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CN100433365C - Aluminium gallium nitride/gallium nitride high electronic migration rate transistor and its manufacturing method - Google Patents

Aluminium gallium nitride/gallium nitride high electronic migration rate transistor and its manufacturing method Download PDF

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CN100433365C
CN100433365C CNB2006100966455A CN200610096645A CN100433365C CN 100433365 C CN100433365 C CN 100433365C CN B2006100966455 A CNB2006100966455 A CN B2006100966455A CN 200610096645 A CN200610096645 A CN 200610096645A CN 100433365 C CN100433365 C CN 100433365C
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dielectric layer
barrier layer
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gallium nitride
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CN1937249A (en
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陈堂胜
焦刚
任春江
陈辰
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CETC 55 Research Institute
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Abstract

本发明针对现有的半导体器件存在的耐击穿电压高但跨导小或跨导大而耐击穿电压低的双重矛盾,公开了一种兼具二者优点的铝镓氮化物/氮化镓高电子迁移率晶体管,同时给出其制造方法,包括沟道层(3)、势垒层(4),在势垒层(4)上设有源电极(5)和漏电极(6),在源电极(5)和漏电极(6)之间的势垒层(4)上提供一凹槽(7),在凹槽(7)中安装有方形或T形栅电极并覆盖有介质层,介质层的作用是减小栅电极上的泄漏电流,同时增加器件的最大电流;凹槽(7)的作用是提高器件的跨导。本发明同时公开了制作方法。本发明的优点在于保持了器件大的跨导的同时使器件具有小的栅极泄漏电流和大的驱动电流。

Aiming at the dual contradictions of high breakdown voltage but small transconductance or large transconductance and low breakdown voltage existing in existing semiconductor devices, the present invention discloses an aluminum gallium nitride/nitride compound with both advantages. Gallium high electron mobility transistor, and its manufacturing method is given at the same time, including a channel layer (3), a barrier layer (4), and a source electrode (5) and a drain electrode (6) are arranged on the barrier layer (4) , a groove (7) is provided on the barrier layer (4) between the source electrode (5) and the drain electrode (6), and a square or T-shaped gate electrode is installed in the groove (7) and covered with a dielectric The role of the dielectric layer is to reduce the leakage current on the gate electrode and increase the maximum current of the device; the function of the groove (7) is to increase the transconductance of the device. The invention also discloses a production method. The advantage of the present invention is that the device has small gate leakage current and large driving current while maintaining large transconductance of the device.

Description

铝镓氮化物/氮化镓高电子迁移率晶体管及制造方法 AlGaN/GaN High Electron Mobility Transistor and Manufacturing Method

技术领域 technical field

本发明涉及一种半导体结构及其制造方法,具体地说是一种铝镓氮化物/氮化镓高电子迁移率晶体管及制造方法。The invention relates to a semiconductor structure and a manufacturing method thereof, in particular to an aluminum gallium nitride/gallium nitride high electron mobility transistor and a manufacturing method thereof.

背景技术 Background technique

目前,微波系统采用半导体固态器件能够有效的减小系统体积,并提高可靠性。随着科技的发展,各种微波应用系统迫切需要适用于高温、高频、大功率、抗辐射的电子器件,基于Si和GaAs等传统半导体的电子器件在输出功率密度、耐高温及抗辐射等方面都受到很大限制,因而需要寻找新型半导体材料来替代Si和GaAs等。GaN属于新型宽带隙半导体材料,基于它的绝缘栅铝镓氮化合物(AlGaN)/氮化镓(GaN)HEMT在输出功率密度、耐高温及抗辐射上与基于Si和GaAs的器件相比具有相当大的优势,人们预计AlGaN/GaN HEMT将在2.5~30GHz频率范围内其功率输出能力全面超过GaAs器件,因而AlGaN/GaN HEMT近年来成为国际上研究的热点。At present, the use of semiconductor solid-state devices in microwave systems can effectively reduce the size of the system and improve reliability. With the development of science and technology, various microwave application systems urgently need electronic devices suitable for high temperature, high frequency, high power, and radiation resistance. All aspects are greatly restricted, so it is necessary to find new semiconductor materials to replace Si and GaAs. GaN is a new type of wide-bandgap semiconductor material. The insulated gate aluminum gallium nitride (AlGaN)/gallium nitride (GaN) HEMT based on it has comparable output power density, high temperature resistance and radiation resistance compared with devices based on Si and GaAs. It is expected that AlGaN/GaN HEMT will fully exceed the power output capability of GaAs devices in the frequency range of 2.5-30GHz, so AlGaN/GaN HEMT has become a hot spot in international research in recent years.

Khan等人(Khan et al.Applied Physics Letters,vol.63,no.9,pp.1214-1215,1993.)在1993年公开了第一只具有直流特性的AlGaN/GaNHEMT,并于公开了第一只具有微波特性的AlGaN/GaN HEMT(Khan et al.Applied Physics Letters,Vol.65,no.9,pp.1121-1123,Aug.1994.),此后对AlGaN/GaN HEMT器件的研究得到广泛开展,并取得了飞速进展。Khan et al. (Khan et al. Applied Physics Letters, vol.63, no.9, pp.1214-1215, 1993.) disclosed the first AlGaN/GaN HEMT with DC characteristics in 1993, and published the first An AlGaN/GaN HEMT with microwave characteristics (Khan et al.Applied Physics Letters, Vol.65, no.9, pp.1121-1123, Aug.1994.), and the research on AlGaN/GaN HEMT devices has been extensive since then developed and made rapid progress.

Wu等人(Wu et al.IEEE Electron Device Letters,vol.17,no.9,pp.455-457,1996.)在1996年公开了第一只具有微波功率输出的AlGaN/GaNHEMT器件,器件在2GHz输出功率密度为1.1W/mm。紧接着2000年Green等人(Green et al.IEEE Electron Device Lett.,Vol.21no.6,pp.268-270,2000.)公开了采用SiN钝化技术可以有效地抑制AlGaN/GaN HEMT的电流崩塌,为器件性能提高打下了基础,在那以后MIS、场板、栅挖槽等器件结构和工艺技术相继得到公开,并结合钝化技术,AlGaN/GaN HEMT的功率输出能力得到了进一步提高。目前,公开的小尺寸AlGaN/GaN HEMT的输出功率密度可达30W/mm以上(Wu et al.IEEE Electron Device Lett.,Vol.25,No.3,pp.117-119,2004.),大尺寸器件单芯片连续波输出功率也已达到了100W以上(Nagy et al.IEEE MTT-S International Microwave Symposium Digest,pp.483-486,2005.),脉冲功率输出甚至达到了368W(Therrien et al.IEEEIEDM Tech.Digest,pp.568-571,2005.)Wu et al. (Wu et al. IEEE Electron Device Letters, vol.17, no.9, pp.455-457, 1996.) disclosed the first AlGaN/GaN HEMT device with microwave power output in 1996. The 2GHz output power density is 1.1W/mm. Then in 2000, Green et al. (Green et al.IEEE Electron Device Lett., Vol.21no.6, pp.268-270, 2000.) disclosed that the use of SiN passivation technology can effectively suppress the current of AlGaN/GaN HEMT The collapse laid the foundation for the improvement of device performance. Since then, device structures and process technologies such as MIS, field plate, and gate trench have been disclosed one after another. Combined with passivation technology, the power output capability of AlGaN/GaN HEMT has been further improved. At present, the output power density of published small-size AlGaN/GaN HEMTs can reach more than 30W/mm (Wu et al. IEEE Electron Device Lett., Vol.25, No.3, pp.117-119, 2004.), large The single-chip continuous wave output power of large-scale devices has also reached more than 100W (Nagy et al. IEEE MTT-S International Microwave Symposium Digest, pp.483-486, 2005.), and the pulse power output even reached 368W (Therrien et al. IEEEIEDM Tech. Digest, pp.568-571, 2005.)

