CN103478910A - Easy-to-clean shirt - Google Patents
Easy-to-clean shirt Download PDFInfo
- Publication number
- CN103478910A CN103478910A CN201310365714.8A CN201310365714A CN103478910A CN 103478910 A CN103478910 A CN 103478910A CN 201310365714 A CN201310365714 A CN 201310365714A CN 103478910 A CN103478910 A CN 103478910A
- Authority
- CN
- China
- Prior art keywords
- easy
- clean
- shirt
- cationic surfactant
- collar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 230000003670 easy-to-clean Effects 0.000 title claims abstract description 40
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000004744 fabric Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 7
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000003093 cationic surfactant Substances 0.000 claims description 19
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 10
- -1 dimethyl hydrogen Chemical compound 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- WCRKLZYTQVZTMM-UHFFFAOYSA-N 2-octadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC=CC=C1O WCRKLZYTQVZTMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- SXPWTBGAZSPLHA-UHFFFAOYSA-M cetalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SXPWTBGAZSPLHA-UHFFFAOYSA-M 0.000 claims description 3
- 229960000228 cetalkonium chloride Drugs 0.000 claims description 3
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 3
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims description 2
- 230000003252 repetitive effect Effects 0.000 claims description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 2
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 5
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract 1
- 239000004205 dimethyl polysiloxane Substances 0.000 abstract 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 description 8
- 239000002105 nanoparticle Substances 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002803 maceration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 239000003642 reactive oxygen metabolite Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005320 surfactant adsorption Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an easy-to-clean shirt, which comprises a shirt main body, a collar and cuffs. The collar and the cuffs are respectively made of easy-to-clean fabric; an easy-to-clean finishing agent is attached to the easy-to-clean fabric. The easy-to-clean finishing agent consists of the following components in parts by weight: 70-80 parts of nanometer titania, 10-15 parts of octadecyl, 5-8 parts of hydrogenous dimethyl polysiloxane, 5-10 parts of cationic surface active agent and 0.2-1 part of sodium polyacrylate dispersing agent. According to the easy-to-clean shirt disclosed by the invention, special finishing is performed on the collar and the cuffs, and therefore, the cost is greatly reduced. Moreover, the easy-to-clean shirt has self-cleaning and oil rub resistance, and is strong in durability.
Description
Technical field
The present invention relates to a kind of shirt easy to clean.
Background technology
Shirt is people's daily life clothes commonly used, owing to being underclothes, is very easy to make dirty.Utilize nano-TiO
2photodegradation, can effectively remove the part harmful substance.Nano-TiO
2under the irradiation of ultraviolet ray or daylight, can be by oxychloride, formaldehyde catalytic degradation.Its principle is TiO
2when being subject to the ultraviolet ray irradiation, will produce free electron and hole, they make airborne oxygen activation, produce reactive oxygen species and free radicals, and some organic pollution is decomposed into CO the most at last
2and H
2o.Contain nano-TiO
2non-weaving cloth or textile, can make curtain, sheet, wall paper, carpet, furniture and cloth, various adornments etc. for car and boat, also can be used as the purified treatment articles for use of air and waste water.But prior art adopts direct method for sorting, due to nano-TiO
2interfacial effect, itself and fibrous binding force are not strong, cause the durability of finished product and water-wash resistance poor, affect its result of use.Develop a kind of shirt easy to clean with excellent durability and become important research topic.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of shirt easy to clean, the above-mentioned defect existed to overcome prior art.
For solving the problems of the technologies described above, the present invention's shirt easy to clean, comprise shirt main body, collar and cuff, and described collar and cuff adopt fabric easy to clean to make, be attached with finishing agent easy to clean in described fabric easy to clean, described finishing agent easy to clean is comprised of the component of following weight portion:
As preferred version, the average grain diameter of described nano titanium oxide is the 50-100 nanometer; Preferred nanometer anatase titania;
The quantity of the siloxy repetitive of described dimethyl hydrogen containing siloxane is 40-50;
Described Sodium Polyacrylate dispersant preferred viscosities 200-250mPas;
Described cationic surfactant comprises one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cetalkonium chloride, stearyl dimethyl benzyl ammonium chloride, hexadecyltrimethylammonium chloride, softex kw, hexadecylpyridinium chloride.
