CN102365956A - Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds - Google Patents
Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds Download PDFInfo
- Publication number
- CN102365956A CN102365956A CN2011103429301A CN201110342930A CN102365956A CN 102365956 A CN102365956 A CN 102365956A CN 2011103429301 A CN2011103429301 A CN 2011103429301A CN 201110342930 A CN201110342930 A CN 201110342930A CN 102365956 A CN102365956 A CN 102365956A
- Authority
- CN
- China
- Prior art keywords
- bacterium amine
- pyrrole bacterium
- fluorine pyrrole
- pyraclostrobin
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 150000001875 compounds Chemical class 0.000 title abstract description 10
- 239000005782 Fluopicolide Substances 0.000 title abstract description 4
- GBOYJIHYACSLGN-UHFFFAOYSA-N fluopicolide Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CNC(=O)C1=C(Cl)C=CC=C1Cl GBOYJIHYACSLGN-UHFFFAOYSA-N 0.000 title abstract description 4
- 230000001954 sterilising effect Effects 0.000 title abstract 4
- 238000004659 sterilization and disinfection Methods 0.000 title abstract 4
- LQAQMOIBXDELJX-UHFFFAOYSA-N 2-methoxyprop-2-enoic acid Chemical compound COC(=C)C(O)=O LQAQMOIBXDELJX-UHFFFAOYSA-N 0.000 title abstract 2
- 201000010099 disease Diseases 0.000 claims abstract description 24
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 24
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 14
- 206010039509 Scab Diseases 0.000 claims abstract description 9
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 241000221785 Erysiphales Species 0.000 claims abstract description 8
- 241000918585 Pythium aphanidermatum Species 0.000 claims abstract 2
- 241000894006 Bacteria Species 0.000 claims description 157
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical compound [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 claims description 149
- 150000001412 amines Chemical class 0.000 claims description 149
- 239000005869 Pyraclostrobin Substances 0.000 claims description 70
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 70
- -1 methoxy acrylic ester compounds Chemical class 0.000 claims description 32
- 239000000839 emulsion Substances 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 25
- 239000000375 suspending agent Substances 0.000 claims description 25
- 238000009736 wetting Methods 0.000 claims description 20
- 239000004562 water dispersible granule Substances 0.000 claims description 17
- 230000000844 anti-bacterial effect Effects 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 15
- 239000004530 micro-emulsion Substances 0.000 claims description 13
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 12
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 4
- 230000000855 fungicidal effect Effects 0.000 abstract description 3
- 230000002829 reductive effect Effects 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 6
- 239000000417 fungicide Substances 0.000 abstract 2
- 241000322338 Loeseliastrum Species 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 239000002131 composite material Substances 0.000 description 27
- 238000012360 testing method Methods 0.000 description 20
- 239000008367 deionised water Substances 0.000 description 19
- 229910021641 deionized water Inorganic materials 0.000 description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 230000002195 synergetic effect Effects 0.000 description 18
- 230000003449 preventive effect Effects 0.000 description 16
- 239000002270 dispersing agent Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 10
- 230000002528 anti-freeze Effects 0.000 description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 239000002518 antifoaming agent Substances 0.000 description 9
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 9
- 239000000080 wetting agent Substances 0.000 description 9
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 240000008067 Cucumis sativus Species 0.000 description 7
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 7
- 240000008790 Musa x paradisiaca Species 0.000 description 7
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 7
- 241000233629 Phytophthora parasitica Species 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 239000000470 constituent Substances 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 231100000419 toxicity Toxicity 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000004996 alkyl benzenes Chemical class 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 238000009313 farming Methods 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 239000002562 thickening agent Substances 0.000 description 6
- 229920001732 Lignosulfonate Polymers 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 5
- 229910000278 bentonite Inorganic materials 0.000 description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 206010067482 No adverse event Diseases 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 241000233622 Phytophthora infestans Species 0.000 description 4
- 239000005821 Propamocarb Substances 0.000 description 4
- 240000003377 Shepherdia canadensis Species 0.000 description 4
- 235000018324 Shepherdia canadensis Nutrition 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 239000007884 disintegrant Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 4
- 231100000820 toxicity test Toxicity 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 229960000892 attapulgite Drugs 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- HTSABYAWKQAHBT-UHFFFAOYSA-N trans 3-methylcyclohexanol Natural products CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 3
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000007957 coemulsifier Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- NDDVRXSINJWQDX-UHFFFAOYSA-N 1,2,2,3,3,4-hexafluoropyrrole Chemical compound FC=1C(C(N(C=1)F)(F)F)(F)F NDDVRXSINJWQDX-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- UXPRZZZNGFVXRR-UHFFFAOYSA-N 2,3-difluoro-1h-pyrrole Chemical compound FC=1C=CNC=1F UXPRZZZNGFVXRR-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 1
- 241000233654 Oomycetes Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 description 1
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds, in particular a sterilization composition containing an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from fluopicolide; the active ingredient B is selected from any one fungicide of phenylate oxystrobin andpyraclostrobin; furthermore, the weight ratio of the active ingredient A to the active ingredient B is 60:1 to 1:60. The composition disclosed by the invention is capable of controlling a plurality of crop diseases and has obvious synergism; furthermore, the fungicide spectrum is enlarged; the sterilization composition has higher activity on diseases, such as powdery mildew, downy mildew, anthracnose, rust disease, epidemic disease, apple scab, calico, damping off, and the like; in addition, the pesticide use amount is reduced; the residual quantity of pesticide on crops is reduced; and the environmental pollution is lightened.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and methoxy acrylic ester compounds.