AlGaN/GaN HEMT的电流崩塌现象严重制约着器件性能发挥,目前工艺上普遍采用SiN钝化抑制电流崩塌,但是带来的问题是钝化后器件栅上的泄漏电流增加。材料结构上考虑,Kikkawa等人(Kikkawa et al.IEEE IEDM Tech.Digest,pp.585-588,2001.)公开了引入GaN帽层也能很好的起到抑制电流崩塌的作用。由于GaN帽层的禁带宽度比AlGaN来的小,GaN帽层的引入将导致器件在钝化后的击穿电压下降更多或者说引起器件栅上的泄漏电流进一步增大,特别是当GaN帽层处于掺杂的状态下。器件击穿电压下降则器件相应的工作电压也就降低,使得器件在微波工作状态下的动态范围减小,从而减小了器件的微波功率输出能力;同时栅上泄漏电流的增大也不利器件的可靠性。The current collapse phenomenon of AlGaN/GaN HEMT seriously restricts the performance of the device. At present, SiN passivation is generally used to suppress the current collapse in the process, but the problem is that the leakage current on the gate of the device increases after passivation. Considering the material structure, Kikkawa et al. (Kikkawa et al. IEEE IEDM Tech. Digest, pp.585-588, 2001.) disclosed that the introduction of a GaN cap layer can also effectively suppress the current collapse. Since the band gap of the GaN cap layer is smaller than that of AlGaN, the introduction of the GaN cap layer will lead to a greater drop in the breakdown voltage of the device after passivation or a further increase in the leakage current on the device gate, especially when GaN The cap layer is in a doped state. When the breakdown voltage of the device decreases, the corresponding working voltage of the device will also decrease, which will reduce the dynamic range of the device in the microwave working state, thereby reducing the microwave power output capability of the device; at the same time, the increase of the leakage current on the gate is also detrimental to the device. reliability.

为了减小器件栅上的泄漏电流、提高击穿电压,就有必要在器件栅下引入具有高击穿电场强度的介质层制成绝缘栅AlGaN/GaN HEMT。参照图1所示为一种常用的绝缘栅AlGaN/GaN HEMT结构,该HEMT包括半绝缘SiC衬底1,在衬底上依次通过金属有机化合物化学气相淀积(MOCVD)或其他合适外延方法外延生长的AlN缓冲层2、GaN高阻层3及AlGaN势垒层4,制作在势垒层4上的源欧姆接触5以及漏欧姆接触6,在源欧姆接触及漏欧姆接触之间的介质层51以及制作在介质层上的金属栅8。In order to reduce the leakage current on the device gate and increase the breakdown voltage, it is necessary to introduce a dielectric layer with high breakdown electric field strength under the device gate to make an insulating gate AlGaN/GaN HEMT. Referring to Fig. 1, it shows a commonly used insulated gate AlGaN/GaN HEMT structure, the HEMT includes a semi-insulating SiC substrate 1, on which epitaxy is sequentially carried out by metal-organic compound chemical vapor deposition (MOCVD) or other suitable epitaxy methods. The grown AlN buffer layer 2, the GaN high resistance layer 3 and the AlGaN barrier layer 4, the source ohmic contact 5 and the drain ohmic contact 6 made on the barrier layer 4, the dielectric layer between the source ohmic contact and the drain ohmic contact 51 and the metal grid 8 fabricated on the dielectric layer.

Khan等人(Khan et al.Appl.Phys.Letters,Vol.77,p.1339,2000)公开了图中介质层为SiO2的绝缘栅AlGaN/GaN HEMT。参照图1,在制备这一HEMT的过程中,介质层51为SiO2,并采用等离子体增强化学气相淀积(PECVD)方法得到的。Khan et al. (Khan et al. Appl. Phys. Letters, Vol. 77, p. 1339, 2000) disclosed an insulating gate AlGaN/GaN HEMT in which the dielectric layer is SiO 2 in the figure. Referring to FIG. 1, during the preparation of this HEMT, the dielectric layer 51 is SiO 2 , and is obtained by plasma-enhanced chemical vapor deposition (PECVD).

Hu等人(Hu et al.Appl.Phys.Letters,Vol.79,p.2832,2000)公开了图1中介质层51为氮化硅(SiN)的绝缘栅AlGaN/GaN HEMT。参照图1,该HEMT的SiN介质层51同样采用PECVD淀积方法得到。Hu et al. (Hu et al. Appl. Phys. Letters, Vol. 79, p. 2832, 2000) disclosed an insulating gate AlGaN/GaN HEMT in which the dielectric layer 51 in FIG. 1 is silicon nitride (SiN). Referring to FIG. 1 , the SiN dielectric layer 51 of the HEMT is also deposited by PECVD.

Ye等人(Ye et al.Appl.Phys.Letters,Vol.86,p.2832,2005)公开了图1中介质层51为原子层淀积技术制作的三氧化二铝(Al2O3)的绝缘栅AlGaN/GaN HEMT。参照图1,在制备这一HEMT的过程中,介质层51是通过以下方法获取的:利用原子层淀积技术在由MOCVD生长得到的AlGaN/GaN异质结材料上淀积一层Al2O3介质层51,然后再在600℃、氧气氛下退火60s。淀积完成Al2O3介质层51后才进行源欧姆接触5、漏欧姆接触6以及金属栅8的制作,其中源欧姆接触5、漏欧姆接触6制作过程中需要增加额外的光刻、刻蚀步骤以去除其下的介质层51露出势垒层4。Ye et al. (Ye et al.Appl.Phys.Letters, Vol.86, p.2832, 2005) disclosed that the dielectric layer 51 in FIG. 1 is aluminum oxide (Al 2 O 3 ) fabricated by atomic layer deposition technology. insulated gate AlGaN/GaN HEMT. Referring to Fig. 1, in the process of preparing this HEMT, the dielectric layer 51 is obtained by the following method: a layer of Al 2 O is deposited on the AlGaN/GaN heterojunction material grown by MOCVD by using atomic layer deposition technology. 3 Dielectric layer 51, and then annealed at 600°C for 60s under an oxygen atmosphere. The source ohmic contact 5, the drain ohmic contact 6, and the metal gate 8 are not fabricated until the Al2O3 dielectric layer 51 is deposited, and additional photolithography and etching processes are required during the fabrication of the source ohmic contact 5 and the drain ohmic contact 6. etch to remove the underlying dielectric layer 51 to expose the barrier layer 4 .

器件1中金属栅8和势垒层4之间引入具有高击穿电场强度的介质层51减小了金属栅8上的泄漏电流,相应的提高了击穿电压,但不利的一方面是提高了器件的阈值电压,也就是减小了器件的跨导,这将影响器件的频率特性。The introduction of a dielectric layer 51 with a high breakdown electric field strength between the metal gate 8 and the barrier layer 4 in the device 1 reduces the leakage current on the metal gate 8 and correspondingly increases the breakdown voltage, but the disadvantage is that it increases The threshold voltage of the device is reduced, that is, the transconductance of the device is reduced, which will affect the frequency characteristics of the device.

发明内容 Contents of the invention

本发明的目的是针对现有的半导体器件存在的耐击穿电压高但跨导小或跨导大而耐击穿电压低的双重矛盾,发明一种兼具二者优点的铝镓氮化物/氮化镓高电子迁移率晶体管,同时给出其制造方法。The purpose of the present invention is to invent a kind of aluminum gallium nitride/aluminum nitride compound having both advantages in view of the double contradiction of high breakdown voltage but small transconductance or large transconductance and low breakdown voltage existing in existing semiconductor devices. Gallium nitride high electron mobility transistor, and its manufacturing method is also given.

本发明的技术方案是:Technical scheme of the present invention is:

一种铝镓氮化物/氮化镓高电子迁移率晶体管,包括:An aluminum gallium nitride/gallium nitride high electron mobility transistor comprising:

一从蓝宝石、Si及SiC中选出的一种作为衬底1,One selected from sapphire, Si and SiC as the substrate 1,

一位于所述的衬底1上的缓冲层2,a buffer layer 2 on the substrate 1,

一位于所述的缓冲层2上的氮化镓沟道层3,a gallium nitride channel layer 3 on the buffer layer 2,

一在所述的沟道层3上形成的铝镓氮化物势垒层4,an aluminum gallium nitride barrier layer 4 formed on the channel layer 3,

在势垒层4上形成的源电极5和漏电极6,源电极5和漏电极6之间的间距为2-5微米,The source electrode 5 and the drain electrode 6 formed on the barrier layer 4, the distance between the source electrode 5 and the drain electrode 6 is 2-5 microns,

其特征是:在所述的源电极5和漏电极6之间的势垒层4上设有一凹槽7,在所述的凹槽7中安装有栅电极,所述的栅电极或为方形栅电极8,或为T形栅电极12;当凹槽7中安装的栅电极为方形栅电极8时,其下端伸入所述的凹槽7中,其上端凸起在第一介质层9的最高表面上,第一介质层9的覆盖范围包括源电极5和漏电极6之间的势垒层4的上表面以凹槽7的底面;当凹槽7中安装的栅电极为T形栅电极8时,其竖形下端伸入所述的凹槽7中,其横形上端凸起在第四介质层18上,所述的第四介质层18位于凹槽7中,其上部位于第三介质层13之上,第三介质层13位于源电极5和漏电极6之间的除了凹槽7部分的势垒层4上。It is characterized in that a groove 7 is provided on the barrier layer 4 between the source electrode 5 and the drain electrode 6, and a gate electrode is installed in the groove 7, and the gate electrode may be square Gate electrode 8, or T-shaped gate electrode 12; when the gate electrode installed in the groove 7 is a square gate electrode 8, its lower end extends into the groove 7, and its upper end protrudes from the first dielectric layer 9 On the highest surface, the coverage of the first dielectric layer 9 includes the upper surface of the barrier layer 4 between the source electrode 5 and the drain electrode 6 and the bottom surface of the groove 7; when the gate electrode installed in the groove 7 is T-shaped When the gate electrode 8 is used, its vertical lower end extends into the groove 7, and its horizontal upper end protrudes on the fourth dielectric layer 18. The fourth dielectric layer 18 is located in the groove 7, and its upper part is located in the second dielectric layer. Above the three dielectric layers 13 , the third dielectric layer 13 is located on the barrier layer 4 between the source electrode 5 and the drain electrode 6 except for the groove 7 .

