CN101112349B - Shampoo composition provided with anti-dandruff and opsonize efficacy - Google Patents
Shampoo composition provided with anti-dandruff and opsonize efficacy Download PDFInfo
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- CN101112349B CN101112349B CN2007101357815A CN200710135781A CN101112349B CN 101112349 B CN101112349 B CN 101112349B CN 2007101357815 A CN2007101357815 A CN 2007101357815A CN 200710135781 A CN200710135781 A CN 200710135781A CN 101112349 B CN101112349 B CN 101112349B
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- shampoo composite
- shampoo
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- dandruff
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- 239000002453 shampoo Substances 0.000 title claims abstract description 93
- 208000001840 Dandruff Diseases 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title description 27
- -1 dihydroxy ammonium chloride alkyl quaternary ammonium salts Chemical class 0.000 claims abstract description 56
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 229920006317 cationic polymer Polymers 0.000 claims abstract description 13
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 69
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 16
- 229940043810 zinc pyrithione Drugs 0.000 claims description 10
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 6
- XMAYWYJOQHXEEK-OZXSUGGESA-N (2R,4S)-ketoconazole Chemical compound C1CN(C(=O)C)CCN1C(C=C1)=CC=C1OC[C@@H]1O[C@@](CN2C=NC=C2)(C=2C(=CC(Cl)=CC=2)Cl)OC1 XMAYWYJOQHXEEK-OZXSUGGESA-N 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 5
- 239000000665 guar gum Substances 0.000 claims description 5
- 235000010417 guar gum Nutrition 0.000 claims description 5
- 229960002154 guar gum Drugs 0.000 claims description 5
- 229960004125 ketoconazole Drugs 0.000 claims description 5
- 229950001046 piroctone Drugs 0.000 claims description 5
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 claims description 5
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 4
- 229960003344 climbazole Drugs 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000011280 coal tar Substances 0.000 claims description 3
- 229940116335 lauramide Drugs 0.000 claims description 3
- 235000014593 oils and fats Nutrition 0.000 claims description 3
- VIDTVPHHDGRGAF-UHFFFAOYSA-N selenium sulfide Chemical compound [Se]=S VIDTVPHHDGRGAF-UHFFFAOYSA-N 0.000 claims description 3
- 229960005265 selenium sulfide Drugs 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- KQEBGRLRYABJRL-UHFFFAOYSA-N 3-aminopropane-1,2-diol;hydrochloride Chemical compound [Cl-].[NH3+]CC(O)CO KQEBGRLRYABJRL-UHFFFAOYSA-N 0.000 claims description 2
- BYBLEWFAAKGYCD-UHFFFAOYSA-N Miconazole Chemical compound ClC1=CC(Cl)=CC=C1COC(C=1C(=CC(Cl)=CC=1)Cl)CN1C=NC=C1 BYBLEWFAAKGYCD-UHFFFAOYSA-N 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 229960002509 miconazole Drugs 0.000 claims description 2
- 229960005349 sulfur Drugs 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 229960002358 iodine Drugs 0.000 claims 1
- ZZHGIUCYKGFIPV-UHFFFAOYSA-M n-butylcarbamate Chemical compound CCCCNC([O-])=O ZZHGIUCYKGFIPV-UHFFFAOYSA-M 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 14
- 210000004761 scalp Anatomy 0.000 abstract description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 208000003251 Pruritus Diseases 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
- 229920001296 polysiloxane Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 239000004034 viscosity adjusting agent Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000001662 opsonic effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- DHHFDKNIEVKVKS-FMOSSLLZSA-N Betanin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC(C[C@H]2C([O-])=O)=C1[N+]2=C\C=C\1C=C(C(O)=O)N[C@H](C(O)=O)C/1 DHHFDKNIEVKVKS-FMOSSLLZSA-N 0.000 description 2
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- YGVNXVAFXQNFLV-UHFFFAOYSA-N azonous acid;hydrochloride Chemical compound Cl.ONO YGVNXVAFXQNFLV-UHFFFAOYSA-N 0.000 description 2
- 235000012677 beetroot red Nutrition 0.000 description 2
- 239000001654 beetroot red Substances 0.000 description 2
- 235000002185 betanin Nutrition 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229940117986 sulfobetaine Drugs 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical class CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- OMENDIULIHMDHU-UHFFFAOYSA-N 3-(tetradecanoylamino)propanoic acid Chemical class CCCCCCCCCCCCCC(=O)NCCC(O)=O OMENDIULIHMDHU-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- LZMLXSPDUJUUDB-UHFFFAOYSA-N C(CC)OC(CNC(C(=O)O)CCCCCCCCCCCC)=O Chemical compound C(CC)OC(CNC(C(=O)O)CCCCCCCCCCCC)=O LZMLXSPDUJUUDB-UHFFFAOYSA-N 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 244000173166 Pyrus ussuriensis Species 0.000 description 1
