CN102031691B - Microcapsule finishing agent, preparation and application of highly dispersed and stable multifunctional core material - Google Patents
Microcapsule finishing agent, preparation and application of highly dispersed and stable multifunctional core material Download PDFInfo
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- CN102031691B CN102031691B CN2010105348319A CN201010534831A CN102031691B CN 102031691 B CN102031691 B CN 102031691B CN 2010105348319 A CN2010105348319 A CN 2010105348319A CN 201010534831 A CN201010534831 A CN 201010534831A CN 102031691 B CN102031691 B CN 102031691B
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- 239000003094 microcapsule Substances 0.000 title claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000011162 core material Substances 0.000 title claims abstract 15
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 25
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 24
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 20
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 20
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 19
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000011709 vitamin E Substances 0.000 claims abstract description 19
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 19
- 229940046009 vitamin E Drugs 0.000 claims abstract description 19
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- 229920006318 anionic polymer Polymers 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 230000007935 neutral effect Effects 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims abstract description 3
- 239000004519 grease Substances 0.000 claims description 29
- 239000006185 dispersion Substances 0.000 claims description 14
- -1 under stirring Substances 0.000 claims description 14
- 238000004945 emulsification Methods 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 11
- 235000019198 oils Nutrition 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 150000007524 organic acids Chemical class 0.000 claims description 6
- 150000007530 organic bases Chemical class 0.000 claims description 6
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 240000008415 Lactuca sativa Species 0.000 claims description 3
- 244000269722 Thea sinensis Species 0.000 claims description 3
- 239000004006 olive oil Substances 0.000 claims description 3
- 235000008390 olive oil Nutrition 0.000 claims description 3
- 235000012045 salad Nutrition 0.000 claims description 3
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
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- 210000004927 skin cell Anatomy 0.000 abstract description 4
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- 229930003231 vitamin Natural products 0.000 abstract description 4
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- 241001122767 Theaceae Species 0.000 abstract 3
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- 238000010438 heat treatment Methods 0.000 abstract 1
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- 230000036541 health Effects 0.000 description 10
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 7
- 229910000077 silane Inorganic materials 0.000 description 7
- 238000005303 weighing Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 241000237502 Ostreidae Species 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000020636 oyster Nutrition 0.000 description 4
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 4
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 4
- 229940113124 polysorbate 60 Drugs 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000001900 immune effect Effects 0.000 description 3
- 238000003760 magnetic stirring Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 150000003722 vitamin derivatives Chemical class 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CITFYDYEWQIEPX-UHFFFAOYSA-N Flavanol Natural products O1C2=CC(OCC=C(C)C)=CC(O)=C2C(=O)C(O)C1C1=CC=C(O)C=C1 CITFYDYEWQIEPX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
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- 239000011257 shell material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000013616 tea Nutrition 0.000 description 2
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- CIOAGBVUUVVLOB-NJFSPNSNSA-N Strontium-90 Chemical compound [90Sr] CIOAGBVUUVVLOB-NJFSPNSNSA-N 0.000 description 1
- 206010047631 Vitamin E deficiency Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 235000010208 anthocyanin Nutrition 0.000 description 1
- 229930002877 anthocyanin Chemical class 0.000 description 1
- 239000004410 anthocyanin Chemical class 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- HVQAJTFOCKOKIN-UHFFFAOYSA-N flavonol Chemical class O1C2=CC=CC=C2C(=O)C(O)=C1C1=CC=CC=C1 HVQAJTFOCKOKIN-UHFFFAOYSA-N 0.000 description 1
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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Landscapes
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
本发明涉及一种高度分散稳定的多功能芯材的微胶囊整理剂、制备和应用，组分包括：维生素E、茶多酚和有机锗，0＜维生素≤10％，0≤茶多酚＜5.5％，0＜有机锗≤2.5％；制备包括：将油脂维生素E、茶多酚、有机锗和有机硅硅偶联剂混合得复合油脂芯材；在加入表面活性剂，升温至30-50℃；滴加含有阴离子高分子乳液稳定剂的水溶液，将复合油脂在水中乳化；在乳化后的体系中调节溶液pH值至3.5-4或调节pH值至7.5-9.5，加热至40-60℃，调pH值至中性，即得。本发明的微胶囊整理剂同时具有维生素E的高效抗氧化、改善皮肤血液循环，增强肌肤细胞活力及延缓衰老的作用，又具有机锗倍的增强人体免疫调节等功能。The invention relates to a highly dispersed and stable multifunctional core material microcapsule finishing agent, preparation and application, the components include: vitamin E, tea polyphenols and organic germanium, 0<vitamins≤10%, 0≤tea polyphenols 5.5%, 0 < organic germanium ≤ 2.5%; preparation includes: mixing oil vitamin E, tea polyphenols, organic germanium and silicone coupling agent to obtain a composite oil core material; adding surfactant, heating to 30-50 ℃; add dropwise an aqueous solution containing an anionic polymer emulsion stabilizer to emulsify the compound oil in water; adjust the pH value of the solution to 3.5-4 or 7.5-9.5 in the emulsified system, and heat to 40-60°C , adjust the pH value to neutral, that is, too. The microcapsule finishing agent of the present invention has the functions of high-efficiency anti-oxidation of vitamin E, improving skin blood circulation, enhancing skin cell vitality and delaying aging, and also has the functions of enhancing human immune regulation twice as much as organic germanium.
