CN103749462B - Containing pyrrole metsulfovax and antibiotic bactericidal composition - Google Patents
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Abstract
Description
本申请为发明专利“含有吡噻菌胺的杀菌组合物”的分案申请，原专利申请号为2013100910407，申请日为2013年3月20日。This application is a divisional application of the invention patent "Fungicidal Composition Containing Penthiopyrad". The original patent application number is 2013100910407, and the filing date is March 20, 2013.
技术领域technical field
本发明涉及含有吡噻菌胺与抗生素的杀菌组合物，属于植物保护领域，涉及含有吡噻菌胺的杀菌组合物，该组合物用于防治灰霉病、白粉病、霜霉病、菌核病、锈病病、黑星病等。The invention relates to a fungicidal composition containing penthiopyrad and antibiotics, which belongs to the field of plant protection, and relates to a fungicidal composition containing penthiopyrad, which is used for preventing gray mold, powdery mildew, downy mildew and sclerotia disease, rust, scab, etc.
背景技术Background technique
吡噻菌胺是含酰胺结构的新型杀菌剂,对多种农作物的的病害具有优良的防效，尤其对灰霉病、白粉病、霜霉病具有很高的效果。为合理保护药剂、延缓病菌对新药剂抗药性的产生及提高药剂的防治效果，有必要进行合理的复配研究。目前已经有吡噻菌胺与其他杀菌剂的复配制剂，本发明通过实验发现了现有技术还没有发现的其他效果比较好的含有吡噻菌胺的杀菌组合物。这些杀菌组合物具有预料不到的技术效果。Penthiopyrad is a new fungicide containing amide structure, which has excellent control effect on various crop diseases, especially botrytis cinerea, powdery mildew and downy mildew. In order to reasonably protect agents, delay the emergence of bacteria resistance to new agents, and improve the control effect of agents, it is necessary to carry out reasonable compound research. At present, there are already compound preparations of penthiopyrad and other fungicides. The present invention has discovered other fungicidal compositions containing penthiopyrad that have not been found in the prior art through experiments. These fungicidal compositions have unexpected technical effects.
发明内容Contents of the invention
本发明的目的在于提供含有吡噻菌胺与抗生素的杀菌组合物，它是将两种不同结构进行复配，可是扩大防治谱和提高药效的有效途径，更重要的是避免或延缓病害对新成份抗性的产生。为实现本发明的目的，发明人将吡噻菌胺与具有杀菌成分的化合物复配，用于防治作物的病害。The object of the present invention is to provide a bactericidal composition containing penthiopyrad and antibiotics, which is an effective way to expand the spectrum of control and improve efficacy by compounding two different structures, and more importantly, to avoid or delay the impact of diseases on The emergence of resistance to new ingredients. In order to achieve the purpose of the present invention, the inventor compounded penthiopyrad with a compound having a bactericidal component for preventing and controlling crop diseases.
本发明的目的是通过下列措施来实现的。The object of the present invention is achieved by the following measures.
本发明提供了一种含有吡噻菌胺的杀菌组合物，其特征在于该组合物包括有效量的A组分和B组分两种活性成分，A组分是吡噻菌胺，B组分选自井冈霉素、春雷霉素、多抗霉素、宁南霉素中的一种。The invention provides a fungicidal composition containing penthiopyrad, which is characterized in that the composition comprises effective doses of two active ingredients, component A and component B, component A is penthiopyrad, and component B One selected from Jinggangmycin, Kasugamycin, Polyoxin and Ningnanmycin.
上述组合物中，优选的，A组分和B组分的质量份数比为1：40-40：1，优选的，A组分和B组分的质量份数比为10:1-1:20。In the above composition, preferably, the mass fraction ratio of A component and B component is 1:40-40:1, preferably, the mass fraction ratio of A component and B component is 10:1-1 :20.
本发明的上述组合物中，优选的，B组分选自春雷霉素、多抗霉素中的一种。In the above composition of the present invention, preferably, component B is selected from one of kasugamycin and polyoxamycin.
本发明上述组合物中，A组分和B组分的质量之和占组合物总质量的1-90%。In the above composition of the present invention, the sum of the mass of component A and component B accounts for 1-90% of the total mass of the composition.
本发明上述组合物可被制成悬浮剂、可湿性粉剂、水分散粒剂、水剂、微乳剂或水乳剂。The above composition of the present invention can be made into suspension, wettable powder, water dispersible granule, water, microemulsion or water emulsion.
本发明还提供了上述组合物用于防治作物病害的方法，其特征在于将组合物通过喷雾、灌根或拌种施用于作物或作物部分。。The present invention also provides a method of using the above composition for controlling crop diseases, characterized in that the composition is applied to crops or crop parts by spraying, root irrigation or seed dressing. .