- 235000011572 Pyrus ussuriensis Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005376 alkyl siloxane group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920013750 conditioning polymer Polymers 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- PSHRANCNVXNITH-UHFFFAOYSA-N dimethylamino acetate Chemical compound CN(C)OC(C)=O PSHRANCNVXNITH-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229940068939 glyceryl monolaurate Drugs 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229940071085 lauroyl glutamate Drugs 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
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- Cosmetics (AREA)
Abstract
The present invention provides a shampoo compound which has the effects of scurf removal and conditioning. The shampoo compound of the present invention includes the following components with the weight percentages: a) 5 percent to 50 percent surfactant; b) 0.01 percent to 10 percent alkyl propyl dimethyl 2, 3 dihydroxy ammonium chloride alkyl quaternary ammonium salts; c) 0.01 percent to 10 percent non-volatile siloxane; d) 0.01 percent to 3 percent cationic polymer; e) 0.01 percent to 5 percent scurf-removing agent and f) deionized water. Compared with other scurf-removing shampoos, the shampoo compound of the present invention has better effect conditioning of the scalp and hair and better scurf-removing and itch reliving effects.
Description
Technical field
The present invention relates to a kind of shampoo composite, be specifically related to have the shampoo composite of anti-dandruff and opsonic action.
Background technology
Occurred many shampoo composites that excellent cleaning hair and conditioning hair effect can be provided on the market, these shampoo composites contain multiple rinse additives such as detersive surfactant, cationic cellulose, cation guar gum, polysiloxanes conditioner mostly.But when containing alkyl quaternary ammonium salts commonly used such as three-cetyl chloride ammonium in the shampoo composite, then can increase the zest of shampoo, head pruritus dandruff phenomenon is well improved.
The shampoo that contains the anti-dandruff composition also is to have bought in market, and they are to have introduced the anti-dandruff active substance on the basis of detersive surfactant.Wherein, Chang Yong anti-dandruff composition mainly contains 1-oxygen-2-mercaptopyridine salt or selenium sulfide, sulfur, coal tar, ketoconazole, climbazole and Octopirox etc.When using anti-dandruff dose, in the finite concentration scope, better effects is arranged, when use amount is big, also scalp is produced zest.
United States Patent (USP) 5624666 is enumerated and claimed anion surfactant, cationic polymer and the Zinc Pyrithione shampoo composite as dandruff removing agent that comprises.Though these shampoos make every effort to the conditioning effect and anti-dandruff between reach optimum balance, but the compound action with better anti-dandruff effect and conditioning performance is difficult to reach, deposition anti-dandruff active substance can be to opsonic action on hair and scalp, and particularly Qing Jie hair feel has a negative impact.
Shampoo composite reaches better anti-dandruff effect and conditioning performance and depends on all many-sides such as the amount of the consumption of the cationic polymer that uses in type and proportioning, the especially compositions of each conditioning component in the shampoo formula and anti-dandruff dose and type, the type of employed dandruff removing agent, employed anion surfactant and type.
Summary of the invention
Although it is very difficult to obtain the shampoo composite of anti-dandruff efficacy and conditioning performance perfect combination, the applicant still finds to use alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss are during as conditioner, can not only effectively reduce the zest of anti-dandruff shampoo, and can effectively improve wet comb and do the comb performance.
The purpose of this invention is to provide a kind of shampoo composite, can not only reduce the zest of shampoo, improve the shampoo mildness, and can play the effect of the effective removal dandruff scalp with anti-dandruff effect and conditioning performance.
Shampoo composite provided by the present invention comprises following component by weight percentage:
A) 5% to 50% surfactant;
B) 0.01% to 10% alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss;
C) 0.01% to 10% fixedness siloxanes;
D) 0.01% to 3% cationic polymer;
E) anti-dandruff dose of 0.01% to 5%; With
F) deionized water.