Description
Technical field
The invention belongs to fabric microcapsule dressing agent, preparation and Application Areas, particularly relate to microcapsule dressing agent, preparation and the application of the stable multi-functional core of a kind of high degree of dispersion.
Background technology
Textiles at first is warming as its major function to keep out the cold in the historical process of the mankind's development; Development and progress along with society; Textiles combines with life fashion, quality; Popular colour, popular money look emerge in an endless stream, and in this in riotous profusion piece market, the appearance of health textile more and more causes people's attention.
So-called health textile is put health substance on the clothing in order exactly, slowly discharges then, contacts with the direct of skin through clothes; Health substance is to the infiltration of the pore of skin and be absorbed by the body; Replenish the various materials of needed by human body, reach health-care function, improve user's the general level of the health.
Vitamin e deficiency comprises: red blood cell is destroyed, the sex change of muscle, anemia, reproductive dysfunction.
Vitamin E can promote human body metabolism, and enhancing body endurance improves immunity.In addition, vitamin E is a kind of high-efficiency antioxidant agent, can protect biomembrane to avoid suffering the infringement of peroxide, plays and improves cutaneous circulation, strengthens skin cell vitality and function in delaying senility.Lack it, can produce adverse consequences such as skin is dry, coarse, overaging.Vitamin E mainly be to obtain from nut fruits food, can be absorption of human body also through skin.Human body skin will be nursed by Germany textile production company and anti-aging function combines; Developed the vitamin E finishing agent, this finishing agent is a kind of special textile finish, and is effective with its premature senescence resistance; Get into fashionable health-oriented products ranks; Can be used for the multiple textiles that directly contacts with human body skin, particularly underwear, bedding, shirt, socks and sportswear etc., also can be used for women's family health care clothes.
Tea Polyphenols is the general name of polyphenols in the tealeaves, comprises flavanol compound, anthocyanin class, flavonoids, flavonols and phenolic acid class etc.Wherein important with flavanol compound material (catechin).Tea Polyphenols claims that again tea is tanned or tea tannin, is one of Main Ingredients and Appearance that forms the tealeaves color, smell and taste, also is one of Main Ingredients and Appearance that has in the tealeaves health care.Japan's thousand scientists research shows; Detoxifcation of Tea Polyphenols isoreactivity material tool and radiation resistance can stop radioactive substance to invade marrow effectively, and strontium 90 and cobalt 60 are excreted rapidly; Tea Polyphenols has very strong antioxidation simultaneously; Its oxidation resistance is artificial synthetized oxidation preventive agent BHT, BHA 4-6 a times, is 6-7 times of VE, and the 5-10 of VC doubly.
