CN102845845A - Fouling-resisting shirt and manufacture process - Google Patents
Fouling-resisting shirt and manufacture process Download PDFInfo
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- CN102845845A CN102845845A CN2012103636217A CN201210363621A CN102845845A CN 102845845 A CN102845845 A CN 102845845A CN 2012103636217 A CN2012103636217 A CN 2012103636217A CN 201210363621 A CN201210363621 A CN 201210363621A CN 102845845 A CN102845845 A CN 102845845A
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- soil
- fabric
- cationic surfactant
- blouse
- fouling
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- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a fouling-resisting shirt which comprises a shirt main body, a collar and sleeve cuffs. The collar and the sleeve cuffs are made of a fouling-resisting fabric, a fouling-resisting finishing agent is adhered to the fouling-resisting fabric and consists of, by weight, nanometer titania 70-80 parts, ethyl containing hydrogen silicone oil 5-8 parts, positive ion surface active agent 5-10 parts and sodium polyacrylate dispersing agent 0.2-1 part. The collar and the sleeve cuffs are subjected to the fouling-resisting finishing, the cost is greatly reduced, and simultaneously the fouling-resisting shirt has the self-cleaning and oil-contamination-resisting performance and is strong in durability.
Description
Technical field
The present invention relates to a kind of anti-soil blouse, and the manufacturing process of this anti-soil blouse.
Background technology
Shirt is people's daily life clothes commonly used, owing to being underclothes, is very easy to make dirty.Utilize nano-TiO
2Photodegradation, can effectively remove the part harmful substance.Nano-TiO
2Under the irradiation of ultraviolet ray or daylight, can be with oxychloride, formaldehyde catalytic degradation.Its principle is TiO
2When being subject to the ultraviolet ray irradiation, will produce free electron and hole, they make airborne oxygen activation, produce reactive oxygen species and free radicals, and some organic pollution is decomposed into CO the most at last
2And H
2O.Contain nano-TiO
2Non-weaving cloth or textile, can make curtain, sheet, wall paper, carpet, furniture and car and boat with cloth, various adornments etc., also can be used as the purified treatment articles for use of air and waste water.But prior art adopts direct method for sorting, because nano-TiO
2Interfacial effect, itself and fibrous binding force are not strong, cause the durability of finished product and water-wash resistance poor, affect its result of use.Develop a kind of anti-soil blouse with excellent durability and become important research topic.
Summary of the invention
The technical problem to be solved in the present invention provides the manufacturing process of a kind of anti-soil blouse and this kind anti-soil blouse, the defects that exists to overcome prior art.
For solving the problems of the technologies described above, the invention provides a kind of anti-soil blouse, comprise shirt main body, collar and cuff, described collar and cuff adopt the anti-soil fabric to make, be attached with the anti-soil finishing agent in the described anti-soil fabric, described anti-soil finishing agent is comprised of the component of following weight portion:
As preferred version, the average grain diameter of described nano titanium oxide is the 50-100 nanometer; Preferred nanometer anatase titania;
The quantity of the siloxy repetitive of described ethyl containing hydrogen silicone oil is 20-30;
Described Sodium Polyacrylate dispersant preferred viscosities 200-250mPas;
Described cationic surfactant comprises one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cetalkonium chloride, stearyl dimethyl benzyl ammonium chloride, hexadecyltrimethylammonium chloride, softex kw, the hexadecylpyridinium chloride.
The anti-soil finishing agent can adopt general mixed method, preferably adopts following method preparation:
Nano titanium oxide, ethyl containing hydrogen silicone oil, Sodium Polyacrylate dispersant and water mixing are made into the water slurry that mass content is 20-60%, then in suspension, add cationic surfactant at twice, add for the first time 50% cationic surfactant, add for the second time remaining cationic surfactant, needed respectively to mix 0.5-3.0 hour behind twice adding cationic surfactant.
The invention also discloses a kind of manufacturing process of above-mentioned anti-soil blouse, comprise the steps:
Fabric is padded processing in the maceration extract that contains the anti-soil finishing agent, pressure 2.5-3kg/cm2, liquid carrying rate 60-70%, after the oven dry with fabric between 115-150 ℃ constant temperature 0.5-2 hour; Fabric is cut into collar and cuff, then is stitched into shirt with the shirt main body.