在所述的第一介质层9上设有能将势垒层4暴露部分覆盖的第二介质层11。A second dielectric layer 11 capable of covering the exposed portion of the barrier layer 4 is provided on the first dielectric layer 9 .

当所述的第四介质层18未覆盖或部分覆盖在第三介质层13上时,在所述的第三介质层13上设有能将势垒层4暴露部分覆盖的第五介质层19,当所述的第四介质层18完全覆盖在第三介质层13上时,在所述的第三介质层13上设有能将势垒层4暴露部分覆盖的第六介质层20。When the fourth dielectric layer 18 is not covered or partially covered on the third dielectric layer 13, a fifth dielectric layer 19 capable of covering the exposed part of the barrier layer 4 is provided on the third dielectric layer 13 , when the fourth dielectric layer 18 completely covers the third dielectric layer 13 , a sixth dielectric layer 20 capable of covering the exposed part of the barrier layer 4 is provided on the third dielectric layer 13 .

所述的第一介质层9、第二介质层11、第三介质层13、第四介质层18、第五介质层19、第六介质层20为氮化硅、氮化铝、二氧化硅或三氧化二铝中的任一种,其厚度为5-15nm。The first dielectric layer 9, the second dielectric layer 11, the third dielectric layer 13, the fourth dielectric layer 18, the fifth dielectric layer 19, and the sixth dielectric layer 20 are silicon nitride, aluminum nitride, silicon dioxide Or any one of aluminum oxide, the thickness of which is 5-15nm.

所述的势垒层4的厚度介于15-50nm之间。The thickness of the barrier layer 4 is between 15-50nm.

所述的T形栅电极12的下端偏置在所述的凹槽7中,且其第一侧面14与第二侧面15间距小于0.5微米,而第三侧面16与第四侧面17间距为0.5~1.5微米,即栅电极横形上端凸起二侧面与其下端的横向距离最近分别为小于0.5微米和0.5~1.5微米。The lower end of the T-shaped gate electrode 12 is biased in the groove 7, and the distance between the first side 14 and the second side 15 is less than 0.5 microns, and the distance between the third side 16 and the fourth side 17 is 0.5 microns. ~1.5 microns, that is, the shortest lateral distances between the two sides of the horizontal upper end of the gate electrode and the lower end of the protrusion are less than 0.5 micron and 0.5-1.5 micron respectively.

根据栅电极的不同,本发明的方法共有二种,分别如下:According to the difference of gate electrode, the method of the present invention has two kinds, respectively as follows:

一、一种制造带有方形栅电极的铝镓氮化物/氮化镓高电子迁移率晶体管的方法,其特征是它包括以下步骤:1. A method for manufacturing an aluminum gallium nitride/gallium nitride high electron mobility transistor with a square gate electrode, characterized in that it comprises the following steps:

——在衬底1上采用MOCVD或RF-MBE法依次形成缓冲层2、GaN沟道层3和AlGaN势垒层4;- sequentially forming a buffer layer 2, a GaN channel layer 3 and an AlGaN barrier layer 4 on the substrate 1 by MOCVD or RF-MBE;

——在势垒层4上形成第一欧姆接触区5作为源电极;- forming a first ohmic contact region 5 on the barrier layer 4 as a source electrode;

——在势垒层4上与第一欧姆接触区相距2-5微米的地方形成第二欧姆接触区6作为漏电极;- forming a second ohmic contact region 6 on the barrier layer 4 at a distance of 2-5 microns from the first ohmic contact region as a drain electrode;

——在源电极和漏电极之间的势垒层4上利用干法或者湿法腐蚀的方法形成一凹槽7;- forming a groove 7 on the barrier layer 4 between the source electrode and the drain electrode by dry or wet etching;

——在源电极5与漏电极6之间的势垒层4上淀积一第一介质层9,第一介质层9的淀积方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积PECVD中的任一种;- Deposit a first dielectric layer 9 on the barrier layer 4 between the source electrode 5 and the drain electrode 6, the deposition method of the first dielectric layer 9 includes but not limited to sputtering, electron beam evaporation, plasma enhanced Any of chemical vapor deposition PECVD;

——在第一介质层9上形成栅电极8,栅电极8位于凹槽7两个侧壁所在的平行平面所夹的空间内。— Forming the gate electrode 8 on the first dielectric layer 9 , the gate electrode 8 is located in the space between the parallel planes where the two sidewalls of the groove 7 are located.

上述方法必要时还包括利用相同的方法在第一介质层9上再淀积一层覆盖住势垒层4暴露部分的第二介质层11。If necessary, the above method also includes depositing a second dielectric layer 11 on the first dielectric layer 9 to cover the exposed portion of the barrier layer 4 by using the same method.

二、一种制造T形栅电极的铝镓氮化物/氮化镓高电子迁移率晶体管的方法,其特征是它包括以下步骤:Two, a method for manufacturing an aluminum gallium nitride/gallium nitride high electron mobility transistor of a T-shaped gate electrode, is characterized in that it comprises the following steps:

——在衬底1上采用MOCVD或RF-MBE方法依次形成缓冲层2、GaN沟道层3、AlGaN势垒层4;——The buffer layer 2, the GaN channel layer 3, and the AlGaN barrier layer 4 are sequentially formed on the substrate 1 by MOCVD or RF-MBE method;

——在势垒层4上形成第一欧姆接触区5作为源电极;- forming a first ohmic contact region 5 on the barrier layer 4 as a source electrode;

——在势垒层4上与第一欧姆接触区相距2-5微米的地方形成第二欧姆接触区6作为漏电极;- forming a second ohmic contact region 6 on the barrier layer 4 at a distance of 2-5 microns from the first ohmic contact region as a drain electrode;

——在源电极和漏电极之间的势垒层4上利用干法或者湿法腐蚀的方法形成一凹槽7;- forming a groove 7 on the barrier layer 4 between the source electrode and the drain electrode by dry or wet etching;

——在源电极5与漏电极6之间的势垒层4除凹槽7外的表面上淀积一第三介质层13,第三介质层13的淀积方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积PECVD;- Deposit a third dielectric layer 13 on the surface of the barrier layer 4 between the source electrode 5 and the drain electrode 6 except the groove 7, the deposition method of the third dielectric layer 13 includes but not limited to sputtering, Electron beam evaporation, plasma enhanced chemical vapor deposition PECVD;

——在第三介质层13和凹槽7上淀积一第四介质层18,第四介质层18的淀积方法包括但不限于溅射、电子束蒸发或等离子体增强化学汽相淀积PECVD;- Deposit a fourth dielectric layer 18 on the third dielectric layer 13 and the groove 7, the deposition method of the fourth dielectric layer 18 includes but not limited to sputtering, electron beam evaporation or plasma enhanced chemical vapor deposition PECVD;

——在第四介质层18上形成T形栅电极12,栅电极12的两个第二侧面15,16位于凹槽7两个侧壁所在的平行平面所夹的空间内。— Form a T-shaped gate electrode 12 on the fourth dielectric layer 18 , and the two second side surfaces 15 and 16 of the gate electrode 12 are located in the space between the parallel planes where the two side walls of the groove 7 are located.

上述方法必要时还包括利用相同的方法在第三介质层13上淀积一能将势垒层4上的暴露部分覆盖的第五介质层19或在第四介质层18上淀积一能将势垒层4上的暴露部分覆盖的第六介质层20。If necessary, the above method also includes depositing a fifth dielectric layer 19 that can cover the exposed portion on the barrier layer 4 by using the same method on the third dielectric layer 13 or depositing a fifth dielectric layer 19 that can cover The exposed part on the barrier layer 4 is covered by the sixth dielectric layer 20 .

