蚀形成槽,宽度为6μm,深度为3μm,这样槽的两个底角被P-外延层包裹;Step f, etching to form a groove: use ICP etching to form a groove directly above the N-type heavily doped drift layer mesa, with a width of 6 μm and a depth of 3 μm, so that the two bottom corners of the groove are wrapped by the P- epitaxial layer;

步骤g,刻蚀形成源区:采用ICP刻蚀形成源区接触;Step g, etching to form a source region: using ICP etching to form a source region contact;

步骤h,氧化形成槽栅:通过热氧化工艺制备槽栅介质SiO2,厚度为100nm。Step h, oxidize to form the groove gate: prepare the groove gate dielectric SiO 2 through a thermal oxidation process, with a thickness of 100 nm.

步骤i,淀积多晶硅:在槽栅内的槽栅介质SiO2上淀积polySi层;Step i, depositing polysilicon: depositing a polySi layer on the trench gate dielectric SiO2 in the trench gate;

步骤j,开接触孔:制备钝化层,开电极接触孔;Step j, opening a contact hole: preparing a passivation layer, and opening an electrode contact hole;

步骤k,制备电极:蒸发金属,制备电极。Step k, preparing electrodes: evaporating metals to prepare electrodes.

进一步,在上述步骤a中,先对N型的碳化硅衬底片进行RCA标准清洗,然后在整个衬底片上外延生长厚度为12μm~25μm,氮离子掺杂浓度为1×1015cm-3~5×1015cm-3的N-漂移层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。Further, in the above step a, the N-type silicon carbide substrate is firstly cleaned by RCA standard, and then epitaxially grown on the entire substrate with a thickness of 12 μm to 25 μm and a nitrogen ion doping concentration of 1×10 15 cm -3 to 5×10 15 cm -3 N-drift layer, the process conditions are: temperature 1600 ℃, pressure 100mbar, reaction gas using silane and propane, carrier gas using pure hydrogen, dopant source using liquid nitrogen.

进一步,上述步骤b的具体过程为:Further, the specific process of the above step b is:

步骤b01,采用低压化学汽相淀积方式在整个碳化硅表面淀积一层厚度为0.2μm的SiO2,再淀积厚度为1μm的Al作为氮离子注入的阻挡层,通过光刻和刻蚀形成N+阱注入区,N+阱注入区宽度为3-4μm;In step b01, a layer of SiO 2 with a thickness of 0.2 μm is deposited on the entire surface of silicon carbide by low-pressure chemical vapor deposition, and Al with a thickness of 1 μm is deposited as a barrier layer for nitrogen ion implantation. Form the N+ well implantation region, the width of the N+ well implantation region is 3-4 μm;

步骤b02,在500℃的环境温度下进行三次氮离子注入,先后注入能量分别为520keV、300keV、150keV,对应的剂量为9.8×1011cm-2、7×1011cm-2、4.9×1011cm-2,注入深度为0.5μm;In step b02, perform nitrogen ion implantation three times at an ambient temperature of 500°C. The implantation energies are 520keV, 300keV, and 150keV respectively, and the corresponding doses are 9.8×10 11 cm -2 , 7×10 11 cm -2 , 4.9×10 11 cm -2 , the injection depth is 0.5μm;

步骤b03,采用标准RCA对碳化硅表面进行清洗,烘干后做C膜保护。然后在1750℃氩气氛围中进行离子激活退火,时间为15min。In step b03, standard RCA is used to clean the surface of the silicon carbide, and protect it with a C film after drying. Then ion-activated annealing was performed at 1750° C. in an argon atmosphere for 15 minutes.

进一步,上述步骤c中,N+阱宽度为3μm~4μm,注入杂质为氮离子,深度为0.5μm,掺杂浓度为1×1017cm-3,其工艺条件为:注入温度500℃,离子激活退火温度1750℃,退火时间10min。Further, in the above step c, the width of the N+ well is 3 μm to 4 μm, the implanted impurities are nitrogen ions, the depth is 0.5 μm, and the doping concentration is 1×10 17 cm -3 , the process conditions are: implantation temperature 500°C, ion activation The annealing temperature is 1750°C, and the annealing time is 10min.

进一步,上述步骤d中,在N型漂移区和N+漂移层台面上生长一层P-外延层,厚度为3μm,铝离子掺杂浓度为5×1017cm-3~1×1018cm-3;N+阱刻蚀为台面,台面的高度等于N+阱宽度,其工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。Further, in the above step d, a P- epitaxial layer is grown on the N-type drift region and the N+ drift layer mesa, with a thickness of 3 μm and an aluminum ion doping concentration of 5×10 17 cm -3 to 1×10 18 cm - 3 ; The N+ well is etched into a mesa, and the height of the mesa is equal to the width of the N+ well. The process conditions are: ICP coil power 850W, source power 100W, and reaction gases SF 6 and O 2 are 48 sccm and 12 sccm respectively.

