CN102273444A - Ultralow volume liquid containing thiamethoxam - Google Patents
Ultralow volume liquid containing thiamethoxam Download PDFInfo
- Publication number
- CN102273444A CN102273444A CN2011102699534A CN201110269953A CN102273444A CN 102273444 A CN102273444 A CN 102273444A CN 2011102699534 A CN2011102699534 A CN 2011102699534A CN 201110269953 A CN201110269953 A CN 201110269953A CN 102273444 A CN102273444 A CN 102273444A
- Authority
- CN
- China
- Prior art keywords
- thiophene worm
- low volume
- ultra low
- worm piperazine
- weight content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005941 Thiamethoxam Substances 0.000 title abstract description 8
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 title abstract description 8
- 239000004560 ultra-low volume (ULV) liquid Substances 0.000 title abstract 4
- 239000002904 solvent Substances 0.000 claims abstract description 27
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 241000209094 Oryza Species 0.000 claims abstract description 12
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims abstract description 10
- 239000005660 Abamectin Substances 0.000 claims abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 10
- 235000009566 rice Nutrition 0.000 claims abstract description 10
- 239000005885 Buprofezin Substances 0.000 claims abstract description 9
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 claims abstract description 9
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract description 9
- 241000176086 Sogatella furcifera Species 0.000 claims abstract description 8
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims abstract description 8
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 241000426497 Chilo suppressalis Species 0.000 claims abstract description 3
- 241001556089 Nilaparvata lugens Species 0.000 claims abstract description 3
- 241001161749 Stenchaetothrips biformis Species 0.000 claims abstract description 3
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 132
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 116
- 229930192474 thiophene Natural products 0.000 claims description 66
- 239000007788 liquid Substances 0.000 claims description 58
- 241000238631 Hexapoda Species 0.000 claims description 41
- 238000005507 spraying Methods 0.000 claims description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 16
- -1 polyoxyethylene, phenethyl phenol Polymers 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 241001124076 Aphididae Species 0.000 claims description 12
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 claims description 10
- 239000005899 Fipronil Substances 0.000 claims description 10
- 229940013764 fipronil Drugs 0.000 claims description 10
- 150000002576 ketones Chemical class 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 9
- NHOIBRJOQAYBJT-IMGVWCFESA-N nimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4OC(C)=O)C(=O)OC)C)CC(=O)OC)C=COC=1 NHOIBRJOQAYBJT-IMGVWCFESA-N 0.000 claims description 9
- ZQIYJHBQRBBBRZ-UHFFFAOYSA-N nimbin Natural products COC(=O)CC1C2C(C(OC(=O)C)C3OC4CC(C(=C4C13C)C)c5cocc5)C(C)(C=CC2=O)C(=O)OC ZQIYJHBQRBBBRZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 241000675108 Citrus tangerina Species 0.000 claims description 7
- 150000001408 amides Chemical class 0.000 claims description 7
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- 241001498622 Cixius wagneri Species 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000010452 phosphate Substances 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 241000270322 Lepidosauria Species 0.000 claims description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 150000003851 azoles Chemical class 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 4
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims description 4
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 4
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- 241001465828 Cecidomyiidae Species 0.000 claims description 4
- 241001364569 Cofana spectra Species 0.000 claims description 4
- 241000578422 Graphosoma lineatum Species 0.000 claims description 4
- 235000018519 Scolymus Nutrition 0.000 claims description 4
- 240000005687 Scolymus hispanicus Species 0.000 claims description 4
- 244000269722 Thea sinensis Species 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 4
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 claims description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 239000010773 plant oil Substances 0.000 claims description 4
- 239000002798 polar solvent Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 3
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 3
- 240000003768 Solanum lycopersicum Species 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- YQZBFMJOASEONC-UHFFFAOYSA-N 1-Methyl-2-propylbenzene Chemical compound CCCC1=CC=CC=C1C YQZBFMJOASEONC-UHFFFAOYSA-N 0.000 claims description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- 241001014341 Acrosternum hilare Species 0.000 claims description 2
- 241000239290 Araneae Species 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- 241001347511 Carposina sasakii Species 0.000 claims description 2
- 241000008892 Cnaphalocrocis patnalis Species 0.000 claims description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 2
- 239000001293 FEMA 3089 Substances 0.000 claims description 2
- 241001515929 Fulmekiola serrata Species 0.000 claims description 2
- 244000068988 Glycine max Species 0.000 claims description 2
- 235000010469 Glycine max Nutrition 0.000 claims description 2
- 241000661348 Leptocorisa acuta Species 0.000 claims description 2
- 241000594036 Liriomyza Species 0.000 claims description 2
- 241001179564 Melanaphis sacchari Species 0.000 claims description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 241000437063 Phyllotreta striolata Species 0.000 claims description 2
- 241000500437 Plutella xylostella Species 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 241000339374 Thrips tabaci Species 0.000 claims description 2
- 241000669245 Unaspis Species 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021329 brown rice Nutrition 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229960001760 dimethyl sulfoxide Drugs 0.000 claims description 2
- 230000009189 diving Effects 0.000 claims description 2
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 2
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 2
- 229940093471 ethyl oleate Drugs 0.000 claims description 2
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 2
- 229940073769 methyl oleate Drugs 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- 210000004894 snout Anatomy 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- 229940116411 terpineol Drugs 0.000 claims description 2
- GYICYQJEVCIYJY-UHFFFAOYSA-N thiophen-1-ylidenemethanone Chemical compound O=C=S1C=CC=C1 GYICYQJEVCIYJY-UHFFFAOYSA-N 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 7
- 239000004480 active ingredient Substances 0.000 abstract description 6
- 239000005886 Chlorantraniliprole Substances 0.000 abstract description 4
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract description 3
- 229950008167 abamectin Drugs 0.000 abstract description 3
- 230000000361 pesticidal effect Effects 0.000 abstract description 3