Background technology
Fluorine pyrrole bacterium amine, English name: fluopicolide, molecular formula: C
14H
8Cl
3F
3N
2O, chemical name: 2,6-two chloro-N-[(3-chloro-5-trifluoromethyl-2-pyridine radicals) methyl] benzamide.Fluorine pyrrole bacterium amine protectiveness is good, permeability is strong, and the true guiding principle fungus diseases of oomycetes is had higher biologically active, has good control efficiency.Can conduct from leaves of plants basal orientation blade tip direction.To protecting blade not receive infection process after the young shoot processing.Can also distribute from root along the plant xylem to whole strain crop, but can not conduct along phloem.
This product has good system's conductivity and stronger thin layer penetration power, and each main form of pathogen is all had good inhibitory effect, can provide comprehensively and lasting protection for young leaves, stem, stem tuber, young fruit.Since medicament can be through the blade face fast Absorption, so resistance of rainwater washing against, for vegetables diseases prevention in rainy season provides reliable guarantee.
Yet in the real process of agricultural production, preventing and treating the problem that disease is easy to generate most is the drug-fast generation of germ.The different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor research, find fluorine pyrrole bacterium amine and ZJ0712, pyraclostrobin can produce good synergistic effect after composite, and still unexposed about the composite relevant report of fluorine pyrrole bacterium amine and ZJ0712, pyraclostrobin.
Summary of the invention
A kind of bactericidal composition that contains fluorine pyrrole bacterium amine and methoxy acrylic ester compounds; Comprise effective active component, auxiliary agent and filler; It is characterized in that: active components A, B weight ratio are 60: 1～1: 60; Described active components A is selected from fluorine pyrrole bacterium amine, and active component B is selected from a kind of in ZJ0712, the pyraclostrobin.
Described a kind of bactericidal composition that contains fluorine pyrrole bacterium amine and methoxy acrylic ester compounds is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 40.
The said bactericidal composition that contains fluorine pyrrole bacterium amine is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and ZJ0712 is 20: 1～1: 20, is preferably 10: 1～1: 10, more preferably 5: 1～1: 5.
The said bactericidal composition that contains fluorine pyrrole bacterium amine is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and pyraclostrobin is 20: 1～1: 20, is preferably 10: 1～1: 10, more preferably 5: 1～1: 5.
The weight ratio of A, two kinds of active components of B is 60: 1～1: 60.Usually active weight percentage is 0.5～90% of a gross weight in the composition, and preferable is 5%～85%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 1～70% active substance by weight, preferably is 5～50%; Solid pharmaceutical preparation contains 5～85% active substance by weight, preferably is 10～80%.
At least contain a kind of surfactant in the bactericidal composition of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The surfactant that bactericidal composition of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the antifoaming agent one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Described dispersant is selected from alkylnaphthalene sulfonate; Two (alkyl) naphthalenesulfonate formaldehyde condensation compound; Naphthalene sulfonic acid-formaldehyde condensation product; Aryl phenol polyoxyethylene succinate sulfonate; Octylphenol polyethylene oxyethylene group ether sulfate; Polycarboxylate; Lignosulfonates; The alkylaryl APEO; Aliphatic alcohol polyethenoxy base ether; The phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy; Alkyl benzene sulfonate calcium salt; The naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Alkylphenol-polyethenoxy is phonetic; Aliphatic amine polyoxyethylene is phonetic; Polyoxyethylene carboxylate; During the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described thickener is selected from: one or more in CMC, hydroxyethylcellulose, Magnesiumaluminumsilicate, gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, PVPP, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described solvent is selected from: N, dinethylformamide, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, toluene, propyl alcohol, cyclohexanone, acetone, methyl alcohol, ethanol, butanols, EGME, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Described antifoaming agent is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (like capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate); OP series phosphate (NPE phosphate); 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate); Styrene polyoxyethylene ether ammonium sulfate salt; Alkyl biphenyl ether disulfonic acid magnesium salts; Triethanolamine salt; Farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether); Farming newborn 600# (phenyl phenol polyoxy ethyl ether); Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether); Farming newborn 36# (phenethyl fluosite polyoxy ethyl ether); Farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether); Ethylene oxide-propylene oxide block copolymer; OP series (NPE); By series (castor oil polyoxyethylene ether); Farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether); Farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether); Sapn series (sorbitan monostearate); Tween series (sorbitan fatty acid ester APEO); In the AEO series (AEO) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by the preparation of common processing method, is about to active substance and after liquid flux or solid carrier mix, and adds in surfactant such as dispersant, stabilizing agent, wetting agent, adhesive, the antifoaming agent etc. one or more again.