概而言之,本发明一方面提供了一种凹槽绝缘栅铝镓氮化合物/氮化镓HEMT。该HEMT包括:从蓝宝石、Si及SiC中选出的一种作为衬底,形成在衬底上的由III族氮化物构成的缓冲层,缓冲层上具有高阻特性的III族氮化物层(称之为“沟道层”)上及其上生长的一层具有更宽能隙的III族氮化物层(称之为“势垒层”),制作在势垒层上的第一个欧姆接触区作为源电极,制作在势垒层上并与第一个欧姆接触区隔开的第二个欧姆接触区作为漏极,在源电极与漏电极之间的势垒层上形成的凹槽,覆盖在源电极和漏电极之间势垒层上的介质,在介质上并正对于凹槽的栅电极,栅电极与介质层、势垒层形成三明治结构。In summary, one aspect of the present invention provides a grooved insulating gate AlGaN/GaN HEMT. The HEMT comprises: one selected from sapphire, Si and SiC as a substrate, a buffer layer formed on the substrate made of III-nitride, and a III-nitride layer ( called "channel layer") and a layer of III-nitride layer with a wider energy gap (called "barrier layer") grown on it, the first ohm layer made on the barrier layer The contact area is used as the source electrode, the second ohmic contact area formed on the barrier layer and separated from the first ohmic contact area is used as the drain, and the groove formed on the barrier layer between the source electrode and the drain electrode , the dielectric covering the barrier layer between the source electrode and the drain electrode, the gate electrode on the dielectric and facing the groove, and the gate electrode forms a sandwich structure with the dielectric layer and the barrier layer.

本发明另一方面提供了一种凹槽绝缘栅铝镓氮化合物/氮化镓HEMT的制作方法。该方法包括以下步骤:采用如MOCVD、RF-MBE等任何合适的生长方法在衬底上依次外延生长得到器件的缓冲层、GaN沟道层和势垒层,并且势垒层的带隙大于GaN沟道层,加上III族氮化物自身较强的自发极化和压电极化效应,这样将在异质结材料的界面附近形成具有高密度的二维电子气。衬底为蓝宝石、Si及SiC中的任意一种,优选地,采用半绝缘的4H-SiC和半绝缘的6H-SiC作为衬底,缓冲层的选择与衬底材料有关,势垒层一般为带隙大于GaN沟道层的AlXGa1-xN(0<x<1),其厚度约15纳米到50纳米。Another aspect of the present invention provides a method for manufacturing a grooved insulating gate aluminum gallium nitride/gallium nitride HEMT. The method includes the following steps: using any suitable growth method such as MOCVD, RF-MBE, etc. to sequentially grow epitaxially on the substrate to obtain the buffer layer, GaN channel layer and barrier layer of the device, and the band gap of the barrier layer is larger than that of GaN The channel layer, coupled with the strong spontaneous polarization and piezoelectric polarization effects of the III-nitride itself, will form a two-dimensional electron gas with high density near the interface of the heterojunction material. The substrate is any one of sapphire, Si and SiC. Preferably, semi-insulating 4H-SiC and semi-insulating 6H-SiC are used as the substrate. The selection of the buffer layer is related to the substrate material. The barrier layer is generally The AlxGa1 - xN (0<x<1) with a bandgap larger than the GaN channel layer has a thickness of about 15nm to 50nm.

在势垒层上提供两个具有相距2微米到5微米的欧姆接触区分别作为源欧姆接触电极和漏欧姆接触电极,在源欧姆接触电极和漏欧姆接触电极之间的势垒层上采用干法或者湿法刻蚀的方法形成一矩形凹槽,凹槽宽度、凹槽的两侧面与源欧姆接触电极及漏欧姆接触电极的距离取决于所制作器件的用途,凹槽的深度取决于势垒层的厚度。Two ohmic contact regions with a distance of 2 microns to 5 microns are provided on the barrier layer as the source ohmic contact electrode and the drain ohmic contact electrode respectively, and the dry barrier layer between the source ohmic contact electrode and the drain ohmic contact electrode is used method or wet etching method to form a rectangular groove, the width of the groove, the distance between the two sides of the groove and the source ohmic contact electrode and the drain ohmic contact electrode depends on the purpose of the device to be fabricated, and the depth of the groove depends on the potential The thickness of the barrier layer.

凹槽制作完成后在源欧姆接触电极和漏欧姆接触电极之间的势垒层上淀积一层5纳米到15纳米厚度的介质材料,可选择的介质材料包括但不限于氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,介质淀积的方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积(PECVD)。之后在介质层上制作金属栅电极,使得势垒层、介质层以及金属栅电极形成三明治结构,完成凹槽绝缘栅铝镓氮化合物/氮化镓HEMT的制作。After the groove is made, deposit a layer of dielectric material with a thickness of 5 nanometers to 15 nanometers on the barrier layer between the source ohmic contact electrode and the drain ohmic contact electrode. The optional dielectric material includes but is not limited to aluminum nitride (AlN ), silicon nitride (SiN), silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ), dielectric deposition methods include but not limited to sputtering, electron beam evaporation, plasma enhanced Chemical vapor deposition (PECVD). After that, a metal gate electrode is formed on the dielectric layer, so that the barrier layer, the dielectric layer and the metal gate electrode form a sandwich structure, and the fabrication of the grooved insulating gate AlGaN/GaN HEMT is completed.

本发明具有以下优点:The present invention has the following advantages:

本发明一方面继承了传统绝缘栅结构器件具有小的栅极泄漏电流、高的击穿电压和更大的电流驱动能力的优点,增大了器件在微波信号驱动下的动态范围,从而提高器件微波功率输出能力。另一方面又通过增设凹槽栅结构,以弥补引入氧化物层或者绝缘层导致器件跨导的降低,从而提高器件微波功率增益,改善器件频率特性。本发明所提出的方法具有简单、实用的优点。On the one hand, the present invention inherits the advantages of small gate leakage current, high breakdown voltage and greater current driving capability of traditional insulated gate structure devices, increases the dynamic range of devices driven by microwave signals, thereby improving the performance of devices. Microwave power output capability. On the other hand, the recessed gate structure is added to compensate for the decrease in device transconductance caused by the introduction of an oxide layer or an insulating layer, thereby increasing the microwave power gain of the device and improving the frequency characteristics of the device. The method proposed by the invention has the advantages of simplicity and practicality.

附图说明 Description of drawings

图1是常规绝缘栅AlGaN/GaN HEMT的剖面图;Figure 1 is a cross-sectional view of a conventional insulated gate AlGaN/GaN HEMT;

图2是本发明的结构示意图之一;Fig. 2 is one of structural representations of the present invention;

图3是图2中的AlGaN/GaN HEMT表面再淀积一介质层的剖面图;Fig. 3 is the sectional view of depositing a dielectric layer again on the surface of AlGaN/GaN HEMT in Fig. 2;

图4A-4C是图2结构的HEMT的制造过程示意图;4A-4C are schematic diagrams of the manufacturing process of the HEMT with the structure of FIG. 2;

图5A-5B本发明的可能存在的栅电极对不准的情况;5A-5B the possible misalignment of the gate electrodes of the present invention;

图6是本发明的结构示意图之二;Fig. 6 is the second structural representation of the present invention;

图7是图6中的AlGaN/GaN HEMT表面再淀积一介质层的剖面图;Fig. 7 is a sectional view of a dielectric layer deposited on the surface of the AlGaN/GaN HEMT in Fig. 6;

图8是本发明的结构示意图之三;Fig. 8 is the third structural diagram of the present invention;

图9是图8中的AlGaN/GaN HEMT表面再淀积一介质层的剖面图;Fig. 9 is a cross-sectional view of a dielectric layer deposited on the surface of the AlGaN/GaN HEMT in Fig. 8;

图10A-10D是本发明图2和/或图3结构的HEMT的制造过程示意图。10A-10D are schematic diagrams of the manufacturing process of the HEMT with the structure shown in FIG. 2 and/or FIG. 3 of the present invention.

具体实施方式 Detailed ways

下面结构附图和实施例对本发明作进一步的说明。The following structural drawings and embodiments further illustrate the present invention.

实施例一。Embodiment one.