Finishing agent easy to clean can adopt general mixed method, preferably adopts following method preparation:
Nano titanium oxide, octadecyl phenol, dimethyl hydrogen containing siloxane, Sodium Polyacrylate dispersant and water are mixed and is made into the water slurry that mass content is 20-60%, then add cationic surfactant at twice in suspension, add for the first time 50% cationic surfactant, add for the second time remaining cationic surfactant, need respectively to mix 0.5-3.0 hour after adding cationic surfactant for twice.
The invention also discloses a kind of manufacturing process of above-mentioned shirt easy to clean, comprise the steps:
Fabric is padded to processing in containing the maceration extract of finishing agent easy to clean, pressure 2.5-3kg/cm
2, liquid carrying rate 60-70%, after oven dry by fabric constant temperature 0.5-2 hour between 115-150 ℃; Fabric is cut into to collar and cuff, then with the shirt main body, is stitched into shirt.
The present invention adds cationic surfactant in the nano titanium oxide water slurry, and cationic surfactant one end is the cation that polarity is very strong, and the other end is the very weak longer hydrocarbon chain of polarity.Cationic surfactant adds at twice, after surfactant adds for the first time, cation one end that surfactant polarity is very strong and the anion generation effect on nano titanium oxide surface, SURFACTANT ADSORPTION is to the titanium dioxide nanoparticle surface, by other end polarity, very weak long-chain hydrocarbon covers the titanium dioxide nanoparticle surface, makes the titanium dioxide nanoparticle surface become low pole.After surfactant adds for the second time, surfactant low pole long-chain hydrocarbon can with the generation effect of the titanium dioxide nanoparticle of low pole surface, the surface of very strong cation nanometer titanium dioxide granule by other end polarity, make positive charge on original electronegative titanium dioxide nanoparticle surface band, make nano titanium oxide become cationic.The cation nanometer titanium dioxide of this surface band positive charge, can with fabric surface with negative electrical charge produce strong effect, make titanium dioxide nanoparticle be adsorbed on firmly fabric surface.Add octadecyl phenol and dimethyl hydrogen containing siloxane in finishing agent easy to clean, can be effectively to oil rub resistance.The present invention's shirt durability easy to clean is strong, has good functions.
The specific embodiment
Embodiment 1
The manufacturing process of shirt easy to clean:
Fabric is padded to processing in containing the maceration extract of finishing agent easy to clean, pressure 2.5kg/cm
2, liquid carrying rate 60%, after oven dry by fabric constant temperature 2 hours between 115 ℃; Fabric is cut into to collar and cuff, then with the shirt main body, is stitched into shirt.
The wherein preparation of finishing agent easy to clean:
Nano titanium oxide, octadecyl phenol, dimethyl hydrogen containing siloxane, Sodium Polyacrylate dispersant and water are mixed and is made into the water slurry that mass content is 20%, then add cetalkonium chloride 6 grams at twice in suspension, add for the first time cationic surfactant 3 grams, add for the second time remaining cationic surfactant, need respectively to mix 1 hour after adding cationic surfactant for twice.
Embodiment 2
The manufacturing process of shirt easy to clean:
Fabric is padded to processing in containing the maceration extract of finishing agent easy to clean, pressure 3kg/cm
2, liquid carrying rate 70%, after oven dry by fabric constant temperature 0.5 hour between 150 ℃; Fabric is cut into to collar and cuff, then with the shirt main body, is stitched into shirt.
The wherein preparation of finishing agent easy to clean:
Nano titanium oxide, octadecyl phenol, dimethyl hydrogen containing siloxane, Sodium Polyacrylate dispersant and water are mixed and is made into the water slurry that mass content is 60%, then add hexadecylpyridinium chloride 8 grams at twice in suspension, add for the first time cationic surfactant 4 grams, add for the second time remaining cationic surfactant, need respectively to mix 1.5 hours after adding cationic surfactant for twice.