- 239000005878 Azadirachtin Substances 0.000 abstract description 2
- 239000005901 Flubendiamide Substances 0.000 abstract description 2
- 239000005925 Pymetrozine Substances 0.000 abstract description 2
- VEHPJKVTJQSSKL-UHFFFAOYSA-N azadirachtin Natural products O1C2(C)C(C3(C=COC3O3)O)CC3C21C1(C)C(O)C(OCC2(OC(C)=O)C(CC3OC(=O)C(C)=CC)OC(C)=O)C2C32COC(C(=O)OC)(O)C12 VEHPJKVTJQSSKL-UHFFFAOYSA-N 0.000 abstract description 2
- FTNJWQUOZFUQQJ-IRYYUVNJSA-N azadirachtin A Natural products C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C/C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-IRYYUVNJSA-N 0.000 abstract description 2
- ZGNITFSDLCMLGI-UHFFFAOYSA-N flubendiamide Chemical compound CC1=CC(C(F)(C(F)(F)F)C(F)(F)F)=CC=C1NC(=O)C1=CC=CC(I)=C1C(=O)NC(C)(C)CS(C)(=O)=O ZGNITFSDLCMLGI-UHFFFAOYSA-N 0.000 abstract description 2
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 abstract description 2
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 abstract description 2
- 241000098289 Cnaphalocrocis medinalis Species 0.000 abstract 1
- 241001466042 Fulgoromorpha Species 0.000 abstract 1
- 241001470017 Laodelphax striatella Species 0.000 abstract 1
- FTNJWQUOZFUQQJ-NDAWSKJSSA-N azadirachtin A Chemical compound C([C@@H]([C@]1(C=CO[C@H]1O1)O)[C@]2(C)O3)[C@H]1[C@]23[C@]1(C)[C@H](O)[C@H](OC[C@@]2([C@@H](C[C@@H]3OC(=O)C(\C)=C\C)OC(C)=O)C(=O)OC)[C@@H]2[C@]32CO[C@@](C(=O)OC)(O)[C@@H]12 FTNJWQUOZFUQQJ-NDAWSKJSSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 16
- 239000002917 insecticide Substances 0.000 description 13
- 239000003814 drug Substances 0.000 description 10
- 239000000575 pesticide Substances 0.000 description 10
- 239000003905 agrochemical Substances 0.000 description 7
- 235000013305 food Nutrition 0.000 description 7
- 238000001228 spectrum Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 230000010534 mechanism of action Effects 0.000 description 6
- 231100000419 toxicity Toxicity 0.000 description 6
- 230000001988 toxicity Effects 0.000 description 6
- 229940079593 drug Drugs 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 210000002784 stomach Anatomy 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- QPUMEZIFDXYGPG-UHFFFAOYSA-N piperazine 1H-pyrrole Chemical compound N1CCNCC1.N1C=CC=C1 QPUMEZIFDXYGPG-UHFFFAOYSA-N 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000982105 Brevicoryne brassicae Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 241000255777 Lepidoptera Species 0.000 description 3
- 206010033799 Paralysis Diseases 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000009885 systemic effect Effects 0.000 description 3
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- QWCKQJZIFLGMSD-GSVOUGTGSA-N D-alpha-aminobutyric acid Chemical compound CC[C@@H](N)C(O)=O QWCKQJZIFLGMSD-GSVOUGTGSA-N 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 241000258937 Hemiptera Species 0.000 description 2
- 241000124008 Mammalia Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 240000000111 Saccharum officinarum Species 0.000 description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 229930014550 juvenile hormone Natural products 0.000 description 2
- 239000002949 juvenile hormone Substances 0.000 description 2
- 150000003633 juvenile hormone derivatives Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 210000005036 nerve Anatomy 0.000 description 2
- 210000004681 ovum Anatomy 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 description 1
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- QMNWYGTWTXOQTP-UHFFFAOYSA-N 1h-triazin-6-one Chemical compound O=C1C=CN=NN1 QMNWYGTWTXOQTP-UHFFFAOYSA-N 0.000 description 1
- CYMRPDYINXWJFU-UHFFFAOYSA-N 2-carbamoylbenzoic acid Chemical compound NC(=O)C1=CC=CC=C1C(O)=O CYMRPDYINXWJFU-UHFFFAOYSA-N 0.000 description 1
- 102000012440 Acetylcholinesterase Human genes 0.000 description 1
- 108010022752 Acetylcholinesterase Proteins 0.000 description 1
- 241000288283 Allata Species 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
- 235000010591 Appio Nutrition 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 208000018380 Chemical injury Diseases 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 239000005888 Clothianidin Substances 0.000 description 1
- 241001465977 Coccoidea Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 description 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 description 1
- 235000009685 Crataegus X maligna Nutrition 0.000 description 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 1
- 235000009486 Crataegus bullatus Nutrition 0.000 description 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 description 1
- 235000009682 Crataegus limnophila Nutrition 0.000 description 1
- 240000000171 Crataegus monogyna Species 0.000 description 1
- 235000004423 Crataegus monogyna Nutrition 0.000 description 1
- 235000002313 Crataegus paludosa Nutrition 0.000 description 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 241001414830 Diaspididae Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000234830 Eupteryx aurata Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 241000409991 Mythimna separata Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 241000194622 Tagosodes orizicolus Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241001630065 Unaspis yanonensis Species 0.000 description 1
- 241000251539 Vertebrata <Metazoa> Species 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 235000010726 Vigna sinensis Nutrition 0.000 description 1
- 244000042314 Vigna unguiculata Species 0.000 description 1
- 108010090932 Vitellogenins Proteins 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229940022698 acetylcholinesterase Drugs 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000655 anti-hydrolysis Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 125000000917 azadirachtin group Chemical group 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000002490 cerebral effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002061 ecdysteroids Chemical class 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 210000000087 hemolymph Anatomy 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- 230000036403 neuro physiology Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 210000002955 secretory cell Anatomy 0.000 description 1
- 210000002460 smooth muscle Anatomy 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 210000002948 striated muscle cell Anatomy 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses ultralow volume liquid containing thiamethoxam. The ultralow volume liquid is prepared from the thiamethoxam used as an active ingredient or the thiamethoxam and an active ingredient II which are compounded into the active ingredient, and the balance of aid and solvent, wherein the active ingredient II is any one of beta-cypermethrin, pymetrozine, chlorantraniliprole, flubendiamide, tolfenpyrad, azadirachtin, buprofezin, abamectin, emamectin benzoate and diazinon. The ultralow volume liquid containing the thiamethoxam can be used for controlling crop pests such as rice planthoppers, Cnaphalocrocis medinalis, brown planthoppers, white-backed planthoppers, small brown planthoppers, Chilo suppressalis, rice thrips and the like, and has the advantages of convenience in processing, water conservation, good pesticide effect, long duration, synergistic effect and the like, and the work efficiency is high.
