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CN102223762B - High-precision jacquard glass fiber fabric - Google Patents

High-precision jacquard glass fiber fabric Download PDF

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CN102223762B
CN102223762B CN2010101454253A CN201010145425A CN102223762B CN 102223762 B CN102223762 B CN 102223762B CN 2010101454253 A CN2010101454253 A CN 2010101454253A CN 201010145425 A CN201010145425 A CN 201010145425A CN 102223762 B CN102223762 B CN 102223762B
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precision
circuit board
glass fiber
printed circuit
jacquard
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CN102223762A (en
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方新
赵林惠
李军
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Beijing Union University
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Abstract

本发明提供一种高精度印刷电路板的制作方法,采用提花公知织造高精度提花玻璃纤维布基材,将基材预裁剪后浸渍粘合剂并烘干,冷却后根据实际电路进行精确裁剪,并对其进行表面处理、电镀和蚀刻从而获得本发明的高精度印刷电路板。本发明的高精度印刷电路板可以满足小型化、高精度、大批量、高效率生产的需求,具有十分广阔的市场前景。

Figure 201010145425

The invention provides a method for manufacturing a high-precision printed circuit board. The known jacquard weaves a high-precision jacquard glass fiber cloth base material, pre-cuts the base material, impregnates the adhesive and dries it, and performs precise cutting according to the actual circuit after cooling. And it is subjected to surface treatment, electroplating and etching to obtain the high-precision printed circuit board of the present invention. The high-precision printed circuit board of the invention can meet the requirements of miniaturization, high precision, large batch and high efficiency production, and has very broad market prospects.

Figure 201010145425

Description

高精度提花玻璃纤维布High precision jacquard glass fiber cloth

技术领域 technical field

本发明涉及一种印刷电路板的制造方法,其更具体地涉及一种以提花玻璃纤维布为基材制造印刷电路板的方法,其能够适用于高密度、高精度的电子元件安装。The present invention relates to a method for manufacturing a printed circuit board, and more particularly relates to a method for manufacturing a printed circuit board with jacquard glass fiber cloth as a base material, which can be applied to high-density, high-precision electronic component installation.

背景技术 Background technique

近年来,随着电子产品向小型化、薄型化、轻重量化、高性能化的不断发展,其中的印刷电路板在尺寸不断变小的同时却需要在更小的面积上安装更多的电子元件,而在目前形成规模的生产方法中,出于生产效率的考虑,普遍采用流水线自动插装电子元件的方法,对于这样的自动插装技术而言,要求每次插装的电子元件都能够被准确定位在印刷电路板上。In recent years, with the continuous development of electronic products towards miniaturization, thinning, light weight, and high performance, the printed circuit boards need to be installed with more electronic components in a smaller area while the size is getting smaller. , and in the current large-scale production methods, for the sake of production efficiency, the method of automatically inserting electronic components on the assembly line is generally used. For such automatic insertion technology, it is required that the electronic components inserted each time can be accurately positioned on the printed circuit board.

现有技术中的印刷电路板通常采用由玻璃纤维制成的玻璃纤维布作为基材,现有技术中大量使用由喷气织机织成的平纹玻璃纤维布,由于经纱和纬纱会在其表面形成突起的组织点,因此其表面平整度较差通常无法满足高精度、高密度电路板的制作需求,同时,由于玻璃纤维在后续的树脂粘合以及加温加压工艺中会产生膨胀和/或收缩,而平纹织物中经纱纬纱的交织结构会将这种细微的膨胀和/或收缩表现为基材的对角边缘翘曲,这尤其不适合于高精度、高密度电路板。Printed circuit boards in the prior art usually use glass fiber cloth made of glass fiber as the base material. In the prior art, a large number of plain glass fiber cloth woven by air-jet looms are used. Because the warp and weft yarns will form on the surface Protruding tissue points, so its surface flatness is poor and usually cannot meet the production requirements of high-precision and high-density circuit boards. At the same time, due to the expansion and/or Shrinkage, and the interweaving structure of the warp and weft yarns in plain weave fabrics can manifest this slight expansion and/or shrinkage as warping of the diagonal edges of the substrate, which is especially unsuitable for high-precision, high-density circuit boards.