The various compositions of shampoo composite of the present invention will be described below, the qualification of also having described the various selection compositions that are applicable in the specific embodiments of the present invention and preferred composition, component in addition and having made.Except as otherwise noted, all percentage ratio and ratio be all with the percentage by weight of the total weight gained of shampoo composite of the present invention, and described composition is all with the cubage of active ingredient.
A. surfactant
The surfactant that the present invention adopts can be to be selected from least a in anion surfactant, zwitterionic surfactant and the non-ionic surface active agent, it accounts for shampoo composite weight 5%-50%, be preferably 5%-25%, more preferably 8%-20% most preferably is 10%-18%.Above-mentioned anion surfactant not only can play cleaning and blistered performance, and should be compatible on physics and chemical property with other component of the present invention, and can keep the attractive in appearance and stable of shampoo composite.
It is following at least a to be applicable to that anion surfactant of the present invention comprises: alkylsulfonate; alkyl sulfate; acylated amino salt; polyoxyethylene alkyl ether sulfate salt; alkylbenzenesulfonate; N-acyl group-N methyl taurine salt; alpha-alefinically sulfonate; the higher fatty acids sulfonated ester; the alkyl ether acetate; the polyoxyethylene alkyl ether acetate; fatty acid soaps; alkyl phosphate salt; the N-lauroyl glutamate; N-palmityl glutamate, Glu; N-lauroyl-Ethylglycocoll salt; N-Hamposyl L salt and N-myristoyl-Beta-alanine salt.
It is following at least a to be applicable to that zwitterionic surfactant of the present invention comprises: alkyl betaine-type surfactant, amido betaine type surfactant, sulfobetaines type surfactant, hydroxyl sulfo betaine type surfactant, amidosulfobetaines type surfactant, phosphoric acid betaine type surfactant, imidazolinium betaine type surfactant, alanine type surfactant and amino acid type surfactant.
Wherein, preferably CAB lauramide, betanin lauryl dimethyl aminoacetate, fatty acid distribution of coconut oil amido propyl betaine, fatty acid distribution of coconut oil dimethylamino acetas betanin, lauryl hydroxyl sulfo betaine, 2-alkyl-N-carboxymethyl-N-ethoxy-imidazolinium betaine, lauryl imino-diacetic propyl ester, N-(3-alkyl (12,14) oxygen-2-hydroxypropyl)-L-arginine hydrochloride.
Be applicable to that ionic surfactant pack of the present invention draws together following at least a: polyoxyethylene fatty acid ester, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene dehydration Pyrusussuriensis (sugar) alcohol fatty acid ester, polyoxy fatty acid glyceride, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene glycol, fatty acid distribution of coconut oil alkane alcohol amide, sucrose fatty acid ester, alkylglycoside, alkyl glycerol base glucoside and methyl glucoside fatty acid ester.Wherein, preferred polyethylene glycol mono stearate, decyl glyceryl monolaurate, single Tridocosanoin, polyoxyethylene lauryl ether, polyoxyethylene 8 stearate ether, polyoxyethylene mountain Yu acid ether, polyoxyethylene (160) polyoxypropylene (30) glycol, alkylglycoside.
B. alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss
Its alkyl of alkyl quaternary ammonium salts that is suitable for shampoo composite of the present invention is side chain or the linear chain structure that contains 4 above carbochains, be preferably the alkyl propyl-dimethyl 2 that contains 12 above carbochains, 3 dihydroxy ammonium chloride, most preferably be alkyl propyl-dimethyl 2, the 3 dihydroxy ammonium chloride of the carbochain that contains 12 above straight chains.It should be compatible on physics and chemical property with other component of the present invention, and can keep the stability of shampoo composite, attractive in appearance or performance.
It is 0.01%-10% that alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss of the present invention account for shampoo composite weight, is preferably 0.05%-8.0%.
C. non-volatile siloxane
It is 0.01%-10% that non-volatile siloxane conditioner of the present invention accounts for shampoo composite weight, is preferably 0.05%-8.0%, and more preferably 0.1%-5% most preferably is 0.5%-4.0%.The siloxanes hair conditioner that the is used for shampoo composite preferably viscosity under 25 ℃ is 20-2, and 000,000 centistoke is preferred 1,000-1,500,000 centistokes, most preferably 10,000-1,000,000 centistoke.
