CN103621518A - Pesticide composition containing spiromesifen and biological sources - Google Patents
Pesticide composition containing spiromesifen and biological sources Download PDFInfo
- Publication number
- CN103621518A CN103621518A CN201210313550.XA CN201210313550A CN103621518A CN 103621518 A CN103621518 A CN 103621518A CN 201210313550 A CN201210313550 A CN 201210313550A CN 103621518 A CN103621518 A CN 103621518A
- Authority
- CN
- China
- Prior art keywords
- spiromesifen
- active component
- weight ratio
- pleocidin
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005665 Spiromesifen Substances 0.000 title claims abstract description 88
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 239000000575 pesticide Substances 0.000 title claims abstract description 30
- 239000005660 Abamectin Substances 0.000 claims abstract description 23
- 241000238631 Hexapoda Species 0.000 claims abstract description 22
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 16
- -1 ethyl spinosad Chemical compound 0.000 claims abstract description 9
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract 3
- 239000000375 suspending agent Substances 0.000 claims description 33
- 241000607479 Yersinia pestis Species 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 21
- 239000003094 microcapsule Substances 0.000 claims description 14
- 239000000839 emulsion Substances 0.000 claims description 12
- 239000000725 suspension Substances 0.000 claims description 12
- 241001414989 Thysanoptera Species 0.000 claims description 11
- 230000000035 biogenic effect Effects 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
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- 241001517923 Douglasiidae Species 0.000 claims description 8
- 241000255967 Helicoverpa zea Species 0.000 claims description 8
- 241000255969 Pieris brassicae Species 0.000 claims description 8
- 241000500437 Plutella xylostella Species 0.000 claims description 8
- 241000256247 Spodoptera exigua Species 0.000 claims description 8
- 241001124076 Aphididae Species 0.000 claims description 6
- 239000004530 micro-emulsion Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 241000985245 Spodoptera litura Species 0.000 claims description 5
- 241001182720 Cacopsylla pyrisuga Species 0.000 claims description 4
- 241001347511 Carposina sasakii Species 0.000 claims description 4
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- 235000007164 Oryza sativa Nutrition 0.000 claims description 4
- 244000269722 Thea sinensis Species 0.000 claims description 4
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- 230000002195 synergetic effect Effects 0.000 abstract description 21
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 238000003912 environmental pollution Methods 0.000 abstract description 2
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- 238000001228 spectrum Methods 0.000 abstract description 2
- 239000005930 Spinosad Substances 0.000 abstract 2
- 229940014213 spinosad Drugs 0.000 abstract 2
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 37
- 239000003814 drug Substances 0.000 description 32
- 239000002131 composite material Substances 0.000 description 30
- 230000003449 preventive effect Effects 0.000 description 23
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000013530 defoamer Substances 0.000 description 13
- 239000002270 dispersing agent Substances 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 11
- 229910021641 deionized water Inorganic materials 0.000 description 11
- 239000012071 phase Substances 0.000 description 11
- 239000003995 emulsifying agent Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- 244000061458 Solanum melongena Species 0.000 description 8
- 235000002597 Solanum melongena Nutrition 0.000 description 8
- 239000002562 thickening agent Substances 0.000 description 8
- 231100000820 toxicity test Toxicity 0.000 description 8
- 235000013311 vegetables Nutrition 0.000 description 8
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 7
- 241000488581 Panonychus citri Species 0.000 description 7
- 229950008167 abamectin Drugs 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 229940079593 drug Drugs 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 206010011732 Cyst Diseases 0.000 description 5
- 206010067482 No adverse event Diseases 0.000 description 5
- 230000010165 autogamy Effects 0.000 description 5
- 208000031513 cyst Diseases 0.000 description 5
- 239000004495 emulsifiable concentrate Substances 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 231100000636 lethal dose Toxicity 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 3
- 241001674939 Caulanthus Species 0.000 description 3
- 241000258937 Hemiptera Species 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
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- 241000934064 Acarus siro Species 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 241001525654 Phyllocnistis citrella Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 239000002502 liposome Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000002611 ovarian Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000008569 process Effects 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing spiromesifen and biological sources. The pesticide composition contains an active component A and an active component B. The active component A is spiromesifen, the active component B is selected from anyone of the following compounds: avermectin, spinosad, emamectin benzoate and ethyl spinosad, and the weight ratio of the active component A to the active component B is 1:60-80:1. The pesticide composition can control a plurality of insects, and has obvious synergistic effects. the insecticidal spectrum is enlarged, the pesticide dosage can be lowered, the pesticide residual quantity on crops is lowered, and the environmental pollution is reduced.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application of a kind of composition pesticide containing Spiromesifen and biogenic substances on crop pest.
