CN101735747A - Non-formaldehyde artificial board adhesive formula and manufacturing process thereof - Google Patents
Non-formaldehyde artificial board adhesive formula and manufacturing process thereof Download PDFInfo
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- CN101735747A CN101735747A CN200910200643A CN200910200643A CN101735747A CN 101735747 A CN101735747 A CN 101735747A CN 200910200643 A CN200910200643 A CN 200910200643A CN 200910200643 A CN200910200643 A CN 200910200643A CN 101735747 A CN101735747 A CN 101735747A
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- polyvinyl alcohol
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- 239000000853 adhesive Substances 0.000 title claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title abstract description 19
- 239000012188 paraffin wax Substances 0.000 claims abstract description 31
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 9
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005642 Oleic acid Substances 0.000 claims abstract description 9
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 6
- 235000013312 flour Nutrition 0.000 claims abstract description 6
- 235000009566 rice Nutrition 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 28
- 239000011259 mixed solution Substances 0.000 claims description 7
- 241000209094 Oryza Species 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000002023 wood Substances 0.000 abstract description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 4
- 229910021529 ammonia Inorganic materials 0.000 abstract description 2
- -1 that is Substances 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000012669 liquid formulation Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 6
- 238000004945 emulsification Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明提供一种不含甲醛的人造板粘合剂,该粘合剂由两种配方的液体混合制成,即石蜡乳化液和聚乙烯醇混合液二种液体混合而成,其中,石蜡乳化液配方是:石蜡,按重量计占全部重量的32.9%,氨水,按重量计占全部重量的6.8%,油酸,按重量计占全部重量的5.48%,水,按重量计占全部重量的54.82%;聚乙烯醇混合液的配方是:糖,按重量计占全部重量的3.66%,糯米粉,按重量计占全部重量的4.89%,聚乙烯醇,按重量计占全部重量的3.05%,水,按重量计占全部重量的88.4%。本发明的优点是用这种粘合剂制作人造板,不含有对人体有害的甲醛。The invention provides a formaldehyde-free wood-based panel adhesive, which is made by mixing two liquids, that is, paraffin wax emulsion and polyvinyl alcohol mixed liquid, wherein the paraffin emulsified The liquid formulation is: paraffin wax, 32.9% by weight of the total weight, ammonia, 6.8% by weight of the total weight, oleic acid, 5.48% by weight of the total weight, water, 5.4% by weight of the total weight 54.82%; The formula of polyvinyl alcohol mixed liquid is: sugar, account for 3.66% of total weight by weight, glutinous rice flour, account for 4.89% of total weight by weight, polyvinyl alcohol, account for 3.05% of total weight by weight , water, accounting for 88.4% of the total weight by weight. The advantage of the present invention is that the man-made board is made by using the adhesive, which does not contain formaldehyde which is harmful to the human body.
Description
技术领域technical field
本发明涉及一种制作人造板用的粘合剂。The invention relates to an adhesive for making wood-based panels.
背景技术Background technique
现在市场上所供应的人造板,都含有甲醛,用这种人造板装修房屋,会慢慢释放出有害人体健康的甲醛,因为人造板所使用的粘合剂都含有甲醛,所以,当今市场上还没有一种不含甲醛的人造板。The wood-based panels currently available on the market all contain formaldehyde. Using this wood-based panel to decorate a house will slowly release formaldehyde that is harmful to human health, because the adhesives used in wood-based panels contain formaldehyde. There is also no formaldehyde-free wood-based panel.
发明内容Contents of the invention
本发明的目的是要提供一种不含甲醛的人造板粘合剂,该粘合剂由两种配方的液体混合制成,即石蜡乳化液和聚乙稀醇混合液二种液体混合而成,其中,石蜡乳化液配方是:The object of the present invention is to provide a formaldehyde-free wood-based panel adhesive, which is made by mixing two kinds of liquids, i.e. paraffin wax emulsion and polyvinyl alcohol mixed liquid. , wherein, the paraffin emulsion formula is:
石蜡 按重量计 占全部重量的32.9%;Paraffin wax accounts for 32.9% by weight of the total weight;
氨水 按重量计 占全部重量的6.8%;Ammonia by weight accounts for 6.8% of the total weight;
油酸 按重量计 占全部重量的5.48%;Oleic acid by weight accounts for 5.48% of the total weight;
水 按重量计 占全部重量的54.82%;Water by weight accounts for 54.82% of the total weight;
聚乙稀醇混合液的配方是:The formula of polyvinyl alcohol mixture is:
糖 按重量计 占全部重量的3.66%;Sugar 3.66% by weight of the total weight;
糯米粉 按重量计 占全部重量的4.89%;Glutinous rice flour accounts for 4.89% of the total weight by weight;
聚乙稀醇按重量计 占全部重量的3.05%;Polyvinyl alcohol accounts for 3.05% of the total weight by weight;
水 按重量计 占全部重量的88.4%。Water accounts for 88.4% of the total weight by weight.
