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CN101880131A - Production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter - Google Patents

Production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter Download PDF

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Publication number
CN101880131A
CN101880131A CN 201010196056 CN201010196056A CN101880131A CN 101880131 A CN101880131 A CN 101880131A CN 201010196056 CN201010196056 CN 201010196056 CN 201010196056 A CN201010196056 A CN 201010196056A CN 101880131 A CN101880131 A CN 101880131A
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film
ito
flow
coating chamber
substrate
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胡安春
吴勇
温景成
吴永光
董坚
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Shenzhen Leaguer Film Technology Co ltd
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Shenzhen Leaguer Film Technology Co ltd
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Abstract

The invention relates to a production method of a low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of a color filter, belonging to the technical field of filter coating. The production method comprises the following processing steps of: A. cleaning a substrate, and then carrying out flat plate cleaning and hot-air drying; B. mounting the substrate for coating, wherein SiO2 is firstly coated, the heating temperature of the substrate is 210-250 DEG C, the transmission speed frequency in a coating chamber is 7.0-13.0Hz, a SiO2 film is coated by using two polycrystalline silicon targets, and processing conditions are as follows: the flow of O2 is 35Sccm, the flow of Ar is 200-220Sccm, the vacuum degree is 3.0*10<-1>-4.5*10<-1>Pa, and the total air pressure is 0.40-0.45Pa; and C. coating an ITO film, wherein the ITO film is coated by using six ITO targets, and processing conditions are as follows: the flow of Ar in the coating chamber is 200-220Sccm, and the vacuum degree of the coating chamber is 4.0*10<-1>-4.5*10<-1>Pa. The production method has the advantages of simple process and high product qualification rate.

Description

The production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter
Technical field:
The present invention relates to a kind of production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it belongs to the coating technique field of spectral filter.
Background technology:
Colored filter is widely used in mobile phone, digital camera, Digital Video, PDA, MP4, vehicle-carrying display screen, Industry Control panel etc.Along with the market requirement of this type of consumption electronic product constantly increases, colored filter has vast market prospect, and the development of colored filter has the good market space.The colored filter production technology, contain photoetching technique, cleaning technique, the film thickness monitoring technology, section difference control techniques, the live width control techniques, total spacing control techniques, the control of figure aligning accuracy, surface quality control techniques etc., and colored filter low temperature plating ITO be indium tin oxide conductive film is the gordian technique that colored filter is produced, there is following problem in its production technology at present: be easy to generate color exception, pin hole exceeds standard, beat arc, the defective of membrane uniformity difference, cause the colored filter Show Color unusual, short circuit, open circuit or the like is bad, qualification rate is on the low side, has a strong impact on the quality of colorized optical filtering flake products.
Summary of the invention:
The object of the present invention is to provide and a kind ofly can guarantee that the colored filter color of producing is normal, the production method of the low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter that product percent of pass is high.
The object of the present invention is achieved like this:
A kind of production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it comprises following processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 210 ℃~250 ℃, and coating chamber transmission speed frequency is 7.0Hz~13.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
The production method of described low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 250 ℃, and coating chamber transmission speed frequency is 11.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
The production method of described low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter is characterized in that it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 230 ℃, and coating chamber transmission speed frequency is 9.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
The production method of described low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 210 ℃, and coating chamber transmission speed frequency is 7.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
The production method of described low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 240 ℃, and coating chamber transmission speed frequency is 12.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
The saturating conducting film of low square resistance ITO that the present invention adopts low temperature, many target position sputtering method to be coated with on colored filter substrate, because resistance is low, can play energy-saving and cost-reducing effect, owing to adopt low temperature, many target position sputtering method plated film, effectively colored filter substrate is aging behind the fragmentation of colored filter substrate and the plated film, has improved the qualification rate of product.
Embodiment:
Embodiment 1
Earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques; The substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 250 ℃, and coating chamber transmission speed frequency is 11.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa; Plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
Test result: the SiO of basic unit 2Thickness is 200 SiO 2Transmitance is 90.5%; ITO thickness 2300 ~2500
Figure BSA00000146259800053
ITO face resistance is 8 Ω/~10 Ω/, and transmitance (550nm wavelength) is 〉=81.0%, color even, and the product final inspection is qualified.
Embodiment 2
Earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques; The substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 230 ℃, and coating chamber transmission speed frequency is 9.0Hz, at No. 4 chamber plating SiO 2, O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa, uses 2 polycrystalline silicon targets to plate SiO 2Film, 6 ITO target plating ITO films, coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.Test result: the SiO of basic unit 2Thickness is 150
Figure BSA00000146259800061
~200
Figure BSA00000146259800062
SiO 2Transmitance is 90.5%; ITO thickness 2500
Figure BSA00000146259800063
~2800
Figure BSA00000146259800064
ITO face resistance is 7 Ω/~8 Ω/, and transmitance (550nm wavelength) is 〉=82.0%, color even, and the product final inspection is qualified.
Embodiment 3
Earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques; The substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 210 ℃, and coating chamber transmission speed frequency is 7.0Hz, at No. 4 chamber plating SiO 2, O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa, uses 2 polycrystalline silicon targets to plate SiO 2Film, 6 ITO target plating ITO films, coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.Test result: the SiO of basic unit 2Thickness is 150
Figure BSA00000146259800071
~200
Figure BSA00000146259800072
SiO 2Transmitance is 90.5%; ITO thickness 2800
Figure BSA00000146259800073
~3500
Figure BSA00000146259800074
ITO face resistance is 5 Ω/~7 Ω/, and transmitance (550nm wavelength) is 〉=83.0%, color even, and the product final inspection is qualified.
Embodiment 4
Earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques; The substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 240 ℃, and coating chamber transmission speed frequency is 12.0Hz, at No. 4 chamber plating SiO 2, O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa, uses 2 SiO 2Target plates SiO 2Film, 6 ITO target plating ITO films, coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.Test result: the SiO of basic unit 2Thickness is 150
Figure BSA00000146259800075
~200
Figure BSA00000146259800076
The SiO2 transmitance is 90.5%; ITO thickness 2000
Figure BSA00000146259800077
~2300
Figure BSA00000146259800078
ITO face resistance is 10 Ω/~12 Ω/, and transmitance (550nm wavelength) is 〉=81.0%, color even, and the product final inspection is qualified.
Embodiment 5
Earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques; The substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 240 ℃, and coating chamber transmission speed frequency is 13.0Hz, at No. 4 chamber plating SiO 2, O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa, uses 2 polycrystalline silicon targets to plate SiO 2Film uses 2 ITO targets to plate the ITO film, 6 ITO target plating ITO films, and coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.Test result: the SiO of basic unit 2Thickness is 150
Figure BSA00000146259800081
~200
Figure BSA00000146259800082
SiO 2Transmitance is 90.5%; ITO thickness 1800
Figure BSA00000146259800083
~2000
Figure BSA00000146259800084
ITO face resistance is 12 Ω/~15 Ω/, and transmitance (550nm wavelength) is 〉=83.0%, color even, and the product final inspection is qualified.