The preferred non-volatile siloxane conditioner of the present invention mixes in shampoo composite usually, thus make its with disperse insoluble granule separately, the discontinuous phase form exists, and is also referred to as " droplet ".This droplet will suspend in the suspending agent of describing usually below.This siloxanes hair conditioner comprises siloxanes fluids hair conditioner such as siloxanes fluids, also can comprise other composition, as siloxane glue and silicone resin, with deposition that strengthens siloxanes fluids or the gloss that improves hair.
Term " non-volatile " is meant and has silicone material very little or that almost do not have vapour pressure under environmental condition herein.Boiling point under 1 atmospheric pressure preferably is at least about 250 ℃, more preferably at least about 275 ℃, most preferably at least about 300 ℃.At 25 ℃ or more under the low temperature, vapour pressure is preferably less than about 0.2mmHg, most preferably less than about 0.1mmHg.
Other siloxanes hair conditioner that is used for shampoo composite comprises silicone oil, and this silicone oil is a kind of flowable silicone material, and its viscosity under 25 ℃ is less than 1,000,000 centistoke, preferred 5-1,000,000 centistoke, more preferably 10-600,000 centistoke, more preferably 10-500 again, 000 centistoke, 10-300 most preferably, 000 centistoke.Suitable silicone oil comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer and its mixture.
Other suitable siloxanes fluids that is applicable to silicone conditioning agent is an insoluble silicone glue.These glue are polysiloxane, and the viscosity in the time of 25 ℃ is more than or equal to 1,000,000 centistoke.The matter average molecular weight of siloxane glue surpasses 200,000 centistoke, usually between 200,000-1,000,000 centistoke, at least a as in polydimethylsiloxane, dimethyl siloxane-methyl ethylene silicone copolymers, the dimethyl siloxane-diphenyl siloxane-methyl ethylene silicone copolymers.
The siloxanes hair conditioner also comprises polydimethylsiloxane glue (viscosity greater than 1,000,000 centistoke) and polydimethyl siloxane oil (viscosity is about 10-100,000 centistoke).
D. anti-dandruff dose
It is 0.01%-5% that in the shampoo composite of the present invention anti-dandruff dose accounts for shampoo composite weight, is preferably 0.5%-1.5%.
In the shampoo composite of the present invention anti-dandruff dose comprises at least a in the following material: pyrithione slaine, ketoconazole, miconazole, Octopirox, IPBC, climbazole, selenium sulfide, sulfur, coal tar.Preferred anti-dandruff dose is Zinc Pyrithione (ZPT), ketoconazole, Octopirox, climbazole, and preferred anti-dandruff dose is Zinc Pyrithione (ZPT), ketoconazole, Octopirox.ZPT is a flat crystal, can or not wrap up with the oils and fats parcel.In order to reduce zest and/or to increase anti-dandruff effect, can use parcel ZPT, its wrappage is various oil substances, the oils and fats of parcel ZPT can be alkane, paraffin oil, vegetable oil, animal oil and their lipid or mixture.
Be applicable to that anti-dandruff dose of the present invention can be microgranular or dissolved form, can be preferably compatible with the physicochemical property of other component of shampoo composite, keep the stability of shampoo composite.Anti-dandruff dose optimum quantum of utilization can determine that this can realize those skilled in the art according to the composition of employed concrete anti-dandruff dose of kind and compositions.
E. cationic polymer
Be applicable to that cationic polymer of the present invention can be dissolved in the shampoo composite, perhaps in shampoo composite, form the liquid condensation layer, can promote the opsonic action of shampoo, can promote that in application process the polysiloxane particle among the present invention deposits on hair and/or the scalp from shampoo composite.
It is 0.01%-3% that in the shampoo composite of the present invention anti-dandruff dose accounts for shampoo composite weight, preferred 0.1%-1.0%.Be applicable to that cationic charge density of the present invention is 0.1-1.2 milliequivalent/gram, preferred 0.3-0.8 milliequivalent/gram, more preferably 0.5-0.7 milliequivalent/gram, wherein the molecular weight of cationic polymer is greater than 600,000, be preferably 800,000-2,000,000, more preferably 1,000,000-1,500,000, most preferably be 1,250,000-1,350,000.Preferably, the molecular weight of this cationic polymer is lower than 5,000,000.