Research shows that germanium is a kind of element that human body needs, and it has multiple function.Because it has dehydrogenation enriched in oxygen function, can make physical efficiency keep sufficient oxygen, thereby safeguard the health of human body.Functions such as organic germanium has the hematopoietic stimulation system, participates in internal metabolism, oxygen coalescence, delays senility, immunological regulation.Therefore; Chemist in the world, pharmacologist and nutritionist give the jinx of organic germanium sesquioxide " people " type disease ", " 21 century help germanium " many good names, and gradually it is applied in cosmetics and skincare product, Medicines and Health Product and the food additives.
The rich germanium finishing agent HGE5600 of Germany He Te global group; Contain organic germanium compound and have the physiological function of promotion normalization, improve the human immunologic function, prevent and treat the effect of multiple disease; Can be used for the processing of fabrics such as cotton, hair, silk, the fabric after the processing has lasting health care.
The domestic germanium finishing functions liquid that relevant scholar is also arranged at the research used for textiles makes textiles obtain new application prospect through the germanium finishing functions processing to textiles.
Summary of the invention
Technical problem to be solved by this invention provides microcapsule dressing agent, preparation and the application of the stable multi-functional core of a kind of high degree of dispersion; This microcapsule dressing agent have simultaneously vitamin E high-efficiency antioxidant, improve cutaneous circulation; Strengthen skin cell vitality and function in delaying senility, the organic germanium of having again functions such as enhances human body immunological regulation doubly.
The microcapsule dressing agent of the multi-functional core that a kind of high degree of dispersion of the present invention is stable; Component comprises: vitamin E, Tea Polyphenols and organic germanium; The content of three kinds of materials in microcapsules is respectively: 0＜vitamin E≤10%, 0≤Tea Polyphenols＜5.5%, 0＜organic germanium≤2.5%.
The preparation method of the microcapsule dressing agent of the multi-functional core that a kind of high degree of dispersion of the present invention is stable comprises:
(1) with grease vitamin E, Tea Polyphenols, organic germanium and organosilicon silicone couplet mix compound grease core; Tea Polyphenols is 0-5.5% in the wherein compound grease core, and vitamin E is 0.01-10%, and organic germanium is 0.01-2.5%, and organo-silicon coupling agent is 50-80%;
(2) add surfactant at above-mentioned compound grease core, under stirring condition, be warming up to 30-50 ℃; Dropping contains the aqueous solution of 0-3% anionic polymer emulsion stabilizer, under agitation with the emulsification in water of compound grease; Wherein surfactant to the consumption of compound grease core at 1%-12%; The content of compound oil phase is 1-15% in the emulsification system, and emulsification times was at 2-4 hour;
(3) Dropwise 5 % organic acid regulator solution pH value to 3.5-4 or organic base regulated the pH value to 7.5-9.5 in the system after step (2) emulsification; Be heated to 40-60 ℃, insulation 1-5h, adjust pH is to neutral; Finish reaction, obtain the stable dispersion of microcapsules system of oyster white high degree of dispersion.
Grease in the said step (1) is edible oil and fat or Synthetic Oil: edible salad oil, olive oil or synthetic polyoxyethylene-oxypropylene copolymer etc.
Adopt organo-silicon coupling agent for becoming shell material, under acidity or alkali condition, the organo-silicon coupling agent hydrolytic condensation forms shell structure; Adopt the alkyl such as the octyl group of three ethyoxyls of organo-silicon coupling agent or a methoxyl group and a backbone, or ester group such as acryllic acid butyl ester base, or contain the substituting group etc. of phenyl ring.
Organo-silicon coupling agent in the said step (1) is that structural formula is: [R
1O]
3SiR
2
Wherein: R
1For: CH
3-, CH
3CH
2-
R
2For: CH
3[CH
2] nCH
2-wherein n is 0-10;
R
2Also can be-CH
2CH2COO [CH
2] nCH
3Wherein n is 0-10
R
2Also can for:
Organo-silicon coupling agent in the said step (1) can be triethoxy butyl propionate base silane.
Surfactant in the said step (2) is this dish 60 and polysorbate60.
Surfactant in the said step (2) to the consumption of compound grease core at 3%-8%
Anionic polymer emulsion stabilizer in the said step (2) is CMC, CMS, acrylic acid-copolymer-maleic anhydride etc.
Organic acid in the said step (3) is a citric acid, and organic base is a triethanolamine.