本发明还发现，上述组合物在各自活性成分使用总量降低的情况下，对番茄灰霉病、黄瓜霜霉病、小麦白粉病具有优良的防治效果，增效作用明显。The present invention also finds that the above composition has excellent control effects on tomato gray mold, cucumber downy mildew and wheat powdery mildew, and the synergistic effect is obvious when the total amount of active ingredients used is reduced.
本发明还提供了上述组合物用于防治作物的多种农业病害的用途，其特征在于所述病害为半知菌类真菌引起的番茄灰霉病、黑星病等，鞭毛菌亚门真菌引起的霜霉病、晚疫病、霜疫霉病等，子囊菌亚门真菌引起的白粉病、炭疽病、叶斑病等，担子菌亚门引起的锈病、黑穗病等。The present invention also provides the application of the above-mentioned composition for preventing and controlling various agricultural diseases of crops, which is characterized in that the diseases are gray mold of tomato, scab, etc. Downy mildew, late blight, downy mildew, etc., powdery mildew, anthracnose, leaf spot, etc. caused by Ascomycotina fungi, rust, smut, etc. caused by Basidiomycotina.
上述用途中，所述的作物优选为番茄、黄瓜、小麦、水稻、西瓜、苹果、葡萄、柑橘、梨、荔枝或花卉等。In the above uses, the crops are preferably tomato, cucumber, wheat, rice, watermelon, apple, grape, citrus, pear, lychee or flowers.
本发明有益效果是：The beneficial effects of the present invention are:
1、增效作用明显：组合物在一定配比范围内表现良好的增效作用，提高了组合物的防病效果。1. Obvious synergistic effect: the composition exhibits good synergistic effect within a certain proportion range, which improves the disease prevention effect of the composition.
2、扩大防治谱：组合物可防治农业生产上的多种病害。2. Expand control spectrum: the composition can prevent and control various diseases in agricultural production.
3、降低使用成本：因复配具有提高防效、防治谱增大，减少了使用次数，降低了使用成本；3. Reduce the cost of use: because the compound can improve the control effect and increase the control spectrum, the number of uses is reduced, and the cost of use is reduced;
4、延缓抗药性：两种不同作用机制的成分复配，病原菌不易产生抗药性，延缓病原物对单剂抗药性的产生。4. Delaying drug resistance: The combination of two ingredients with different mechanisms of action makes it difficult for pathogenic bacteria to develop drug resistance and delays the emergence of pathogens' resistance to a single drug.
具体实施方式detailed description
以下实施例是对本发明的进一步说明，但本发明不只局限于本实施方式中的组合物和用途。The following examples are further descriptions of the present invention, but the present invention is not limited only to the compositions and uses in this embodiment.
实施例1吡噻菌胺组合物对番茄灰霉病的防治效果Example 1 Control Effect of Penthiopyrad Composition on Botrytis Botrytis of Tomato
将单一化合物或组合物用有机溶剂溶解制备成1000mg/L的母液。根据生物活性测定预试验，将一定量的上述母液用0.1%吐温80稀释，配制成需要的浓度。测定时，先将药液喷施于盆栽番茄植株，然后接种病原菌，保湿培养24h后，置于温室中培养，一定时间后测定植物叶面侵染的百分率。使用Abbot公式，将百分率转换成防效。A single compound or composition is dissolved in an organic solvent to prepare a 1000 mg/L mother solution. According to the pretest of biological activity determination, a certain amount of the above mother solution was diluted with 0.1% Tween 80 to prepare the required concentration. During the measurement, spray the medicinal liquid on the potted tomato plants first, then inoculate the pathogenic bacteria, keep moist and cultivate for 24 hours, then place them in the greenhouse for cultivation, and measure the percentage of plant foliage infection after a certain period of time. Convert percentages to efficacy using Abbot's formula.
x为使用浓度为a时的活性组分A的防效，y为使用浓度为b时的活性组分B的防效。比较理论效果和实际效果，评价组合物的协同作用，以实际防效大于理论防效时为增效作用。结果见表1。x is the control effect of active component A when the concentration is a, and y is the control effect of active component B when the concentration is b. Compare the theoretical effect and the actual effect, evaluate the synergistic effect of the composition, and take the synergistic effect when the actual control effect is greater than the theoretical control effect. The results are shown in Table 1.
表1吡噻菌胺组合物对番茄灰霉病的防治效果The control effect of table 1 penthiopyrad composition on tomato gray mold
通过盆栽测试，从表1看出，吡噻菌胺与春雷霉素的组合物对番茄灰霉病的效果均高于组合物的的理论防效。显而易见，吡噻菌胺与上述杀菌化合物的复配对番茄灰霉病是增效的。Through the pot test, it can be seen from Table 1 that the effect of the composition of penthiopyrad and kasugamycin on tomato gray mold is higher than the theoretical control effect of the composition. Obviously, the compounding of penthiopyrad and the above fungicidal compounds is synergistic against Botrytis cinerea.