The charge density of this cationic polymer can be measured according to the Kjeldahl method.It will be appreciated by those skilled in the art that the charge density that contains amino polymer will become with pH and amino isoelectric point, IP.Described pH value is generally about 3 to about 9, is about 4 to about 8 the most commonly.
Term " polymer " used herein " comprise by a kind of material of monomer polymerization generation or by the material (being copolymer) of two kinds of monomer polymerizations generations or material or the naturally occurring polymer that produces by multiple monomer polymerization.
The cationic polymer that is applicable to shampoo of the present invention comprises at least a in the following material: cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-11, Salcare SC60 (ciba company), Salcare SC96 (ciba company).Preferred cationic guar gum, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, most preferably polyquaternary ammonium salt-10.
F. water
In the shampoo composite of the present invention, except the above composition and other optional auxiliary element, be supplemented to requirement with deionization.
G. optional components
Shampoo composite of the present invention can also comprise one or more optional members, and optional member comprises that suspending agent, antistatic additive, antioxidant, foam booster, viscosity modifier, thickening agent, PH regulator, antiseptic, pigment, organic solvent or diluent, pearling agent, spice, aliphatic alcohol etc. are known or is effective to additional optional components among hair nursing or the personal care product.
The suspending agent that is suitable for shampoo composite of the present invention should play and make siloxanes conditioning composition protect special suspended state, to keep its homogeneously dispersed state in shampoo composite.
It is 0.01%-10.0% that the suspending agent that is suitable for shampoo composite of the present invention accounts for shampoo composite weight, preferred 0.1%-8.0%.
The suspending agent that is suitable for shampoo composite of the present invention comprises at least a in following: HANSHENGJIAO, acrylate copolymer (with Carbopol SF-1 is trade name, buys from NOVEON company), hydroxypropyl cellulose, hydroxypropyl guar gum, polyvinyl pyrrolidone and maleic anhydride-methyl ethylene ether copolymer.Preferred HANSHENGJIAO, acrylate copolymer.
Optional antistatic additive can be water-insoluble cationic surfactant, accounts for the 0.1%-5.0% of composition weight usually.The concrete non-limiting example of suitable antistatic additive is a quaternary ammonium salt-80.
The foam booster that is used for shampoo composite of the present invention comprises cocos nucifera oil acyl monoethanolamine, cocos nucifera oil acyl diethanolamine and their mixture.
Viscosity modifier of selecting for use and thickening agent are used for shampoo composite of the present invention with effective dose ground, to regulate mastic to suitable viscosity.The concrete non-limiting example of this viscosity modifier and thickening agent comprises: sodium chloride, ammonium chloride and their mixture.
Shampoo composite with anti-dandruff effect and conditioning performance of the present invention, use alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss are as conditioner, and can not only effectively reduce the zest of anti-dandruff shampoo through scientific matching with other shampoo component, and can effectively improve wet comb and do the comb performance, and play the effect of the effective removal dandruff.
Shampoo composite of the present invention can by any known or other effectively be suitable for providing the technology preparation of shampoo composite, the method that prepare shampoo composite of the present invention comprises the preparation and the hybrid technology of routine.
Shampoo composite of the present invention uses with the cleaning of routine and the mode of conditioning hair, and comprise following step: (a) water is with the hair moistening; (b) the above-mentioned shampoo composite (2-20 gram) with effective dose is administered on the hair, rubs in hair and on the scalp and smears shampoo composite, thereby make compositions contact with scalp with hair; (C) water rinsing shampoo composite from the hair.These steps can repeat many times as required, to reach cleaning, conditioning and anti-dandruff efficacy.
The specific embodiment
Be the indefiniteness embodiment of shampoo composite of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention.Because without departing from the spirit and scope of the present invention, can carry out many conversion to the present invention.In these embodiments, unless stated otherwise, all concentration all is that the weight with shampoo composite is the percentage by weight that the basis draws.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, PH regulator, spice, pigment etc.