Claims (5)

1. the production method of a low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter, it comprises following processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 210 ℃~250 ℃, and coating chamber transmission speed frequency is 7.0Hz~13.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
2. the production method of the low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter described in claim 1 is characterized in that it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 250 ℃, and coating chamber transmission speed frequency is 11.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
3. the production method of the low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter described in claim 1 is characterized in that it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 230 ℃, and coating chamber transmission speed frequency is 9.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
4. the production method of the low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter described in claim 1 is characterized in that it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 210 ℃, and coating chamber transmission speed frequency is 7.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
5. the production method of the low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter described in claim 1 is characterized in that it comprises following concrete processing step:
A: earlier carry out the ultrasonic cleaning substrate, carry out again that flat board cleans, heat is dried dry according to routine techniques;
B: the substrate of the above-mentioned processing load of putting on the shelf is carried out plated film, earlier plating SiO 2, plated film employing power is closed the vertical full-automatic continuous magnetron sputtering coating equipment of film science and technology, and substrate heating temperature is 240 ℃, and coating chamber transmission speed frequency is 12.0Hz, uses 2 polycrystalline silicon targets to plate SiO No. 4 chamber 2Film, its processing condition are: O 2Flow is 35Sccm, Ar flow 200~220Sccm, vacuum tightness 3.0 * 10 -1Pa~4.5 * 10 -1Between the Pa, total gas pressure is 0.40~0.45Pa;
C: plate the ITO film again: use 6 ITO target plating ITO films, processing condition are: coating chamber Ar flow is 200~220Sccm, coating chamber vacuum tightness 4.0*10 -1Pa~4.5*10 -1Between the Pa.
CN 201010196056 2010-06-09 2010-06-09 Production method of low-temperature coated ITO (Indium Tin Oxide) transparent conductive film of color filter Pending CN101880131A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106544644A (en) * 2016-10-27 2017-03-29 广东星弛光电科技有限公司 A kind of anti-fingerprint handset touch panel colour coating process
CN110928012A (en) * 2019-12-06 2020-03-27 深圳市康盛光电科技有限公司 Anti-electric breakdown preparation method of ITO conductive film for light modulation film

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CN2516564Y (en) * 2001-12-03 2002-10-16 深圳豪威真空光电子股份有限公司 On-line joint coating device with intermediate-frequeney reactive sputtering silica for indium oxide tin glass
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US7215391B2 (en) * 2004-07-16 2007-05-08 United Microelectronics Corp. Liquid crystal on silicon display with micro color filters positioned on the top surface of the transparent substrate
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CN2441813Y (en) * 2000-08-18 2001-08-08 深圳威士达真空系统工程有限公司 Gas isolator for reaction sputtering silicon dioxide and conductive film contineous plating
US7070987B2 (en) * 2000-10-30 2006-07-04 Sru Biosystems, Inc. Guided mode resonant filter biosensor using a linear grating surface structure
CN2516564Y (en) * 2001-12-03 2002-10-16 深圳豪威真空光电子股份有限公司 On-line joint coating device with intermediate-frequeney reactive sputtering silica for indium oxide tin glass
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106544644A (en) * 2016-10-27 2017-03-29 广东星弛光电科技有限公司 A kind of anti-fingerprint handset touch panel colour coating process
CN110928012A (en) * 2019-12-06 2020-03-27 深圳市康盛光电科技有限公司 Anti-electric breakdown preparation method of ITO conductive film for light modulation film

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