CN101054499A - H62 brass polishing liquid and its preparing process - Google Patents
H62 brass polishing liquid and its preparing process Download PDFInfo
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- 238000005498 polishing Methods 0.000 title claims abstract description 98
- 239000007788 liquid Substances 0.000 title claims abstract description 44
- 229910001369 Brass Inorganic materials 0.000 title claims abstract description 18
- 239000010951 brass Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title abstract description 7
- 239000003350 kerosene Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000012530 fluid Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 7
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 11
- 239000003082 abrasive agent Substances 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 5
- 235000013311 vegetables Nutrition 0.000 claims 7
- 239000003595 mist Substances 0.000 claims 4
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 18
- 239000008158 vegetable oil Substances 0.000 abstract description 18
- 239000003921 oil Substances 0.000 abstract description 16
- 235000019198 oils Nutrition 0.000 abstract description 16
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract description 8
- 230000003746 surface roughness Effects 0.000 abstract description 8
- 239000007769 metal material Substances 0.000 abstract description 7
- -1 lard Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 238000004458 analytical method Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005088 metallography Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010639 cypress oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
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Abstract
H62黄铜专用抛光液及其制备方法属于精密机械抛光领域。普通抛光液不能很好地满足塑性金属材料精密镜面加工而开发的一种专用的抛光液。抛光液由粒径为0.5~1.0μm的Al2O3微粉、煤油、猪油、植物油和锭子油混合而成;其中Al2O3微粉为磨料,煤油作溶剂,猪油、植物油和锭子油的混合液作添加剂;抛光液按体积比由2%的猪油、2%的磨料、8%的植物油和锭子油的混合液、88%的煤油配制而成;该抛光液能够加工出表面质量均匀,表面粗糙度值达到0.008μm的H62黄铜工件,具有不腐蚀工件、有效缓解机械刻划作用、加工表面质量好的特点,可以用于塑性金属材料的外观装饰性加工,以及材料金相分析前的表面抛光加工。The H62 special polishing liquid for brass and a preparation method thereof belong to the field of precision mechanical polishing. A special polishing fluid developed for the ordinary polishing fluid that cannot satisfy the precision mirror processing of plastic metal materials. The polishing liquid is made by mixing Al 2 O 3 fine powder with a particle size of 0.5-1.0 μm, kerosene, lard, vegetable oil and spindle oil; among them, Al 2 O 3 fine powder is used as abrasive, kerosene is used as solvent, lard, vegetable oil and spindle oil The mixed liquid is used as an additive; the polishing liquid is prepared by volume ratio from 2% lard, 2% abrasive, 8% vegetable oil and spindle oil mixture, and 88% kerosene; the polishing liquid can process surface quality Uniform, H62 brass workpiece with a surface roughness value of 0.008μm has the characteristics of no corrosion of the workpiece, effective relief of mechanical scoring, and good surface quality. It can be used for decorative processing of plastic metal materials, and material metallography Surface polishing before analysis.
Description
技术领域technical field
本发明涉及一种精密机械抛光领域的专用抛光液,是一种液态抛光混合剂。主要用于典型塑性金属材料H62黄铜的精密机械抛光,也适用于其他类似性质的塑性金属材料抛光。该抛光液可广泛用于精密机械制造、精密仪器、航空航天制造工程领域。The invention relates to a special polishing liquid in the field of precision mechanical polishing, which is a liquid polishing mixture. It is mainly used for precision mechanical polishing of typical plastic metal material H62 brass, and is also suitable for polishing other plastic metal materials with similar properties. The polishing liquid can be widely used in the fields of precision machinery manufacturing, precision instruments, and aerospace manufacturing engineering.