进一步,在上述步骤e中,在P-外延层上生长一层厚度为0.5μm,氮离子掺杂浓度为5×1018cm-3的N型碳化硅外延层,作为N+源区层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。Further, in the above step e, an N-type silicon carbide epitaxial layer with a thickness of 0.5 μm and a nitrogen ion doping concentration of 5×10 18 cm -3 is grown on the P- epitaxial layer as the N+ source region layer, which The process conditions are as follows: the temperature is 1600°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is liquid nitrogen.

进一步,在上述步骤f中,首先磁控溅射一层的Ti膜作为ICP刻蚀掩膜,然后涂胶光刻,进行ICP刻蚀,刻蚀出槽的宽度为6μm,深度为3μm,最后去胶,去刻蚀掩膜,清洗成光片;工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。Further, in the above step f, at first magnetron sputtering a layer The Ti film is used as an ICP etching mask, and then coated with photolithography, and then ICP etching is performed. The width of the etched groove is 6 μm, and the depth is 3 μm. Finally, the glue is removed, the etching mask is removed, and the optical film is cleaned; The conditions are: ICP coil power 850W, source power 100W, reaction gas SF6 and O2 are 48sccm and 12sccm, respectively.

进一步,在上述步骤g中,首先磁控溅射一层的Ti膜作为ICP刻蚀掩膜,然后涂胶光刻,进行ICP刻蚀,形成源区接触孔,最后去胶,去刻蚀掩膜,清洗成光片;工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。Further, in the above step g, at first magnetron sputtering a layer The Ti film is used as an ICP etching mask, and then coated with photolithography, and then ICP is etched to form a contact hole in the source area. Finally, the glue is removed, the etching mask is removed, and it is cleaned into a light sheet; the process conditions are: ICP coil power 850W , source power 100W, reaction gas SF 6 and O 2 were 48sccm and 12sccm.

进一步,在上述步骤h中,采用干氧工艺在1150℃下制备SiO2栅,厚度为100nm,然后在1050℃,N2氛围下进行退火,降低SiO2薄膜表面的粗糙度。Further, in the above step h, the dry oxygen process is used to prepare the SiO 2 gate at 1150°C with a thickness of 100nm, and then annealing is performed at 1050°C under N 2 atmosphere to reduce the surface roughness of the SiO 2 film.

进一步,在上述步骤i中,采用低压热壁化学汽相淀积法生长ploySi填满沟槽,淀积温度为600~650℃,淀积压强为60~80Pa,反应气体为硅烷和磷化氢,载运气体为氦气,然后涂胶光刻,刻蚀ploySi层,形成多晶硅栅,最后去胶,清洗。Further, in the above step i, low-pressure hot-wall chemical vapor deposition is used to grow polySi to fill the trenches, the deposition temperature is 600-650°C, the deposition pressure is 60-80Pa, and the reaction gases are silane and phosphine , the carrier gas is helium, and then glue photolithography, etch the polySi layer to form a polysilicon gate, and finally remove the glue and clean.

与现有技术相比较本发明的有益效果在于:本发明通过离子注入和刻蚀工艺提高了带有N型漂移层台面的碳化硅UMOSFET器件中的N型漂移区台面的掺杂浓度,降低了该器件的导通电阻;离子注入工艺可以精确的控制注入离子的浓度和深度,另外对于基体材料来说,离子注入没有明显界面,因此不存在粘附破裂和剥落问题,而且离子注入不浪费材料节省成本。Compared with the prior art, the present invention has the beneficial effects that: the present invention improves the doping concentration of the N-type drift region mesa in the silicon carbide UMOSFET device with the N-type drift layer mesa through the ion implantation and etching process, and reduces the The on-resistance of the device; the ion implantation process can precisely control the concentration and depth of implanted ions. In addition, for the base material, ion implantation has no obvious interface, so there is no problem of adhesion cracking and peeling, and ion implantation does not waste materials cut costs.

附图说明Description of drawings

图1为本发明带有N型漂移层台面的碳化硅UMOSFET器件的结构示意图;Fig. 1 is the structural representation of the silicon carbide UMOSFET device with N-type drift layer mesa of the present invention;

图2为本发明带有N型漂移层台面的碳化硅UMOSFET器件的制作工艺流程图。Fig. 2 is a flow chart of the manufacturing process of the silicon carbide UMOSFET device with N-type drift layer mesa according to the present invention.