Technical background
Spiromesifen (Spiromesifen) molecular formula: C
23h
30o
4.The mechanism of action of Spiromesifen is the growth that affects aleyrodid and acarid, disturb the biosynthesis of its liposome, especially larval stage is had to good activity, can also produce ovarian duct closure function simultaneously, the fertility that reduces acarid and adult whitefly, greatly reduces the quantity of laying eggs.
Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin are all the upper conventional biogenic substances insecticides of agricultural, and emamectin-benzoate is called for short " first dimension salt ".
In the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, discovery is mutually composite by Spiromesifen and Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin, there is within the specific limits good synergistic effect, and relevant composite about Spiromesifen and Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin, there is not yet relevant report at present at home and abroad.
Summary of the invention
The object of the invention is to propose a kind of have synergistic function, use cost is low, preventive effect the is good composition pesticide containing Spiromesifen and biogenic substances.
The present invention is achieved through the following technical solutions:
A kind of composition pesticide containing Spiromesifen and biogenic substances, contain active components A and active component B, active components A and active component B weight ratio are 1 ︰ 60 ~ 80 ︰ 1, described active components A is selected from Spiromesifen, and active component B is selected from a kind of in Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin; Active components A and the preferred weight ratio of active component B are 1 ︰ 40 ~ 60 ︰ 1; More preferably the weight ratio of Spiromesifen and Avermectin is 1 ︰ 5 ~ 40 ︰ 1, the weight ratio of Spiromesifen and pleocidin is 1 ︰ 5 ~ 20 ︰ 1, the weight ratio of Spiromesifen and emamectin-benzoate is 1 ︰ 5 ~ 40 ︰ 1, and the weight ratio of Spiromesifen and ethyl pleocidin is 1 ︰ 5 ~ 20 ︰ 1; The weight ratio that most preferably is Spiromesifen and Avermectin is 1 ︰ 1 ~ 20 ︰ 1, the weight ratio of Spiromesifen and pleocidin is 1 ︰ 1 ~ 10 ︰ 1, the weight ratio of Spiromesifen and emamectin-benzoate is 1 ︰ 1 ~ 20 ︰ 1, and the weight ratio of Spiromesifen and ethyl pleocidin is 1 ︰ 1 ~ 10 ︰ 1.
The described composition pesticide containing Spiromesifen and biogenic substances, composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
The described composition pesticide containing Spiromesifen and biogenic substances is for preventing and treating the application of crop pests, and described crops comprise cereal crops, legume crop, fiber crop, sugar [yielding, melon crop, fruits crop, dry fruit crop, hobby crop, root crop, oil crop, flowers crop, medicinal crop, raw material crop, green manure pasture crop; Described insect comprises two spotted spider mite, Tetranychus urticae, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, aleyrodid, thrips, Americal rice leaf miner, cotton bollworm, pear sucker, leaf miner, blister mite, peach fruit borer, aphid, tea lesser leafhopper, tea geometrid, rice leaf roller.
The amount of application when content of active component depends on independent use in the present composition, also depends on mixed ratio and the synergistic effect degree of a kind of compound and another kind of compound, and the while is also relevant with target pest.Conventionally in composition, the weight percentage of active component is gross weight 1%～90%, is preferably 5%～80%.According to different preparation types, active component content scope is different.Conventionally, liquid preparation contains 1%～60% active substance by weight, is preferably 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, is preferably 10%～80%.
In composition pesticide of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 2%～30% of total formulation weight amount, and surplus is solid or liquid diluent.
Composition pesticide of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by processing method known in those skilled in the art, after being about to active component and mixing with liquid flux or solid carrier, then adds surfactant as one or more in dispersant, wetting agent, binding agent, defoamer etc.According to different dosage form, in preparation, can also contain stabilizing agent known in those skilled in the art, antifreeze etc.
When making wetting powder, composition comprises following component and content: active components A 0.1% ~ 80%, active component B0.1% ~ 60%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, filler surplus.