背景技术Background technique
塑性金属的精密抛光,通常采用化学或电化学的加工方式,所用抛光液通常为酸性溶液,不容易加工出均匀的表面质量。在化学机械抛光中,必须采用性能很好的化学机械抛光液才能达到预期的抛光效果,而通常这种抛光液的价格昂贵。传统的抛光液一般不含有磨料,磨料一般嵌在比工件更软的抛光工具里,抛光时随着抛光工具的磨损,加入抛光液以进行研磨加工。The precision polishing of plastic metals usually adopts chemical or electrochemical processing methods, and the polishing liquid used is usually an acidic solution, which is not easy to process a uniform surface quality. In chemical mechanical polishing, a chemical mechanical polishing fluid with good performance must be used to achieve the desired polishing effect, and usually the polishing fluid is expensive. The traditional polishing liquid generally does not contain abrasives, and the abrasives are generally embedded in the polishing tool which is softer than the workpiece. During polishing, as the polishing tool wears out, the polishing liquid is added for grinding.
发明内容Contents of the invention
本发明的目的在于针对典型塑性金属材料H62黄铜的精密机械抛光中,普通抛光液不能很好地满足塑性金属材料精密镜面加工而开发的一种专用的抛光液。使用中,只需将适量抛光液加在抛光垫上,放置工件进行加工即可,操作简单,污染小。The purpose of the present invention is to develop a special polishing liquid for the precision mechanical polishing of H62 brass, a typical plastic metal material, because ordinary polishing liquid cannot well meet the precision mirror processing of plastic metal materials. In use, you only need to add an appropriate amount of polishing liquid to the polishing pad, and place the workpiece for processing. The operation is simple and the pollution is small.
本发明的H62黄铜抛光液,其特征在于:抛光液由粒径为0.5~1.0μm的Al2O3微粉、煤油、猪油、植物油和锭子油混合而成;其中Al2O3微粉为磨料,煤油作溶剂,猪油、植物油和锭子油的混合液作添加剂;抛光液按体积比由2%的猪油、2%的磨料、8%的植物油和锭子油的混合液、88%的煤油配制而成;The H62 brass polishing liquid of the present invention is characterized in that: the polishing liquid is formed by mixing Al2O3 micropowder, kerosene, lard, vegetable oil and spindle oil with a particle size of 0.5~1.0 μm; wherein the Al2O3 micropowder is Abrasives, kerosene as a solvent, a mixture of lard, vegetable oil and spindle oil as an additive; the polishing liquid consists of 2% lard, 2% abrasive, 8% vegetable oil and spindle oil, 88% made from kerosene;
根据环境温度的不同,添加剂的配制有两种方案:环境温度为20~30℃时,熔化的猪油、植物油和锭子油的体积比分别为20%、40%和40%;环境温度为10~20℃时,熔化的猪油、植物油和锭子油的体积比分别为30%、45%和35%。According to different ambient temperatures, there are two schemes for the preparation of additives: when the ambient temperature is 20-30°C, the volume ratios of the melted lard, vegetable oil, and spindle oil are 20%, 40%, and 40% respectively; when the ambient temperature is 10 At ~20°C, the volume ratios of molten lard, vegetable oil and spindle oil are 30%, 45% and 35%, respectively.
本发明的内容包括典型塑性金属H62黄铜专用抛光液的选料、配比和配制的工艺方法。抛光液主要起到润滑、清洗、冷却、成膜、微切削作用,且要求试件材料能够均匀去除。根据H62黄铜的性能特点,所选抛光液的主要成分包括:粒径为0.5~1.0μm的Al2O3微粉、煤油、植物油、猪油、锭子油。其中,磨料起微量切削作用,煤油作为溶剂主要起润滑、冷却、清洗和运送磨料的作用,添加剂中的成分主要起到包裹并均匀分散磨粒、缓解机械作用、润滑、工件表面的附着成膜作用。配置时,首先将猪油加热溶化,与同体积比的磨料搅拌均匀成糊状,然后将体积比为88%的煤油加入搅拌好的热的糊状混合剂中,摇匀放置至室温,再根据环境温度的不同,加入表1所示的植物油和锭子油,搅拌均匀,得到所要的抛光液。The content of the invention includes the process method of material selection, proportioning and preparation of typical plastic metal H62 special polishing liquid for brass. The polishing fluid mainly plays the role of lubrication, cleaning, cooling, film formation, and micro-cutting, and requires the specimen material to be removed evenly. According to the performance characteristics of H62 brass, the main components of the selected polishing liquid include: Al 2 O 3 powder with a particle size of 0.5-1.0 μm, kerosene, vegetable oil, lard, and spindle oil. Among them, the abrasive plays a role in micro-cutting, kerosene as a solvent mainly plays the role of lubricating, cooling, cleaning and transporting the abrasive, and the ingredients in the additive mainly play the role of wrapping and evenly dispersing the abrasive, relieving the mechanical action, lubricating, and forming a film on the surface of the workpiece effect. When configuring, first heat the lard to melt, stir it with the same volume ratio of abrasives to form a paste, then add kerosene with a volume ratio of 88% to the stirred hot paste mixture, shake it well and place it to room temperature, then According to the difference of ambient temperature, add the vegetable oil and spindle oil shown in Table 1, and stir evenly to obtain the desired polishing liquid.