具体实施方式detailed description

以下结合附图,对本发明上述的和另外的技术特征和优点作更详细的说明。The above and other technical features and advantages of the present invention will be described in more detail below in conjunction with the accompanying drawings.

请参阅图2所示,其为本发明带有N型漂移层台面的碳化硅UMOSFET器件的结构示意图,该具体过程为:Please refer to Figure 2, which is a schematic structural diagram of a silicon carbide UMOSFET device with an N-type drift layer mesa according to the present invention, and the specific process is:

步骤a,外延生长N型漂移区:在碳化硅N+衬底样片上外延生长厚度约为12μm~25μm,氮离子掺杂浓度为1×1015cm-3~5×1015cm-3的N型漂移区;Step a, epitaxial growth of N-type drift region: epitaxially grow N on the silicon carbide N+ substrate sample with a thickness of about 12 μm to 25 μm and a nitrogen ion doping concentration of 1×10 15 cm -3 to 5×10 15 cm -3 Type drift zone;

步骤b,离子注入形成N+阱:在N型漂移区中进行离子注入,形成重掺杂的N+阱,N+阱宽度为3μm~4μm,注入杂质为氮离子,深度为0.5μm,掺杂浓度为1×1017cm-3Step b, ion implantation to form an N+ well: perform ion implantation in the N-type drift region to form a heavily doped N+ well, the width of the N+ well is 3 μm to 4 μm, the implanted impurities are nitrogen ions, the depth is 0.5 μm, and the doping concentration is 1×10 17 cm −3 ;

步骤c,N+阱刻蚀为台面:把N+阱刻蚀成一个台面,台面高度和N+阱的深度相等,N+阱宽度为3μm~4μm,注入杂质为氮离子,深度为0.5μm,掺杂浓度为1×1017cm-3,其工艺条件为:注入温度500℃,离子激活退火温度1750℃,退火时间10min。Step c, etch the N+ well into a mesa: etch the N+ well into a mesa, the height of the mesa is equal to the depth of the N+ well, the width of the N+ well is 3 μm to 4 μm, the implanted impurities are nitrogen ions, the depth is 0.5 μm, and the doping concentration 1×10 17 cm -3 , and the process conditions are: implantation temperature 500°C, ion activation annealing temperature 1750°C, annealing time 10min.

步骤d,外延生长P-外延层:在N型漂移区和N+漂移层台面上生长一层P-外延层,厚度为3μm,铝离子掺杂浓度为5×1017cm-3~1×1018cm-3;N+阱刻蚀为台面,台面的高度等于N+阱宽度,其工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。Step d, epitaxially growing a P- epitaxial layer: growing a P- epitaxial layer on the N-type drift region and N+ drift layer mesa, with a thickness of 3 μm and an aluminum ion doping concentration of 5×10 17 cm -3 to 1×10 18 cm -3 ; the N+ well is etched into a mesa, and the height of the mesa is equal to the width of the N+ well. The process conditions are: ICP coil power 850W, source power 100W, reaction gas SF 6 and O 2 respectively 48sccm and 12sccm.

步骤e,外延生长N+源区层:在P-外延层上生长一层N+源区层,厚度为0.5μm,掺杂浓度为5×1018cm-3Step e, epitaxially growing an N+ source region layer: growing an N+ source region layer on the P- epitaxial layer with a thickness of 0.5 μm and a doping concentration of 5×10 18 cm −3 ;

步骤f,刻蚀成槽:在N型重掺杂漂移层台面正上方采用ICP刻蚀形成槽,宽度为6μm,深度为3μm,这样槽的两个底角被P-外延层包裹;Step f, etching to form a groove: use ICP etching to form a groove directly above the N-type heavily doped drift layer mesa, with a width of 6 μm and a depth of 3 μm, so that the two bottom corners of the groove are wrapped by the P- epitaxial layer;

步骤g,刻蚀形成源区:采用ICP刻蚀形成源区接触;Step g, etching to form a source region: using ICP etching to form a source region contact;

步骤h,氧化形成槽栅:通过热氧化工艺制备槽栅介质SiO2,厚度为100nm。Step h, oxidize to form the groove gate: prepare the groove gate dielectric SiO 2 through a thermal oxidation process, with a thickness of 100 nm.

步骤i,淀积多晶硅:在槽栅内的槽栅介质SiO2上淀积polySi层;Step i, depositing polysilicon: depositing a polySi layer on the trench gate dielectric SiO2 in the trench gate;

步骤j,开接触孔:制备钝化层,开电极接触孔;Step j, opening a contact hole: preparing a passivation layer, and opening an electrode contact hole;

步骤k,制备电极:蒸发金属,制备电极。Step k, preparing electrodes: evaporating metals to prepare electrodes.

