CN101878778A - Stable acephate abamectin missible oil - Google Patents
Stable acephate abamectin missible oil Download PDFInfo
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- CN101878778A CN101878778A CN2010102229816A CN201010222981A CN101878778A CN 101878778 A CN101878778 A CN 101878778A CN 2010102229816 A CN2010102229816 A CN 2010102229816A CN 201010222981 A CN201010222981 A CN 201010222981A CN 101878778 A CN101878778 A CN 101878778A
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- China
- Prior art keywords
- acephate
- stable
- missible oil
- abamectin
- abamectin missible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005660 Abamectin Substances 0.000 title claims abstract description 43
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 title claims abstract description 42
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 title claims abstract description 28
- 229950008167 abamectin Drugs 0.000 title claims abstract description 28
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract 2
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- 230000003078 antioxidant effect Effects 0.000 claims description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- 239000001294 propane Substances 0.000 claims description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 11
- 241000607479 Yersinia pestis Species 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000575 pesticide Substances 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 241000254127 Bemisia tabaci Species 0.000 abstract description 3
- 241000426497 Chilo suppressalis Species 0.000 abstract description 3
- 241000255967 Helicoverpa zea Species 0.000 abstract description 3
- 241000255969 Pieris brassicae Species 0.000 abstract description 3
- 241000985245 Spodoptera litura Species 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 241000008892 Cnaphalocrocis patnalis Species 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 241000488583 Panonychus ulmi Species 0.000 abstract 1
- 241000500441 Plutellidae Species 0.000 abstract 1
- 241001249129 Scirpophaga incertulas Species 0.000 abstract 1
- 230000009885 systemic effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 12
- 241000238631 Hexapoda Species 0.000 description 10
- 241000500437 Plutella xylostella Species 0.000 description 9
- 230000003449 preventive effect Effects 0.000 description 6
- 239000003814 drug Substances 0.000 description 5
- 239000003905 agrochemical Substances 0.000 description 4
- 241001454293 Tetranychus urticae Species 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000003958 fumigation Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241001517923 Douglasiidae Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 241000176086 Sogatella furcifera Species 0.000 description 1
- 241000488533 Tetranychus viennensis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- -1 lactone compounds Chemical class 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000003012 network analysis Methods 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 210000004894 snout Anatomy 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide preparation, in particular to stable acephate abamectin missible oil. The stable acephate abamectin missible oil is prepared by mixing the following raw materials in percentage by weight: 1 to 40 percent of acephate, 0.1 to 5 percent of abamectin, 0.1 to 20 percent of stabilizing agent, 1 to 10 percent of emulsifying agent, and 25 to 97.8 percent of solvent. The stable acephate abamectin missible oil has the following advantages and beneficial effects: (1) the stable acephate abamectin missible oil improves the control effect on resistant pests, further enlarges the control spectrum to the pests, the suitable occasions and the serviceable range, and has excellent control effect on rice leaf rollers, striped rice borers, yellow rice borers, diamond back moths, cabbage worms, bemisia tabaci, prodenia litura, cotton bollworms, red spiders and the like; (2) the stable acephate abamectin missible oil has systemic properties and strong permeability, is long in lasting period and is environment-friendly; (3) a product of the stable acephate abamectin missible oil has high storage stability and a long guarantee period; and (4) the stable acephate abamectin missible oil reduces the used amount of the abamectin, the manufacturing cost and the use cost.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, specifically a kind of stable acephate abamectin missible oil.
Background technology
Because the agricultural chemicals abuse makes insect more and more serious to the resistance that agricultural chemicals produces, and causes single pesticidal preparations pest control effect to reduce year by year.The composite conduct of insecticide delays one of effective means that insect develops immunity to drugs and comes into one's own just day by day.
Orthene is the good alternative kind of height organophosphorous pesticide, belongs to the lower toxicity broad-spectrum organic insecticide, has very strong interior suction, stomach toxicity and action of contace poison, and can kill ovum.The drug effect height, the lasting period was 15 days.Insecticidal spectrum is wide, can prevent and treat more than 100 kind of chewing type, sucking pest, evil mite, some lepidoptera pests are had concurrently certain fumigation action, be applicable to crop pest controls such as grain, cotton, oil, vegetables, fruit tree, tea, mulberry, beet, sugarcane, herbage, good especially to the rice fulgorid drug effect.Safety is good, and the half life period in plant tissue is 5～10 days, is 0.5～4 day in general soil, in clayed soil 6～13 days.Unicellular alga so that inanimate object enrichment phenomenon all in mammal and the bird body, to aquatic livestock safety such as fish.
Avermectin is a kind of ten hexa-atomic Macrocyclic lactone compounds that have desinsection, kill mite, eelworm-killing activity, is a kind of antibiotics novel agrochemical.Insecticidal spectrum is wide, is mainly used to prevent and treat pear sucker, cotten aphid etc. in China, the insect of leaf mining such as Americal rice leaf miner etc., evil mite such as Tetranychus urticae, tea orange tetranychid, tetranychus viennensis and the host is wide, feeding habits are assorted insect such as diamond-back moth etc.Insect and mite class had tag and stomach poison function and faint fumigation action is arranged.Blade is had very strong osmosis, can kill subepidermal insect, and the longevity of residure is long.Damage to beneficial insect is little.In soil, degraded inanimate object enrichment, environmental friendliness rapidly by microorganism.