Claims (7)
1. a shirt easy to clean, comprise shirt main body, collar and cuff, and described collar and cuff adopt fabric easy to clean to make, and in described fabric easy to clean, is attached with finishing agent easy to clean, and described finishing agent easy to clean is comprised of the component of following weight portion:
2. shirt easy to clean according to claim 1, is characterized in that, the average grain diameter of described nano titanium oxide is the 50-100 nanometer.
3. shirt easy to clean according to claim 2, is characterized in that, the crystal formation of described nano titanium oxide is anatase titanium dioxide.
4. shirt easy to clean according to claim 1, is characterized in that, the quantity of the siloxy repetitive of described dimethyl hydrogen containing siloxane is 40-50.
5. shirt easy to clean according to claim 1, is characterized in that, described Sodium Polyacrylate dispersant viscosity is 200-250mPas.
6. shirt easy to clean according to claim 1, it is characterized in that, described cationic surfactant comprises one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cetalkonium chloride, stearyl dimethyl benzyl ammonium chloride, hexadecyltrimethylammonium chloride, softex kw, hexadecylpyridinium chloride.
7. according to the described shirt easy to clean of claim 1-6 any one, it is characterized in that, described finishing agent easy to clean adopts following method preparation: nano titanium oxide, octadecyl phenol, dimethyl hydrogen containing siloxane, Sodium Polyacrylate dispersant and water are mixed and is made into the water slurry that mass content is 20-60%, then add cationic surfactant at twice in suspension, add for the first time 50% cationic surfactant, add for the second time remaining cationic surfactant, need respectively to mix 0.5-3.0 hour after adding cationic surfactant for twice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310365714.8A CN103478910A (en) | 2013-08-21 | 2013-08-21 | Easy-to-clean shirt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310365714.8A CN103478910A (en) | 2013-08-21 | 2013-08-21 | Easy-to-clean shirt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103478910A true CN103478910A (en) | 2014-01-01 |
Family
ID=49819767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310365714.8A Pending CN103478910A (en) | 2013-08-21 | 2013-08-21 | Easy-to-clean shirt |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103478910A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105212283A (en) * | 2015-09-18 | 2016-01-06 | 宿迁市豹子头服饰科技有限公司 | A kind of nanometer anti-soil blouse and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11247001A (en) * | 1998-02-27 | 1999-09-14 | Toray Ind Inc | Stainproof shirt |
| JP2003213509A (en) * | 2002-01-18 | 2003-07-30 | Nisshinbo Ind Inc | Shirt or blouse collar and cuffs antifouling processing method |
| CN1824884A (en) * | 2005-02-25 | 2006-08-30 | 中科纳米技术工程中心有限公司 | Self-cleaning suiting containing nano-functional material and method for making garment products |
| CN102277724A (en) * | 2011-06-28 | 2011-12-14 | 东华大学 | Method for clearing up nanometer uvioresistant antibacterial self-cleaning fabric |
| CN102845845A (en) * | 2012-09-26 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Fouling-resisting shirt and manufacture process |
| CN102851943A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Finishing method of automatic-cleaning textiles |
-
2013
- 2013-08-21 CN CN201310365714.8A patent/CN103478910A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11247001A (en) * | 1998-02-27 | 1999-09-14 | Toray Ind Inc | Stainproof shirt |
| JP2003213509A (en) * | 2002-01-18 | 2003-07-30 | Nisshinbo Ind Inc | Shirt or blouse collar and cuffs antifouling processing method |
| CN1824884A (en) * | 2005-02-25 | 2006-08-30 | 中科纳米技术工程中心有限公司 | Self-cleaning suiting containing nano-functional material and method for making garment products |
| CN102277724A (en) * | 2011-06-28 | 2011-12-14 | 东华大学 | Method for clearing up nanometer uvioresistant antibacterial self-cleaning fabric |
| CN102851943A (en) * | 2012-08-29 | 2013-01-02 | 昆山铁牛衬衫厂 | Finishing method of automatic-cleaning textiles |
| CN102845845A (en) * | 2012-09-26 | 2013-01-02 | 昆山市周市斐煌服饰厂 | Fouling-resisting shirt and manufacture process |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105212283A (en) * | 2015-09-18 | 2016-01-06 | 宿迁市豹子头服饰科技有限公司 | A kind of nanometer anti-soil blouse and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140101 |