基于上述步骤的各实施例,如下所述:Each embodiment based on above-mentioned steps, as follows:

实施例一:Embodiment one:

步骤a1,外延生长N型漂移区,如图2中的a所示;Step a1, epitaxially growing an N-type drift region, as shown in a in FIG. 2 ;

先对N型的碳化硅衬底片进行RCA标准清洗,然后在整个衬底片上外延生长厚度为12μm,氮离子掺杂浓度为1×1015cm-3的N-漂移层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。RCA standard cleaning is performed on the N-type silicon carbide substrate first, and then an N-drift layer with a thickness of 12 μm and a nitrogen ion doping concentration of 1×10 15 cm -3 is epitaxially grown on the entire substrate. The process conditions are: The temperature is 1600°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is liquid nitrogen.

步骤b1,离子注入形成N+阱,如图2中的b所示;Step b1, ion implantation to form an N+ well, as shown in b in Figure 2;

步骤b11,采用低压化学汽相淀积方式在整个碳化硅表面淀积一层厚度为0.2μm的SiO2,再淀积厚度为1μm的Al作为氮离子注入的阻挡层,通过光刻和刻蚀形成N+阱注入区,N+阱注入区宽度为3μm;In step b11, a layer of SiO 2 with a thickness of 0.2 μm is deposited on the entire surface of silicon carbide by low-pressure chemical vapor deposition, and Al with a thickness of 1 μm is deposited as a barrier layer for nitrogen ion implantation. Form the N+ well implantation region, the width of the N+ well implantation region is 3 μm;

步骤b12,在500℃的环境温度下进行三次氮离子注入,先后注入能量分别为520keV、300keV、150keV,对应的剂量为9.8×1011cm-2、7×1011cm-2、4.9×1011cm-2,注入深度为0.5μm;In step b12, nitrogen ion implantation was performed three times at an ambient temperature of 500°C. The implantation energies were 520keV, 300keV, and 150keV respectively, and the corresponding doses were 9.8×10 11 cm -2 , 7×10 11 cm -2 , 4.9×10 11 cm -2 , the injection depth is 0.5μm;

步骤b13,采用标准RCA对碳化硅表面进行清洗,烘干后做C膜保护。然后在1750℃氩气氛围中进行离子激活退火,时间为15min。In step b13, standard RCA is used to clean the surface of the silicon carbide, and protect it with a C film after drying. Then ion-activated annealing was performed at 1750° C. in an argon atmosphere for 15 minutes.

步骤c1,N+阱刻蚀为台面,如图2中的c所示;In step c1, the N+ well is etched into a mesa, as shown in c in FIG. 2 ;

首先磁控溅射一层的Ti膜作为ICP刻蚀掩膜,然后涂胶光刻,进行ICP刻蚀,将N+阱刻蚀成台面结构,台面高度等于N+阱深度。最后去胶,去刻蚀掩膜,清洗成光片。ICP刻蚀工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。First magnetron sputtering a layer The Ti film is used as an ICP etching mask, and then photolithography is applied to perform ICP etching, and the N+ well is etched into a mesa structure, and the height of the mesa is equal to the depth of the N+ well. Finally, the glue is removed, the etching mask is removed, and it is cleaned into a light sheet. The ICP etching process conditions are: ICP coil power 850W, source power 100W, reaction gas SF 6 and O 2 are 48 sccm and 12 sccm respectively.

步骤d1,外延生长P-外延层,如图2中的d所示;Step d1, epitaxially growing a P- epitaxial layer, as shown in d in FIG. 2 ;

在N型漂移区和重掺杂的漂移区台面上生长一层厚度为3μm,铝离子掺杂浓度为5×1017cm-3的P-外延层,其外延生长工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用三甲基铝。A P-epitaxial layer with a thickness of 3 μm and an aluminum ion doping concentration of 5×10 17 cm -3 is grown on the N-type drift region and the heavily doped drift region mesa. The epitaxial growth process conditions are: the temperature is 1600 °C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is trimethylaluminum.

步骤e1,外延生长N+源区层,如图2中的e所示;Step e1, epitaxially growing the N+ source region layer, as shown in e in FIG. 2 ;

在P-外延层上生长一层厚度为0.5μm,氮离子掺杂浓度为5×1018cm-3的N型碳化硅外延层,作为N+源区层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。An N-type silicon carbide epitaxial layer with a thickness of 0.5 μm and a nitrogen ion doping concentration of 5×10 18 cm -3 is grown on the P- epitaxial layer as the N+ source region layer. The process conditions are: the temperature is 1600°C , the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is liquid nitrogen.