现有技术中还使用由非织造工艺制成的玻璃纤维毡,但对于这种非织造玻璃纤维毡,虽然通过层压工艺能在一定程度上确保其表面平整度,但由于工艺需求,这种纤维毡的厚度通常较厚,这显然不符合小型化、高精度、高密度电路板的需求,同时,这种纤维毡在后续处理之后也会发生一定的翘曲,这同样无法满足高精度、高密度插装电子元件的需求。Also use the glass fiber mat made by non-woven process in the prior art, but for this non-woven glass fiber mat, although its surface flatness can be ensured to a certain extent by lamination process, but due to process requirements, this The thickness of the fiber mat is usually thick, which obviously does not meet the requirements of miniaturization, high precision, and high density circuit boards. At the same time, the fiber mat will also warp to a certain extent after subsequent processing, which also cannot meet the requirements of high precision, high precision, and high density circuit boards. Demand for high-density plug-in electronic components.

因此,随着电路微型化和电路板元件密集化的不断发展,解决印刷电路板上高精度插装电子元件的需求也变得更加迫切。Therefore, with the continuous development of miniaturization of circuits and densification of circuit board components, the demand for high-precision insertion of electronic components on printed circuit boards has become more urgent.

发明内容 Contents of the invention

针对现有技术中印刷电路板的缺陷,本发明要解决的技术问题是现有技术中玻璃纤维布基材表面不平整、易翘曲的问题,提供一种电子元件插装表面平整且不易发生翘曲的印刷电路板制作方法。Aiming at the defects of the printed circuit board in the prior art, the technical problem to be solved by the present invention is the problem that the surface of the glass fiber cloth base material in the prior art is uneven and easy to warp, and a kind of electronic component insertion surface is flat and not easy to be warped. Warped printed circuit board fabrication method.

为解决该技术问题,本发明通过如下的技术方案实现:In order to solve this technical problem, the present invention realizes through following technical scheme:

一种高精度印刷电路板的制作方法,包括如下步骤:提花工艺织造高精度提花玻璃纤维布基材:选取单根玻璃纤维或捻度1.4~2.0转/50毫米之间的低捻度玻璃纤维作为经纱和纬纱进行提花织造,其中所述经纱和纬纱形成大致电路形状的提花图案;预裁剪:根据预设的提花图案进行裁剪;浸渍粘合剂:将裁剪后的玻璃纤维布基材浸渍粘合剂,粘合剂包括如下重量份的原料:45~55份的酚醛树脂,35~45份的环氧树脂,20~40份的溶剂,以及5~35份的助剂,所述溶剂选自二甲基甲酰胺、乙二醇单甲醚、丁酮、丙酮、环己酮、丙二醇单甲醚、丙二醇甲醚醋酸酯和甲苯中的一种或多种,所述助剂包括环氧稀释剂、二氧化硅、阻燃剂、固化引发剂以及交联助剂;粘合剂中另外加入微粒填料,所述微粒填料包括无机填料和/或有机填料,无机填料选自SiC、SiO2、TiO2、Al2O3、MgO和AlN中的一种或多种,有机填料选自苯并二氨基三嗪、聚酰胺、聚酰亚胺、三聚氰氨树脂、环氧树脂中的一种或多种;烘干:180~250℃烘干0.5~1.5小时;待冷却后再根据实际电路板大小进行精确裁剪,并对其进行表面处理、电镀和蚀刻后,即能够获得本发明所述的高精度印刷电路板。A method for manufacturing a high-precision printed circuit board, comprising the following steps: weaving a high-precision jacquard glass fiber cloth base material by a jacquard process: selecting a single glass fiber or a low-twist glass fiber with a twist of 1.4 to 2.0 turns/50 mm as the warp yarn Jacquard weaving with weft yarns, wherein the warp yarns and weft yarns form a roughly circuit-shaped jacquard pattern; pre-cutting: cutting according to a preset jacquard pattern; impregnating adhesive: impregnating the cut glass fiber cloth substrate with adhesive , the adhesive includes the following raw materials in parts by weight: 45 to 55 parts of phenolic resin, 35 to 45 parts of epoxy resin, 20 to 40 parts of solvent, and 5 to 35 parts of auxiliary agent, and the solvent is selected from two One or more of methyl formamide, ethylene glycol monomethyl ether, butanone, acetone, cyclohexanone, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate and toluene, and the additives include epoxy diluent , silicon dioxide, flame retardant, curing initiator and cross-linking aid; in addition, particulate fillers are added to the adhesive, and the particulate fillers include inorganic fillers and/or organic fillers, and the inorganic fillers are selected from SiC, SiO 2 , TiO 2. One or more of Al 2 O 3 , MgO and AlN, and the organic filler is selected from one of benzodiaminotriazine, polyamide, polyimide, melamine resin, and epoxy resin or more; drying: drying at 180-250°C for 0.5-1.5 hours; after cooling, it can be precisely cut according to the size of the actual circuit board, and after surface treatment, electroplating and etching, the circuit board described in the present invention can be obtained. high-precision printed circuit boards.