实施例2吡噻菌胺组合物对小麦白粉病田间试验Example 2 Penthiopyrad Composition Field Test on Wheat Powdery Mildew
用组合物进行了小麦白粉病田间试验，并设相应单剂和空白对照，每药剂设小区30m2。采用背负式喷雾器常规常量喷雾，试验在孕穗和扬花初期各喷1次，药前及第2次施药后7～10d，每处理按五点取样，每点50株，每株调查全部叶片，记录调查总叶数、病叶数，按照以下分级方法计算病情指数和防效。A field test on wheat powdery mildew was carried out with the composition, and a corresponding single dose and a blank control were set up, and a plot of 30 m 2 was set up for each dose. A knapsack sprayer was used for regular constant spraying, and the test was sprayed once at the booting stage and the early stage of flowering, before the drug and 7-10 days after the second spraying, and each treatment was sampled at five points, 50 plants at each point, and all leaves were investigated for each plant. Record and investigate the total number of leaves and the number of diseased leaves, and calculate the disease index and control effect according to the following grading method.
叶片分级法：Leaf Grading Method:
0级：无病Level 0: no disease
1级：病斑相连面积占整个叶面积的1%以下；Level 1: The connected area of disease spots accounts for less than 1% of the entire leaf area;
3级：病斑相连面积占整个叶面积的1%-5%；Grade 3: The connected area of disease spots accounts for 1%-5% of the entire leaf area;
5级：病斑相连面积占整个叶面积的6%-25%；Grade 5: The connected area of lesions accounts for 6%-25% of the entire leaf area;
7级：病斑相连面积占整个叶面积的26%-50%；Grade 7: The connected area of disease spots accounts for 26%-50% of the entire leaf area;
9级：病斑相连面积占整个叶面积的51%以上；Grade 9: The connected area of disease spots accounts for more than 51% of the entire leaf area;
x为使用浓度为a时的活性组分A的防效，y为使用浓度为b时的活性组分B的防效。比较理论效果和实际效果，评价组合物的协同作用，以实际防效大于理论防效时为增效作用。防治效果见表3。x is the control effect of active component A when the concentration is a, and y is the control effect of active component B when the concentration is b. Compare the theoretical effect and the actual effect, evaluate the synergistic effect of the composition, and take the synergistic effect when the actual control effect is greater than the theoretical control effect. The control effect is shown in Table 3.
表2含有吡噻菌胺的农药组合物对小麦白粉病田间效果Table 2 The field effect of the pesticide composition containing penthiopyrad on wheat powdery mildew
通过吡噻菌胺组合物对小麦白粉病测试发现，吡噻菌胺与多抗霉素的组合物对小麦白粉病的效果均高于相应组合物的理论防效。显而易见，吡噻菌胺与上述杀菌化合物的组合物对小麦白粉病是增效的。Through the test of the penthiopyrad composition against wheat powdery mildew, it was found that the effects of the combination of penthiopyrad and polyoxin on wheat powdery mildew were higher than the theoretical control effects of the corresponding compositions. Obviously, the combination of penthiopyrad and the above fungicidal compounds is synergistic against wheat powdery mildew.
Claims (4)
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| CN201310091040.7A Active CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
| CN201410036205.5A Active CN103798240B (en) | 2013-03-20 | 2013-03-20 | Composition containing pyrrole metsulfovax and methoxy acrylic sterilization component |
| CN201410038784.7A Active CN103749462B (en) | 2013-03-20 | 2013-03-20 | Containing pyrrole metsulfovax and antibiotic bactericidal composition |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310091040.7A Active CN103141484B (en) | 2013-03-20 | 2013-03-20 | Sterilizing composition containing penthiopyrad |
| CN201410036205.5A Active CN103798240B (en) | 2013-03-20 | 2013-03-20 | Composition containing pyrrole metsulfovax and methoxy acrylic sterilization component |
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| CN103141496A (en) * | 2013-04-02 | 2013-06-12 | 海利尔药业集团股份有限公司 | Sterilizing composite containing pyraclostrobin and penthiopyrad |
| CN104247710B (en) * | 2013-06-29 | 2016-02-24 | 深圳诺普信农化股份有限公司 | Health composition containing pyraclostrobin |
| US9788544B2 (en) * | 2013-11-26 | 2017-10-17 | Upl Limited | Method for controlling rust |
| WO2015160619A1 (en) * | 2014-04-16 | 2015-10-22 | Bayer Cropscience Lp | Compositions comprising ningnanmycin and a fungicide |
| CN104137833B (en) * | 2014-07-18 | 2016-05-18 | 江苏丘陵地区镇江农业科学研究所 | One is prevented and treated the biological composite bactericide of wheat scab and application thereof |