Description
Technical field
The present invention relates to technical field of pesticide, particularly a kind of ultra low volume liquids that contains thiophene worm piperazine.
Background technology
At present for the control of insect that easily produces resistance on the agricultural, main way is that exploitation and existing kind do not have composite between the new composition of cross resistance or the existing pesticide species, the former since required development cost height, cycle long, and at present development rate far away less than the speed of pest resistance to insecticide generation.Therefore, being mixed for the different existing pesticide species of the mechanism of action is a kind of selection of the best.If reasonable mixture ratio then can produce significant synergistic effect, make field control effect significantly be better than the effect of each single agent.Usually there is certain defective in the insecticide that contains the single-activity composition on agricultural insect pests control, continuous several times is used and is not only made insect be easy to generate pesticide resistance, and easily cause pollution, can overcome above shortcoming by rationally being mixed between the pesticide active ingredient to food and environment.The reasonably composite simultaneously synergistic effect that active component is produced, can improve preventive effect, reduce the effective ingredient consumption, save cost, delay the drug-fast generation of insect, closely can alleviate even avoid the pollution of agricultural chemicals food and environment, and the efficient novel pesticide of the low toxicity that the present invention researchs and develops out, not only the target drug effect is significantly strengthened, and very low to the influence of people, crop, non-target and environment.
Thiophene worm piperazine is novel chloro nicotinic insecticide, and English name is thiamethoxam, and molecular formula is C8H10ClN5O3S, chemical name is 3-(2-chloro-1,3-thiazoles-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine, chemical structural formula is:
Characteristics such as that thiophene worm piperazine has is active high, effect is fast, toxicity is low, the lasting period is long, insecticidal spectrum is wide, first generation anabasine insecticides such as the mechanism of action and Imidacloprid are similar, but have higher activity.To insect based on stomach toxicity, tag and systemic action, be used for foliar spray and soil root irrigation, rapidly by interior suction, and be transmitted to each position of plant after its dispenser, be mainly used to prevent and treat Lepidoptera, coleoptera, thrips insect.
Beta-cypermethrin belongs to chrysanthemum ester insecticide, and English name is beta-Cypermethrin, and molecular formula is
C
22H
19Cl
2NO
3, chemical name be (R, S)-alpha-cyano-3-benzyloxy phenoxy base (1R.3R)-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, chemical structural formula is:
Beta-cypermethrin is the efficient isomer of cypermethrin, has and tags and stomach poison function, and insecticidal spectrum is wide, and the speed of knocking down is fast, the biologically active height.Be mainly used in the control cotton, vegetables, fruit tree, the various pests on the crops such as tealeaves.
Pyrrole aphid ketone belongs to pyridines or Triazinone insecticide English name is Pymetrozine, and molecular formula is C
10H
11N
5O, chemical name are (E)-4,5-dihydro-6-methyl-4-(3-pyridine methylene amino)-1,2, and 4-triazine-3 (2H)-ketone, chemical structural formula is:
Pyrrole aphid ketone is the brand-new non-insects agent of killing livestock, and is developed in 1988 by Switzerland Ciba-Geigy company the earliest, and this product shows excellent control efficiency to the sucking pest of various crop.Utilizing electricity to penetrate figure (EPG) technology studies show that, no matter be drop, feed or test injection, almost produce the lancet blocking effect immediately, stop to get food at once as long as aphid or plant hopper one touch pyrrole aphid ketone, and final hungry causing death, and this process is irreversible.Therefore, pyrrole aphid ketone has excellent blocking-up insect and passes malicious function.Although at present the caused lancet obstruction of pyrrole aphid ketone mechanism be it be unclear that, existing studies show that this irreversible " stopping eating " be not since " food refusal effect " cause.
Rynaxypyr belongs to the benzamide insecticides, and English name is chlorantraniliprole, and molecular formula is C
18H
14N
5O
2BrC
12, chemical name is 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl) and benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyrazoles-5-formamide, chemical structural formula is:
Mainly be to activate blue Buddhist nun's alkali acceptor, discharge the calcium ion of storing in smooth muscle and the striated muscle cell, cause that the muscle adjusting is weak, paralysis is until last insect death.This active component shows mammal and the extremely significant selective difference of the blue Buddhist nun's alkali of insect acceptor, has improved greatly mammal and other vertebrate safeties.
Fipronil bisamide is the phthalic amide insecticides, and English name is flubendiamide, and chemical formula is C
23H
22F
7IN
2O
4S, chemical name be 3-iodo-N '-(2-mesyl-1,1-dimethyl ethyl group-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]-the 0-tolyl phthalamide, chemical structural formula is:
Fipronil bisamide mainly is to activate calcium release channel in blue Buddhist nun's alkali recipient cell, the property out of control release that causes storing calcium ion.It is the compound that acts on the blue Buddhist nun's alkali of insect cell acceptor at present few in number.Lepidoptera pest there is the spectrum preventive effect, does not have cross resistance with existing insecticide and produce, be suitable for very much the control that existing insecticide produces the insect of resistance.Larva there is very outstanding preventive effect, limited to the adult preventive effect, there is not ovicidal action.Slightly conduct by xylem the back in the infiltration plant body.Resistance of rainwater washing against.
The azoles insect amide is a novel pyrazole heterocyclic broad spectrum disinfestation miticide, and English name is Tolfenpyrad, and molecular formula is C
21H
22ClN
3O
2, chemical name is 4-chloro-3-ethyl-1-methyl-N-{[4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acid amides, chemical structural formula is:
The mechanism of action of azoles insect amide is passed on the complex I of system for the electronics that hinders in the mitochondrial metabolic system, is hindered thereby electronics is passed on, and insect can not be provided and storing energy, is called as the mitochondria electronics and passes on complex Inhibitors (METI).