Bactericidal composition of the present invention can be processed into acceptable forms on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
When processing wetting powder, composition comprises following constituent content: fluorine pyrrole bacterium amine 1%～60%, active component B 1%～60%, dispersant 5%～10%, wetting agent 2%～10%, filler surplus.
Active component fluorine pyrrole bacterium amine, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into the wetting powder product of the present composition.
When processing water dispersible granules, composition comprises following constituent content: fluorine pyrrole bacterium amine 1%～60%, active component B 1%～60%, dispersant 3%～12%, wetting agent 1%～8%, disintegrant 1%～10%, binding agent 1%～8%, filler surplus.
Active component fluorine pyrrole bacterium amine, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that article are quantitatively sent the fluidized bed granulation dryer to, makes the water dispersible granules product of the present composition.
Comprise following constituent content when composition is processed suspending agent: active component fluorine pyrrole bacterium amine 1%～50%, active component B 1%～50%, dispersant 2%～10%, wetting agent 2%～10%, antifoaming agent 0.1%～1%, binding agent 0.1%～2%, antifreeze 0.1%～8%, deionized water add to 100%.
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear; Add active component fluorine pyrrole bacterium amine, active component B; Ball milling is 2～3 hours in ball mill; Make diameter of particle all below 5 μ m, make the suspending agent product of the present composition.
Comprise following constituent content when composition is processed suspension emulsion: fluorine pyrrole bacterium amine 1%～50%, effective active composition B 1%～50%, emulsifier 2%～12%, dispersant 2%～10%, antifoaming agent 0.1%～2%, thickener 0.1%～2%, antifreeze 0.1%～8%, stabilizing agent 0.05%～3%, water add to 100%.
Dispersant, antifoaming agent, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of fluorine pyrrole bacterium amine; Ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes fluorine pyrrole bacterium amine suspending agent; Then with the former medicine of effective active composition B, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make present composition suspension emulsion product.
When processing aqueous emulsion, composition comprises following constituent content: fluorine pyrrole bacterium amine 1%～50%, active component B 1%～50%, solvent 2%～10%, emulsifier 2%～12%; Dispersant 2%～10%, co-emulsifier 0.2%～5%, antifreeze 0.1%～8%, antifoaming agent 0.1%～2%, thickener 0.1%～2%, deionized water adds to 100%.
Be dissolved into even oil phase with having former medicine, solvent, emulsifier, co-emulsifier to add together in the above-mentioned prescription, making.Deionized water, dispersant, antifreeze, antifoaming agent, thickener are mixed, become the homogeneous water, under high-speed stirred, water is slowly splashed into oil phase, process the finely disseminated aqueous emulsion product of the present composition.
When processing microemulsion, composition comprises following constituent content: fluorine pyrrole bacterium amine 1%～50%, active component B 1%～50%, and emulsifier 5%～15%, solvent 2%～10%, antifreeze 5%～10%, stabilizing agent 0.5%～3%, deionized water adds to 100%.
Above-mentioned prescription Central Plains medicine, solvent, emulsifier are added in the mother liquor modulation kettle; Make even oil phase; Deionized water, antifreeze etc. is mixed injection product modulation kettle,, mix and process the transparent or semitransparent microemulsion product of the present composition through high-speed stirred.
The invention has the advantages that: after (1) fluorine pyrrole bacterium amine and active component B are composite, have notable synergistic and lasting effect; (2) enlarged fungicidal spectrum, diseases such as powdery mildew, downy mildew, anthracnose, rust, eqpidemic disease, scab, leaf spot, damping off have all been had greater activity; (3) the present invention not with an organic solvent is not difficult for producing poisoning, is convenient to transportation and storage; (4) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution.
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.
Application implementation example one
Instance 1 20% fluorine pyrrole bacterium amine ZJ0712 wetting powder
Fluorine pyrrole bacterium amine 15%, ZJ0712 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 9%, soapberry powder 5%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 20% fluorine pyrrole bacterium amine ZJ0712 wetting powder.
Instance 2 35% fluorine pyrrole bacterium amine ZJ0712 wetting powders
Fluorine pyrrole bacterium amine 20%, ZJ0712 15%, ester polyoxyethylene are phonetic 6%, neopelex 4%, diatomite add to 100%, and mixture carries out comminution by gas stream, makes 35% fluorine pyrrole bacterium amine ZJ0712 wetting powder.
Instance 3 61% fluorine pyrrole bacterium amine ZJ0712 wetting powders
Fluorine pyrrole bacterium amine 1%, ZJ0712 60%, polyoxyethylene carboxylate 8%, lauryl sodium sulfate 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 61% fluorine pyrrole bacterium amine ZJ0712 wetting powder.
Instance 4 20% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules
Fluorine pyrrole bacterium amine 10%, ZJ0712 10%, polycarboxylate 10%, spaonin powder 5%, aluminium chloride 3%, diatomite add to 100%, the mixed 20% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules that gets.
Instance 5 36% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules
Fluorine pyrrole bacterium amine 6%, ZJ0712 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, tea are withered 5%, ammonium sulfate 2.8%, attapulgite add to 100%, mixed 36% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules.