上述混合液的制作工艺是:The manufacturing process of above-mentioned mixed solution is:
制作石蜡乳化液的步骤是:The steps to make paraffin emulsion are:
(1)按重量比例称好石蜡投入乳化罐内,打开蒸汽阀向罐内注入蒸汽,使石蜡逐渐融化成液体;(1) Put the paraffin into the emulsification tank according to the weight ratio, open the steam valve and inject steam into the tank, so that the paraffin gradually melts into liquid;
(2)启动快速搅拌机,加入按比例称好的油酸,待油酸与石蜡液体经搅拌混合均匀;(2) Start the fast mixer, add the oleic acid weighed in proportion, and wait for the oleic acid and the paraffin liquid to mix evenly through stirring;
(3)加入按比例称好的水,停止快速搅拌,转为慢速搅拌;(3) Add the water weighed in proportion, stop the rapid stirring, and turn to slow stirring;
(4)逐渐升温至70℃,同时慢速搅拌;再将温度升至90℃,快速搅拌5分钟;(4) Gradually raise the temperature to 70°C while stirring slowly; then raise the temperature to 90°C and stir rapidly for 5 minutes;
(5)关闭蒸汽阀门,停止供汽,加入按比例称好的氨水,快速搅拌5分钟;温度降至70℃,同时慢速搅拌;(5) Close the steam valve, stop the steam supply, add ammonia water weighed in proportion, and stir rapidly for 5 minutes; the temperature is lowered to 70°C, and at the same time, stir slowly;
(6)继续降温至40℃-50℃,停止搅拌即出料,便制成石蜡乳化液;(6) Continue to cool down to 40°C-50°C, stop stirring and discharge immediately, and then make paraffin wax emulsion;
聚乙稀醇混合液的制作步骤是:The preparation steps of polyvinyl alcohol mixed solution are:
(1)按比例称好糖、糯米粉和水,放入加温罐内,打开蒸汽阀门,同时加温至100℃快速搅拌5分钟;然后转为慢速搅拌2小时;(1) Weigh the sugar, glutinous rice flour and water in proportion, put them into the heating tank, open the steam valve, and heat to 100°C and stir quickly for 5 minutes; then turn to slow stirring for 2 hours;
(2)升温至90℃,缓慢加入按比例稀烂好的聚乙稀醇,使罐内呈稀湖状态;(2) Raise the temperature to 90°C, slowly add polyvinyl alcohol that has been smashed in proportion, so that the inside of the tank is in a dilute lake state;
(3)降温至45℃;(3) cooling down to 45°C;
将石蜡乳化液制作步骤(6)的石蜡乳化液,与聚乙稀醇混合液的制作步骤(3)混合慢速搅拌,即是无甲醛的人造板粘合剂。The paraffin emulsion in the preparation step (6) of the paraffin emulsion is mixed with the preparation step (3) of the polyvinyl alcohol mixture and stirred at a slow speed, that is, a formaldehyde-free wood-based panel adhesive.
本发明的优点是,用这种粘合剂制作人造板,不含有对人体有害的甲醛。The advantage of the present invention is that the man-made board is made by using the adhesive, which does not contain formaldehyde which is harmful to the human body.