The present invention adds cationic surfactant in the nano titanium oxide water slurry, cationic surfactant one end is the very strong cation of polarity, and the other end is the very weak long hydrocarbon chain of polarity.Cationic surfactant adds at twice, after surfactant adds for the first time, cation one end that surfactant polarity is very strong and the anion generation effect on nano titanium oxide surface, SURFACTANT ADSORPTION is to the titanium dioxide nanoparticle surface, the long-chain hydrocarbon that other end polarity is very weak covers the titanium dioxide nanoparticle surface, makes the titanium dioxide nanoparticle surface become low pole.After surfactant adds for the second time, surfactant low pole long-chain hydrocarbon can with the generation effect of the titanium dioxide nanoparticle of low pole surface, the surface of the cation nanometer titanium dioxide granule that other end polarity is very strong, make positive charge on the original electronegative titanium dioxide nanoparticle surface band, make nano titanium oxide become cationic.The cation nanometer titanium dioxide of this surface band positive charge, can with fabric surface with negative electrical charge produce strong effect, make titanium dioxide nanoparticle be adsorbed on firmly fabric surface.In the anti-soil finishing agent, add the ethyl containing hydrogen silicone oil, can be effectively to oil rub resistance.Anti-soil blouse durability of the present invention is strong, has good functions.
The specific embodiment
Embodiment 1
The manufacturing process of anti-soil blouse:
Fabric is padded processing in the maceration extract that contains the anti-soil finishing agent, pressure 2.5kg/cm2, liquid carrying rate 60%, after the oven dry with fabric constant temperature 2 hours between 115 ℃; Fabric is cut into collar and cuff, then is stitched into shirt with the shirt main body.
The wherein preparation of anti-soil finishing agent:
Nano titanium oxide, ethyl containing hydrogen silicone oil, Sodium Polyacrylate dispersant and water mixed to be made into mass content be 20% water slurry, then in suspension, add cetalkonium chloride 6 grams at twice, add for the first time cationic surfactant 3 grams, add for the second time remaining cationic surfactant, needed respectively to mix 1 hour behind twice adding cationic surfactant.
Embodiment 2
The manufacturing process of anti-soil blouse:
Fabric is padded processing in the maceration extract that contains the anti-soil finishing agent, pressure 3kg/cm2, liquid carrying rate 70%, after the oven dry with fabric constant temperature 0.5 hour between 150 ℃; Fabric is cut into collar and cuff, then is stitched into shirt with the shirt main body.
The wherein preparation of anti-soil finishing agent:
Nano titanium oxide, ethyl containing hydrogen silicone oil, Sodium Polyacrylate dispersant and water mixed to be made into mass content be 60% water slurry, then in suspension, add hexadecylpyridinium chloride 8 grams at twice, add for the first time cationic surfactant 4 grams, add for the second time remaining cationic surfactant, needed respectively to mix 1.5 hours behind twice adding cationic surfactant.
In sum, the present invention adds cationic surfactant in the nano titanium oxide water slurry, and cationic surfactant one end is the very strong cation of polarity, and the other end is the very weak long hydrocarbon chain of polarity.Cationic surfactant adds at twice, after surfactant adds for the first time, cation one end that surfactant polarity is very strong and the anion generation effect on nano titanium oxide surface, SURFACTANT ADSORPTION is to the titanium dioxide nanoparticle surface, the long-chain hydrocarbon that other end polarity is very weak covers the titanium dioxide nanoparticle surface, makes the titanium dioxide nanoparticle surface become low pole.After surfactant adds for the second time, surfactant low pole long-chain hydrocarbon can with the generation effect of the titanium dioxide nanoparticle of low pole surface, the surface of the cation nanometer titanium dioxide granule that other end polarity is very strong, make positive charge on the original electronegative titanium dioxide nanoparticle surface band, make nano titanium oxide become cationic.The cation nanometer titanium dioxide of this surface band positive charge, can with fabric surface with negative electrical charge produce strong effect, make titanium dioxide nanoparticle be adsorbed on firmly fabric surface.In the anti-soil finishing agent, add the ethyl containing hydrogen silicone oil, can be effectively to oil rub resistance.Anti-soil blouse durability of the present invention is strong, has good functions.