步骤f1,刻蚀成槽,如图2中的f所示;Step f1, etching into grooves, as shown in f in Figure 2;

首先磁控溅射一层的Ti膜作为ICP刻蚀掩膜,然后涂胶光刻,进行ICP刻蚀,刻蚀出槽的宽度为6μm,深度为3μm,最后去胶,去刻蚀掩膜,清洗成光片。工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。First magnetron sputtering a layer The Ti film is used as an ICP etching mask, and then coated with photolithography, and then ICP etching is performed, and the width of the etched groove is 6 μm, and the depth is 3 μm. Finally, the glue is removed, the etching mask is removed, and a light sheet is cleaned. The process conditions are: ICP coil power 850W, source power 100W, reaction gas SF6 and O2 are 48sccm and 12sccm respectively.

步骤g1,刻蚀形成源区,如图2中的g所示;Step g1, etching to form a source region, as shown in g in FIG. 2;

首先磁控溅射一层的Ti膜作为ICP刻蚀掩膜,然后涂胶光刻,进行ICP刻蚀,形成源区接触孔,最后去胶,去刻蚀掩膜,清洗成光片。工艺条件为:ICP线圈功率850W,源功率100W,反应气体SF6和O2分别为48sccm和12sccm。First magnetron sputtering a layer The Ti film is used as an ICP etching mask, and then photolithography is applied, and ICP etching is performed to form a contact hole in the source region. Finally, the glue is removed, the etching mask is removed, and a light sheet is cleaned. The process conditions are: ICP coil power 850W, source power 100W, reaction gas SF6 and O2 are 48sccm and 12sccm respectively.

步骤h1,氧化形成槽栅,如图2中的h所示;Step h1, oxidation to form trench gates, as shown in h in FIG. 2 ;

采用干氧工艺在1150℃下制备SiO2栅,厚度为100nm,然后在1050℃,N2氛围下进行退火,降低SiO2薄膜表面的粗糙度。The SiO2 gate was prepared at 1150°C by dry oxygen process with a thickness of 100nm, and then annealed at 1050°C under N2 atmosphere to reduce the roughness of the SiO2 film surface.

步骤i1,淀积多晶硅,如图2中的i所示;Step i1, deposit polysilicon, as shown in i in Figure 2;

采用低压热壁化学汽相淀积法生长ploySi填满沟槽,淀积温度为600~650℃,淀积压强为60~80Pa,反应气体为硅烷和磷化氢,载运气体为氦气,然后涂胶光刻,刻蚀ploySi层,形成多晶硅栅,最后去胶,清洗。Low-pressure hot-wall chemical vapor deposition is used to grow polySi to fill the trenches, the deposition temperature is 600-650°C, the deposition pressure is 60-80Pa, the reaction gases are silane and phosphine, the carrier gas is helium, and then Glue photolithography, etch the polySi layer to form a polysilicon gate, and finally remove the glue and clean.

步骤j1,开接触孔,如图2中的j所示;Step j1, opening a contact hole, as shown in j in Figure 2;

在器件表面淀积一层场氧或者Si3N4层,然后涂胶光刻,腐蚀钝化层开电极接触孔,最后去胶,清洗。Deposit a layer of field oxygen or Si 3 N 4 on the surface of the device, then apply glue for photolithography, etch the passivation layer to open electrode contact holes, and finally remove the glue and clean.

步骤k1,制备电极,如图2中的k所示;Step k1, preparing electrodes, as shown in k in Figure 2;

电子束蒸发Ti/Ni/Au制作正面栅,源电极,然后涂胶光刻,金属腐蚀形成正面栅,源电极接触图形,去胶,清洗。E-beam evaporation of Ti/Ni/Au to make the front grid and source electrode, then glue photolithography, metal corrosion to form the front grid, source electrode contact pattern, glue removal, and cleaning.

在背面电子束蒸发Ti/Ni/Au制作背面漏电极,然后制作正面栅,源电极,最后在Ar气氛中围快速退火3min,温度为1050℃。Evaporate Ti/Ni/Au on the back side to make the back drain electrode, then make the front gate and source electrode, and finally anneal in an Ar atmosphere for 3min at a temperature of 1050°C.

实施例二:Embodiment two:

步骤a2,外延生长N型漂移区;Step a2, epitaxially growing an N-type drift region;

先对N型的碳化硅衬底片进行RCA标准清洗,然后在整个衬底片上外延生长厚度为25μm,氮离子掺杂浓度为5×1015cm-3的N-漂移层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。RCA standard cleaning is performed on the N-type silicon carbide substrate first, and then an N-drift layer with a thickness of 25 μm and a nitrogen ion doping concentration of 5×10 15 cm -3 is epitaxially grown on the entire substrate. The process conditions are: The temperature is 1600°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is liquid nitrogen.