通过在玻璃纤维布表面对应于电路的区域中形成提花图案,并将经纱和纬纱织成大致的电路形状,可以使得即使玻璃纤维发生细微的膨胀和/或收缩,也能够确保在整个电路相对位置的基本稳定,从而确保各插装位置之间的相对位置不会发生不可预测的变化;采用如本发明所述的粘合剂和填料的组合,可以保证印刷电路板的介电常数较低、介质损耗较小。By forming a jacquard pattern in the area corresponding to the circuit on the surface of the glass fiber cloth, and weaving the warp and weft yarns into a rough circuit shape, it is possible to ensure that the relative position of the entire circuit is maintained even if the glass fiber slightly expands and/or shrinks. basically stable, so as to ensure that the relative positions between the insertion positions will not change unpredictablely; the combination of adhesive and filler as described in the present invention can ensure that the dielectric constant of the printed circuit board is low, The dielectric loss is small.

根据如本发明所述的高精度印刷电路板的制作方法,可以获得表面平整度较高,并且工作耐受温度较高、频率较高、介电常数较低、介质损耗较小的印刷电路板,很好地满足了业界的需求。According to the manufacturing method of the high-precision printed circuit board as described in the present invention, it is possible to obtain a printed circuit board with high surface flatness, high working temperature tolerance, high frequency, low dielectric constant and small dielectric loss , well meet the needs of the industry.

附图说明Description of drawings

图1是本发明高精度玻璃纤维布第一实施例的局部示意图;Fig. 1 is a partial schematic view of the first embodiment of the high-precision glass fiber cloth of the present invention;

图2是本发明高精度玻璃纤维布第二实施例的局部示意图;Fig. 2 is a partial schematic diagram of the second embodiment of the high-precision glass fiber cloth of the present invention;

具体实施方案 specific implementation plan

下面通过几个优选实施例详细描述本发明的具体技术方案Describe the concrete technical scheme of the present invention in detail below by several preferred embodiments

实施例1Example 1

提花织造:选取直径0.009~0.05mm的玻璃纤维,通过提花编织工艺织成如图1所示的电路区域,由于提花机幅宽通常在190~350厘米左右,因此在整个玻璃纤维布的宽度上可以根据需要形成多个如图1所示的相同的电路区域,以满足现代化批量生产的需求,图1中央电路区域就是预设的需要形成电路的区域,在该实施例中,该织物的正面仅能看到经纱1,即最后形成印刷电路板时承载电子元件的一面仅有经纱1或纬纱2。在中央区域以外的其他部分是周围过渡区域,经纱1和纬纱2正常交织形成平纹组织,从而形成牢固的编织结构。Jacquard weaving: select glass fiber with a diameter of 0.009-0.05mm, and weave the circuit area shown in Figure 1 through the jacquard weaving process. Since the width of the jacquard machine is usually about 190-350 cm, the width of the entire glass fiber cloth Multiple identical circuit areas as shown in Figure 1 can be formed as required to meet the needs of modern mass production. The central circuit area in Figure 1 is the preset area that needs to form a circuit. In this embodiment, the front side of the fabric Only warp 1 can be seen, that is, only warp 1 or weft 2 is on the side carrying electronic components when the printed circuit board is finally formed. The rest of the area other than the central area is the surrounding transition area, where the warp 1 and weft 2 are normally interwoven to form a plain weave, thereby forming a firm weave structure.