When making water dispersible granules, composition comprises following component and content: active components A 0.1% ~ 80%, active component B0.1% ~ 60%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
When making suspending agent, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, dispersant 1% ~ 10%, wetting agent 1% ~ 10%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making suspension emulsion, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, emulsifier 1% ~ 10%, dispersant 1% ~ 10%, solvent 1% ~ 20%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
When making microemulsion, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, emulsifier 3% ~ 25%, solvent 1% ~ 20%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, deionized water add to 100%.
When making aqueous emulsion, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, solvent 1% ~ 20%, emulsifier 1% ~ 12%, antifreeze 0 ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, deionized water add to 100%.
When making microcapsule suspending agent, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, macromolecule cyst material 1% ~ 10%, dispersant 2% ~ 10%, solvent 1% ~ 10%, emulsifier 1% ~ 7%, pH adjusting agent 0.01% ~ 5%, defoamer 0.01% ~ 2%, deionized water add to 100%.
When making microcapsule suspension-suspending agent, composition comprises following component and content: active components A 0.1% ~ 50%, active component B0.1% ~ 50%, macromolecule cyst material 1% ~ 12%, dispersant 1% ~ 12%, wetting agent 1% ~ 8%, solvent 1% ~ 15%, emulsifier 1% ~ 8%, defoamer 0.01% ~ 2%, thickener 0 ~ 2%, pH adjusting agent 0.01% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspending agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) present composition has good synergy and lasting effect within the specific limits, and preventive effect is higher than single dose, thereby minimizing agricultural chemicals dosage, when reducing peasant's drug cost, reduces the residual quantity of agricultural chemicals on crop, alleviates environmental pollution; (2) between kind, structure differs larger, thereby can delay the resistance generation and development of single dose; (3) expanded insecticidal spectrum, the various pests on crops has been had to greater activity; (4), to person poultry safety, Environmental compatibility is good; And preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 1～12 wetting powder
Spiromesifen, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into wetting powder product of the present invention.Specifically in Table 1.
Table 1 embodiment 1～12 each component and content
Embodiment 13～24 water dispersible granules
Spiromesifen, active component B, dispersant, wetting agent, disintegrant, filler are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent (can add and can not add), obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make water dispersible granules product of the present invention.Specifically in Table 2.
Table 2 embodiment 13～24 each component and content
Embodiment 25～36 suspending agents
Dispersant, wetting agent, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add Spiromesifen, active component B, surplus is supplied by deionized water, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent product of the present invention.Specifically in Table 3.
Table 3 embodiment 25～36 each component and content
Embodiment 37～40 suspension emulsions
Dispersant, defoamer, thickener (can add and can not add), antifreeze (can add and can not add) are mixed through high speed shear, add Spiromesifen, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make Spiromesifen suspending agent, then by active component B, solvent, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make suspension emulsion product of the present invention.Specifically in Table 4.
Table 4 embodiment 37～40 each component and content
Embodiment 41～52 aqueous emulsions
Spiromesifen, active component B, solvent, emulsifier are added together, make to be dissolved into even oil phase; Deionized water, antifreeze (can add and can not add), thickener (can add and can not add), defoamer are mixed, become homogeneous water.Under high-speed stirred, water is added to oil phase, make aqueous emulsion product of the present invention.Specifically in Table 5.
Table 5 embodiment 41～52 each component and content
Table 1 to Avermectin, pleocidin, emamectin-benzoate in table 5 exchanged, can make novel formulation.
Embodiment 53～55 microemulsions
Spiromesifen, active component B are dissolved in the homogenizer that solvent is housed, emulsifier, antifreeze (can add and can not add), defoamer are joined in the homogenizer that above-mentioned solution is housed, surplus gives strong mixing and homogenize after supplying by deionized water, finally obtain the as clear as crystal microemulsion product of the present invention of outward appearance.Specifically in Table 6.
Table 6 embodiment 53～55 each component and content
Embodiment 56～58 microcapsule suspending agents
By Spiromesifen, active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, under shearing condition, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent, dispersant, defoamer, surplus is supplied by deionized water, bi-material reacts at oil-water interfaces, forms macromolecule cyst wall, makes the finely disseminated microcapsule suspending agent product of the present composition.Specifically in Table 7.