Instance 6 60% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules
Fluorine pyrrole bacterium amine 15%, ZJ0712 45%, lignosulfonates 8%, soapberry powder 5%, sodium carbonate 2%, bentonite add to 100%, the mixed 60% fluorine pyrrole bacterium amine ZJ0712 water dispersible granules that gets.
Instance 7 15% fluorine pyrrole bacterium amine ZJ0712 suspending agents
Fluorine pyrrole bacterium amine 12%, ZJ0712 3%, alkyl benzene sulfonate calcium salt 7%, Nekal BX 3%, silicone 0.4%, hydroxyethylcellulose 0.9%, ethylene glycol 2.2%, deionized water add to 100%, the mixed 15% fluorine pyrrole bacterium amine ZJ0712 suspending agent that gets.
Instance 8 16% fluorine pyrrole bacterium amine ZJ0712 suspending agents
Fluorine pyrrole bacterium amine 6%, ZJ0712 10%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 5%, lauryl sodium sulfate 4%, silicone oil 0.1%, PAA 1.1%, diethylene glycol (DEG) 2.5%, deionized water add to 100%, the mixed 16% fluorine pyrrole bacterium amine ZJ0712 suspending agent that gets.
Instance 9 30% fluorine pyrrole bacterium amine ZJ0712 suspending agents
Fluorine pyrrole bacterium amine 25%, ZJ0712 5%, polycarboxylate 6%, neopelex 4%, C
8～10Aliphatic alcohols 0.2%, xanthans 0.7%, glycerine 2%, deionized water add to 100%, the mixed 30% fluorine pyrrole bacterium amine ZJ0712 suspending agent that gets.
Instance 10 11% fluorine pyrrole bacterium amine ZJ0712 suspension emulsions
Fluorine pyrrole bacterium amine 1%, ZJ0712 10%, polyoxyethylene carboxylate 5%, lauryl sodium sulfate 3%, hydroxyethylcellulose 0.9%, polyethylene glycol 2.8%, silicone 0.3%, agricultural newborn 400#8%, water add to 100%, the mixed 11% fluorine pyrrole bacterium amine ZJ0712 suspension emulsion that gets.
Instance 11 24% fluorine pyrrole bacterium amine ZJ0712 suspension emulsions
Fluorine pyrrole bacterium amine 8%, ZJ0712 16%, alkyl benzene sulfonate calcium salt 6%, sldium lauryl sulfate 4%, xanthans 1%, propane diols 2.5%, silicone 0.2%, alkyl benzene calcium sulfonate 6%, water add to 100%, the mixed 24% fluorine pyrrole bacterium amine ZJ0712 suspension emulsion that gets.
Instance 12 42% fluorine pyrrole bacterium amine ZJ0712 suspension emulsions
Fluorine pyrrole bacterium amine 40%, ZJ0712 2%, lignosulfonates 7%, spaonin powder 3%, Magnesiumaluminumsilicate 1.1%, polyethylene glycol 2.3%, silicone compound 0.4%, styrene polyoxyethylene ether ammonium sulfate salt 5%, water add to 100%, the mixed 42% fluorine pyrrole bacterium amine ZJ0712 suspension emulsion that gets.
Instance 13 10% fluorine pyrrole bacterium amine ZJ0712 microemulsions
Fluorine pyrrole bacterium amine 5%, ZJ0712 5%, 3-methyl cyclohexanol ketenes 4%, methyl alcohol 3%, alkylaryl polyoxyethylene poly-oxygen propylene aether 8%, methylcellulose 0.9%, ethylene glycol 3%, silicone oil 0.2%; Deionized water supplies 100%, the mixed 10% fluorine pyrrole bacterium amine ZJ0712 microemulsion that gets.
Instance 14 30% fluorine pyrrole bacterium amine ZJ0712 microemulsions
Fluorine pyrrole bacterium amine 20%, ZJ0712 10%, cyclohexanone 6%, EGME 4%, Magnesiumaluminumsilicate 0.7%, castor oil polyoxyethylene ether 6%, propane diols 2.5%, silicone 0.1%; Deionized water supplies 100%, makes 30% fluorine pyrrole bacterium amine ZJ0712 microemulsion.
Instance 15 20% fluorine pyrrole bacterium amine ZJ0712 aqueous emulsions
Fluorine pyrrole bacterium amine 8%, ZJ0712 12%, ethyl acetate 5%, acetone 4%, alkyl biphenyl ether disulfonic acid magnesium salts 7%, ethylene glycol 2.1%, xanthans 0.8%, C
8～10Aliphatic alcohols 0.3%, deionized water supplies 100%, makes 20% fluorine pyrrole bacterium amine ZJ0712 aqueous emulsion.
Instance 16 25% fluorine pyrrole bacterium amine ZJ0712 aqueous emulsions
Fluorine pyrrole bacterium amine 5%, ZJ0712 20%, cyclohexanone 4%, acetonitrile 5%, gum Arabic 1.1%, diethylene glycol (DEG) 2.8%, ethylene oxide-propylene oxide block copolymer 7%, silicone compound 0.2%; Deionized water supplies 100%, makes 25% fluorine pyrrole bacterium amine ZJ0712 aqueous emulsion.
