CN100382691C - Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application - Google Patents
Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application Download PDFInfo
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- CN100382691C CN100382691C CNB2005100943957A CN200510094395A CN100382691C CN 100382691 C CN100382691 C CN 100382691C CN B2005100943957 A CNB2005100943957 A CN B2005100943957A CN 200510094395 A CN200510094395 A CN 200510094395A CN 100382691 C CN100382691 C CN 100382691C
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- Prior art keywords
- grams
- prochloraz
- dimethachlon
- manganese salt
- dimetachlone
- Prior art date
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- CFZLNRGUBAVQNO-UHFFFAOYSA-N N-(3,5-Dichlorophenyl)succinimide Chemical compound ClC1=CC(Cl)=CC(N2C(CCC2=O)=O)=C1 CFZLNRGUBAVQNO-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000005820 Prochloraz Substances 0.000 title claims abstract description 31
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 150000002696 manganese Chemical class 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 title abstract description 15
- 230000002070 germicidal effect Effects 0.000 title abstract 3
- 239000000843 powder Substances 0.000 claims abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 239000000546 pharmaceutical excipient Substances 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 241000221662 Sclerotinia Species 0.000 claims description 12
- 230000000844 anti-bacterial effect Effects 0.000 claims description 11
- 235000006008 Brassica napus var napus Nutrition 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 9
- 238000009736 wetting Methods 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 240000000385 Brassica napus var. napus Species 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 manganese salt Chemical class 0.000 description 16
- 244000060924 Brassica campestris Species 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- OXOKTPUZOHPXSA-UHFFFAOYSA-L manganese(2+);n-propyl-n-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide;dichloride Chemical compound Cl[Mn]Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl.C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl OXOKTPUZOHPXSA-UHFFFAOYSA-L 0.000 description 7
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 6
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 6
- 239000011565 manganese chloride Substances 0.000 description 6
- 229940099607 manganese chloride Drugs 0.000 description 6
- 241000221785 Erysiphales Species 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- 235000002566 Capsicum Nutrition 0.000 description 4
- 240000007594 Oryza sativa Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 125000003368 amide group Chemical group 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241000198596 Alternaria tomatophila Species 0.000 description 2
- 244000099147 Ananas comosus Species 0.000 description 2
- 235000007119 Ananas comosus Nutrition 0.000 description 2
- 241001465180 Botrytis Species 0.000 description 2
- 235000004936 Bromus mango Nutrition 0.000 description 2
- 240000008574 Capsicum frutescens Species 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 240000007228 Mangifera indica Species 0.000 description 2
- 235000014826 Mangifera indica Nutrition 0.000 description 2
- 244000302512 Momordica charantia Species 0.000 description 2
- 235000009811 Momordica charantia Nutrition 0.000 description 2
- 235000009812 Momordica cochinchinensis Nutrition 0.000 description 2
- 235000018365 Momordica dioica Nutrition 0.000 description 2
- 240000005561 Musa balbisiana Species 0.000 description 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 2
- 239000006002 Pepper Substances 0.000 description 2
- 235000016761 Piper aduncum Nutrition 0.000 description 2
- 240000003889 Piper guineense Species 0.000 description 2
- 235000017804 Piper guineense Nutrition 0.000 description 2
- 235000008184 Piper nigrum Nutrition 0.000 description 2
- 241000899394 Pseudocercospora Species 0.000 description 2
- 241000589516 Pseudomonas Species 0.000 description 2
- 206010039509 Scab Diseases 0.000 description 2
- 241001533598 Septoria Species 0.000 description 2
- 235000009184 Spondias indica Nutrition 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 244000098338 Triticum aestivum Species 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000001390 capsicum minimum Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000223600 Alternaria Species 0.000 description 1
- 241000223602 Alternaria alternata Species 0.000 description 1
- 241000222195 Ascochyta Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 1
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241001157813 Cercospora Species 0.000 description 1
- 241000228437 Cochliobolus Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000221787 Erysiphe Species 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses one kind of synergistic germicide composition containing prochloraz or its manganese salt and dimetachlone. The synergistic germicide composition contains prochloraz or its manganese salt in 10-60 weight portions, dimetachlone in 1-30 weight portions and assistant in 0-15 weight portions, as well as excipient. It may be re-compounded into powder preparation, wettable powder, emulsion, oil emulsion or other preparation forms, and has the advantages of small consumption, low cost and high effect.