| CN104126595B (en) * | 2014-08-21 | 2016-04-13 | 陕西上格之路生物科学有限公司 | A kind of microbicide compositions containing pyraclostrobin |
| CN104186486B (en) * | 2014-09-22 | 2017-01-11 | 江苏省绿盾植保农药实验有限公司 | Sterilizing composition containing fluopicolide and metconazole and application thereof |
| CN104381293B (en) * | 2014-11-03 | 2016-05-25 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of bactericidal composition containing Silthiopham and jinggangmeisu |
| CN104823976A (en) * | 2015-04-09 | 2015-08-12 | 江门市植保有限公司 | Pesticide composition containing bromothalonil and kasugamycin |
| CN104770381A (en) * | 2015-04-24 | 2015-07-15 | 常熟市植保植检站 | Fungicidal composition for prevention and treatment of crop diseases and applications of fungicidal composition |
| CN107006500A (en) * | 2017-04-28 | 2017-08-04 | 广东广康生化科技股份有限公司 | Composition pesticide comprising folpet and pyrrole metsulfovax |
| CN109418270A (en) * | 2017-09-01 | 2019-03-05 | 浙江省化工研究院有限公司 | A kind of bactericidal composition of fluorine-containing phenylate amide |
| CN108576029A (en) * | 2018-06-05 | 2018-09-28 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing pyrrole metsulfovax and its application |
| CN109042677A (en) * | 2018-08-24 | 2018-12-21 | 广东顾地丰生物科技有限公司 | A kind of bactericidal composition, fungicide and its application of the metsulfovax containing pyrrole |
| CN108794075A (en) * | 2018-08-28 | 2018-11-13 | 陕西省生物农业研究所 | The feces of livestock and poultry base-material preparation method cured based on separating dry space from moist space and microbial deodorant |
| CN112438269A (en) * | 2019-08-30 | 2021-03-05 | 佛山市海力盈生物科技有限公司 | Sterilization composition containing penthiopyrad and amino-oligosaccharin and application thereof |
| CN113412838A (en) * | 2021-06-01 | 2021-09-21 | 四川瑞象农业科技发展有限公司 | Bactericidal composition for citrus brown spot and control method |
| CN114208566A (en) * | 2021-12-27 | 2022-03-22 | 云南省农业科学院药用植物研究所 | Prevention and treatment method for anthracnose of tsaoko amomum fruits |
| CN114916552B (en) * | 2022-05-16 | 2023-10-31 | 中农立华生物科技股份有限公司 | Compound agricultural bactericide containing penthiopyrad and application thereof |
| CN116076519B (en) * | 2023-03-08 | 2024-08-16 | 福建省农业科学院植物保护研究所 | A bactericidal composition containing pyraclostrobin and myclobutanil and its application |
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| CN101184391A (en) * | 2005-04-06 | 2008-05-21 | 拜尔农作物科学股份公司 | Synergistic fungicidal active substance combinations |
| CN103651539A (en) * | 2012-09-11 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticide composition containing penthiopyrad |
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| CN1288662A (en) * | 2000-06-22 | 2001-03-28 | 张长兴 | Farm chemical for preventing and controlling black spot of fruit tree |
| CN1461592A (en) * | 2002-05-26 | 2003-12-17 | 汪建利 | Composition of ethylicin and insecticide and miticide |
| CN1461590A (en) * | 2002-05-26 | 2003-12-17 | 汪建利 | Sterilizing composition contg. ethylicin |
| KR101302266B1 (en) * | 2004-09-27 | 2013-09-02 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Fungicidal mixtures of thiophene derivative |
| CN102669164B (en) * | 2012-05-30 | 2013-11-20 | 陕西上格之路生物科学有限公司 | Syp-1620 containing sterilization composition |
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| CN103125494A (en) * | 2013-03-16 | 2013-06-05 | 海利尔药业集团股份有限公司 | Bactericidal composition containing (E,E,E)-N-methyl-2-[((((1-methyl-3-(2,6-dichlorophenyl)-2-propenyl)imino)oxy)methyl)phenyl]-2-methoxyiminoacetamide and penthiopyrad |
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| CN101184391A (en) * | 2005-04-06 | 2008-05-21 | 拜尔农作物科学股份公司 | Synergistic fungicidal active substance combinations |
| CN103651539A (en) * | 2012-09-11 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticide composition containing penthiopyrad |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103749462A (en) | 2014-04-30 |
| CN103798240B (en) | 2016-03-02 |
| CN103798240A (en) | 2014-05-21 |
| CN103141484A (en) | 2013-06-12 |
| CN103141484B (en) | 2014-07-09 |
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