The rate of addition of organic acid or organic base is 0.5mL/min in the said step (3).
The microcapsule dressing agent of multi-functional core of the present invention, through padding or infusion process is applied on the fabric, under the effect of adhesive, microcapsules can anchor on the textiles, keep certain durability.Microcapsule dressing agent can be absorbed through human body skin after being applied on the fabric, realizes the health-care function to human body.Said fabric is main with natural fabric, as cotton, numb, especially more suitable with cotton fabric.
Beneficial effect
(1) microcapsule dressing agent of multi-functional core of the present invention have simultaneously vitamin E high-efficiency antioxidant, improve cutaneous circulation, strengthen skin cell vitality and function in delaying senility, the organic germanium of having again functions such as enhances human body immunological regulation doubly; Nutriment is absorbed by human body through the skin of human body in this microcapsule dressing agent;
(2) the used for textiles microcapsule dressing agent of the multi-functional core of the present invention is used for the multifunctionality of textiles processing can raising textiles, satisfies the demands of consumers, realize the high added value of textiles.
The specific embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in the restriction scope of the present invention.Should be understood that in addition those skilled in the art can do various changes or modification to the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Embodiment 1
Taking by weighing salad oil, vitamin E, Tea Polyphenols, organic germanium and triethoxy butyl propionate base silane respectively stirs under magnetic stirring apparatus and obtains compound grease; Polyphenol content is 1.5% in compound grease, vitamin content E is 5%, organic germanium content is 0.01%, triethoxy butyl propionate base silane 60%.
Taking by weighing the compound grease of 10 grams adds in the three-necked bottle; And add compound grease and weigh 2.1% this Pan 60 and 2.9% polysorbate60; Under stirring condition, be warming up to the 30-50 degree, will contain the 85 gram aqueous solution of 0-3% anionic polymer emulsion stabilizer CMC, be added drop-wise in the oil phase; With the emulsification in water of compound grease, the machinery emulsification time was at 2-4 hour under magnetic agitation.
To 3.5-4, be heated to 60 ℃ with the speed Dropwise 5 % citric acid adjust pH of 0.5mL/min, insulation 2.5h is warming up to 90 ℃ then, continues reaction 1h.To neutral, finish reaction with the triethanolamine adjust pH.Be cooled to 25 ℃, obtain the stable micro-capsule dispersion liquid of oyster white high degree of dispersion.
Embodiment 2
Taking by weighing olive oil, vitamin E, Tea Polyphenols, organic germanium and triethoxy butyl propionate base silane respectively stirs under magnetic stirring apparatus and obtains compound grease; Polyphenol content is 0.1% in compound grease, vitamin content E is 5.5%, organic germanium content is 2.5%, triethoxy butyl propionate base silane 80%.
Taking by weighing the compound grease of 10 grams adds in the three-necked bottle; And add compound grease and weigh 2.1% this Pan 60 and 2.9% polysorbate60; Under stirring condition, be warming up to the 30-50 degree, will contain the 85 gram aqueous solution of 0-3% anionic polymer emulsion stabilizer CMS, be added drop-wise in the oil phase; With the emulsification in water of compound grease, the machinery emulsification time was at 2-4 hour under magnetic agitation.
Speed Dropwise 5 % triethanolamine adjust pH to 8.5 with 0.5mL/min is heated to 60 ℃, and insulation 2.5h is warming up to 90 ℃ then, continues reaction 1h.To neutral, finish reaction with the acetate adjust pH.Be cooled to 25 ℃, obtain the stable micro-capsule dispersion liquid of oyster white high degree of dispersion.
Embodiment 3
Taking by weighing polyoxyethylene-oxypropylene copolymer, vitamin E, Tea Polyphenols, organic germanium and triethoxy butyl propionate base silane respectively stirs under magnetic stirring apparatus and obtains compound grease; Polyphenol content is 2.5% in compound grease, vitamin content E is 10%, organic germanium content is 1.0%, triethoxy butyl propionate base silane 50%.