Description
Technical field
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of is the bactericidal composition and the application thereof of main active with Prochloraz (or its manganese salt) and dimethachlon.
Background technology
Prochloraz (prochloraz) (or its manganese salt prochloraz-manganese chloridecomplex) is a kind of efficient, broad spectrum activity imidazoles bactericide and freshness preserving agent for fruit and vegetable, be used for cereal controls pseudo-cercospora, nuclear cavity Pseudomonas, spore and belong to and the Septoria fungi, to early stage eye spot disease, leaf spot and powdery mildew, preventive effect is arranged.Be used for that oilseeds, grape can be prevented and treated Alternaria, Botrytis, pseudo-cercospora, bury Sclerotinia, the Sclerotinia fungi.Living Cercospora and Erysiphe on Ascochyta on the control leguminous plant, Botrytis, the beet have preventive and therapeutic effect for the cochliobolus genus on the cereal, Fusarium, nuclear cavity Pseudomonas, the fungus-caused disease of Septoria.In addition, can prevent and treat the cauliflower leaf spot, rice blast.
Prochloraz is in Crop in China, and especially fresh-keeping aspect is widely used, and use obtains good result on sclerotinia rot of colza does not also have the pertinent literature explanation.
Dimethachlon (dimetachlone) is a kind of protective fungicide punishment, and certain interior suction therapeutic action is arranged.Be mainly used in and prevent and treat rice sheath blight disease and sclerotinia rot of colza, Alternaria alternate.Because the long-term dimethachlon control sclerotinia rot of colza that uses causes present drug effect obviously to descend, and can not satisfy and prevent and treat stalk break, guarantees the needs of crops normal growth.
Summary of the invention
The purpose of this invention is to provide a kind of is the bactericidal composition and the application thereof of main active with Prochloraz (or its manganese salt) and dimethachlon.
Technical scheme of the present invention is:
A kind of efficient bactericidal composite that contains Prochloraz or its manganese salt and dimethachlon, it is characterized in that it is is effective ingredient by Prochloraz (or its manganese salt) and dimethachlon, add preparations such as auxiliary agent, the composite pulvis that forms of excipient, wetting powder, suspension emulsion, missible oil, wherein the weight portion of Prochloraz (or its manganese salt) is 20～60, the weight portion of dimethachlon is 1～30, auxiliary agent is 0～15 part, and surplus is an excipients.
Optimum weight part of Prochloraz (or its manganese salt) is 15～50, and optimum weight part of dimethachlon is 2～30.
The efficient bactericidal composite that contains Prochloraz or its manganese salt and dimethachlon of the present invention can be used for preventing and treating cereal class, melon, really, vegetables, banana, capsicum, paddy rice, mango, pineapple, tobacco diseases.
The efficient bactericidal composite that contains Prochloraz or its manganese salt and dimethachlon of the present invention can be used for preventing and treating wheat powdery mildew, sclerotinia rot of colza, pepper anthracnose, balsam pear scab, scutellum rot of orange, powdery mildew of cucumber, early blight of tomato and late blight.