图2为本发明的实施例的一个器件32。器件32中1为衬底,2为缓冲层,3为GaN沟道层,4为AlXGa1-xN(0<x<1)势垒层。衬底1为蓝宝石、Si及SiC中的任意一种,优选地,采用半绝缘的4H-SiC(0001)和半绝缘的6H-SiC(0001)作为衬底,它们具有热导率高、与GaN晶格失配小等特点,不仅易于生长高质量的GaN外延材料,同时也有利于器件的散热,目前美国的Cree公司和II-VI公司都有4H和6H两种形态的SiC衬底出售。缓冲层2位于衬底和沟道层之间,主要用来作为过渡作用,以减小由于沟道层和衬底晶格失配所引入的应力,缓冲层的选取与衬底材料有关,这在本领域是众所周知的,不再进一步描述。沟道层3为GaN层,其厚度为1微米左右。势垒层4中铝的组分x最好在0.15到0.3之间,厚度最好为15纳米到30纳米,由于势垒层1的带隙大于沟道层3,故在两层的界面处将出现一片状电荷区,该片状电荷区内所有的电子组成了一个二维电子气,有时候为增加界面处的二维电子气浓度,可对势垒层4进行掺杂,掺杂浓度最大约为4×1018cm-3。缓冲层2、沟道层3、势垒层4为采用MOCVD、RF-MBE或者其他任何合适的生长方法依次在衬底1上外延生长得到,其具体生长过程可参考相关文献。Figure 2 shows a device 32 of an embodiment of the invention. In the device 32, 1 is a substrate, 2 is a buffer layer, 3 is a GaN channel layer, and 4 is an AlxGa1 -xN (0<x<1) barrier layer. The substrate 1 is any one of sapphire, Si and SiC. Preferably, semi-insulating 4H-SiC (0001) and semi-insulating 6H-SiC (0001) are used as substrates, which have high thermal conductivity, and GaN has the characteristics of small lattice mismatch, not only easy to grow high-quality GaN epitaxial materials, but also conducive to the heat dissipation of devices. Currently, Cree and II-VI companies in the United States sell SiC substrates in 4H and 6H forms. . The buffer layer 2 is located between the substrate and the channel layer, and is mainly used as a transitional effect to reduce the stress introduced by the lattice mismatch between the channel layer and the substrate. The selection of the buffer layer is related to the substrate material. are well known in the art and will not be described further. The channel layer 3 is a GaN layer with a thickness of about 1 micron. The composition x of aluminum in the barrier layer 4 is preferably between 0.15 and 0.3, and the thickness is preferably 15 nanometers to 30 nanometers. Since the band gap of the barrier layer 1 is greater than that of the channel layer 3, at the interface of the two layers There will be a sheet-like charge region, and all the electrons in the sheet-like charge region form a two-dimensional electron gas. Sometimes in order to increase the concentration of the two-dimensional electron gas at the interface, the barrier layer 4 can be doped, doped The maximum concentration is about 4×10 18 cm -3 . The buffer layer 2, the channel layer 3, and the barrier layer 4 are obtained by epitaxial growth on the substrate 1 sequentially by MOCVD, RF-MBE or any other suitable growth method, and the specific growth process can refer to relevant literature.

在势垒层上提供欧姆接触电极5作为源电极,欧姆接触电极6作为漏电极,源电极5和漏电极6可以是Ti/Al/Ni/Au、Ti/Al/Mo/Au、Ti/Al/Ti/Au或者任何其它可与势垒层形成欧姆接触的合适的材料,源电极5和漏电极6上的金属优选的采用电子束蒸发形成,并在780℃到900℃高温下快速退火30s左右,在快速退火过程中需氮气(N2)或者任何其它合适的惰性气体保护源电极5和漏电极6的金属不被氧化。如前所述,源电极5和漏电极6的间距一般为2微米到5微米。On the barrier layer provide ohmic contact electrode 5 as source electrode, ohmic contact electrode 6 as drain electrode, source electrode 5 and drain electrode 6 can be Ti/Al/Ni/Au, Ti/Al/Mo/Au, Ti/Al /Ti/Au or any other suitable material that can form an ohmic contact with the barrier layer, the metal on the source electrode 5 and the drain electrode 6 is preferably formed by electron beam evaporation, and rapidly annealed at a high temperature of 780°C to 900°C for 30s About, nitrogen (N 2 ) or any other suitable inert gas is required to protect the metals of the source electrode 5 and the drain electrode 6 from being oxidized during the rapid annealing process. As mentioned above, the distance between the source electrode 5 and the drain electrode 6 is generally 2 microns to 5 microns.

在源欧姆接触电极和漏欧姆接触电极之间的势垒层上提供一凹槽7,凹槽7的形成可采用干法或者湿法刻蚀的方法,优选的刻蚀方法为干法刻蚀,包括反应离子刻蚀(RIE)和电感耦合等离子体刻蚀(ICP),对于干法刻蚀III族氮化物的方法和原理是众所周知的,这里不再赘述,具体可参见Egawa等人的文献(Egawa et al.Appl.Phys.Lett.,vol.76,pp.121-123,2000)或者Coffie等人的文献(Coffie et al.Applied Physics Letters Vol.83,p.4779,2003)。凹槽源侧侧壁与源电极的距离、漏侧侧壁与漏电极的距离及凹槽宽度根据实际需要而定,并取决于制造中光刻所能达到的精度,如前所述,凹槽深度取决于势垒层厚度,优选的使得凹槽下势垒层厚度剩余8纳米到20纳米。A groove 7 is provided on the barrier layer between the source ohmic contact electrode and the drain ohmic contact electrode, the groove 7 can be formed by dry or wet etching, and the preferred etching method is dry etching , including Reactive Ion Etching (RIE) and Inductively Coupled Plasma Etching (ICP), the methods and principles of dry etching Group III nitrides are well known, so I won’t go into details here. For details, please refer to the literature of Egawa et al. (Egawa et al. Appl. Phys. Lett., vol.76, pp.121-123, 2000) or Coffie et al. (Coffie et al. Applied Physics Letters Vol.83, p.4779, 2003). The distance between the side wall of the source side of the groove and the source electrode, the distance between the side wall of the drain side and the drain electrode, and the width of the groove are determined according to actual needs, and depend on the precision that can be achieved by photolithography in manufacturing. As mentioned above, the groove The depth of the groove depends on the thickness of the barrier layer, and it is preferable that the thickness of the barrier layer under the groove remains 8 nm to 20 nm.

在势垒层4暴露的表面淀积一层第一介质层9,介质层可使用的材料包括但不限于氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,第一介质层9淀积的方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积(PECVD),优选的采用电子束蒸发淀积技术。介质层厚度如前所述最好为5纳米到15纳米。A first dielectric layer 9 is deposited on the exposed surface of the barrier layer 4. The materials that can be used for the dielectric layer include but are not limited to aluminum nitride (AlN), silicon nitride (SiN), silicon oxide (SiO 2 ) and three A kind of in aluminum oxide (Al 2 O 3 ), the method for depositing the first dielectric layer 9 includes but not limited to sputtering, electron beam evaporation, plasma enhanced chemical vapor deposition (PECVD), preferably adopts electron Beam Evaporation Deposition Technology. The thickness of the dielectric layer is preferably 5 nm to 15 nm as mentioned above.

在第一介质层9上提供栅电极8,栅电极可采用的金属包括但不限于Ni/Au、Ni/Pt/Au。栅电极8源侧的侧壁可选择与凹槽7源侧侧壁接触或者不接触,同样对于栅电极8的漏侧侧壁也可选择与凹槽7漏侧侧壁接触或者分离。A gate electrode 8 is provided on the first dielectric layer 9, and metals that can be used for the gate electrode include but not limited to Ni/Au, Ni/Pt/Au. The sidewall of the source side of the gate electrode 8 can be selected to be in contact with or not in contact with the sidewall of the source side of the groove 7 , and the sidewall of the drain side of the gate electrode 8 can also be selected to be in contact with or separated from the sidewall of the drain side of the groove 7 .

图4A-4C为本实施例的一些实施方案,包括在势垒层上形成凹槽7、并在凹槽上利用自对准技术形成第一介质层9和栅金属8。如前所述,在基板1上采用MOCVD、RF-MBE或者其他任何合适的生长方法依次外延生长形成缓冲层2、沟道层3和势垒层4,在势垒层4上形成源欧姆接触电极5和漏欧姆接触电极6。4A-4C are some implementations of this embodiment, including forming a groove 7 on the barrier layer, and forming a first dielectric layer 9 and a gate metal 8 on the groove by using a self-alignment technique. As mentioned above, the buffer layer 2, the channel layer 3 and the barrier layer 4 are formed by sequential epitaxial growth on the substrate 1 by MOCVD, RF-MBE or any other suitable growth method, and the source ohmic contact is formed on the barrier layer 4. Electrode 5 and drain ohmic contact electrode 6 .