步骤b2,离子注入形成N+阱;Step b2, ion implantation to form an N+ well;

步骤b21,采用低压化学汽相淀积方式在整个碳化硅表面淀积一层厚度为0.2μm的SiO2,再淀积厚度为1μm的A1作为氮离子注入的阻挡层,通过光刻和刻蚀形成N+阱注入区,N+阱注入区宽度为4μm;In step b21, a layer of SiO 2 with a thickness of 0.2 μm is deposited on the entire silicon carbide surface by low-pressure chemical vapor deposition, and then Al with a thickness of 1 μm is deposited as a barrier layer for nitrogen ion implantation. Form the N+ well implantation region, the width of the N+ well implantation region is 4 μm;

步骤b22,在500℃的环境温度下进行三次氮离子注入,先后注入能量分别为520keV、300keV、150keV,对应的剂量为9.8×1011cm-2、7×1011cm-2、4.9×1011cm-2,注入深度为0.5μm;In step b22, perform nitrogen ion implantation three times at an ambient temperature of 500°C. The implantation energies are 520keV, 300keV, and 150keV respectively, and the corresponding doses are 9.8×10 11 cm -2 , 7×10 11 cm -2 , 4.9×10 11 cm -2 , the injection depth is 0.5μm;

步骤b23,采用标准RCA对碳化硅表面进行清洗,烘干后做C膜保护。然后在1750℃氩气氛围中进行离子激活退火,时间为15min。In step b23, standard RCA is used to clean the surface of the silicon carbide, and protect it with a C film after drying. Then ion-activated annealing was performed at 1750° C. in an argon atmosphere for 15 minutes.

步骤c2,与实施例一的步骤c1相同;Step c2 is the same as step c1 of Embodiment 1;

步骤d2,外延生长P-外延层;Step d2, epitaxially growing a P- epitaxial layer;

在N型漂移区和重掺杂的漂移区台面上生长一层厚度为3μm,铝离子掺杂浓度为1×1018cm-3的P-外延层,其外延生长工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用三甲基铝。A P-epitaxial layer with a thickness of 3 μm and an aluminum ion doping concentration of 1×10 18 cm -3 is grown on the N-type drift region and the heavily doped drift region mesa. The epitaxial growth process conditions are: the temperature is 1600 °C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is trimethylaluminum.

步骤e2,与实施例一的步骤e1相同。Step e2 is the same as step e1 in Embodiment 1.

步骤f2,与实施例一的步骤f1相同。Step f2 is the same as step f1 in Embodiment 1.

步骤g2,与实施例一的步骤g1相同。Step g2 is the same as step g1 in Embodiment 1.

步骤h2,与实施例一的步骤h1相同。Step h2 is the same as step h1 in Embodiment 1.

步骤i2,与实施例一的步骤i1相同。Step i2 is the same as step i1 in Embodiment 1.

步骤j2,与实施例一的步骤j1相同。Step j2 is the same as step j1 in Embodiment 1.

步骤k2,与实施例一的步骤k1相同。Step k2 is the same as step k1 in Embodiment 1.

实施例三:Embodiment three:

步骤a3,外延生长N型漂移区;Step a3, epitaxially growing an N-type drift region;

先对N型的碳化硅衬底片进行RCA标准清洗,然后在整个衬底片上外延生长厚度为20μm,氮离子掺杂浓度为3×1015cm-3的N-漂移层,其工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用液态氮气。RCA standard cleaning is performed on the N-type silicon carbide substrate first, and then an N-drift layer with a thickness of 20 μm and a nitrogen ion doping concentration of 3×10 15 cm -3 is epitaxially grown on the entire substrate. The process conditions are: The temperature is 1600°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is liquid nitrogen.

步骤b3,离子注入形成N+阱;Step b3, ion implantation to form an N+ well;

步骤b31,采用低压化学汽相淀积方式在整个碳化硅表面淀积一层厚度为0.2μm的SiO2,再淀积厚度为1μm的Al作为氮离子注入的阻挡层,通过光刻和刻蚀形成N+阱注入区,N+阱注入区宽度为3.5μm。In step b31, a layer of SiO 2 with a thickness of 0.2 μm is deposited on the entire surface of silicon carbide by low-pressure chemical vapor deposition, and then Al with a thickness of 1 μm is deposited as a barrier layer for nitrogen ion implantation. An N+ well implantation region is formed, and the width of the N+ well implantation region is 3.5 μm.