Preparation embodiment
The method for preparing shampoo composite (seeing Table 1) in embodiment (I, III, V) and the Comparative Examples (II, IV, VI) suitably is as follows: will about 1/3 join in the blending tank that strap clamp overlaps to whole surfactants and part water, under slowly stirring, be heated to about 70 ℃ to 80 ℃, then add 16 octadecanol, glycol distearate, coconut oil single ethanol amide, two lauramide propyl-dimethyls 2,3-dihydroxypropyl ammonium chloride, zinc sulfate etc. further mix.If there is conditioning polymer (as polyquaternary ammonium salt-7 and polyquaternary ammonium salt-10), can add at this moment after pre-dispersed.Mixing is at least about after 30 minutes, and this mixture is cooled to about 50 ℃, and cation guar gum is pre-dispersed in the water, obtains about 0.1% to about 10% aqueous solution, with this dispersion liquid and aforementioned mixture mix homogeneously.Cooling gained mixture is collected these mixture in the finished product jar, under agitation adds remaining surfactant and remaining ingredient, continues to stir, and guarantees to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, viscosity and the pH value of regulating product arrive suitable degree.Randomly can add an amount of small amount of matter at last, supply with deionized water at last.
The composition of table 1. shampoo composite
Effect embodiment
Effect evaluation method for embodiment is: the shampoo composite of preparation embodiment (I, III, V) and Comparative Examples (II, IV, VI) is done the contrast test, promptly prepare example I and Comparative Example II and do the contrast test, preparation EXAMPLE III and Comparative Examples I V do the contrast test, preparation EXAMPLE V and Comparative Examples VI do the contrast test, issue test crowd (each 50 people) contrast respectively and use.
According to identical method hair washing, every kind of shampoo used for two weeks when the tester used the shampoo sample.The people of half uses a kind of shampoo wherein earlier, second half people uses another kind of shampoo earlier, for example, when I and II contrast test sample, 25 people are at the last fortnight I shampoo on probation, two weeks of back are tried out II shampoo, and 25 people are at the last fortnight II shampoo on probation in addition, and two weeks of back are tried out I shampoo.The tester according to oneself feel mark.Standards of grading adopt 7 fens systems, and 1 minute the poorest, and 7 minutes best, and mark is high more good more.
The various shampoo composite results of use of table 2. are estimated
Claims (14)
1. shampoo composite comprises following component by weight percentage:
A), 5% to 50% surfactant, described surfactant is selected from least a in anion surfactant, zwitterionic surfactant and the non-ionic surface active agent;
B), 0.01% to 10% two lauramide propyl-dimethyls 2,3-dihydroxypropyl ammonium chloride;
C), 0.01% to 10% fixedness siloxanes;
D), 0.01% to 3% cationic polymer;
E), anti-dandruff dose of 0.01% to 5%; With
F), deionized water.
2. according to the shampoo composite of claim 1, described surface-active contents is 5% to 25%.
3. according to the shampoo composite of claim 1, described surface-active contents is 8% to 20%.
4. according to the shampoo composite of claim 1, described surface-active contents is 10% to 18%.
5. according to the shampoo composite of claim 1, the viscosity of described fixedness siloxanes under 25 ℃ is 20-2,000,000 centistoke.
6. according to the shampoo composite of claim 5, the viscosity of described fixedness siloxanes under 25 ℃ is 1,000-1,500,000 centistokes.
7. according to the shampoo composite of claim 5, the viscosity of described fixedness siloxanes under 25 ℃ is 10,000-1,000,000 centistoke.
8. according to the shampoo composite of claim 5, described fixedness content of siloxane is 0.05% to 8.0%.
9. shampoo composite according to Claim 8, described fixedness content of siloxane is 0.1% to 5%.
10. shampoo composite according to Claim 8, described fixedness content of siloxane is 0.5% to 4.0%.
11. according to the shampoo composite of claim 1, described cationic polymer is to be selected from least a in cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, the polyquaternary ammonium salt-11.
12. according to the shampoo composite of claim 11, the charge density of described cationic polymer is between 0.1 to 1.2meq/g, molecular weight is between 500,000 to 2,000,000.
13. according to the shampoo composite of claim 1, described anti-dandruff dose is to be selected from least a in Zinc Pyrithione, ketoconazole, miconazole, octopirox, iodine propinyl n-butyl carbamate, climbazole, selenium sulfide, sulfur, the coal tar.
14. according to the shampoo composite of claim 13, described Zinc Pyrithione is the flat crystal with the oils and fats parcel.
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