The synergistic complex of agricultural chemicals is the effective measures that the expanding prevention spectrum improves preventive effect.Though it is existing many at present relevant with the report of orthene as the compounded preparation of pesticide of one of active component, but Shang Weiyou is with orthene and the two report as the Pesticidal combination registration listing of active component of Avermectin, the present invention establishes physicochemical property, processing technology, the synergy preventive and therapeutic effect of this novel mixture get off in a creative way, having solved the stability problem of active component, is a kind ofly good can effectively reduce applications of pesticide amount, delay the target organisms pesticide resistance, reduce the orthene of environmental pollution and the complex preparation of Avermectin.
Summary of the invention
Purpose of the present invention is exactly by the network analysis to orthene and abamectin pest killing characteristic, and both are composite according to certain ratio, obtains a kind of stable acephate abamectin missible oil.Antagonism insect of the present invention has better effect, and rice fir leaf roll snout moth's larva, striped rice borer, paddy stem borer, diamond-back moth, cabbage caterpillar, Bemisia tabaci, prodenia litura, cotton bollworm, two spotted spider mite etc. are all had excellent preventive effect.
The present invention is made up of the former medicine of orthene, the former medicine of Avermectin, solvent, emulsifier and stabilizing agent, and its each composition and percentage by weight thereof are:
Orthene 1～40%
Avermectin 0.1～5%
Emulsifier 1～10%
Stabilizing agent 0.1～20%
Solvent 25～97.8%.
Optimized technical scheme of the present invention is:
Orthene 20%
Avermectin 4%
Emulsifier 6%
Stabilizing agent 10%
Solvent 60%.
In the invention described above, described stabilizing agent be 2-expoxy propane, isopropyl alcohol, n-butanol, ethylene glycol, polyethylene glycol, propane diols, glycerine, turpentine oil, urea, antioxidant BHT, antioxidant BHA, DAA, acetone, cyclohexanone and stabilizing agent known in those skilled in the art any one or multiple, preferably urea, antioxidant BHT, antioxidant BHA, N-Methyl pyrrolidone, acetone or cyclohexanone.More preferably urea, antioxidant BHA and N-Methyl pyrrolidone were by weight 1: 1: 1 mixture.The adding stabilizing agent can increase the physics and the chemical stability of mixture.
Among the present invention, described emulsifier is any one or the multiple combination among emulsifier 500#, 600#, 700#, 1600#, phenolic ether emulsifier, fatty alcohol emulsifier and the emulsifier known in those skilled in the art.Described solvent is any one or multiple combination of methyl alcohol, ethanol, dimethyl formamide, dimethylacetylamide, methyl-sulfoxide and solvent known in those skilled in the art.
Preparation method of the present invention is dissolved in orthene and Avermectin in the solvent, drops into emulsifier then, stirs, and then drops into stabilizing agent, stirs, and promptly obtains acephate abamectin missible oil.
Advantage that the present invention has and beneficial effect: (1) the present invention has improved the preventive effect of antagonism insect, and has further enlarged control spectrum and the applicable situation and the scope of application to insect.Rice leaf roller, striped rice borer, paddy stem borer, diamond-back moth, cabbage caterpillar, Bemisia tabaci, prodenia litura, cotton bollworm, two spotted spider mite etc. all there is excellent preventive effect; (2) absorption and strong permeability in the present invention has concurrently, the lasting period is long, and is environmentally friendly; (3) product storage-stable of the present invention is good, long shelf-life; (4) the present invention has reduced the consumption of Avermectin, has reduced manufacturing cost and use cost, and market is acceptant, is beneficial to popularization; (5) production technology of the present invention is simple relatively, the simple easy operating of equipment.
Embodiment
Below in conjunction with embodiment the present invention is described further:
Embodiment 1
Preparation method of the present invention is dissolved in orthene 20% and Avermectin 4% in 60% alcohol solvent, drop into the emulsifier of 3%500# and 3%600# then, stir, then drop into 10% stabilizing agent, stabilizing agent is the mixture that urea, antioxidant BHA and N-Methyl pyrrolidone were formed by weight 1: 1: 1, stir, promptly obtain acephate abamectin missible oil.
Embodiment 2
Preparation method of the present invention is dissolved in orthene 1% and Avermectin 0.1% in 97.8% alcohol solvent, drop into the emulsifier of 1%600# then, stir, then drop into 0.1% urea as stabilizing agent, stir, promptly obtain acephate abamectin missible oil.
Embodiment 3
Preparation method of the present invention is dissolved in orthene 20% and Avermectin 0.5% in 67% alcohol solvent, dropping into 1% 600# emulsifier, 1% fatty alcohol, 4% 1600# emulsifier then stirs, then drop into 0.5% urea, 4%2-expoxy propane, 2% isopropyl alcohol and stir, promptly obtain acephate abamectin missible oil.