Nimbin-A is exactly the nimbin of common indication, and English name is Azadirachtin, and molecular formula is C
35H
44O
16, chemical structural formula is:
Nimbin-A is that a class is separated the strongest active compound from the seal chinaberry, and it belongs to tetracyclic triterpenes.Nimbin can be divided into nimbin-A,-B,-C ,-D ,-E,-F, totally 8 kinds of-G ,-I, characteristics such as nimbin has efficiently, low toxicity, control spectrum is wide, but effect slowly, and it has following several aspect to the mechanism of action of insect: directly or indirectly produce the food refusal effect by the chemical co-ordination organ that destroys the insect mouthpart; Effect by centering intestinal digestion enzyme makes that the nutrition conversion of food is not enough, influences the vitality of insect.The nimbin of high dose is kill insects directly, and low dosage then causes and permanent larva or the pupa of deformity, adult etc. occur.By of the synthetic and release of inhibition cerebral nerve secretory cell, influence the synthetic and release of prothoracic gland, and corporal allata is to the synthetic and release of juvenile hormone to ecdysteroids to thoratropic hormone (PTrH).The destruction of juvenile hormone normal concentration level makes the synthetic deficiency of the needed vitellogenin of the insect maturation of ovum simultaneously and causes sterile in the insect hemolymph.
Buprofezin is the diazthines insect growth regulator, IGR, and English name is Buprofezin, and molecular formula is C
16H
23N
3OS, chemical name are 2-tertbutylimido-3-isopropyl-5-phenyl-1,3,5-thiadiazine-4-ketone, and chemical structural formula is:
Buprofezin is the insect molting inhibitor, by suppressing the synthetic and interference metabolism of chitin, insect can not normally be casted off a skin with abnormal and dead gradually.Have high activity, high selectivity, the characteristics in the long longevity of residure.Plant hopper, leafhopper, aleyrodid there are special efficacy, some scale insects such as arrowhead scales, long white a red-spotted lizard are also had better effects, be mainly used in control rice-leaf hopper and plant hopper, potato leaf hopper, oranges and tangerines, cotton and vegetables aleyrodid, oranges and tangerines armored scale and mealybug.
Avermectin is a kind of wide spectrum, efficient, safe microbial source insecticide, and English name is abamectin, and the chemical constitution structural formula is:
Avermectin is a kind of macrolide disaccharide compounds, it is the natural products that from edaphon, separates, insect and mite class had tag and stomach poison function and faint fumigation action is arranged, no systemic action, but it has very strong osmosis to blade, can kill subepidermal insect, and the longevity of residure is long.It does not kill ovum.What its mechanism of action was different with general insecticide is that it disturbs the neurophysiology activity, stimulate and discharge the r-aminobutyric acid, and the r-aminobutyric acid has inhibitory action to arthropodan nerve conduction, the mite class becomes, if mite and insect and larva with paralysis symptom promptly appears after medicament contacts, inertia is not got food, and is dead after 2～4 days.Because of not causing that insect dewaters rapidly, so its lethal effect is slower.But though predatism and parasite are had direct killing effect, because of plant surface is residual few, therefore little to the damage of beneficial insect.
Emamectin-benzoate is the biogenic insecticidal/acaricidal agent, and English name is emamectin benzoate, chemical name is 4 '-Biao-methylamino-4 '-the deoxidation abamectin benzoate, chemical structural formula is:
Characteristics such as emamectin-benzoate has efficiently, wide spectrum, the longevity of residure are long, its mechanism of action are to hinder pest movements nerve information transmission and make the health paralysis dead.The mode of action does not have interior absorption energy to crop, but can infiltrate crop epidermal tissue, thereby have the longer longevity of residure based on stomach toxicity and tagging.In the routine dose scope to useful insect and natural enemy, people, animal safety, can with most of combined use of pesticides.
Diazinon belongs to broad-spectrum organic insecticide, and English name is diazinon, and molecular formula is C
12H
21N
2O
3PS, chemical name are 0,0-diethyl-0-(2-isopropyl-6-methyl-4-pyrimidine radicals) phosphorothionate, and chemical structural formula is:
Diazinon have tag, stomach toxicity, stifling and certain systemic function, have certain mite, eelworm-killing activity of killing concurrently.Active by suppressing the performance of insect acetylcholinesterase, be widely used in paddy rice, corn, sugarcane, tobacco, fruit tree, vegetables, herbage, flowers, forest and greenhouse, be used for preventing and treating multiple sucking and leaf-feeding insect.Can be used for preventing and treating soil insect and nematode, also can be used for preventing and treating domestic animal vermin and house pests such as fly class, cockroach.Various pests such as Lepidoptera, Homoptera all there is the better prevention effect.
The inventor is by studies have shown that, the ultra low volume liquids that the arbitrary pesticide active ingredient in thiophene worm piperazine and beta-cypermethrin, pyrrole aphid ketone, Rynaxypyr, fipronil bisamide, azoles insect amide, nimbin, Buprofezin, Avermectin, emamectin-benzoate, the diazinon is re-dubbed has extremely strong synergistic effect to target pest.
But the existing preparation of thiophene worm piperazine mainly comprises suspending agent, water dispersible granules, seed treatment dispersion powder etc., patent publication No. CN101755814A discloses a kind of Pesticidal combination that contains thiophene worm piperazine and fipronil bisamide, comprise effective active component, auxiliary agent and filler, it is characterized in that: effective active composition thiophene worm piperazine and fipronil bisamide percentage by weight are 1～30: 50～1.This invention with thiophene worm piperazine and fipronil bisamide composite after, have notable synergistic and lasting effect; Enlarged insecticidal spectrum, aphid, rice fulgorid etc. has been had greater activity; Reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; , insect good to person poultry safety, Environmental compatibility is difficult for developing immunity to drugs.But the formulation of this invention is wetting powder, water dispersible granules, suspending agent, and contains the ultra low volume liquids of thiophene worm piperazine, does not appear in the newspapers both at home and abroad.。
Ultra low volume liquids is low by the screening volatility, flash-point is high, to former medicine dissolubility is good, low to chemical injury of crops, viscosity is low solvent, do not convert water during dispenser, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is not owing to contain the high volatile volatile composition in the droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, reduced volatilization with elegant.Droplet is tiny and even, meets " biological optimum grain-diameter " requirement, has significantly improved deposition.Because need not to convert water uses, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large tracts of land takes place and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
Summary of the invention
The objective of the invention is the deficiency that proposes at said method, a kind of low toxicity ultra low volume liquids of clothianidin-containing efficiently is provided, this ultra low volume liquids is easy to process, work efficiency is high, good drug efficacy, hold and imitate length, Synergistic, saving water; Can reduce environmental pollution, improve the agricultural chemicals availability, reduce applications of pesticide amount.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
A kind of ultra low volume liquids that contains thiophene worm piperazine, it is with thiophene worm piperazine, or thiophene worm piperazine and active component II composite be active component, all the other used additives and solvent complement to 100% ultra low volume liquids; Active component II is any one in beta-cypermethrin, pyrrole aphid ketone, Rynaxypyr, fipronil bisamide, azoles insect amide, nimbin, Buprofezin, Avermectin, emamectin-benzoate, the diazinon.