Instance 17 15% fluorine pyrrole bacterium amine pyraclostrobin wetting powders
Fluorine pyrrole bacterium amine 5%, pyraclostrobin 10%, naphthalene sulfonic acid-formaldehyde condensation product 8%, wetting and penetrating agent F 5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 15% fluorine pyrrole bacterium amine pyraclostrobin wetting powder.
Instance 18 40% fluorine pyrrole bacterium amine pyraclostrobin wetting powders
Fluorine pyrrole bacterium amine 10%, pyraclostrobin 30%, polycarboxylate 7%, silkworm excrement 5%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 40% fluorine pyrrole bacterium amine pyraclostrobin wetting powder.
Instance 19 61% fluorine pyrrole bacterium amine pyraclostrobin wetting powders
Fluorine pyrrole bacterium amine 1%, pyraclostrobin 60%, lignosulfonates 8%, spaonin powder 4%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 61% fluorine pyrrole bacterium amine pyraclostrobin wetting powder.
Instance 20 25% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules
Fluorine pyrrole bacterium amine 10%, pyraclostrobin 15%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 6%, Nekal BX 4%, ammonium sulfate 2.5%, starch 10%, kaolin add to 100%, the mixed 25% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules that gets.
Instance 21 50% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules
Fluorine pyrrole bacterium amine 15%, pyraclostrobin 35%, alkyl benzene sulfonate calcium salt 8%, lauryl sodium sulfate 7%, aluminium chloride 3%, attapulgite add to 100%, the mixed 50% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules that gets.
Instance 22 60% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules
Fluorine pyrrole bacterium amine 10%, pyraclostrobin 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, soapberry powder 5%, urea 3%, starch add to 100%, the mixed 60% fluorine pyrrole bacterium amine pyraclostrobin water dispersible granules that gets.
Instance 23 12% fluorine pyrrole bacterium amine pyraclostrobin suspending agents
Fluorine pyrrole bacterium amine 6%, pyraclostrobin 6%, polycarboxylate 8%, neopelex 4%, silicone oil 0.2%, methylcellulose 0.9%, triethylene glycol 2.5%, deionized water add to 100%, the mixed 12% fluorine pyrrole bacterium amine pyraclostrobin suspending agent that gets.
Instance 24 30% fluorine pyrrole bacterium amine pyraclostrobin suspending agents
Fluorine pyrrole bacterium amine 12%, pyraclostrobin 18%, lignosulfonates 6%, tea are withered 3%, silicone 0.4%, PAA 1.2%, polyethylene glycol 2%, deionized water add to 100%, mixed 30% fluorine pyrrole bacterium amine pyraclostrobin suspending agent.
Instance 25 40% fluorine pyrrole bacterium amine pyraclostrobin suspending agents
Fluorine pyrrole bacterium amine 8%, pyraclostrobin 32%, aliphatic amine polyoxyethylene are phonetic 7%, Nekal BX 4%, silicone compound 0.3%, Magnesiumaluminumsilicate 0.9%, ethylene glycol 2.7%, deionized water add to 100%, mixed 40% fluorine pyrrole bacterium amine pyraclostrobin suspending agent.
Instance 26 21% fluorine pyrrole bacterium amine pyraclostrobin suspension emulsions
Fluorine pyrrole bacterium amine 20%, pyraclostrobin 1%, ester polyoxyethylene phonetic 5%; Wetting and penetrating agent F 4%, hydroxyethylcellulose 1%, glycerine 2%, silicone oil 0.2%, sorbitan monostearate 8%, water add to 100%, the mixed 21% fluorine pyrrole bacterium amine pyraclostrobin suspension emulsion that gets.
Instance 27 35% fluorine pyrrole bacterium amine pyraclostrobin suspension emulsions
Fluorine pyrrole bacterium amine 5%, pyraclostrobin 30%, alkylnaphthalene sulfonate 6%; Lauryl sodium sulfate 5%, xanthans 1.2%, diethylene glycol (DEG) 2.6%, silicone compound 0.1%, AEO 7%, water add to 100%, the mixed 35% fluorine pyrrole bacterium amine pyraclostrobin suspension emulsion that gets.
Instance 28 20% fluorine pyrrole bacterium amine pyraclostrobin microemulsions
Fluorine pyrrole bacterium amine 15%, pyraclostrobin 5%, N-pyrrolidones 5%, ethyl acetate 3%, sorbitan fatty acid ester APEO 6%, propane diols 2%, C
8～10Aliphatic alcohols 0.3%, deionized water adds to 100%, through the mixed 20% fluorine pyrrole bacterium amine pyraclostrobin microemulsion that gets.
Instance 29 30% fluorine pyrrole bacterium amine pyraclostrobin microemulsions
Fluorine pyrrole bacterium amine 10%, pyraclostrobin 20%, vegetable oil 7%, N; Dinethylformamide 5%, castor oil polyoxyethylene ether 7%, ethylene glycol 2.6%, silicone oil 0.2%; Deionized water adds to 100%, through the mixed 30% fluorine pyrrole bacterium amine pyraclostrobin microemulsion that gets.