具体实施方式Detailed ways
一种不含甲醛的人造板粘合剂,该粘合剂由两种配方的液体混合制成,即石蜡乳化液和聚乙稀醇混合液二种液体混合而成,其中,制作石蜡乳化液:A formaldehyde-free wood-based panel adhesive, which is made by mixing two kinds of liquids, that is, paraffin emulsion and polyvinyl alcohol mixture. Among them, the paraffin emulsion is made :
(1)按重量比例称好石蜡12Kg投入乳化罐内,乳化罐可以加温;打开蒸汽阀向罐内注入蒸汽,使石蜡逐渐融化成液体;(1) Put 12Kg of paraffin wax into the emulsification tank according to the weight ratio, and the emulsification tank can be heated; open the steam valve and inject steam into the tank, so that the paraffin wax gradually melts into liquid;
(2)启动快速搅拌机,加入按比例称好的油酸2Kg,待油酸与石蜡液经搅拌混合均匀;(2) Start the fast mixer, add 2Kg of oleic acid weighed in proportion, and wait for oleic acid and paraffin liquid to mix evenly through stirring;
(3)加入按比例称好的水20Kg,停止快速搅拌,转为慢速搅拌;(3) Add 20Kg of water weighed in proportion, stop the rapid stirring, and turn to slow stirring;
(4)逐渐升温至70℃,同时慢速搅拌;将温度升至90℃,快速搅拌5分钟;(4) Gradually raise the temperature to 70°C while stirring slowly; raise the temperature to 90°C and stir rapidly for 5 minutes;
(5)关闭蒸汽阀门,停止供汽,加入按比例称好的氨水,快速搅拌5分钟;温度降至70℃,同时慢速搅拌;(5) Close the steam valve, stop the steam supply, add ammonia water weighed in proportion, and stir rapidly for 5 minutes; the temperature is lowered to 70°C, and at the same time, stir slowly;
(6)继续降温至40℃-50℃,停止搅拌即出料,制成石蜡乳化液;(6) Continue to cool down to 40°C-50°C, stop stirring and discharge to make paraffin wax emulsion;
聚乙稀醇混合液的制作步骤是:The preparation steps of polyvinyl alcohol mixed solution are:
(4)按比例称好糖15Kg、糯米粉20Kg和水362Kg,放入加温罐内,打开蒸汽阀门,同时加温至100℃快速搅拌5分钟;然后转为慢速搅拌2小时;(4) Weigh 15Kg of sugar, 20Kg of glutinous rice flour and 362Kg of water in proportion, put them into the heating tank, open the steam valve, and heat to 100°C and stir quickly for 5 minutes; then turn to slow stirring for 2 hours;
(5)升温至90℃,缓慢加入按比例稀烂好的聚乙稀醇12.5Kg,使罐内呈稀湖状态;(5) Warm up to 90°C, slowly add 12.5Kg of polyvinyl alcohol, which is pulpy in proportion, to make the tank in a dilute lake state;
(6)降温至45℃;(6) cooling down to 45°C;
将石蜡乳化液制作步骤(6)的石蜡乳化液,与聚乙稀醇混合液的制作步骤(3)混合慢速搅拌,即是无甲醛的人造板粘合剂。The paraffin emulsion in the preparation step (6) of the paraffin emulsion is mixed with the preparation step (3) of the polyvinyl alcohol mixture and stirred at a slow speed, that is, a formaldehyde-free wood-based panel adhesive.
本发明的优点是,用这种粘合剂制作人造板,不含有对人体有害的甲醛。The advantage of the present invention is that the man-made board is made by using the adhesive, which does not contain formaldehyde which is harmful to the human body.
Claims (2)
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CN200910200643XA CN101735747B (en) | 2009-12-24 | 2009-12-24 | Non-formaldehyde artificial board adhesive formula and manufacturing process thereof |
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CN200910200643XA CN101735747B (en) | 2009-12-24 | 2009-12-24 | Non-formaldehyde artificial board adhesive formula and manufacturing process thereof |
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CN101735747A true CN101735747A (en) | 2010-06-16 |
CN101735747B CN101735747B (en) | 2011-12-07 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104419372A (en) * | 2013-09-11 | 2015-03-18 | 兰州大翔制木股份有限公司 | Adhesive |
CN104526832A (en) * | 2014-12-16 | 2015-04-22 | 上海振森木业机械有限公司 | Method for manufacturing high-density fiber board by crop straws |
CN113305968A (en) * | 2021-06-17 | 2021-08-27 | 东台市艺和园装饰品有限公司 | Manufacturing process of artificial decorative plate |
CN113801611A (en) * | 2021-10-29 | 2021-12-17 | 威海新元化工有限公司 | Green, safe and environment-friendly process for industrial continuous large-scale production of formaldehyde-free water-based adhesive |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179456A (en) * | 1996-10-10 | 1998-04-22 | 赵国发 | Adhesive |
CN1229461C (en) * | 2003-10-27 | 2005-11-30 | 西北大学 | A kind of nontoxic adhesive and preparation method thereof |
CN101153210A (en) * | 2006-09-25 | 2008-04-02 | 中宏(天津)实业有限公司 | Method of producing polyvinyl alcohol rubber polymer adhesive |
-
2009
- 2009-12-24 CN CN200910200643XA patent/CN101735747B/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104419372A (en) * | 2013-09-11 | 2015-03-18 | 兰州大翔制木股份有限公司 | Adhesive |
CN104526832A (en) * | 2014-12-16 | 2015-04-22 | 上海振森木业机械有限公司 | Method for manufacturing high-density fiber board by crop straws |
EP3233403A4 (en) * | 2014-12-16 | 2018-08-29 | Shanghai Zhensen Wood-Working Machinery Co., Ltd | Method of manufacturing crop straw fiber board |
CN113305968A (en) * | 2021-06-17 | 2021-08-27 | 东台市艺和园装饰品有限公司 | Manufacturing process of artificial decorative plate |
CN113801611A (en) * | 2021-10-29 | 2021-12-17 | 威海新元化工有限公司 | Green, safe and environment-friendly process for industrial continuous large-scale production of formaldehyde-free water-based adhesive |
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