预裁剪:根据形成中央电路区域的提花形状,进行裁剪,保留部分的周围过渡区域,以确保裁剪获得的玻璃纤维布基材能保持基本的形状。Pre-cutting: Cut according to the jacquard shape forming the central circuit area, and retain some of the surrounding transition areas to ensure that the cut glass fiber cloth substrate can maintain the basic shape.

浸渍粘合剂:将裁剪获得的高精度玻璃纤维布基材浸渍在粘合剂中,所述粘合剂包括如下重量份的原料:45~55份的酚醛树脂,35~45份的环氧树脂,20~40份的溶剂,以及5~35份的助剂,所述溶剂选自二甲基甲酰胺、乙二醇单甲醚、丁酮、丙酮、环己酮、丙二醇单甲醚、丙二醇甲醚醋酸酯和甲苯中的一种或多种,所述助剂包括环氧稀释剂、二氧化硅、阻燃剂、固化引发剂以及交联助剂。粘合剂中另外加入微粒填料,所述微粒填料包括无机填料和/或有机填料,无机填料选自SiC、SiO2、TiO2、Al2O3、MgO和AlN中的一种或多种,有机填料选自苯并二氨基三嗪、聚酰胺、聚酰亚胺、三聚氰氨树脂、环氧树脂中的一种或多种。Adhesive impregnation: The high-precision glass fiber cloth base material obtained by cutting is impregnated in the adhesive. The adhesive includes the following raw materials in parts by weight: 45-55 parts of phenolic resin, 35-45 parts of epoxy Resin, 20-40 parts of solvent, and 5-35 parts of auxiliary agent, the solvent is selected from dimethylformamide, ethylene glycol monomethyl ether, butanone, acetone, cyclohexanone, propylene glycol monomethyl ether, One or more of propylene glycol methyl ether acetate and toluene, and the auxiliary agent includes epoxy diluent, silicon dioxide, flame retardant, curing initiator and crosslinking auxiliary agent. Adding particulate fillers to the binder, the particulate fillers include inorganic fillers and/or organic fillers, and the inorganic fillers are selected from one or more of SiC, SiO 2 , TiO 2 , Al 2 O 3 , MgO and AlN, The organic filler is selected from one or more of benzodiaminotriazine, polyamide, polyimide, melamine resin and epoxy resin.

作为本发明的优选实施方式,印刷电路板使用的粘合剂中的溶剂优选为二甲基甲酰胺和丁酮,也可以包括其它一种或几种混合溶剂,可以任意比例混合。As a preferred embodiment of the present invention, the solvent in the adhesive used for the printed circuit board is preferably dimethylformamide and methyl ethyl ketone, and may also include one or more mixed solvents in any proportion.

烘干:将浸渍粘合剂的玻璃纤维布基材取出,在温度180~250℃烘干1小时。Drying: Take out the glass fiber cloth substrate impregnated with the adhesive, and dry it at a temperature of 180-250°C for 1 hour.

冷却后再根据实际电路板大小进行精确裁剪,并对其进行表面处理、电镀和蚀刻后,即能够获得本发明所述的高精度印刷电路板。After cooling, it is precisely cut according to the size of the actual circuit board, and after surface treatment, electroplating and etching, the high-precision printed circuit board of the present invention can be obtained.

另外,根据印刷电路板的应用场合不同,可以选择将多块浸渍粘合剂的高精度玻璃纤维布层叠再浸渍,通过层叠获得厚度、硬度等满足需要的多层高精度印刷电路板基材。In addition, depending on the application of the printed circuit board, multiple high-precision glass fiber cloths impregnated with adhesives can be layered and then impregnated to obtain a multi-layer high-precision printed circuit board substrate that meets the needs of thickness and hardness.

实施例2Example 2

与实施例1相比,区别在于提花机织造时中央电路区域具有若干个经纱1和纬纱2交织的区域,该交织区域可以根据电路布线的需要进行设计,其不仅可以保证前期整个玻璃纤维布基材中电路区域的结构稳定,还可以用于最后电路板钻孔等。Compared with Example 1, the difference is that the central circuit area has several interweaving areas of warp yarn 1 and weft yarn 2 when the jacquard machine is weaving. The structure of the circuit area in the material is stable, and it can also be used for drilling holes in the final circuit board.