Instance 30 12% fluorine pyrrole bacterium amine pyraclostrobin aqueous emulsions
Fluorine pyrrole bacterium amine 10%, pyraclostrobin 2%, propyl alcohol 4%, cyclohexanone 4%, 600# phosphate 6%, glycerine 2.8%, silicone compound 0.1%, deionized water adds to 100%, through the mixed 12% fluorine pyrrole bacterium amine pyraclostrobin aqueous emulsion that gets.
Instance 31 20% fluorine pyrrole bacterium amine pyraclostrobin aqueous emulsions
Fluorine pyrrole bacterium amine 8%, pyraclostrobin 12%, toluene 6%, 3-methyl cyclohexanol ketenes 3%, polyethylene glycol 2.4%, agricultural newborn 400#8%, C
8～10Aliphatic alcohols 0.2%, deionized water adds to 100%, through the mixed 20% fluorine pyrrole bacterium amine pyraclostrobin aqueous emulsion that gets.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect, on this basis, carry out field trial again.
Fluorine pyrrole bacterium amine and active component B (B is selected from a kind of of ZJ0712, pyraclostrobin) are composite to the crop pest Toxicity Determination.
After the effective inhibition concentration scope of each medicament was confirmed in prerun, each medicament was established 5 dosage respectively by active constituent content and is handled, and established the clear water contrast.Carry out with reference to " agricultural chemicals indoor bioassay test rule bactericide ", adopt the mycelial growth rate method to measure the virulence of medicament the crop germ.Measure colony diameter with the right-angled intersection method behind the 72h, calculate and respectively handle clean amount of growth, mycelial growth inhibition rate.
Clean amount of growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, tries to achieve virulence regression equation (y=a+bx) with method of least squares, and calculates the EC of every kind of medicament thus
50Value.Calculate the different proportioning synergy ratios (SR) of two medicaments according to the Wadley method simultaneously, SR＜0.5 is an antagonism, and 0.5≤SR≤1.5 are summation action, and SR＞1.5 are synergistic effect.Computing formula is following:
Wherein: a, b are respectively active component fluorine pyrrole bacterium amine and B (ZJ0712, pyraclostrobin) shared ratio in combination;
A is a fluorine pyrrole bacterium amine;
B is a kind of in ZJ0712, the pyraclostrobin.
It is composite to the cucumber downy mildew Toxicity Determination to practice routine difluoro pyrrole bacterium amine and ZJ0712.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of ZJ0712 and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 1 fluorine pyrrole bacterium amine, ZJ0712 and composite toxicity test analysis of results table thereof to cucumber downy mildew
Can know that by table 1 fluorine pyrrole bacterium amine, ZJ0712 are to the EC of cucumber downy mildew
50Be respectively 1.61mg/L and 0.92mg/L.Fluorine pyrrole bacterium amine and ZJ0712 proportioning were at 60: 1 to 1: 60 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and ZJ0712 were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the two proportioning during at 5: 1 to 1: 5; Synergistic effect is more obviously outstanding, synergy ratio SR maximum when fluorine pyrrole bacterium amine and ZJ0712 weight ratio are 1: 1 wherein, and synergistic effect is the most obvious; Test is found; When the proportioning of fluorine pyrrole bacterium amine and ZJ0712 during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 to powdery mildew, anthracnose, rust, eqpidemic disease, scab, leaf spot, damping off, synergistic effect is obvious, synergy ratio is all greater than 1.5.
Practice example three
Fluorine pyrrole bacterium amine and pyraclostrobin are composite to the banana anthracnose Toxicity Determination.
Test medicine provides by Shaanxi agricultural chemicals Co., Ltd of U.S. nation.
Experimental scheme: effective inhibition concentration scope of confirming fluorine pyrrole bacterium amine, the former medicine of pyraclostrobin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 fluorine pyrrole bacterium amine, pyraclostrobin and composite toxicity test analysis of results table thereof to banana anthracnose
Can know that by table 2 fluorine pyrrole bacterium amine, pyraclostrobin are to the EC of banana anthracnose
50Be respectively 1.89mg/L and 2.03mg/L.Fluorine pyrrole bacterium amine and pyraclostrobin proportioning at 60: 1 to 1: 60 o'clock; Synergy ratio SR is all greater than 1.5; Explaining that fluorine pyrrole bacterium amine and pyraclostrobin were mixed in the scope at 60: 1 to 1: 60 all shows synergistic effect; Especially when the two proportioning during at 5: 1 to 1: 5; Synergistic effect is more obviously outstanding, synergy ratio SR maximum when fluorine pyrrole bacterium amine and pyraclostrobin weight ratio are 1: 1 wherein, and synergistic effect is the most obvious; Test is found; When the proportioning of fluorine pyrrole bacterium amine and pyraclostrobin during at 10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10,1: 11,1: 12,1: 13,1: 14,1: 15,1: 16,1: 17,1: 18,1: 19,1: 20 to powdery mildew, downy mildew, rust, eqpidemic disease, scab, leaf spot, damping off, synergistic effect is obvious, synergy ratio is all greater than 1.5.