With thiophene worm piperazine is active component, and its weight content is 0.1%～15%, preferred weight content 1%～10%, and preferred weight content 2%～8%, the weight content of auxiliary agent is 1%～15%, solvent complements to 100%; Composite with thiophene worm piperazine and active component II is active component, the weight content of its total amount is 0.2%～35%, the weight content of thiophene worm piperazine is 0.1%～15%, the weight content of active component II is 0.1%～20%, preferred total amount weight content is 3%～12%, and the weight content of preferred thiophene worm piperazine is 2%～5%, and the weight content of preferred active component II is 1%～7%, the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%.
Described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent;
(1) aromatic hydrocarbon solvent of Shi Heing comprises trimethylbenzene, o-dichlorohenzene, the above heavy aromatics of C10 such as durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil;
(2) the plant oil solvent of Shi Heing comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil, esterified vegetable oil such as methyl oleate, ethyl oleate;
(3) the polar solvent solvent of Shi Heing comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, N,N-dimethylacetamide, the above alcohols of C6 such as n-hexyl alcohol, n-octyl alcohol, terpineol;
Preferred boiling point is higher than 160 ℃, flash-point and is higher than 60 ℃ solvent.
Described auxiliary agent comprises surfactant, synergist, bleeding agent etc., be mainly used to improve adhesiveness, wetability and the permeability of preparation to crop and target, strengthen the absorption of crop and target to medicament, reduce the volatility of solvent, improve stability of formulation, reduce the viscosity of preparation, thereby play the effect that improves drug effect.
Surfactant is selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, the phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, the alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the combination of one or more in the calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, alkylphenol polyoxyethylene, the phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate.
Synergist is selected from synergy phosphorus, sulfoxide, piperonyl butoxide etc.
Bleeding agent is selected from azone, thiophene ketone, oozes T etc. soon.The described T that oozes soon can directly buy on market, also is fast penetrant T or fast T.
The concrete preparation method of ultra low volume liquids who contains thiophene worm piperazine of the present invention is, in reaction vessel with electronic stirring, earlier with solvent with the active component stirring and dissolving after, add auxiliary component again, fully mix, promptly get and contain thiophene worm piperazine ultra low volume liquids; Technological parameter is, the speed of mixing is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
The target crop that is fit to is cereal crops such as paddy rice, wheat, economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon.
The present invention is used to prevent and treat rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resemble the star stinkbug, green rice bug resembles, red palpus fleahopper, rice tube water snout moth's larva, oryza chinensis, Phytophthira, the aleyrodid class, the a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, the tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving, the cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, the sugarcane thrips, oranges and tangerines golden thistle horse, soybean pod gall-midge, crop pests such as tomato Liriomyza or sugarcane aphid.
Application process of the present invention is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.A situation arises determines suitable dosage according to controlling object, and the per hectare formulation rate is 1500～4500ml usually.
Compared with prior art, the invention has the beneficial effects as follows:
1. spouting liquid is few, only is hundreds of/one of conventional spraying.
2. droplet is little, and ultra low volume electrostatic spray fogdrop diameter is that 30～60 μ m, ultra low volume ground spraying droplet diameter are 30～80 μ m, aerial ultra low volume spraying fogdrop diameter 30～60 μ m, and conventional spraying droplet diameter is many more than 200～600 μ m.
3. spray pattern is the spraying of drift accumulation property, and conventional spraying is the specific aim spraying, promptly facing to the crop spraying.
What 4. ultra low volume sprayed is to be the finish of carrier with oil, and concentration is generally a few percent to percent tens; And the conventional water diluent agent concentration that sprays is very low, is generally some thousandths of to ten thousand/several.
5. the work efficiency height is prevented and treated in time.Hand-held ultra low volume spraying machine improves 20～30 times of work efficiency than manual compression sprayer, because of its work efficiency height, can timely and effectively prevent and treat the fulminant insect, as plant hopper, mythimna separata, locust etc.
6. save agricultural chemicals.Save agricultural chemicals more than 30% with general than conventional spraying.
7. water not.Saved water intaking, made up a prescription and heavy physical labor such as negative water operation, the hilly and mountainous land of especially short of rain in arid, manpower shortage and water intaking difficulty is used, and is more convenient.
8. good drug efficacy is held and is imitated length.The oil agricultural chemicals is easy to penetrate ester dissolubility insect body surface and enters in the pest body, show as desinsection rapidly, good drug efficacy; The high boiling point auxiliary agent that occupies larger proportion in the finish can play protective effects such as anti-hydrolysis, anti-oxidant, anti-photodissociation to pesticide activity component, show as hold imitate long.
9. to crop safety.Ultra low volume spraying be difficult for to produce poisoning to crop safety, does not have obviously residually, can improve crop quality.
10. expenses for prevention and control is low.Since ultra low volume spraying have province's medicine, laborsaving, not water, good drug efficacy, hold and imitate advantages such as long, so expenses for prevention and control is lower than conventional spraying.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but embodiments of the present invention are not limited to the scope that embodiment represents.
Preparation technology: in the reaction vessel that band stirs, press formula rate first with solvent with active component thiophene worm piperazine stirring and dissolving after, add auxiliary component again, fully mix, promptly get and contain thiophene worm piperazine ultra low volume liquids; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
Embodiment 1-26 all prepares ultra low volume liquids by this preparation method.