所述的H62黄铜抛光液的制备方法,其特征在于,包括以下步骤:The preparation method of described H62 brass polishing liquid is characterized in that, comprises the following steps:
①将2%的猪油加热熔化;① Heat and melt 2% lard;
②在熔化的猪油中按体积比1∶1加入粒径为0.5~1.0μm的Al2O3微粉,搅拌均匀;② Add Al 2 O 3 micropowder with a particle size of 0.5-1.0 μm in the volume ratio of 1:1 to the melted lard, and stir evenly;
③将88%的煤油加入上述猪油与Al2O3微粉的混合液中,均匀混合,冷却至室温备用;③ Add 88% kerosene to the above-mentioned mixture of lard and Al 2 O 3 micropowder, mix evenly, cool to room temperature for later use;
④当环境温度为10~20℃时,加入4.5%的植物油和3.5%的锭子油均匀混合;当环境温度为20~30℃时,加入4%的植物油和4%的锭子油均匀混合,得到H62黄铜抛光液;④ When the ambient temperature is 10-20°C, add 4.5% vegetable oil and 3.5% spindle oil and mix evenly; when the ambient temperature is 20-30°C, add 4% vegetable oil and 4% spindle oil and mix evenly to obtain H62 brass polishing fluid;
以上的百分比为各成分占该抛光液的体积百分比。The above percentages are the volume percentages of each component in the polishing liquid.
表1添加剂的配比Table 1 Proportion of additives
本发明的专用抛光液与传统的抛光液不同,属于含有磨料的液态抛光混合剂。该抛光液具有以下特点:The special polishing liquid of the present invention is different from the traditional polishing liquid, and belongs to the liquid polishing mixture containing abrasives. The polishing liquid has the following characteristics:
1):不腐蚀工件,抛光时不用另加磨料;1): It does not corrode the workpiece and does not need additional abrasives during polishing;
2):有效缓解机械刻划作用,加工表面质量好。2): Effectively alleviate the mechanical scoring effect, and the processed surface quality is good.
具体实施方式Detailed ways
本发明以具体实施例和具体实验来检验抛光液的抛光效果,并以与其它常用抛光液加工效果对比的方式说明本发明抛光液的优越性。The present invention examines the polishing effect of the polishing liquid with specific examples and specific experiments, and illustrates the superiority of the polishing liquid of the present invention by comparing the processing effects with other commonly used polishing liquids.
实施例1:环境温度16℃时Example 1: When the ambient temperature is 16°C
(1)实施条件(1) Implementation conditions
BDE-1B变频调速光学二轴研磨抛光机,2205表面粗糙度测量仪,专用抛光液,棉质抛光垫,直径为80mm、厚度为6mm的H62黄铜工件,抛光参数为:频率12~18Hz,抛光压力0.35~0.55N/cm2,偏心距15~20mm,抛光时间30min。BDE-1B frequency conversion and speed regulation optical two-axis grinding and polishing machine, 2205 surface roughness measuring instrument, special polishing liquid, cotton polishing pad, H62 brass workpiece with a diameter of 80mm and a thickness of 6mm. The polishing parameters are: frequency 12~ 18Hz, polishing pressure 0.35-0.55N/cm 2 , eccentricity 15-20mm, polishing time 30min.
