A kind of Pesticidal combination that contains Tea Saponin
Technical field
The present invention relates to a kind of Pesticidal combination that contains Tea Saponin, particularly, relate to a kind of Tea Saponin Pesticidal combination that improves desinsection speed.
Background technology
Tea Saponin (Teasaponia) is a kind of pentacyclic triterpenoid that extracts in the tea-seed pancake.It is a kind of natural nonionic surface active agent of function admirable.Along with the application study work of Tea Saponin deepens continuously, the application of Tea Saponin in daily-use chemical industry, light textile, medicine and pesticide industry is also more and more extensive.The bibliographical information Tea Saponin is mainly used in wettable powder as fields such as wetting agent, vegetable insecticide and bactericide, plant growth regulations on pesticide industry
After Tea Saponin joins synthetic pesticide or biogenic pesticide; Itself can reach the toxic effect to insect; Can also reduce simultaneously the consumption of pesticide original medicine, for example add 1000 with the 2000mg/L Tea Saponin after can reduce Rogor consumption 18.13% and 53.70% respectively.This can reduce use cost largely for expensive pesticide species, also can therefore reduce the harmful effects such as residual contamination to environment, improves the agricultural chemicals safety in utilization.That is to say that Tea Saponin can play synergistic effect to a lot of agricultural chemicals.
Because Tea Saponin itself is exactly good insecticide; But its drug effect performance is slow; The drug effect phase is long; Insecticidal effect is not obvious in a short time, rarely has report can improve the auxiliary agent of Tea Saponin to pest controling effect at present, and the composition of the control efficiency that can strengthen Tea Saponin and other insecticides is not provided yet.
For solving the problems of the technologies described above, the invention provides a kind of insecticides adjuvant, this pesticidal preparations can effectively solve the problem of residue of pesticide.
Summary of the invention
For solving the problems of the technologies described above; The invention provides a kind of Tea Saponin Pesticidal combination that improves desinsection speed; Said composition comprises Tea Saponin, APG and sodium alginate, and wherein the weight ratio of Tea Saponin, APG and sodium alginate is 5-15: 1-5: 1-5.
In the above-mentioned composition, can also comprise fulvic acid, wherein the weight ratio of the weight of fulvic acid and Tea Saponin is 0.5-1: 1.
In the above-mentioned composition, can also comprise other insecticides, other insecticides can be pyrethroids, natural pyrethrins, tetramethrin, S-bioallethrin, fenfluthrin, prallethrin etc.; Organophosphorus ester is like the first Toyodan; Carbamates, like carbofuran, furathiocarb etc.; Macrolide, like Olivomitecidin, the close mycin that compares; Organochlorine compound, like 5a,6,9,9a-hexahydro-6,9-methano-2,4, lindane etc.; The amidine class is like galecron, two worm amidines etc.; The chlorine nicotinyl compounds, like Imidacloprid, thiophene worm quinoline, pyridine worm miaow etc.Preferably, can comprise Imidacloprid.
Preferably, other insecticides account for 10% of Tea Saponin weight in the above-mentioned composition.
In the above-mentioned Tea Saponin Pesticidal combination, preferred, APG is APG class material arbitrarily.
Preferably; Above-mentioned Tea Saponin Pesticidal combination can be prepared into wetting powder, sustained release agent, pulvis, micro-capsule suspension, can disperse in dense dose, seed treatment emulsion, aqueous emulsion, big granula, granule, microemulsion, oil-suspending agent, finish, the seed with coated pesticidal, suspension emulsion, water-soluble granule, soluble thick agent, water-dispersible granules any one; Preferably, above-mentioned Tea Saponin Pesticidal combination is prepared into aqueous emulsion.
Above-mentioned Tea Saponin Pesticidal combination of the present invention can for example through mixing, perhaps through methods such as high speed shear mixing, not have special limitation through the conventional insecticides adjuvant preparation method preparation in this area.
The purposes that the present invention also provides above-mentioned Tea Saponin Pesticidal combination to be used to improve the desinsection speed of insecticide and to strengthen pest controling effect, wherein said insecticide is preferably Imidacloprid.
Used Tea Saponin, APG, sodium alginate, fulvic acid among the present invention are the conventional substances that can buy on the market, do not have special qualification.
The present invention also provides a kind of composition that can be used in the control efficiency that improves Tea Saponin and other insecticide compositions; Said composition comprises APG, sodium alginate and fulvic acid; Wherein the weight ratio of APG, sodium alginate and fulvic acid is 2: 1: 5; Or 3: 1: 8,2: 3: 10, other insecticides were Imidacloprid.