Embodiment 1
Prepare 15% thiophene worm piperazine ultra low volume liquids
Embodiment 2
Prepare 0.1% thiophene worm piperazine ultra low volume liquids
Embodiment 3
Prepare 5% thiophene worm piperazine ultra low volume liquids
Embodiment 4
Prepare 0.2% thiophene worm piperazine beta-cypermethrin ultra low volume liquids
Embodiment 5
Prepare 5% thiophene worm piperazine beta-cypermethrin ultra low volume liquids
Embodiment 6
Prepare 30% thiophene worm piperazine beta-cypermethrin ultra low volume liquids
Embodiment 7
Prepare 3% thiophene worm piperazine pyrrole aphid ketone ultra low volume liquids
Embodiment 8
Prepare 10% thiophene worm piperazine pyrrole aphid ketone ultra low volume liquids
Embodiment 9
Prepare 3% chlorantraniliprole and thiamethoxam ultra low volume liquids
Embodiment 10
Prepare 10% chlorantraniliprole and thiamethoxam ultra low volume liquids
Embodiment 11
Prepare 3% fipronil bisamide thiophene worm piperazine ultra low volume liquids
Embodiment 12
Prepare 10% fipronil bisamide thiophene worm piperazine ultra low volume liquids
Embodiment 13
Prepare 3% thiophene worm piperazine azoles insect amide ultra low volume liquids
Embodiment 14
Prepare 10% thiophene worm piperazine azoles insect amide ultra low volume liquids
Embodiment 15
Prepare 3% thiophene worm piperazine nimbin ultra low volume liquids
Embodiment 16
Prepare 6% thiophene worm piperazine nimbin ultra low volume liquids
Embodiment 17
Prepare 3% Buprofezin thiophene worm piperazine ultra low volume liquids
Embodiment 18
Prepare 10% Buprofezin thiophene worm piperazine ultra low volume liquids
Embodiment 19
Prepare 3% Avermectin thiophene worm piperazine ultra low volume liquids
Embodiment 20
Prepare 10% Avermectin thiophene worm piperazine ultra low volume liquids
Embodiment 21
Prepare 3% thiophene worm piperazine emamectin-benzoate ultra low volume liquids
Embodiment 22
Prepare 10% thiophene worm piperazine emamectin-benzoate ultra low volume liquids
Embodiment 23
Prepare 3% thiophene worm piperazine diazinon ultra low volume liquids
Embodiment 24
Prepare 10% thiophene worm piperazine diazinon ultra low volume liquids
Embodiment 25
Prepare 25% thiophene worm piperazine diazinon ultra low volume liquids
Embodiment 26
Prepare 35% thiophene worm piperazine diazinon ultra low volume liquids
The prepared ultra low volume liquids outward appearance that contains thiophene worm piperazine is the homogeneous oily liquids; Low temperature compatibility is good, and under-5 ℃ of conditions, refrigeration 7d does not separate out crystallization and suspension; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, no poisoning; The employing method of remaining silent is measured, and flash-point is greater than 60 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10
-6～1 * 10
-10In the s/cm scope.
Below again in conjunction with using the furthermore bright beneficial effect of the present invention of field efficacy measurement result that embodiment of the invention 1-26 carries out.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80＜CTC＜120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field control effectiveness test again.
Application Example 1
Controlling object: rice fulgorid
Experiment place: Guilin suburban area paddy field
Application method: ultra low volume spraying
Formulation rate: 120g a.i./hm
2
Result of the test sees Table 1.
Table 1: control rice fulgorid field control effectiveness test result
As can be seen from Table 1: ultra low volume liquids of the present invention adopts the ultra low volume spraying method to prevent and treat that rice hoppers quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 2
Controlling object: cabbage aphid
Experiment place: Liuzhou suburban area vegetable field
Application method: ultra low volume spraying
Formulation rate: 100g a.i./hm
2
Result of the test sees Table 2.
Table 2: control cabbage aphid test of pesticide effectiveness result
As can be seen from Table 2: ultra low volume liquids employing ultra low volume spraying method control cabbage aphid quick-acting of the present invention is strong, control efficiency good, the lasting period is longer.
Claims (10)
1. ultra low volume liquids that contains thiophene worm piperazine, it is characterized in that: it is with thiophene worm piperazine, or thiophene worm piperazine and active component II composite be active component, all the other used additives and solvent complement to 100% ultra low volume liquids; Active component II is any one in beta-cypermethrin, pyrrole aphid ketone, Rynaxypyr, fipronil bisamide, azoles insect amide, nimbin, Buprofezin, Avermectin, emamectin-benzoate, the diazinon.
2. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that:
(1) be active component with thiophene worm piperazine, its weight content is 0.1%～15%, and the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%;
(2) composite with thiophene worm piperazine and active component II is active component, the weight content of its total amount is 0.2%～35%, and the weight content of thiophene worm piperazine is 0.1%～15%, and the weight content of active component II is 0.1%～20%, the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%.
3. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that:
(1) be active component with thiophene worm piperazine, its weight content is 1%～10%, and the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%;
(2) composite with thiophene worm piperazine and active component II is active component, the weight content of its total amount is 3%～12%, and the weight content of thiophene worm piperazine is 2%～5%, and the weight content of active component II is 1%～7%, the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%.
4. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: with thiophene worm piperazine is active component, and its weight content is 2%～8%, and the weight content of auxiliary agent is 1%～15%, and solvent complements to 100%.
5. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: described auxiliary agent comprises surfactant, synergist, bleeding agent; Surfactant is one or more the combination in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the calcium dodecyl benzene sulfonate; Synergist is one or more the combination in synergy phosphorus, sulfoxide, the piperonyl butoxide; Bleeding agent is azone, thiophene ketone, oozes one or more combination among the T soon.
6. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and the polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, the above heavy aromatics of C10; The plant oil solvent comprises soybean oil, cottonseed oil, rapeseed oil, castor oil, turpentine oil, esterified vegetable oil; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, N-Methyl pyrrolidone, N, dinethylformamide, N,N-dimethylacetamide, the above alcohols of C6.
7. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: the above heavy aromatics of described C10 is durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil; Esterified vegetable oil is methyl oleate, ethyl oleate; The above alcohols of C6 is n-hexyl alcohol, n-octyl alcohol, terpineol.
8. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1, it is characterized in that: the preparation method of described ultra low volume liquids is, in the reaction vessel that band stirs, earlier with solvent with the active component stirring and dissolving after, add auxiliary component again, fully mix, promptly get and contain thiophene worm piperazine ultra low volume liquids; Technological parameter is: mixing speed is controlled to be 60～150 rev/mins, and mixing time is 15～60 minutes, and temperature is a normal temperature, and pressure is normal pressure.
9. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: it is the control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, resemble the star stinkbug, green rice bug resembles, red palpus fleahopper, rice tube water snout moth's larva, oryza chinensis, Phytophthira, the aleyrodid class, the a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, the tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving, the cured a red-spotted lizard in angle, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, the sugarcane thrips, oranges and tangerines golden thistle horse, soybean pod gall-midge, application on tomato Liriomyza or the sugarcane aphid crop pest.
10. the ultra low volume liquids that contains thiophene worm piperazine according to claim 1 is characterized in that: its application process is ultra low volume spraying, low-gallonage spraying or ultra low volume electrostatic spray.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102699534A CN102273444A (en) | 2011-09-13 | 2011-09-13 | Ultralow volume liquid containing thiamethoxam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102699534A CN102273444A (en) | 2011-09-13 | 2011-09-13 | Ultralow volume liquid containing thiamethoxam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102273444A true CN102273444A (en) | 2011-12-14 |
Family
ID=45099437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102699534A Pending CN102273444A (en) | 2011-09-13 | 2011-09-13 | Ultralow volume liquid containing thiamethoxam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102273444A (en) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103120175A (en) * | 2012-12-06 | 2013-05-29 | 山东农业大学 | Pesticide composition containing thiamethoxam and azadirachtin |
| CN103621532A (en) * | 2012-08-27 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing thiamethoxam and tolfenpyrad and application thereof |
| CN103766384A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing thiamethoxam and epoxiconazole |
| CN103766385A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing thiamethoxam and flutriafol |
| CN103843811A (en) * | 2014-02-21 | 2014-06-11 | 罗晓丹 | Granules for controlling sugarcane stem borer |
| CN104106590A (en) * | 2013-04-19 | 2014-10-22 | 陕西美邦农药有限公司 | Insecticidal composition containing flubendiamide and neonicotinoids |
| CN104126617A (en) * | 2014-07-14 | 2014-11-05 | 卞佳林 | Fruit tree miridae pesticide and preparation method thereof |
| CN104206405A (en) * | 2014-08-26 | 2014-12-17 | 青海省农林科学院 | Pesticide and method for preventing and controlling evergestis extimalis scopoli |
| CN104222156A (en) * | 2014-09-05 | 2014-12-24 | 杨新兰 | Sugarcane insecticidal granules containing 20% chlorantraniliprole suspending agent and humic acid |
| CN104222145A (en) * | 2014-08-18 | 2014-12-24 | 广东中迅农科股份有限公司 | Insecticide composition containing clothianidin and diazinon |
| CN104286015A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Insecticidal composition containing thiamethoxam and diazinon |
| CN104304312A (en) * | 2014-09-15 | 2015-01-28 | 广东中迅农科股份有限公司 | Methylaminoavermectin-diazinon particles |
| CN104472531A (en) * | 2014-12-03 | 2015-04-01 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation of insecticide composition |
| CN104798805A (en) * | 2015-03-26 | 2015-07-29 | 河北博嘉农业有限公司 | Insecticide composition for corn |
| CN104920438A (en) * | 2015-06-12 | 2015-09-23 | 福建省德盛生物工程有限责任公司 | Low-volume spray with thiamethoxam and tolfenpxrad |
| CN105265467A (en) * | 2014-06-18 | 2016-01-27 | 郭秦 | Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof |
| CN105660680A (en) * | 2016-04-15 | 2016-06-15 | 杭州宇龙化工有限公司 | Agricultural insecticide composition containing insect sulfamide and thiamethoxam and application thereof |
| CN106818897A (en) * | 2016-12-30 | 2017-06-13 | 东莞市联洲知识产权运营管理有限公司 | A kind of ultra low volume liquids for preventing and treating thrips and preparation method and application |
| CN107006531A (en) * | 2017-03-13 | 2017-08-04 | 仲恺农业工程学院 | Environment-friendly pesticide and application thereof |
| CN107306988A (en) * | 2017-08-11 | 2017-11-03 | 江西天祥通用航空股份有限公司 | A kind of Diacloden thermal fog and its preparation method and application |
| CN107494577A (en) * | 2017-08-14 | 2017-12-22 | 广西南宁益土生物科技有限责任公司 | Application of the composition containing Diacloden and methyl jasmonate in sugarcane moth borer |
| CN108124900A (en) * | 2017-12-28 | 2018-06-08 | 江苏邦盛生物科技有限责任公司 | A kind of seed treatment compositions and its application |
| CN110178843A (en) * | 2019-05-24 | 2019-08-30 | 安徽省益农化工有限公司 | A kind of rice Pesticidal combination |
| CN119385152A (en) * | 2024-12-31 | 2025-02-07 | 中国热带农业科学院三亚研究院 | A kind of aerosol for preventing and controlling vegetable pests and its preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1037821A (en) * | 1988-04-07 | 1989-12-13 | 奇诺英药物化学工厂有限公司 | Plant protection product |
| WO2004062367A1 (en) * | 2003-01-10 | 2004-07-29 | Battelle Memorial Institute | Sprayable non-aqueous, oil-continuous microemulsions and methods of making same |
| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
-
2011
- 2011-09-13 CN CN2011102699534A patent/CN102273444A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1037821A (en) * | 1988-04-07 | 1989-12-13 | 奇诺英药物化学工厂有限公司 | Plant protection product |
| WO2004062367A1 (en) * | 2003-01-10 | 2004-07-29 | Battelle Memorial Institute | Sprayable non-aqueous, oil-continuous microemulsions and methods of making same |
| CN101785455A (en) * | 2010-02-05 | 2010-07-28 | 深圳诺普信农化股份有限公司 | Pesticide oil suspension agent and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
Non-Patent Citations (1)
| Title |
|---|
| 周本新 等: "《农药新剂型》", 31 January 1997, 化学工业出版社 * |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103621532A (en) * | 2012-08-27 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing thiamethoxam and tolfenpyrad and application thereof |