专用抛光液的制作方法如上述所示:The preparation method of special polishing liquid is as shown above:
(2)专用抛光液的配比(2) Proportion of special polishing liquid
各组分按体积比分别为:2%的猪油、2%的磨料、4.5%的植物油、3.5%的锭子油和88%的煤油。Each component by volume ratio is: 2% lard, 2% abrasive, 4.5% vegetable oil, 3.5% spindle oil and 88% kerosene.
(3)配制方法如下,以下的百分比为占该抛光液的体积百分比。(3) The preparation method is as follows, and the following percentages are the volume percentages of the polishing liquid.
①将2%的猪油加热熔化;① Heat and melt 2% lard;
②在熔化的猪油中按体积比1∶1加入Al2O3微粉,搅拌均匀;② Add Al 2 O 3 micropowder to the melted lard at a volume ratio of 1:1, and stir evenly;
③将88%的煤油加入上述猪油与Al2O3微粉的混合剂中,均匀混合,冷却至室温备用;③Add 88% kerosene to the above-mentioned mixture of lard and Al 2 O 3 micropowder, mix evenly, and cool to room temperature for later use;
④将4.5%的植物油和3.5%的锭子油均匀混合,加入上述的混合溶液中,均匀搅拌。④ Evenly mix 4.5% vegetable oil and 3.5% spindle oil, add to the above mixed solution, and stir evenly.
本实施例的抛光效果见表2。The polishing effect of this embodiment is shown in Table 2.
实施例2:环境温度25℃时Example 2: When the ambient temperature is 25°C
(3)实施条件(3) Implementation conditions
BDE-1B变频调速光学二轴研磨抛光机,2205表面粗糙度测量仪,专用抛光液,棉质抛光垫,直径为80mm、厚度为6mm的H62黄铜工件,抛光参数为:频率12~18Hz,抛光压力0.35~0.55N/cm2,偏心距15~20mm,抛光时间30min。BDE-1B frequency conversion and speed regulation optical two-axis grinding and polishing machine, 2205 surface roughness measuring instrument, special polishing liquid, cotton polishing pad, H62 brass workpiece with a diameter of 80mm and a thickness of 6mm. The polishing parameters are: frequency 12~ 18Hz, polishing pressure 0.35-0.55N/cm 2 , eccentricity 15-20mm, polishing time 30min.
专用抛光液的制作方法如上述所示:The preparation method of special polishing liquid is as shown above:
(4)专用抛光液的配比(4) Proportion of special polishing liquid
各组分按体积比分别为:2%的猪油、2%的磨料、4%的植物油、4%的锭子油和88%的煤油。The components are respectively by volume: 2% lard, 2% abrasive, 4% vegetable oil, 4% spindle oil and 88% kerosene.
(3)配制方法如下,以下的百分比为占该抛光液的体积百分比。(3) The preparation method is as follows, and the following percentages are the volume percentages of the polishing liquid.
①将体积比为2%的猪油加热熔化;① heating and melting lard with a volume ratio of 2%;
②在熔化的猪油中按体积比1∶1加入Al2O3微粉,搅拌均匀;② Add Al 2 O 3 micropowder to the melted lard at a volume ratio of 1:1, and stir evenly;
③将体积比为88%的煤油加入上述猪油与Al2O3微粉的混合剂中,均匀混合,冷却至室温备用;③ Add kerosene with a volume ratio of 88% to the above-mentioned mixture of lard and Al2O3 micropowder, mix evenly , and cool to room temperature for later use;
④将体积比均为4%的植物油和锭子油均匀混合,加入上述的混合溶液中,均匀搅拌。④ Evenly mix vegetable oil and spindle oil with a volume ratio of 4%, add to the above mixed solution, and stir evenly.
本实施例的抛光效果见表3。The polishing effect of this embodiment is shown in Table 3.
抛光效果对比实验:环境温度为23℃。Polishing effect comparison experiment: the ambient temperature is 23°C.