步骤b32,在500℃的环境温度下进行三次氮离子注入,先后注入能量分别为520keV、300keV、150keV,对应的剂量为9.8×1011cm-2、7×1011cm-2、4.9×1011cm-2,注入深度为0.5μm;In step b32, perform nitrogen ion implantation three times at an ambient temperature of 500°C. The implantation energies are 520keV, 300keV, and 150keV respectively, and the corresponding doses are 9.8×10 11 cm -2 , 7×10 11 cm -2 , 4.9×10 11 cm -2 , the injection depth is 0.5μm;

步骤b33,采用标准RCA对碳化硅表面进行清洗,烘干后做C膜保护。然后在1750℃氩气氛围中进行离子激活退火,时间为15min。In step b33, standard RCA is used to clean the surface of the silicon carbide, and protect it with a C film after drying. Then ion-activated annealing was performed at 1750° C. in an argon atmosphere for 15 minutes.

步骤c3,与实施例一的步骤c1相同。Step c3 is the same as step c1 in Embodiment 1.

步骤d3,外延生长P-外延层;Step d3, epitaxially growing a P- epitaxial layer;

在N型漂移区和重掺杂的漂移区台面上生长一层厚度为3μm,铝离子掺杂浓度为8×1017cm-3的P-外延层,其外延生长工艺条件是:温度为1600℃,压力为100mbar,反应气体采用硅烷和丙烷,载运气体采用纯氢气,掺杂源采用三甲基铝。A P-epitaxial layer with a thickness of 3 μm and an aluminum ion doping concentration of 8×10 17 cm -3 is grown on the N-type drift region and the heavily doped drift region mesa. The epitaxial growth process conditions are: the temperature is 1600 °C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, and the dopant source is trimethylaluminum.

步骤e3,与实施例一的步骤e1相同。Step e3 is the same as step e1 in Embodiment 1.

步骤f3,与实施例一的步骤f1相同。Step f3 is the same as step f1 in Embodiment 1.

步骤g3,与实施例一的步骤g1相同。Step g3 is the same as step g1 in Embodiment 1.

步骤h3,与实施例一的步骤h1相同。Step h3 is the same as step h1 in Embodiment 1.

步骤i3,与实施例一的步骤i1相同。Step i3 is the same as step i1 in Embodiment 1.

步骤j3,与实施例一的步骤j1相同。Step j3 is the same as step j1 in Embodiment 1.

步骤k3,与实施例一的步骤k1相同。Step k3 is the same as step k1 in Embodiment 1.

以上所述仅为本发明的较佳实施例,对发明而言仅仅是说明性的,而非限制性的。本专业技术人员理解,在发明权利要求所限定的精神和范围内可对其进行许多改变,修改,甚至等效,但都将落入本发明的保护范围内。The above descriptions are only preferred embodiments of the present invention, and are only illustrative rather than restrictive to the present invention. Those skilled in the art understand that many changes, modifications, and even equivalents can be made within the spirit and scope defined by the claims of the invention, but all will fall within the protection scope of the present invention.

Claims (10)