Claims (8)
1. an anti-soil blouse comprises shirt main body, collar and cuff, and described collar and cuff adopt the anti-soil fabric to make, and are attached with the anti-soil finishing agent in the described anti-soil fabric, and described anti-soil finishing agent is comprised of the component of following weight portion:
2. anti-soil blouse according to claim 1 is characterized in that, the average grain diameter of described nano titanium oxide is the 50-100 nanometer.
3. anti-soil blouse according to claim 2 is characterized in that, the crystal formation of described nano titanium oxide is anatase titanium dioxide.
4. anti-soil blouse according to claim 1 is characterized in that, the quantity of the siloxy repetitive of described ethyl containing hydrogen silicone oil is 20-30.
5. anti-soil blouse according to claim 1 is characterized in that, described Sodium Polyacrylate dispersant viscosity is 200-250mPas.
6. anti-soil blouse according to claim 1, it is characterized in that, described cationic surfactant comprises one or more in dodecyl benzyl dimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cetalkonium chloride, stearyl dimethyl benzyl ammonium chloride, hexadecyltrimethylammonium chloride, softex kw, the hexadecylpyridinium chloride.
7. the manufacturing process of each described anti-soil blouse is characterized in that according to claim 1-6, comprising: fabric is padded processing in the maceration extract that contains the anti-soil finishing agent, the pressure that wherein pads processing is 2.5-3kg/cm
2, liquid carrying rate is 60-70%, to after the oven dry with fabric between 115-150 ℃ constant temperature 0.5-2 hour; Fabric is cut into collar and cuff, then is stitched into shirt with the shirt main body.
8. the manufacturing process of described anti-soil blouse according to claim 7, it is characterized in that, described anti-soil finishing agent adopts following method preparation: nano titanium oxide, ethyl containing hydrogen silicone oil, Sodium Polyacrylate dispersant and water are mixed being made into the water slurry that mass content is 20-60%, then in suspension, add cationic surfactant at twice, add for the first time 50% cationic surfactant, add for the second time remaining cationic surfactant, needed respectively to mix 0.5-3.0 hour behind twice adding cationic surfactant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103636217A CN102845845A (en) | 2012-09-26 | 2012-09-26 | Fouling-resisting shirt and manufacture process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103636217A CN102845845A (en) | 2012-09-26 | 2012-09-26 | Fouling-resisting shirt and manufacture process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102845845A true CN102845845A (en) | 2013-01-02 |
Family
ID=47393136
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103636217A Pending CN102845845A (en) | 2012-09-26 | 2012-09-26 | Fouling-resisting shirt and manufacture process |
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| CN (1) | CN102845845A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469545A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Manufacturing method of easy-to-clean shirt |
| CN103478910A (en) * | 2013-08-21 | 2014-01-01 | 昆山铁牛衬衫厂 | Easy-to-clean shirt |
| CN105212283A (en) * | 2015-09-18 | 2016-01-06 | 宿迁市豹子头服饰科技有限公司 | A kind of nanometer anti-soil blouse and preparation method thereof |
| CN113062117A (en) * | 2021-03-19 | 2021-07-02 | 广州市龙格派服饰有限公司 | Clothes with waterproof and anti-fouling functions and processing technology thereof |
| WO2024090372A1 (en) * | 2022-10-26 | 2024-05-02 | ダイキン工業株式会社 | Oilproofing agent |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103469545A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Manufacturing method of easy-to-clean shirt |
| CN103478910A (en) * | 2013-08-21 | 2014-01-01 | 昆山铁牛衬衫厂 | Easy-to-clean shirt |
| CN105212283A (en) * | 2015-09-18 | 2016-01-06 | 宿迁市豹子头服饰科技有限公司 | A kind of nanometer anti-soil blouse and preparation method thereof |
| CN113062117A (en) * | 2021-03-19 | 2021-07-02 | 广州市龙格派服饰有限公司 | Clothes with waterproof and anti-fouling functions and processing technology thereof |
| WO2024090372A1 (en) * | 2022-10-26 | 2024-05-02 | ダイキン工業株式会社 | Oilproofing agent |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20130102 |