Application implementation example tetrafluoro pyrrole bacterium amine and the ZJ0712 and the composite potato late blight test of pesticide effectiveness of preventing and treating thereof
This EE is the Fuyang City Yingshang County in Anhui Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 10% ZJ0712 suspending agent (commercial).
The investigation potato late blight state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 3 fluorine pyrrole bacterium amine, ZJ0712 and the composite potato late blight test of pesticide effectiveness of preventing and treating thereof
Can find out that by table 3 can effectively prevent and treat potato late blight after fluorine pyrrole bacterium amine and ZJ0712 are composite, control efficiency all is superior to the preventive effect of single agent.The target crop is had no adverse effects in the scope of medication in test, simultaneously to the preventive effect of diseases such as downy mildew, powdery mildew, anthracnose, rust, scab, leaf spot, damping off all more than 95%, preventive effect is superior to contrasting medicament, synergistic effect is obvious.
Application implementation example five fluorine pyrrole bacterium amine and the ZJ0712 and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
This EE is the Yan Luochuan County in Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 10% ZJ0712 suspending agent (commercial).
The investigation apple mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 7 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 4 fluorine pyrrole bacterium amine, ZJ0712 and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
Can find out by table 4; Can effectively prevent and treat apple mildew after fluorine pyrrole bacterium amine and ZJ0712 are composite; Control efficiency all is superior to the preventive effect of single agent, the target crop is had no adverse effects in the scope of medication in test, simultaneously to the preventive effect of diseases such as downy mildew, anthracnose, rust, eqpidemic disease, scab, leaf spot, damping off all more than 95%; Preventive effect is superior to contrasting medicament, and synergistic effect is obvious.
Application implementation example hexafluoro pyrrole bacterium amine and the pyraclostrobin and the composite control banana anthracnose test of pesticide effectiveness thereof
This EE is Xuwen County in the Zhanjiang City, Guangdong Province, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 250 grams per liter pyraclostrobin missible oil (commercial).
The investigation banana anthracnose state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 5 fluorine pyrrole bacterium amine, pyraclostrobin and the composite control banana anthracnose test of pesticide effectiveness thereof
Can find out that by table 5 can effectively prevent and treat banana anthracnose after fluorine pyrrole bacterium amine and pyraclostrobin are composite, control efficiency all is superior to the preventive effect of single agent.The target crop is had no adverse effects in the scope of medication in test, simultaneously to the preventive effect of powdery mildew, downy mildew, rust, eqpidemic disease, scab, leaf spot, damping off disease all more than 95%, preventive effect is superior to contrasting medicament, synergistic effect is obvious.
Application implementation example seven fluorine pyrrole bacterium amine and pyraclostrobin and composite control cucumber downy mildew medicine thereof
Imitate test
This EE is Baqiao District in the Xian City, Shanxi Province, and test medicine is provided by Shaanxi agricultural chemicals Co., Ltd of U.S. nation, contrast medicament 687.5 grams per liter fluorine pyrrole bacterium amine propamocarb suspending agents (commercial), 250 grams per liter pyraclostrobin missible oil (commercial).
The investigation cucumber downy mildew state of an illness before the medicine, in the dispenser for the first time of state of an illness initial stage, dispenser in per 10 days once is total to dispenser 2 times.Investigated disease index respectively and calculated preventive effect in 7 days, 14 days, 30 days after the dispenser for the second time.Experimental result is as follows:
Table 6 fluorine pyrrole bacterium amine, pyraclostrobin and the composite control cucumber downy mildew test of pesticide effectiveness thereof
Can find out that by table 6 can effectively prevent and treat cucumber downy mildew after fluorine pyrrole bacterium amine and pyraclostrobin are composite, control efficiency all is superior to the preventive effect of single agent.The target crop is had no adverse effects in the scope of medication in test, simultaneously to the preventive effect of diseases such as powdery mildew, anthracnose, rust, eqpidemic disease, scab, leaf spot, damping off all more than 95%, preventive effect is superior to contrasting medicament, synergistic effect is obvious.
Claims (7)
1. the bactericidal composition of fluorine-containing pyrrole bacterium amine and methoxy acrylic ester compounds; Comprise effective active component, auxiliary agent; It is characterized in that: active components A, B weight ratio are 60: 1～1: 60; Described active components A is selected from fluorine pyrrole bacterium amine, and active component B is selected from a kind of in ZJ0712, the pyraclostrobin.
2. bactericidal composition according to claim 1 is characterized in that: the weight ratio of A, two kinds of active components of B is 40: 1～1: 40.
3. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and ZJ0712 is 20: 1～1: 20.
4. bactericidal composition according to claim 2 is characterized in that: the weight ratio of fluorine pyrrole bacterium amine and pyraclostrobin is 20: 1～1: 20.
5. bactericidal composition according to claim 1 is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
6. bactericidal composition according to claim 1 is used to prevent and treat the application of the disease on cereal class, vegetables, the fruit tree.