The beneficial effect of technique scheme of the present invention is that the Tea Saponin Pesticidal combination of the application of the invention can strengthen the drug effect of agricultural chemicals Tea Saponin, and the desinsection speed of Tea Saponin is provided.Tea Saponin Pesticidal combination of the present invention can also improve the drug effect and quickening drug effect speed of other agricultural chemicals.
Embodiment
In order to understand the present invention, further specify the present invention with embodiment below, but do not limit the present invention.
Embodiment 1 10% Tea Saponin aqueous emulsion
Get Tea Saponin 5kg, APG 2kg, sodium alginate 1kg, fulvic acid 5kg, 37kg water fully mixes, and said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, get 10% Tea Saponin aqueous emulsion.
Embodiment 2 20% Tea Saponin aqueous emulsions
Get Tea Saponin 10kg, APG 3kg, sodium alginate 1kg, fulvic acid 8kg, 28kg water fully mixes, and said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, get 20% Tea Saponin aqueous emulsion.
Embodiment 3 30% Tea Saponin aqueous emulsions
Get Tea Saponin 15kg, APG 2kg, sodium alginate 3kg, fulvic acid 10kg, 20kg water fully mixes, and said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, get 30% Tea Saponin aqueous emulsion.
Embodiment 4 blank liquid
APG 7kg, sodium alginate 8kg, fulvic acid 15kg, 20kg water fully mixes, and said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, get blank liquid.
Embodiment 5 insecticide effect embodiment
10% Tea Saponin aqueous emulsion with embodiment 1-3;, 20% Tea Saponin aqueous emulsion and 30% Tea Saponin aqueous emulsion; And the blank of embodiment 4, the former powder of 60% Tea Saponin (Tea Inst., Chinese Academy of Agricultural Sciences's purchase), be diluted to low age imported cabbageworm on the finite concentration spraying control Chinese cabbage respectively, observe control efficiency then; 1-3 days statistics control efficiency behind the spray medicine, control efficiency accounts for the percentage calculation of diamond-back moth total amount with the quantity of dead low age imported cabbageworm.Valid density is meant and sprays the concentration that contains Tea Saponin in the liquid, sprays blank and sprays according to the extension rate of the aqueous emulsion of embodiment 1.
Concrete outcome such as following table:
Find through experiment, comprise the Tea Saponin aqueous emulsion of APG, fulvic acid and sodium alginate, because the effect of three kinds of auxiliary components makes the Tea Saponin aqueous emulsion increase the speed of killing of imported cabbageworm, and increased insect killing effect.Because auxiliary agent does not have insecticidal activity, so through making the combination of used additives, actual listing provides the insecticide efficiency of Tea Saponin.
The effect that embodiment 6 mixes other insecticides
Get Tea Saponin 10kg, APG 3kg, sodium alginate 1kg, fulvic acid 8kg, the 1kg Imidacloprid, 27kg water fully mixes, and said mixture is extracted into the high shear mixing still, starts the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just can stop high shear after reaching particle diameter 5-15nm, get 22% Tea Saponin Imidacloprid aqueous emulsion.
Control sample is prepared as follows:
Get Tea Saponin 10kg, alkylaryl formaldehyde resin APEO 4kg, sodium lignin sulfonate 3kg, 1kg Imidacloprid; 32kg water fully mixes, and said mixture is extracted into the high shear mixing still; Start the high-shear emulsifying homogenizer, material is carried out high speed shear mix; Just high shear can be stopped after reaching particle diameter 5-15nm, 22% Tea Saponin Imidacloprid aqueous emulsion must be contrasted.
According to the insecticidal effect of diamond-back moth on the method test Chinese cabbage of embodiment 5, valid density is meant Tea Saponin and the concentration of Imidacloprid gross weight in solution.
Experimental result is following:
Can find out that from experimental result through in the composition of Tea Saponin and Imidacloprid, behind adding APG, sodium alginate and the fulvic acid, the desinsection that has strengthened Tea Saponin and imidacloprid composition is renderd a service, and desinsection speed is also accelerated.APG, sodium alginate and fulvic acid can strengthen the drug effect of Tea Saponin and imidacloprid composition thus, and the composition of Tea Saponin, APG, sodium alginate and fulvic acid can strengthen the drug effect of Imidacloprid in other words.