Table 7 embodiment 56～58 each component and content
Embodiment 59～61 microcapsule suspensions-suspending agent
By active component B, macromolecule cyst material, solvent, make to be dissolved into even oil phase, oil phase is joined in the aqueous phase solution that contains emulsifier, pH adjusting agent under shearing condition, make finely disseminated microcapsule suspending agent.Dispersant, wetting agent, defoamer, thickener (can add and can not add) are mixed through high speed shear, add Spiromesifen, in ball mill, ball milling is 2 ~ 3 hours, make diameter of particle all below 5 μ m, make suspending agent, then suspending agent is joined in the aqueous phase solution of micro-capsule suspension, deionized water is supplied surplus, makes the finely disseminated microcapsule suspension-suspending agent of present composition product.Specifically in Table 8.
Table 8 embodiment 59～61 each component and content
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in respectively beaker standby.Adopt and first to soak the method that connects worm after leaf, after the blade of the same size that does not contact any medicament is soaked to 5s in the liquid configuring, take out, naturally dry, put into insect box, then connect for examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat examination borer population used be 50, establishes blank simultaneously, in 72h, checks dead borer population, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value to (x), with method of least squares, draws virulence regression equation, and calculates thus the value of every kind of medicament.According to the abundant equation of Sun Yun, calculate co-toxicity coefficient CTC.Computing formula following (take Spiromesifen as standard medicament, its toxicity index is 100):
TI * the P of theoretical toxicity index (TTI)=Spiromesifen of M
spiromesifentI * P of+active component B
effective active composition B
In formula: the mixture that M is different proportionings
P
effective active compositionb is effective active composition B shared ratio in composition
P
spiromesifenfor Spiromesifen shared ratio in composition
B is selected from a kind of in Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin.
Application Example two:
For trying insect: citrus red mite.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective lethal concentration scope of determining the former medicine of Spiromesifen and Avermectin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 9 Spiromesifen and the abamectin compounded toxicity test analysis of results table to citrus red mite
As shown in Table 9, the proportioning of Spiromesifen and abamectin compounded control citrus red mite is when 1 ︰ 60 ~ 80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of Spiromesifen and Avermectin is during at 1 ︰ 5 ~ 40 ︰ 1, synergistic effect is more outstanding, co-toxicity coefficient is all greater than 210, through applicant, test and find that the optimum ratio of Spiromesifen and Avermectin is 40:1, 35:1, 30:1, 25:1, 20:1, 15:1, 14:1, 13:1, 12:1, 11:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, wherein when Spiromesifen and Avermectin weight ratio are 10 ︰ 1, co-toxicity coefficient is maximum, synergistic effect is the most obvious.
Application Example three:
For trying insect: brassicaceous vegetable beet armyworm.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective lethal concentration scope of determining the former medicine of Spiromesifen and pleocidin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 10 Spiromesifen and the pleocidin compound toxicity test analysis of results table to brassicaceous vegetable beet armyworm
As shown in Table 10, the proportioning of Spiromesifen and pleocidin compound control brassicaceous vegetable beet armyworm is when 1 ︰ 60 ~ 80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of Spiromesifen and pleocidin is during at 1 ︰ 5 ~ 20 ︰ 1, synergistic effect is more outstanding, co-toxicity coefficient is all greater than 220, through applicant, test and find that the optimum ratio of Spiromesifen and pleocidin is 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 2:3, 1:2, 1:3, 1:4, 1:5, wherein when Spiromesifen and pleocidin weight ratio are 4 ︰ 1, co-toxicity coefficient is maximum, synergistic effect is the most obvious.
Application Example four:
For trying insect: wild cabbage diamond-back moth.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective lethal concentration scope of determining Spiromesifen and Methylaminoemamectin benzoate and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table to wild cabbage diamond-back moth of table 11 Spiromesifen and emamectin-benzoate
As shown in Table 11, the proportioning of the composite control wild cabbage of Spiromesifen and emamectin-benzoate diamond-back moth is when 1 ︰ 60 ~ 80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of Spiromesifen and emamectin-benzoate is during at 1 ︰ 5 ~ 40 ︰ 1, synergistic effect is more outstanding, co-toxicity coefficient is all greater than 215, through applicant, test and find that the optimum ratio of Spiromesifen and emamectin-benzoate is 40:1, 35:1, 30:1, 25:1, 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, wherein when Spiromesifen and emamectin-benzoate weight ratio are 15 ︰ 1, co-toxicity coefficient is maximum, synergistic effect is the most obvious.