对势垒层上的凹槽进行构图,以便刻蚀形成凹槽7。如图4A所示,在器件的表面形成掩模41,以便对器件不需要形成凹槽的地方进行保护,掩模41优选的材料为光刻胶,其厚度在2微米左右,以便起到阻挡刻蚀的作用;如图4B所示,利用前面所述的刻蚀方法对势垒层4进行刻蚀,并使得凹槽7下势垒层剩余厚度为8纳米到20纳米。The groove on the barrier layer is patterned so that the groove 7 can be formed by etching. As shown in Figure 4A, form mask 41 on the surface of device, so that the place that device does not need to form groove is protected, and the preferred material of mask 41 is photoresist, and its thickness is about 2 microns, so that play barrier The effect of etching; as shown in FIG. 4B , the barrier layer 4 is etched using the aforementioned etching method, and the remaining thickness of the barrier layer under the groove 7 is 8 nm to 20 nm.

凹槽7刻蚀形成后,如图4C,去除掩模41,并在势垒层4暴露的表面淀积一第一介质层9,可选的介质层材料包括但不限于氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,淀积第一介质层9的方法优选地采用电子束蒸发的方法,以精确控制第一介质层9的厚度,第一介质层9的厚度如前所述为5纳米到15纳米。使用常规的技术在第一介质层9上形成栅金属8,由于在凹槽、栅金属不是采用自对准工艺形成的,因而有可能发生偏差,如图5A-5B所示,使得栅金属部分的覆盖到了凹槽以外,细微的偏差将不会对器件的功能产生大的影响,但是大的偏差对器件是不利的。After the groove 7 is formed by etching, as shown in FIG. 4C, the mask 41 is removed, and a first dielectric layer 9 is deposited on the exposed surface of the barrier layer 4. The optional dielectric layer material includes but is not limited to aluminum nitride (AlN ), silicon nitride (SiN), silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ), the method of depositing the first dielectric layer 9 preferably adopts the method of electron beam evaporation to The thickness of the first dielectric layer 9 is precisely controlled, and the thickness of the first dielectric layer 9 is 5 nanometers to 15 nanometers as mentioned above. Using conventional technology to form the gate metal 8 on the first dielectric layer 9, since the groove and the gate metal are not formed by a self-alignment process, deviations may occur, as shown in Figures 5A-5B, so that the gate metal part If the coverage is beyond the groove, the slight deviation will not have a big impact on the function of the device, but the large deviation will be detrimental to the device.

为了保护器件,有时候如图3所示在器件32表面再淀积一层第二介质层11对器件进行钝化形成器件33,第二介质层11包括氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,其淀积的方法包括溅射、电子束蒸发、等离子体增强化学汽相淀积(PECVD)。In order to protect the device, sometimes as shown in Figure 3, a second dielectric layer 11 is deposited on the surface of the device 32 to passivate the device to form a device 33. The second dielectric layer 11 includes aluminum nitride (AlN), silicon nitride (SiN), silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ), the deposition methods include sputtering, electron beam evaporation, plasma enhanced chemical vapor deposition (PECVD) .

概而言之,本实施例的制造方法包括以下步骤:In summary, the manufacturing method of this embodiment includes the following steps:

——在衬底1上采用MOCVD或RF-MBE法依次形成缓冲层2、GaN沟道层3和AlGaN势垒层4;- sequentially forming a buffer layer 2, a GaN channel layer 3 and an AlGaN barrier layer 4 on the substrate 1 by MOCVD or RF-MBE;

——在势垒层4上形成第一欧姆接触区5作为源电极;- forming a first ohmic contact region 5 on the barrier layer 4 as a source electrode;

——在势垒层4上与第一欧姆接触区相距2-5微米的地方形成第二欧姆接触区6作为漏电极;- forming a second ohmic contact region 6 on the barrier layer 4 at a distance of 2-5 microns from the first ohmic contact region as a drain electrode;

——在源电极和漏电极之间的势垒层4上利用干法或者湿法腐蚀的方法形成一凹槽7;- forming a groove 7 on the barrier layer 4 between the source electrode and the drain electrode by dry or wet etching;

——在源电极5与漏电极6之间的势垒层4上淀积一第一介质层9,第一介质层9的淀积方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积PECVD中的任一种;- Deposit a first dielectric layer 9 on the barrier layer 4 between the source electrode 5 and the drain electrode 6, the deposition method of the first dielectric layer 9 includes but not limited to sputtering, electron beam evaporation, plasma enhanced Any of chemical vapor deposition PECVD;

——在第一介质层9上形成栅电极8,栅电极8位于凹槽7两个侧壁所在的平行平面所夹的空间内。— Forming the gate electrode 8 on the first dielectric layer 9 , the gate electrode 8 is located in the space between the parallel planes where the two sidewalls of the groove 7 are located.

上述方法必要时还包括利用相同的方法在第一介质层9上再淀积一层覆盖住势垒层4暴露部分的第二介质层11。If necessary, the above method also includes depositing a second dielectric layer 11 on the first dielectric layer 9 to cover the exposed portion of the barrier layer 4 by using the same method.

实施例二。Embodiment two.

图6为本发明的一个实施例的带T形栅的器件34。类似于图2中的器件32,器件34具有衬底1、缓冲层2、GaN沟道层3和AlGaN势垒层4。器件34亦有与器件32位于势垒层上的源电极5和漏电极6,器件34的表面除凹槽7外全部被第三介质层13所覆盖,凹槽底部及侧壁被第四介质层18所覆盖,第四介质层18在器件表面向源电极5和漏电极6延伸并覆盖在第三介质层13上,第四介质层18只存在于栅电极12之下,器件的栅电极12为T形栅结构。T形栅12中第一侧面14与第二侧面15的距离小于0.5微米,第三侧面16与第四侧面17的距离为1微米左右,即T形栅12并不是完全对称的,这种不对称的“T”型栅结构是提高AlGaN/GaN HEMT性能所需要的。FIG. 6 is a device 34 with a T-shaped gate according to an embodiment of the present invention. Similar to device 32 in FIG. 2 , device 34 has substrate 1 , buffer layer 2 , GaN channel layer 3 and AlGaN barrier layer 4 . The device 34 also has a source electrode 5 and a drain electrode 6 located on the barrier layer with the device 32. The surface of the device 34 is covered by the third dielectric layer 13 except the groove 7, and the bottom and side walls of the groove are covered by the fourth dielectric layer. Covered by the layer 18, the fourth dielectric layer 18 extends toward the source electrode 5 and the drain electrode 6 on the surface of the device and covers the third dielectric layer 13, the fourth dielectric layer 18 only exists under the gate electrode 12, and the gate electrode of the device 12 is a T-shaped gate structure. The distance between the first side 14 and the second side 15 in the T-shaped grid 12 is less than 0.5 micron, and the distance between the third side 16 and the fourth side 17 is about 1 micron, that is, the T-shaped grid 12 is not completely symmetrical. A symmetrical "T" gate structure is required to improve the performance of AlGaN/GaN HEMTs.

缓冲层2、GaN沟道层3和AlGaN势垒层4器件32的一样在基板1上采用MOCVD、RF-MBE或者其他任何合适的生长方法依次外延生长形成,之后是源电极5和漏电极6的制作,它们的制作方法与前面实施例中的完全相同。The buffer layer 2, the GaN channel layer 3 and the AlGaN barrier layer 4 device 32 are formed on the substrate 1 by sequential epitaxial growth using MOCVD, RF-MBE or any other suitable growth method, followed by the source electrode 5 and the drain electrode 6 The production of them is exactly the same as in the previous embodiment.

在势垒层4的暴露部分上淀积一层第三介质层13以方便形成所需的“T”型栅,第三介质层13优选的介质材料为SiN,它已被证明能够有效地抑制器件表面态引起的电流崩塌现象,第三介质层13的厚度最好为100nm以上。A third dielectric layer 13 is deposited on the exposed part of the barrier layer 4 to facilitate the formation of the required "T" gate. The preferred dielectric material for the third dielectric layer 13 is SiN, which has been proven to effectively inhibit For the current collapse phenomenon caused by the surface state of the device, the thickness of the third dielectric layer 13 is preferably more than 100 nm.

凹槽7的形成过程如图10A-10B所示。如图10A所示,在器件的表面形成掩模42,以便对器件不需要形成凹槽的地方进行保护,掩模42优选的材料为光刻胶,其厚度为2微米左右,以便起到阻挡刻蚀的作用;如图10B所示,首先是刻蚀介质层,对于SiN介质材料的刻蚀方法是已知的,此处不再详述,然后利用前面所述的刻蚀方法对势垒层4进行刻蚀以形成凹槽7。The forming process of the groove 7 is shown in Figs. 10A-10B. As shown in Figure 10A, form mask 42 on the surface of device, so that the place that device does not need to form groove is protected, and the preferred material of mask 42 is photoresist, and its thickness is about 2 microns, so that play barrier The effect of etching; as shown in Figure 10B, firstly, the dielectric layer is etched, and the etching method for SiN dielectric material is known, and will not be described in detail here, and then the barrier is etched by the etching method described above. Layer 4 is etched to form recesses 7 .