其他步骤同实施例1。Other steps are with embodiment 1.

此外,本实施例2中仅示出了中央区域具有若干个点状交织区域的情况,实际上根据电路布线需要可以设计连续的交织区域,从而使得非交织区域的形状与最后需要形成的电路形状相对应,通过这样设计高精度玻璃纤维布基材,即使由于玻璃纤维在处理过程中发生收缩或拉伸,在整个电路区域中,发生收缩或拉伸的量基本一致,而且其变形方向也完全相同,因此即使整个电路板发生一定的翘曲变形,整个电路的相对位置关系并不会发生不可预测的变化,这样对于高精度电路的设计和插装也是非常有利的。In addition, this embodiment 2 only shows the case where the central region has several dot-shaped interleaving regions. In fact, continuous interweaving regions can be designed according to the needs of circuit wiring, so that the shape of the non-interleaving region is consistent with the final circuit shape to be formed. Correspondingly, by designing the high-precision glass fiber cloth base material in this way, even if the glass fiber shrinks or stretches during processing, the amount of shrinkage or stretching in the entire circuit area is basically the same, and its deformation direction is also completely Similarly, even if the entire circuit board is warped to a certain extent, the relative positional relationship of the entire circuit will not change unpredictablely, which is also very beneficial for the design and insertion of high-precision circuits.

实施例3Example 3

与实施例1和2相比,区别在于提花机织造基布表面具有多个不同的电路区域,即可以根据客户需求数量的不同在连续织造的玻璃纤维布上设计不同的电路形状。Compared with Examples 1 and 2, the difference is that the surface of the Jacquard woven base fabric has multiple different circuit areas, that is, different circuit shapes can be designed on the continuously woven glass fiber cloth according to the different quantities required by customers.

其他步骤同实施例1和2。Other steps are with embodiment 1 and 2.

通过在宽度方向上设置不同的电路区域,可以满足一些小批量可许的需求,同时能够降低整体的织造成本。By arranging different circuit areas in the width direction, some requirements for permitting small batches can be met, and at the same time, the overall weaving cost can be reduced.

Claims (1)

1. the manufacture method of a high accuracy printed circuit board (PCB) comprises the steps:
Jacquard process is weaved high accuracy jacquard weave glass fabric base material: choose the low twist glass fiber of individual glass fibers or the twist 1.4~2.0 between changeing/50 millimeters and carry out jacquard weaving as warp thread and weft yarn, wherein said warp thread and weft yarn form the roughly figured pattern of circuitry shapes;
Pre-cut: the figured pattern according to preset carries out cutting;
Dip bonding agent: with the glass fabric base material dip bonding agent after the cutting; Adhesive comprises the raw material of following weight portion: 45~55 parts phenolic resins; 35~45 parts epoxy resin; 20~40 parts solvent; And 5~35 parts auxiliary agent, said solvent is selected from one or more in dimethyl formamide, glycol monoethyl ether, butanone, acetone, cyclohexanone, propylene glycol monomethyl ether, 1-Methoxy-2-propyl acetate and the toluene, and said auxiliary agent comprises epoxide diluent, silicon dioxide, fire retardant, curing initiator and crosslinking coagent; Add particulate filler in the adhesive in addition, said particulate filler comprises inorganic filler and/or organic filler, and inorganic filler is selected from SiC, SiO 2, TiO 2, Al 2O 3, among MgO and the AlN one or more, organic filler is selected from one or more in benzo diaminourea triazine, polyamide, polyimides, melamine resin, the epoxy resin;
Oven dry: dried 0.5~1.5 hour for 180~250 ℃;
Carry out accurate cutting based on side circuit plate size more after cooling, and after it is carried out surface treatment, plating and etching, promptly obtain the high accuracy printed circuit board (PCB).
CN2010101454253A 2010-04-13 2010-04-13 High-precision jacquard glass fiber fabric Expired - Fee Related CN102223762B (en)

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CN104762726A (en) * 2015-03-30 2015-07-08 安徽丹凤电子材料股份有限公司 Production technology for combined glass fiber cloth
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