Application Example five:
For trying insect: eggplant thrips.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective lethal concentration scope of determining the former medicine of Spiromesifen and ethyl pleocidin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
The composite toxicity test analysis of results table to eggplant thrips of table 12 Spiromesifen and ethyl pleocidin
As shown in Table 12, the proportioning of the composite control eggplant of Spiromesifen and ethyl pleocidin thrips is when 1 ︰ 60 ~ 80 ︰ 1, co-toxicity coefficient is all greater than 120, illustrate that both are mixed and all show synergistic effect in 1 ︰ 60 ~ 80 ︰ 1 scopes, when the proportioning of Spiromesifen and ethyl pleocidin is during at 1 ︰ 5 ~ 20 ︰ 1, synergistic effect is more outstanding, co-toxicity coefficient is all greater than 220, through applicant, test and find that the optimum ratio of Spiromesifen and ethyl pleocidin is 20:1, 15:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, wherein when Spiromesifen and ethyl pleocidin weight ratio are 4 ︰ 1, co-toxicity coefficient is maximum, synergistic effect is the most obvious.
Through test, find: after Spiromesifen and active component B are composite, the control of two spotted spider mite, Tetranychus urticae, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, aleyrodid, thrips, Americal rice leaf miner, cotton bollworm, pear sucker, leaf miner, blister mite, peach fruit borer, aphid, tea lesser leafhopper, tea geometrid, rice leaf roller is had to obvious synergistic effect, co-toxicity coefficient is all greater than 120.
Application Example six Spiromesifens and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
This experimental establishment is at Shaanxi Province's Hanzhong City, test medicine is researched and developed, is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 24% Spiromesifen suspending agent (autogamy), 1.8% abamectin emulsifiable concentrate (commercial), 25 grams per liter pleocidin suspension (commercial), 2% first dimension salt missible oil (commercial), 60 grams per liter ethyl pleocidin suspending agents (commercial).
Investigation citrus red mite insect pest index before medicine, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 7 days, 20 days, 45 days.Result of the test is as follows:
Table 13 Spiromesifen and active component B and the composite control citrus red mite test of pesticide effectiveness thereof
As can be seen from Table 13, after Spiromesifen and active component B are composite, can effectively prevent and treat citrus red mite, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, and can prevent and treat phyllocnistis citrella stainton, aphid, blister mite, and preventive effect is all greater than 97%.In test scope of medication, target crop is had no adverse effects.
Application Example seven Spiromesifens and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This experimental establishment is in Xianyang, Shanxi province city, test medicine is researched and developed, is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 24% Spiromesifen suspending agent (autogamy), 1.8% abamectin emulsifiable concentrate (commercial), 25 grams per liter pleocidin suspension (commercial), 2% first dimension salt missible oil (commercial), 60 grams per liter ethyl pleocidin suspending agents (commercial).
Before medicine, investigation cotton cotton bollworm insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 14 Spiromesifen and active component B and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 14, after Spiromesifen and active component B are composite, can effectively prevent and treat cotton cotton bollworm, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, and can prevent and treat cotton red spider, whitefly in bt cotton, and preventive effect is all greater than 97%.In test scope of medication, target crop is had no adverse effects.
Application Example eight Spiromesifens and active component B and the composite control brassicaceous vegetable cabbage caterpillar test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, test medicine is researched and developed, is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 24% Spiromesifen suspending agent (autogamy), 1.8% abamectin emulsifiable concentrate (commercial), 25 grams per liter pleocidin suspension (commercial), 2% first dimension salt missible oil (commercial), 60 grams per liter ethyl pleocidin suspending agents (commercial).
Before medicine, investigation brassicaceous vegetable cabbage caterpillar insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 15 Spiromesifen and active component B and the composite control brassicaceous vegetable cabbage caterpillar test of pesticide effectiveness thereof
As can be seen from Table 15, after Spiromesifen and active component B are composite, can effectively prevent and treat brassicaceous vegetable cabbage caterpillar, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, and can prevent and treat brassicaceous vegetable diamond-back moth, beet armyworm, prodenia litura, and preventive effect is all greater than 96%.In test scope of medication, target crop is had no adverse effects.
Application Example nine Spiromesifens and active component B and the composite control tomato aleyrodid test of pesticide effectiveness thereof
This experimental establishment is at Xian District, Shanxi Province suburban area, test medicine is researched and developed, is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 24% Spiromesifen suspending agent (autogamy), 1.8% abamectin emulsifiable concentrate (commercial), 25 grams per liter pleocidin suspension (commercial), 2% first dimension salt missible oil (commercial), 60 grams per liter ethyl pleocidin suspending agents (commercial).