Taking by weighing the compound grease of 10 grams adds in the three-necked bottle; And add compound grease and weigh 2.1% this Pan 60 and 2.9% polysorbate60; Under stirring condition, be warming up to the 30-50 degree, will contain the 85 gram aqueous solution of 0-3% anionic polymer emulsion stabilizer acrylic acid ester-copolymer-maleic anhydride, be added drop-wise in the oil phase; With the emulsification in water of compound grease, the machinery emulsification time was at 2-4 hour under magnetic agitation.
Speed Dropwise 5 % triethanolamine adjust pH to 8.5 with 0.5mL/min is heated to 60 ℃, and insulation 2.5h is warming up to 90 ℃ then, continues reaction 1h.To neutral, finish reaction with the acetate adjust pH.Be cooled to 25 ℃, obtain the stable micro-capsule dispersion liquid of oyster white high degree of dispersion.
Embodiment 4
All-cotton fabric vitamin E/organic germanium composite micro-capsule finishing technique:
Microcapsules arrangement 30g among technology preparation: the embodiment 1
Low-temperature adhesive (40%) 45g
Water X
Add up to: 1000g
Technological process:
COTTON FABRIC----hot-air seasoning--120 degree bake 3 (min)---finished product that pads (pick-up rate 130%)
Claims (6)
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| CN103741495A (en) * | 2014-01-03 | 2014-04-23 | 天津工业大学 | Bionic finishing technique for treating cotton fabric by adopting natural functional substances of extra-strong tea stems |
| CN104988716A (en) * | 2015-06-11 | 2015-10-21 | 江苏阳光股份有限公司 | Non-ironing processing method of cotton shirt with physiotherapy function |
| CN105361141A (en) * | 2015-10-12 | 2016-03-02 | 十堰天翔生物科技股份有限公司 | Compound oil microcapsule capable of enhancing immunity and preparation method thereof |
| CN105693756A (en) * | 2016-02-27 | 2016-06-22 | 北京林业大学 | Novel silane coupling agents with ester groups and synthesizing method thereof |
| CN107050055A (en) * | 2017-04-20 | 2017-08-18 | 陈溢民 | A kind of donkey-hide gelatin microcapsules dermalaxia film and preparation method |
| CN110804859A (en) * | 2019-10-25 | 2020-02-18 | 嘉兴市秀洲恒丰纺织有限公司 | Finishing process of vitamin skin-care health-care cellulose fabric |
| CN110820358A (en) * | 2019-10-25 | 2020-02-21 | 嘉兴市秀洲恒丰纺织有限公司 | Finishing process of vitamin skin-care health-care real silk fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1510209A (en) * | 2002-12-25 | 2004-07-07 | 刘光恩 | Fabric with vitamin release function and producing method thereof |
| CN1190549C (en) * | 2002-03-07 | 2005-02-23 | 南京中脉科技发展有限公司 | Weight-lossing fabric and its preparing process |
| KR100500115B1 (en) * | 2003-07-02 | 2005-07-07 | 주식회사 보국전자 | Textile and the manufacture method that Bitamin E and anion are included |
| DE102008032206A1 (en) * | 2008-07-09 | 2010-01-14 | Henkel Ag & Co. Kgaa | Perfumed laundry softener |
| CN101649543A (en) * | 2008-08-13 | 2010-02-17 | 浙江康丝丽家居科技有限公司 | Process for producing organic germanium silk quilt |
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| WO2001062376A1 (en) * | 2000-02-23 | 2001-08-30 | Henkel Kommanditgesellschaft Auf Aktien | Microcapsules and/or nanocapsules |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1190549C (en) * | 2002-03-07 | 2005-02-23 | 南京中脉科技发展有限公司 | Weight-lossing fabric and its preparing process |
| CN1510209A (en) * | 2002-12-25 | 2004-07-07 | 刘光恩 | Fabric with vitamin release function and producing method thereof |
| KR100500115B1 (en) * | 2003-07-02 | 2005-07-07 | 주식회사 보국전자 | Textile and the manufacture method that Bitamin E and anion are included |
| DE102008032206A1 (en) * | 2008-07-09 | 2010-01-14 | Henkel Ag & Co. Kgaa | Perfumed laundry softener |
| CN101649543A (en) * | 2008-08-13 | 2010-02-17 | 浙江康丝丽家居科技有限公司 | Process for producing organic germanium silk quilt |
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