7. application according to claim 6 is characterized in that: described disease comprises powdery mildew, downy mildew, anthracnose, rust, eqpidemic disease, scab, leaf spot, damping off.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103429301A CN102365956A (en) | 2011-11-03 | 2011-11-03 | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103429301A CN102365956A (en) | 2011-11-03 | 2011-11-03 | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102365956A true CN102365956A (en) | 2012-03-07 |
Family
ID=45758576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103429301A Pending CN102365956A (en) | 2011-11-03 | 2011-11-03 | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102365956A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919256A (en) * | 2012-11-28 | 2013-02-13 | 河北省农林科学院植物保护研究所 | Fluopicolide-containing compound bactericide and application thereof |
| CN103004822A (en) * | 2013-01-21 | 2013-04-03 | 山东滨农科技有限公司 | Bactericide composition containing pyraclostrobin and fluopicolide |
| CN103070174A (en) * | 2013-01-22 | 2013-05-01 | 海利尔药业集团股份有限公司 | Bactericidal composition containing fluopicolide and cyflufenamid |
| CN104381266A (en) * | 2014-09-25 | 2015-03-04 | 北京燕化永乐生物科技股份有限公司 | Sterilization composition |
| CN104412981A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Antibacterial composition containing fluoride ether bacteria amide and strobilurin |
| CN107125254A (en) * | 2017-05-30 | 2017-09-05 | 兴农药业（中国）有限公司 | A kind of composition pesticide of fluopicolide and pyraclostrobin |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101822263A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
-
2011
- 2011-11-03 CN CN2011103429301A patent/CN102365956A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101822263A (en) * | 2010-01-27 | 2010-09-08 | 深圳诺普信农化股份有限公司 | Sterilization compound containing ZJ0712 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102919256A (en) * | 2012-11-28 | 2013-02-13 | 河北省农林科学院植物保护研究所 | Fluopicolide-containing compound bactericide and application thereof |
| CN103004822A (en) * | 2013-01-21 | 2013-04-03 | 山东滨农科技有限公司 | Bactericide composition containing pyraclostrobin and fluopicolide |
| CN103070174A (en) * | 2013-01-22 | 2013-05-01 | 海利尔药业集团股份有限公司 | Bactericidal composition containing fluopicolide and cyflufenamid |
| CN104412981A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Antibacterial composition containing fluoride ether bacteria amide and strobilurin |
| CN104412981B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of bactericidal composition of fluorine-containing ether bacterium amide and methoxy acrylic |
| CN108812674A (en) * | 2013-09-02 | 2018-11-16 | 张通 | A kind of bactericidal composition of fluorine-containing ether bacterium amide and methoxy acrylic |
| CN104381266A (en) * | 2014-09-25 | 2015-03-04 | 北京燕化永乐生物科技股份有限公司 | Sterilization composition |
| CN107125254A (en) * | 2017-05-30 | 2017-09-05 | 兴农药业（中国）有限公司 | A kind of composition pesticide of fluopicolide and pyraclostrobin |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102172241B (en) | Pesticide composition containing pyraclostrobin and triazoles | |
| CN102302026A (en) | Bactericidal composition containing pyraclostrobin and antibiotic compounds | |
| CN102365956A (en) | Sterilization composition containing fluopicolide and methoxyl acrylic acid ester compounds | |
| CN102258039A (en) | Bactericidal composition containing prothioconazole and thiocarbamates | |
| CN102210309A (en) | Sterilizing composition containing picoxystrobin and triazole | |
| CN102334493B (en) | Novel fluopicolide-containing antibacterial composition | |
| CN102369939A (en) | Bactericidal combination containing fluopicolide and thiocarbamate compound | |
| CN103250717A (en) | Bactericidal composition containing procymidone | |
| CN102057908B (en) | Bactericidal composite containing dithianon and methoxy acrylic esters | |
| CN102308824B (en) | Bactericide composition containing spiroxamine and methoxyl acrylate | |
| CN103461368A (en) | Bactericidal composition containing picoxystrobin and prochloraz and application of bactericidal composition | |
| CN103238608A (en) | Sterilization composition containing fluoxastrobin and antibiotics | |
| CN102428953A (en) | Bactericidal composition containing silthiopham and methoxy acrylate compound | |
| CN102204535A (en) | Antibacterial composition containing picoxystrobin and chlorothalonil | |
| CN102057913B (en) | Bactericidal composition containing triflumizole and triazole compound | |
| CN102204542A (en) | Bactericidal composition containing enostroburin and triazole compound | |
| CN103238621A (en) | Bactericidal composition containing silthiopham and triazole compound | |
| CN102845442B (en) | Bactericidal composition containing polyoxins and iprovalicarb | |
| CN102197820A (en) | Bactericidal composition containing picoxystrobin and benzimidazoles | |
| CN102342287A (en) | Sterilization composition containing fluopicolide and polyoxin | |
| CN102217619B (en) | Bactericidal composition containing enostroburin and carbamates compound | |
| CN102369940A (en) | Bactericidal composite containing fluopicolide and Zhongshengmycin | |
| CN102204544A (en) | Picoxystrobin-containing synergic bactericidal composition | |
| CN102204554A (en) | Antibacterial composition containing trifloxystrobin and carbamate compound | |
| CN102067859A (en) | Bactericidal composition containing ipconazole and thiocarbamate compound |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120307 |