Embodiment 4
Preparation method of the present invention is dissolved in orthene 30% and Avermectin 1% in 62% alcohol solvent, dropping into 2% fatty alcohol then stirs, then drop into the 4%2-expoxy propane, 2% isopropyl alcohol stirs, and promptly obtains acephate abamectin missible oil.
Embodiment 5
Preparation method of the present invention is dissolved in orthene 40% and Avermectin 5% in 47% alcohol solvent, dropping into 1% 600# emulsifier, 1% phenolic ether emulsifier, 4% 1600# emulsifier then stirs, then drop into 0.5% polyethylene glycol, 1%2-expoxy propane, 0.5% cyclohexanone and stir, promptly obtain acephate abamectin missible oil.
Present composition application dosage is according to all multifactor variations such as different occasions, crop species, time of application and weather conditions and difference is generally 200～300g/667m
2The employing cauline leaf is used, and for example the cauline leaf spraying is handled.1000 times of liquid controls of the missible oil that the present invention produces diamond-back moth is implemented 1 method according to test, and 7d is 87.2% to the preventive effect of diamond-back moth after medication.
Experimental example 1 control diamond-back moth field control effectiveness test
Table 1 20.5% acephate abamectin missible oil control diamond-back moth field control effectiveness test result
Wherein
1000 times of A:20% orthene dilutions
1000 times of B:0.5% Avermectin dilutions
1000 times of AB:20.5% acephate abamectin missible oil dilutions
Experimental example 2 synergism tests
Immersion method is adopted in this test, according to the preliminary experiment result concentration gradient of each medicament is set, and 20 diamond-back moth 2 instar larvaes of every processing repeat 3 times.In certain density soup, soak the several seconds with fresh free of contamination Chinese cabbage leaf, dry, connect diamondback moth larvae, be placed in the culture dish, check the larva death condition behind the 48h.Calculate lethality, corrected mortality, virulence regression equation and LC thereof
50Result of the test shows CTC value 〉=240.7, shows to have synergistic effect (seeing Table 2).
Table 2 20.5% acephate abamectin missible oil synergism test result
Wherein
A:20% orthene missible oil (the Hubei sand swell reaches);
B:0.5% abamectin emulsifiable concentrate (the Hubei sand swell reaches).
Claims (4)
1. stable acephate abamectin missible oil, it is to be mixed with by following raw materials by weight to form:
Orthene 1～40%, Avermectin 0.1～5%, stabilizing agent 0.1～20%, emulsifier 1～10%, solvent 25～97.8%.
2. a kind of stable acephate abamectin missible oil according to claim 1, wherein said stabilizing agent are one or more the compositions in 2-expoxy propane, isopropyl alcohol, n-butanol, ethylene glycol, polyethylene glycol, propane diols, glycerine, turpentine oil, urea, antioxidant BHT, antioxidant BHA, DAA, acetone, cyclohexanone or the N-Methyl pyrrolidone.
3. a kind of stable acephate abamectin missible oil according to claim 1, wherein said emulsifier can be any one or the multiple compositions in farm chemical emulgent 500#, 600#, 700#, 1600#, phenolic ether emulsifier, the fatty alcohol emulsifier.
4. a kind of stable acephate abamectin missible oil according to claim 1, wherein said solvent are any one or the multiple combinations in methyl alcohol, ethanol, dimethyl formamide, dimethylacetylamide or the methyl-sulfoxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102229816A CN101878778A (en) | 2010-07-06 | 2010-07-06 | Stable acephate abamectin missible oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102229816A CN101878778A (en) | 2010-07-06 | 2010-07-06 | Stable acephate abamectin missible oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101878778A true CN101878778A (en) | 2010-11-10 |
Family
ID=43051031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102229816A Pending CN101878778A (en) | 2010-07-06 | 2010-07-06 | Stable acephate abamectin missible oil |
Country Status (1)
| Country | Link |
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| CN (1) | CN101878778A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105557769A (en) * | 2016-01-29 | 2016-05-11 | 卞佳林 | Rice chilo suppressalis pesticide and preparation method thereof |
| CN110447640A (en) * | 2019-07-17 | 2019-11-15 | 中国农业大学 | A kind of orthene missible oil and preparation method thereof |
-
2010
- 2010-07-06 CN CN2010102229816A patent/CN101878778A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 姚安庆等: "乙酰甲胺磷和阿维菌素混配对小菜蛾的防治效果", 《湖北农业科学》 * |
| 张峰等: "20%阿维·乙酰甲WP 防治水稻纵卷叶螟、大螟试验总结", 《农业装备技术》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105557769A (en) * | 2016-01-29 | 2016-05-11 | 卞佳林 | Rice chilo suppressalis pesticide and preparation method thereof |
| CN110447640A (en) * | 2019-07-17 | 2019-11-15 | 中国农业大学 | A kind of orthene missible oil and preparation method thereof |
| CN110447640B (en) * | 2019-07-17 | 2023-02-28 | 中国农业大学 | A kind of acephate emulsifiable concentrate and preparation method thereof |
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Application publication date: 20101110 |