Before medicine, investigation tomato meal mite evil index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 3 days, 7 days, 15 days.Result of the test is as follows:
Table 16 Spiromesifen and active component B and the composite control tomato aleyrodid test of pesticide effectiveness thereof
As can be seen from Table 16, after Spiromesifen and active component B are composite, can effectively prevent and treat tomato aleyrodid, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long.In test scope of medication, target crop is had no adverse effects.
Application Example ten Spiromesifens and active component B and the composite control eggplant thrips test of pesticide effectiveness thereof
This experimental establishment is at Xian District, Shanxi Province suburban area, test medicine is researched and developed, is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 24% Spiromesifen suspending agent (autogamy), 1.8% abamectin emulsifiable concentrate (commercial), 25 grams per liter pleocidin suspension (commercial), 2% first dimension salt missible oil (commercial), 60 grams per liter ethyl pleocidin suspending agents (commercial).
Before medicine, investigation eggplant thrips insect pest index, in the dispenser of insect pest initial stage of origination, investigates insect pest indexes and calculates preventive effect for after dispenser 3 days, 7 days, 20 days.Result of the test is as follows:
Table 17 Spiromesifen and active component B and the composite control eggplant thrips test of pesticide effectiveness thereof
As can be seen from Table 17, after Spiromesifen and active component B are composite, can effectively prevent and treat eggplant thrips, control efficiency is all better than the preventive effect of single dose, and the preventive effect phase is long, and can prevent and treat eggplant two spotted spider mite, aphid, and preventive effect is all greater than 97%.In test scope of medication, target crop is had no adverse effects.
After through different local throughout the country tests, draw, Spiromesifen and Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin composite rear to the preventive effect of the common insect pests such as the two spotted spider mite on crops, Tetranychus urticae, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, aleyrodid, thrips, Americal rice leaf miner, cotton bollworm, whitefly in bt cotton, pear sucker, leaf miner, blister mite, peach fruit borer, aphid, tea lesser leafhopper, tea geometrid, rice leaf roller all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1. the composition pesticide containing Spiromesifen and biogenic substances, it is characterized in that containing active components A and active component B, active components A and active component B weight ratio are 1 ︰ 60 ~ 80 ︰ 1, described active components A is selected from Spiromesifen, and active component B is selected from a kind of in Avermectin, pleocidin, emamectin-benzoate, ethyl pleocidin.
2. the composition pesticide containing Spiromesifen and biogenic substances according to claim 1, is characterized in that: the weight ratio of active components A and active component B is 1 ︰ 40 ~ 60 ︰ 1.
3. the highly effective pesticide composition containing Spiromesifen according to claim 2, is characterized in that:
The weight ratio of Spiromesifen and Avermectin is 1 ︰ 5 ~ 40 ︰ 1;
The weight ratio of Spiromesifen and pleocidin is 1 ︰ 5 ~ 20 ︰ 1;
The weight ratio of Spiromesifen and emamectin-benzoate is 1 ︰ 5 ~ 40 ︰ 1;
The weight ratio of Spiromesifen and ethyl pleocidin is 1 ︰ 5 ~ 20 ︰ 1.
4. according to the composition pesticide of the Spiromesifen described in any one in claims 1 to 3 and biogenic substances, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. the composition pesticide containing Spiromesifen and biogenic substances according to claim 4 is for preventing and treating the application of crop pests.
6. application according to claim 5, is characterized in that: described insect comprises two spotted spider mite, Tetranychus urticae, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, aleyrodid, thrips, Americal rice leaf miner, cotton bollworm, pear sucker, leaf miner, blister mite, peach fruit borer, aphid, tea lesser leafhopper, tea geometrid, rice leaf roller.
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| CN201610250868.6A CN105900985A (en) | 2012-08-30 | 2012-08-30 | Pesticide composition containing spiromesifen and biological source compound |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107517983A (en) * | 2016-06-21 | 2017-12-29 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| WO2025041013A1 (en) * | 2023-08-18 | 2025-02-27 | Geeta Rani | Ternary insecticidal composition comprising spiromesifen, flubendiamide and emamectin benzoate |
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| CN105900985A (en) | 2016-08-31 |
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