第四介质层18和T形栅12的形成如图10C-10D所示。如图10C所示,去除掩模42并在器件表面形成掩模43,对不需要淀积第三介质层13的地方进行保护。如图10D所示,在器件的整个表面淀积一第三介质层13,可选的介质层材料如前所述,淀积第三介质层13的方法优选地采用电子束蒸发的方法,以便其后进行的剥离工艺的实施,第三介质层13的厚度如前所述为5纳米到15纳米,可选的介质层材料包括但不限于氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种。介质层淀积过程中,第三介质层13同时也覆盖在了掩模43上。第三介质层13淀积完成后,利用电子束蒸发淀积技术,在器件的整个表面淀积一层栅金属12,栅金属12淀积过程中,栅金属12同时也覆盖在了位于掩模43上的第三介质层13上,栅金属12的厚度与第三介质层13的厚度总和应保证低于掩模43厚度的一半。最后利用剥离工艺将掩模43及其上的第三介质层13栅金属12去除,得到器件36。The formation of the fourth dielectric layer 18 and the T-shaped gate 12 is shown in FIGS. 10C-10D . As shown in FIG. 10C , the mask 42 is removed and a mask 43 is formed on the surface of the device to protect the place where the third dielectric layer 13 does not need to be deposited. As shown in FIG. 10D, a third dielectric layer 13 is deposited on the entire surface of the device. The optional dielectric layer material is as mentioned above. The method for depositing the third dielectric layer 13 preferably adopts the method of electron beam evaporation, so that In the subsequent implementation of the stripping process, the thickness of the third dielectric layer 13 is 5 nanometers to 15 nanometers as mentioned above, and the optional dielectric layer materials include but are not limited to aluminum nitride (AlN), silicon nitride (SiN) , silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ). During the deposition of the dielectric layer, the third dielectric layer 13 also covers the mask 43 at the same time. After the deposition of the third dielectric layer 13 is completed, a layer of gate metal 12 is deposited on the entire surface of the device using electron beam evaporation deposition technology. During the deposition of the gate metal 12, the gate metal 12 also covers the On the third dielectric layer 13 above 43 , the sum of the thickness of the gate metal 12 and the thickness of the third dielectric layer 13 should be guaranteed to be less than half of the thickness of the mask 43 . Finally, the mask 43 and the gate metal 12 on the third dielectric layer 13 are removed by a lift-off process to obtain the device 36 .

图10C-10D的实施方案中栅金属12和第三介质层13是通过自对准工艺实现的,从而保证了第三介质层13完全处于栅金属12之下。In the embodiments of FIGS. 10C-10D , the gate metal 12 and the third dielectric layer 13 are realized through a self-alignment process, thereby ensuring that the third dielectric layer 13 is completely under the gate metal 12 .

如图6所示,有时候为了保护器件在器件34表面再淀积一层第五介质层19对进行钝化形成器件35,可选的介质层材料包括氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,淀积的方法包括溅射、电子束蒸发、等离子体增强化学汽相淀积(PECVD)。As shown in FIG. 6, sometimes in order to protect the device, a fifth dielectric layer 19 is deposited on the surface of the device 34 to passivate the device 35. The optional dielectric layer materials include aluminum nitride (AlN), silicon nitride (SiN), silicon oxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ), the deposition methods include sputtering, electron beam evaporation, plasma enhanced chemical vapor deposition (PECVD).

概而言之,T形结构的晶体管的制造方法主要包括以下步骤:In a nutshell, the method for manufacturing a transistor with a T-shaped structure mainly includes the following steps:

——在衬底1上采用MOCVD或RF-MBE方法依次形成缓冲层2、GaN沟道层3、AlGaN势垒层4;——The buffer layer 2, the GaN channel layer 3, and the AlGaN barrier layer 4 are sequentially formed on the substrate 1 by MOCVD or RF-MBE method;

——在势垒层4上形成第一欧姆接触区5作为源电极;- forming a first ohmic contact region 5 on the barrier layer 4 as a source electrode;

——在势垒层4上与第一欧姆接触区相距2-5微米的地方形成第二欧姆接触区6作为漏电极;- forming a second ohmic contact region 6 on the barrier layer 4 at a distance of 2-5 microns from the first ohmic contact region as a drain electrode;

——在源电极和漏电极之间的势垒层4上利用干法或者湿法腐蚀的方法形成一凹槽7;- forming a groove 7 on the barrier layer 4 between the source electrode and the drain electrode by dry or wet etching;

——在源电极5与漏电极6之间的势垒层4除凹槽7外的表面上淀积一第三介质层13,第三介质层13的淀积方法包括但不限于溅射、电子束蒸发、等离子体增强化学汽相淀积PECVD;- Deposit a third dielectric layer 13 on the surface of the barrier layer 4 between the source electrode 5 and the drain electrode 6 except the groove 7, the deposition method of the third dielectric layer 13 includes but not limited to sputtering, Electron beam evaporation, plasma enhanced chemical vapor deposition PECVD;

——在第三介质层13和凹槽7上淀积一第四介质层18,第四介质层18的淀积方法包括但不限于溅射、电子束蒸发或等离子体增强化学汽相淀积PECVD;- Deposit a fourth dielectric layer 18 on the third dielectric layer 13 and the groove 7, the deposition method of the fourth dielectric layer 18 includes but not limited to sputtering, electron beam evaporation or plasma enhanced chemical vapor deposition PECVD;

——在第四介质层18上形成T形栅电极12,栅电极12的两个第二侧面15,16位于凹槽7两个侧壁所在的平行平面所夹的空间内。— Form a T-shaped gate electrode 12 on the fourth dielectric layer 18 , and the two second side surfaces 15 and 16 of the gate electrode 12 are located in the space between the parallel planes where the two side walls of the groove 7 are located.

上述方法必要时还包括利用相同的方法在第三介质层13上淀积一能将势垒层4上的暴露部分覆盖的第五介质层19或在第四介质层18上淀积一能将势垒层4上的暴露部分覆盖的第六介质层20If necessary, the above method also includes depositing a fifth dielectric layer 19 that can cover the exposed portion on the barrier layer 4 by using the same method on the third dielectric layer 13 or depositing a fifth dielectric layer 19 that can cover The sixth dielectric layer 20 covered by the exposed part on the barrier layer 4

实施例三。Embodiment three.

图8为本发明的另一个实施例的一个带T形栅的器件36。同前面实施例中的器件,器件36具有衬底1、缓冲层2、GaN沟道层3和AlGaN势垒层4、位于势垒层上的源电极5和漏电极6,器件36的表面除凹槽7外被第三介质层13所覆盖,第四介质层18则不仅仅存在于栅金属下同时也覆盖了第三介质层13的暴露部分,器件36的栅电极12同器件34一样为T形栅结构。同样第一侧面14与第二侧面15的距离小于0.5微米,第三侧面16与第四侧面17的距离为1微米左右,以提高AlGaN/GaN HEMT的性能。FIG. 8 shows a device 36 with a T-shaped gate according to another embodiment of the present invention. Same as the device in the previous embodiment, the device 36 has a substrate 1, a buffer layer 2, a GaN channel layer 3, an AlGaN barrier layer 4, a source electrode 5 and a drain electrode 6 on the barrier layer, and the surface of the device 36 except The groove 7 is covered by the third dielectric layer 13, and the fourth dielectric layer 18 not only exists under the gate metal but also covers the exposed part of the third dielectric layer 13. The gate electrode 12 of the device 36 is the same as the device 34. T-shaped gate structure. Similarly, the distance between the first side 14 and the second side 15 is less than 0.5 micron, and the distance between the third side 16 and the fourth side 17 is about 1 micron, so as to improve the performance of the AlGaN/GaN HEMT.

缓冲层2、GaN沟道层3和AlGaN势垒层4、源电极5和漏电极6的形成同前面实施例,凹槽7的形成过程如图10A-10B所示,方法与器件34中的相同。The formation of the buffer layer 2, the GaN channel layer 3, the AlGaN barrier layer 4, the source electrode 5 and the drain electrode 6 is the same as in the previous embodiment, and the formation process of the groove 7 is shown in Figures 10A-10B, the method and the device 34 same.