1. ion implanting forms a UMOSFET preparation method for N-type heavy doping drift layer table top, its Being characterised by, this detailed process is:
Step a, epitaxial growth N-type drift region: be at silicon carbide N+substrate print Epitaxial growth thickness 12 μm~25 μm, Nitrogen ion doping content is 1 × 1015cm-3~5 × 1015cm-3N-type drift region;
Step b, ion implanting forms N+ trap: carries out ion implanting in N-type drift region, is formed heavily doped Miscellaneous N+ trap, N+ trap width is 3 μm~4 μm, and implanted dopant is Nitrogen ion, and the degree of depth is 0.5 μm, Doping content is 1 × 1017cm-3
Step c, N+ trap etching is for table top: N+ trap is etched into a table top, table surface height and N+ trap Deep equality, mesa width is equal with the width of trap;
Step d, epitaxial growth P-epitaxial layer: grow in N-type drift region and N+ drift layer table top Layer P-epitaxial layer, thickness is 3 μm, and Al-doping concentration is 5 × 1017cm-3~1 × 1018cm-3
Step e, epitaxial growth N+ source region layer: grow one layer of N+ source region layer, thickness on P-epitaxial layer Being 0.5 μm, doping content is 5 × 1018cm-3
Step f, etches grooving: use ICP etching to be formed directly over N-type heavy doping drift layer table top Groove, width is 6 μm, and the degree of depth is 3 μm, and two base angles of such groove are wrapped up by P-epitaxial layer;
Step g, etching forms source region: use ICP etching to form source contact;
Step h, oxidation forms groove grid: by thermal oxidation technology preparation vessel gate medium SiO2, thickness is 100nm;
Step i, depositing polysilicon: the groove gate medium SiO in groove grid2Upper deposit polySi layer;
Step j, opening contact hole: prepare passivation layer, open electrode contact hole;
Step k, prepares electrode: evaporated metal, prepares electrode.
Ion implanting the most according to claim 1 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps a, first serves as a contrast the carborundum of N-type Egative film carries out RCA standard cleaning, is then 12 μm~25 μ at whole substrate slice Epitaxial growth thickness M, Nitrogen ion doping content is 1 × 1015cm-3~5 × 1015cm-3N-drift layer, its process conditions are: Temperature is 1600 DEG C, and pressure is 100mbar, and reacting gas uses silane and propane, and carrier gas is adopted With pure hydrogen, doped source uses liquid nitrogen.
Ion implanting the most according to claim 1 and 2 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that the detailed process of above-mentioned steps b is:
Step b01, uses low pressure chemical vapor deposition mode to deposit thick layer at whole silicon carbide Degree is the SiO of 0.2 μm2, then the Al that deposition thickness is 1 μm is as the barrier layer of N~+ implantation, Forming N+ trap injection region by photoetching and etching, N+ trap injection region width is 3-4 μm;
Step b02, carries out three N~+ implantation, successively Implantation Energies under the environment temperature of 500 DEG C Being respectively 520keV, 300keV, 150keV, corresponding dosage is 9.8 × 1011cm-2、7×1011cm-2、 4.9×1011cm-2, injecting the degree of depth is 0.5 μm;
Step b03, silicon carbide is carried out by standard RCA of employing, does the protection of C film after drying, Then carrying out ion-activated annealing in 1750 DEG C of argon atmospheres, the time is 15min.
Ion implanting the most according to claim 3 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps c, N+ trap width is 3 μm~4 μm, Implanted dopant is Nitrogen ion, and the degree of depth is 0.5 μm, and doping content is 1 × 1017cm-3, its process conditions For: implantation temperature 500 DEG C, ion-activated annealing temperature 1750 DEG C, annealing time 10min.
Ion implanting the most according to claim 3 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps d, drifts about in N-type drift region and N+ Growing one layer of P-epitaxial layer on layer table top, thickness is 3 μm, and Al-doping concentration is 5 × 1017cm-3~1 ×1018cm-3;N+ trap etching is table top, and the height of table top is equal to N+ trap width, and its process conditions are: ICP coil power 850W, source power 100W, reacting gas SF6And O2Be respectively 48sccm and 12sccm。
Ion implanting the most according to claim 3 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps e, grows one on P-epitaxial layer Layer thickness is 0.5 μm, and Nitrogen ion doping content is 5 × 1018cm-3N-type silicon carbide epitaxial layers, make For N+ source region layer, its process conditions are: temperature is 1600 DEG C, and pressure is 100mbar, reacting gas Using silane and propane, carrier gas uses pure hydrogen, and doped source uses liquid nitrogen.
Ion implanting the most according to claim 6 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps f, first magnetron sputtering one layer Ti film as ICP etch mask, then gluing photoetching, carry out ICP etching, etch the width of groove Degree is 6 μm, and the degree of depth is 3 μm, finally removes photoresist, goes etch mask, cleans into mating plate;Process conditions For: ICP coil power 850W, source power 100W, reacting gas SF6And O2It is respectively 48sccm And 12sccm.
Ion implanting the most according to claim 6 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps g, first magnetron sputtering one layer Ti film as ICP etch mask, then gluing photoetching, carry out ICP etching, form source contact Hole, finally removes photoresist, and goes etch mask, cleans into mating plate;Process conditions are: ICP coil power 850W, Source power 100W, reacting gas SF6And O2It is respectively 48sccm and 12sccm.
Ion implanting the most according to claim 8 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps h, uses dry oxygen technique 1150 SiO is prepared at DEG C2Grid, thickness is 100nm, then at 1050 DEG C, N2Anneal under atmosphere, fall Low SiO2The roughness of film surface.
Ion implanting the most according to claim 8 forms N-type heavy doping drift layer table top UMOSFET preparation method, it is characterised in that in above-mentioned steps i, uses low pressure hot wall chemical vapour Phase sedimentation growth ploySi fills up groove, and deposition temperature is 600~650 DEG C, and deposit pressure is 60~80Pa, reacting gas is silane and hydrogen phosphide, and carrier gas is helium, then gluing photoetching, carves Erosion ploySi layer, forms polysilicon gate, finally removes photoresist, and cleans.
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