(1)实验条件(1) Experimental conditions
BDE-1B变频调速光学二轴研磨抛光机,2205表面粗糙度测量仪,专用抛光液,棉质抛光垫,直径为80mm、厚度为6mm的H62黄铜工件,抛光参数为:频率12~18Hz,抛光压力0.35~0.55N/cm2,偏心距15~20mm,抛光时间30min。BDE-1B frequency conversion and speed regulation optical two-axis grinding and polishing machine, 2205 surface roughness measuring instrument, special polishing liquid, cotton polishing pad, H62 brass workpiece with a diameter of 80mm and a thickness of 6mm. The polishing parameters are: frequency 12~ 18Hz, polishing pressure 0.35-0.55N/cm 2 , eccentricity 15-20mm, polishing time 30min.
(2)其它常用抛光液的配制(2) Preparation of other commonly used polishing fluids
适合于塑性金属材料精密抛光的其它常用抛光液通常选用SiC作为磨料,其配比为:体积比为30%的磨料与混合脂的均匀混合物、20%的植物油、50%的煤油。Other commonly used polishing liquids suitable for precision polishing of plastic metal materials usually use SiC as the abrasive, and the ratio is: a homogeneous mixture of abrasive and mixed fat with a volume ratio of 30%, 20% vegetable oil, and 50% kerosene.
配制方法:Preparation method:
①将质量比为40%的硬脂酸颗粒(C17H35COOH)、40%的石蜡(柏子油)和20%的蜂蜡加热熔化、混合形成混合脂,然后过滤备用;①Heating and melting stearic acid granules (C 17 H 35 COOH), 40% paraffin (cypress oil) and 20% beeswax with a mass ratio of 40%, mixed to form a mixed fat, and then filtered for later use;
②按1∶1的体积比将粒径为3.5μm~5μm的SiC磨料,加入上述混合脂中搅拌,至混合脂均匀包裹住磨料;②Add the SiC abrasive with a particle size of 3.5 μm to 5 μm in the volume ratio of 1:1 to the above mixed fat and stir until the mixed fat evenly covers the abrasive;
③加入体积比为20%的植物油搅拌至全部溶解;③ Add vegetable oil with a volume ratio of 20% and stir until completely dissolved;
④将体积比为50%的煤油倒入上述溶液中搅拌,待溶剂全部溶解后,降温至室温。④ Pour kerosene with a volume ratio of 50% into the above solution and stir. After the solvent is completely dissolved, cool down to room temperature.
(3)本发明专用抛光液的配制方法同实施例2所述。(3) The preparation method of the special polishing liquid of the present invention is the same as that described in Example 2.
这两种抛光液的抛光效果对比如表4。The polishing effects of these two polishing solutions are compared in Table 4.
表2H62黄铜抛光后的表面粗糙度Table 2H62 Surface roughness of brass after polishing
表3H62黄铜抛光后的表面粗糙度Table 3H62 Surface roughness of brass after polishing
表4两种抛光液加工的表面粗糙度对比结果
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103275620A (en) * | 2013-06-19 | 2013-09-04 | 北京工业大学 | Special magnesium aluminum alloy polishing liquid and preparation method thereof |
CN103333617A (en) * | 2013-06-27 | 2013-10-02 | 北京工业大学 | Special polishing fluid for plastic soft metallic materials and method for preparing polishing fluid |
CN112980331A (en) * | 2019-12-16 | 2021-06-18 | 航天科工惯性技术有限公司 | Precise alloy grinding paste and manual grinding and polishing method |
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2007
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103275620A (en) * | 2013-06-19 | 2013-09-04 | 北京工业大学 | Special magnesium aluminum alloy polishing liquid and preparation method thereof |
CN103275620B (en) * | 2013-06-19 | 2014-10-22 | 北京工业大学 | Special magnesium aluminum alloy polishing liquid and preparation method thereof |
CN103333617A (en) * | 2013-06-27 | 2013-10-02 | 北京工业大学 | Special polishing fluid for plastic soft metallic materials and method for preparing polishing fluid |
CN103333617B (en) * | 2013-06-27 | 2014-12-31 | 北京工业大学 | Special polishing fluid for plastic soft metallic materials and method for preparing polishing fluid |
CN112980331A (en) * | 2019-12-16 | 2021-06-18 | 航天科工惯性技术有限公司 | Precise alloy grinding paste and manual grinding and polishing method |
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CN100497510C (en) | 2009-06-10 |
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