如图10B中的凹槽7形成之后,器件表面的掩模42被去除,第四介质层18被淀积到势垒层4暴露的表面,可选的介质材料同器件34,淀积第四介质层18的方法优选地采用溅射的方法,以便对凹槽的侧面形成良好的覆盖,第四介质层18的厚度为5纳米到15纳米。使用常规的技术在第四介质层18上形成栅金属12,由于在凹槽、栅金属不是采用自对准工艺形成的,因而同器件32一样有可能发生偏差,同样细微的偏差将不会对器件的功能产生大的影响,但是大的偏差对器件是不利的。After the groove 7 is formed as shown in Figure 10B, the mask 42 on the device surface is removed, and the fourth dielectric layer 18 is deposited on the exposed surface of the barrier layer 4. The optional dielectric material is the same as the device 34, and the fourth dielectric layer is deposited. The method of the dielectric layer 18 is preferably sputtering, so as to form a good coverage on the side of the groove, and the thickness of the fourth dielectric layer 18 is 5 nanometers to 15 nanometers. Use conventional technology to form the gate metal 12 on the fourth dielectric layer 18. Since the groove and the gate metal are not formed by a self-alignment process, deviations may occur as with the device 32, and the same slight deviation will not be correct. The functionality of the device has a large influence, but large deviations are detrimental to the device.

如图9所示再淀积一层第六介质层20在表面对器件进行钝化形成器件37,可选的介质层材料包括氮化铝(AlN)、氮化硅(SiN)、氧化硅(SiO2)和三氧化二铝(Al2O3)中的一种,淀积的方法包括溅射、电子束蒸发、等离子体增强化学汽相淀积(PECVD)。As shown in Figure 9, a sixth dielectric layer 20 is deposited on the surface to passivate the device to form a device 37. The optional dielectric layer materials include aluminum nitride (AlN), silicon nitride (SiN), silicon oxide ( SiO 2 ) and aluminum oxide (Al 2 O 3 ), the deposition method includes sputtering, electron beam evaporation, plasma enhanced chemical vapor deposition (PECVD).

制造方法可参照实施例二进行。The manufacturing method can be carried out with reference to the second embodiment.

本发明未详细描述的部分均与现有技术相同。The parts not described in detail in the present invention are the same as the prior art.

Claims (13)

1, a kind of aluminum gallium nitride/GaN high electron mobility transistor comprises:
One substrate (1),
One is positioned at the resilient coating (2) on the described substrate (1),
One is positioned at the gallium nitride channel layer (3) on the described resilient coating (2),
One at the last aluminum gallium nitride barrier layer (4) that forms of described channel layer (3),
Go up source electrode (5) and the drain electrode (6) that forms at barrier layer (4), the spacing between source electrode (5) and the drain electrode (6) is the 2-5 micron,
It is characterized in that: on the barrier layer (4) between described source electrode (5) and the drain electrode (6), be provided with a groove (7), in described groove (7), gate electrode be installed, described gate electrode or be square gate electrode (8), or be T shape gate electrode (12); When the gate electrode of installing in the groove (7) is square gate electrode (8), its lower end is stretched in the described groove (7), and the coverage of first dielectric layer (9) comprises the bottom surface of the upper surface and the groove (7) of the barrier layer (4) between source electrode (5) and the drain electrode (6); When the gate electrode of installing in the groove (7) is T shape gate electrode (8), its perpendicular shape lower end is stretched in the described groove (7), its horizontal shape upper end projection is on the 4th dielectric layer (18), described the 4th dielectric layer (18) is arranged in groove (7), its top is positioned on the 3rd dielectric layer (13), and the 3rd dielectric layer (13) is positioned on the barrier layer (4) except groove (7) part between source electrode (5) and the drain electrode (6).
2, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1 is characterized in that being provided with second dielectric layer (11) that barrier layer (4) expose portion can be covered on described first dielectric layer (9).
3, aluminum gallium nitride/GaN high electron mobility transistor according to claim 2, it is characterized in that described first dielectric layer (9), second dielectric layer (11) are any in silicon nitride, aluminium nitride, silicon dioxide or the alundum (Al, its thickness is 5-15nm.
4, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1, it is characterized in that when described the 4th dielectric layer (18) does not cover or partly cover on the 3rd dielectric layer (13), on described the 3rd dielectric layer (13), be provided with the 5th dielectric layer (19) that barrier layer (4) expose portion can be covered, when described the 4th dielectric layer (18) covers on the 3rd dielectric layer (13) fully, on described the 3rd dielectric layer (13), be provided with the 6th dielectric layer (20) that barrier layer (4) expose portion can be covered.
5, aluminum gallium nitride/GaN high electron mobility transistor according to claim 4, it is characterized in that described the 3rd dielectric layer (13), the 4th dielectric layer (18), the 5th dielectric layer (19) and the 6th dielectric layer (20) are any in silicon nitride, aluminium nitride, silicon dioxide or the alundum (Al, its thickness is 5-15nm.
6, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1, it is characterized in that described first dielectric layer (9), the 3rd dielectric layer (13), the 4th dielectric layer (18) are any in silicon nitride, aluminium nitride, silicon dioxide or the alundum (Al, its thickness is 5-15nm.
7, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1, the thickness that it is characterized in that described barrier layer (4) is between 15-50nm.
8, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1, the lower end that it is characterized in that described T shape gate electrode (12) is biased in the described groove (7), and its first side (14) and second side (15) spacing are less than 0.5 micron, and the 3rd side (16) are 0.5~1.5 micron with the 4th side (17) spacing.
9, aluminum gallium nitride/GaN high electron mobility transistor according to claim 1, wherein substrate (1) is any among SiC, sapphire or the Si.
10, a kind of described method that has the aluminum gallium nitride/GaN high electron mobility transistor of square gate electrode of claim 1 of making is characterized in that it may further comprise the steps:
---upward adopt MOCVD or RF-MBE method to form resilient coating (2), GaN channel layer (3) and AlGaN barrier layer (4) successively at substrate (1);
---go up formation first ohmic contact regions (5) as the source electrode at barrier layer (4);
---upward form second ohmic contact regions (6) as drain electrode at a distance of the place of 2-5 micron at barrier layer (4) with first ohmic contact regions;
---on the barrier layer between source electrode and the drain electrode (4), utilize the method for dry method or wet etching to form a groove (7);
---the barrier layer (4) between source electrode (5) and drain electrode (6) is gone up deposit one first dielectric layer (9), and the deposition process of first dielectric layer (9) comprises any in sputter or electron beam evaporation or the plasma reinforced chemical vapor deposition;
---go up formation gate electrode (8) at first dielectric layer (9), gate electrode (8) is positioned at the folded space of parallel plane at (7) two sidewall places of groove.
11, manufacturing according to claim 10 has the method for the aluminum gallium nitride/GaN high electron mobility transistor of square gate electrode, it is characterized in that it also comprise utilize identical method on first dielectric layer (9) again deposit one deck cover second dielectric layer (11) of barrier layer (4) expose portion.
12, a kind of method of making the aluminum gallium nitride/GaN high electron mobility transistor of the described T of the having shape of claim 1 gate electrode is characterized in that it may further comprise the steps:
---upward adopt MOCVD or RF-MBE method to form resilient coating (2), GaN channel layer (3), AlGaN barrier layer (4) successively at substrate (1);
---go up formation first ohmic contact regions (5) as the source electrode at barrier layer (4);
---upward form second ohmic contact regions (6) as drain electrode at a distance of the place of 2-5 micron at barrier layer (4) with first ohmic contact regions;
---on the barrier layer between source electrode and the drain electrode (4), utilize the method for dry method or wet etching to form a groove (7);
---deposit 1 the 3rd dielectric layer (13) on the surface of barrier layer (4) except that groove (7) between source electrode (5) and drain electrode (6), the deposition process of the 3rd dielectric layer (13) comprises sputter, electron beam evaporation or plasma reinforced chemical vapor deposition;
---go up deposit 1 the 4th dielectric layer (18) at the 3rd dielectric layer (13) and groove (7), the deposition process of the 4th dielectric layer (18) comprises sputter, electron beam evaporation or plasma reinforced chemical vapor deposition;
---go up formation T shape gate electrode (12) at the 4th dielectric layer (18), second side (15) of gate electrode (12) and the 3rd side (16) are positioned at the folded space of parallel plane at (7) two sidewall places of groove.
13, manufacturing according to claim 12 has the method for the aluminum gallium nitride/GaN high electron mobility transistor of T shape gate electrode, it is characterized in that it comprises that also utilizing identical method to go up deposit one at the 3rd dielectric layer (13) can go up the 6th dielectric layer (20) that deposit one can cover the expose portion on the barrier layer (4) with the 5th dielectric layer (19) of the covering of the expose portion on the barrier layer (4) or at the 4th dielectric layer (18).
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