| CN103120175A (en) * | 2012-12-06 | 2013-05-29 | 山东农业大学 | Pesticide composition containing thiamethoxam and azadirachtin |
| CN104106590A (en) * | 2013-04-19 | 2014-10-22 | 陕西美邦农药有限公司 | Insecticidal composition containing flubendiamide and neonicotinoids |
| CN103766384A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing thiamethoxam and epoxiconazole |
| CN103766385A (en) * | 2013-12-09 | 2014-05-07 | 广东中迅农科股份有限公司 | Ultralow-volume liquid containing thiamethoxam and flutriafol |
| CN103843811A (en) * | 2014-02-21 | 2014-06-11 | 罗晓丹 | Granules for controlling sugarcane stem borer |
| CN103843811B (en) * | 2014-02-21 | 2015-10-14 | 顾祥茂 | A kind of granule preventing and treating sugarcane moth borer |
| CN105265467A (en) * | 2014-06-18 | 2016-01-27 | 郭秦 | Agricultural insecticidal composition comprising thiamethoxam and ZJ4042, and insecticide thereof |
| CN104126617A (en) * | 2014-07-14 | 2014-11-05 | 卞佳林 | Fruit tree miridae pesticide and preparation method thereof |
| CN104222145A (en) * | 2014-08-18 | 2014-12-24 | 广东中迅农科股份有限公司 | Insecticide composition containing clothianidin and diazinon |
| CN104206405A (en) * | 2014-08-26 | 2014-12-17 | 青海省农林科学院 | Pesticide and method for preventing and controlling evergestis extimalis scopoli |
| CN104206405B (en) * | 2014-08-26 | 2016-06-08 | 青海省农林科学院 | A kind of pesticide preventing and treating Fructus Foeniculi thin wing open country snout moth's larva and method thereof |
| CN104222156A (en) * | 2014-09-05 | 2014-12-24 | 杨新兰 | Sugarcane insecticidal granules containing 20% chlorantraniliprole suspending agent and humic acid |
| CN104222156B (en) * | 2014-09-05 | 2017-11-21 | 杨新兰 | It is a kind of containing health is wide and the sugarcane granular insecticide of humic acid |
| CN104286015A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Insecticidal composition containing thiamethoxam and diazinon |
| CN104304312A (en) * | 2014-09-15 | 2015-01-28 | 广东中迅农科股份有限公司 | Methylaminoavermectin-diazinon particles |
| CN104472531A (en) * | 2014-12-03 | 2015-04-01 | 联保作物科技有限公司 | Insecticide composition as well as application and preparation of insecticide composition |
| CN104798805A (en) * | 2015-03-26 | 2015-07-29 | 河北博嘉农业有限公司 | Insecticide composition for corn |
| CN104920438A (en) * | 2015-06-12 | 2015-09-23 | 福建省德盛生物工程有限责任公司 | Low-volume spray with thiamethoxam and tolfenpxrad |
| CN105660680A (en) * | 2016-04-15 | 2016-06-15 | 杭州宇龙化工有限公司 | Agricultural insecticide composition containing insect sulfamide and thiamethoxam and application thereof |
| CN106818897A (en) * | 2016-12-30 | 2017-06-13 | 东莞市联洲知识产权运营管理有限公司 | A kind of ultra low volume liquids for preventing and treating thrips and preparation method and application |
| CN107006531A (en) * | 2017-03-13 | 2017-08-04 | 仲恺农业工程学院 | Environment-friendly pesticide and application thereof |
| CN107306988A (en) * | 2017-08-11 | 2017-11-03 | 江西天祥通用航空股份有限公司 | A kind of Diacloden thermal fog and its preparation method and application |
| CN107494577A (en) * | 2017-08-14 | 2017-12-22 | 广西南宁益土生物科技有限责任公司 | Application of the composition containing Diacloden and methyl jasmonate in sugarcane moth borer |
| CN108124900A (en) * | 2017-12-28 | 2018-06-08 | 江苏邦盛生物科技有限责任公司 | A kind of seed treatment compositions and its application |
| CN110178843A (en) * | 2019-05-24 | 2019-08-30 | 安徽省益农化工有限公司 | A kind of rice Pesticidal combination |
| CN119385152A (en) * | 2024-12-31 | 2025-02-07 | 中国热带农业科学院三亚研究院 | A kind of aerosol for preventing and controlling vegetable pests and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102273444A (en) | Ultralow volume liquid containing thiamethoxam | |
| CN102379307B (en) | Ultra low volume liquid agent containing nitenpyram | |
| CN102349503B (en) | Ultra-low-capacity liquid containing imidaclothiz | |
| CN102349507B (en) | Pymetrozine-containing ultralow volume liquid agent | |
| CN102349504B (en) | Flonicamid-containing ultralow volume liquid agent | |
| CN102273446A (en) | Thiacloprid-containing ultralow-volume liquid | |
| CN102349505B (en) | Ultra-low-capacity liquid containing dinotefuran | |
| CN102273440A (en) | Ultralow volume liquid containing clothianidin | |
| CN102379299A (en) | Ultralow volume liquid containing spirotetramat | |
| CN102630677A (en) | Tolfenpyrad-containing ultra-low volume liquid | |
| CN102379282A (en) | Ultralow volume liquid containing benzoylurea insecticide | |
| CN102626071A (en) | Ultra-low volume liquid containing cyantraniliprole and neonicotinoid insecticides | |
| CN102626077A (en) | Ultra-low-volume liquid containing flubendiamide | |
| CN102657176A (en) | Tolfenpxrad-containing smoke agent | |
| CN102626072B (en) | Ultra-low-volume liquid containing cyantraniliprole and esbiothrin pesticide | |
| CN102630694A (en) | Ultralow-volume liquid containing metaflumizone and nicotine insecticide | |
| CN102626085A (en) | Ultra-low volume liquid containing cyantraniliprole and macrolide insecticide | |
| CN102630700A (en) | Ultra low volume concentrate containing chlorpyrifos | |
| CN103636611B (en) | Ultra-low volume liquid containing tebufenpyrad | |
| CN102630695A (en) | Ultra low volume concentrate containing lufenuron and nicotine insecticides | |
| CN102626068B (en) | Ultra-low-volume liquid containing cyantraniliprole and carbamate pesticide | |
| CN101589720A (en) | A kind of insecticides that contains indenes worm prestige | |
| CN102657213B (en) | Ultra-low volume liquor containing metaflumizone and esbiothrin pesticides | |
| CN103053586A (en) | Synergistic insecticidal composition containing dinotefuran and thiamethoxam, and application thereof | |
| CN101637181A (en) | Pesticide mixture agent for preventing ostrinia nubilalis and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20111214 |