Beneficial effect of the present invention:
The Prochloraz that the present invention is used or its manganese salt are azoles fungicides, and dimethachlon is a carboxylic acid imide fungicides, and both are mixed mutually and can not produce low touching, but Synergistic reduces dosage.The present invention is specially adapted to prevent and treat effect diseases such as cereal class, various melon and fruit, vegetables, banana, capsicum, paddy rice, mango, pineapple, as wheat powdery mildew, sclerotinia rot of colza, pepper anthracnose, balsam pear scab, scutellum rot of orange, powdery mildew of cucumber, early blight of tomato and late blight.Be particularly useful for preventing and treating sclerotinia rot of colza superior effect is arranged
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment 1:
With Prochloraz 10 grams, dimethachlon 20 grams, calcium dodecyl benzene sulfonate 3 grams, phenethyl phenol polyethenoxy ether 2 grams, dimethylbenzene adds to 100 grams, is mixed to homogeneous phase liquid, obtains composition missible oil.
Embodiment 2:
With prochloraz-manganese chloride complex 20 grams, dimethachlon 30 grams, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3 grams, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2 grams, white carbon 5 grams, kaolin adds to 100 gram mixtures and carries out comminution by gas stream, makes wetting powder.
Embodiment 3:
With Prochloraz 20 grams, dimethachlon 5 grams, phenethyl phenol polyethenoxy ether phosphonate ester 3 grams, polyoxyethylene nonylphenol ether 2 grams, propane diols 5 grams, deionized water add to 100 grams, utilize high-shear homogenizer to stir, and obtain aqueous emulsion.
Embodiment 4:
Prochloraz-manganese chloride complex 25 grams, dimethachlon 25 grams, talcum powder 50 grams are mixed, obtain pulvis.
Embodiment 5:
With Prochloraz 10 grams, dimethachlon 15 grams, emulsifier one, all the other are dimethylbenzene, and mixing obtains missible oil.
Embodiment 6:
Just prochloraz-manganese chloride complex 10 grams, dimethachlon 30 grams, detergent LS5 gram, carboxymethyl cellulose 5 grams, precipitated calcium carbonate 50 grams mix, and obtain wetting powder.
Embodiment 7:
Just prochloraz-manganese chloride complex 45 grams, dimethachlon 25 grams, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3 grams, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2 restrain, and kaolin adds to 100 grams to be mixed, and obtains wetting powder.
Embodiment 8:
With Prochloraz 10 grams, dimethachlon 60 grams, calcium dodecyl benzene sulfonate 3 grams, phenethyl phenol polyethenoxy ether 2 grams, dimethylbenzene adds to 100 grams, is mixed to homogeneous phase liquid, obtains composition missible oil.
Embodiment 9:
With prochloraz-manganese chloride complex 60 grams, dimethachlon 1 gram, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3 grams, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2 grams, white carbon 5 grams, kaolin adds to 100 gram mixtures and carries out comminution by gas stream, makes wetting powder.
Embodiment 10:
With Prochloraz 15 grams, dimethachlon 30 grams, phenethyl phenol polyethenoxy ether phosphonate ester 3 grams, polyoxyethylene nonylphenol ether 2 grams, propane diols 5 grams, deionized water add to 100 grams, utilize high-shear homogenizer to stir, and obtain aqueous emulsion.
Embodiment 11:
With Prochloraz 15 grams, dimethachlon 2 grams, calcium dodecyl benzene sulfonate 3 grams, phenethyl phenol polyethenoxy ether 2 grams, dimethylbenzene adds to 100 grams, is mixed to homogeneous phase liquid, obtains composition missible oil.
Embodiment 12:
With prochloraz-manganese chloride complex 50 grams, dimethachlon 30 grams, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 3 grams, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 2 grams, white carbon 5 grams, kaolin adds to 100 gram mixtures and carries out comminution by gas stream, makes wetting powder.
Embodiment 13:
With Prochloraz 50 grams, dimethachlon 2 grams, phenethyl phenol polyethenoxy ether phosphonate ester 3 grams, polyoxyethylene nonylphenol ether 2 grams, propane diols 5 grams, deionized water add to 100 grams, utilize high-shear homogenizer to stir, and obtain aqueous emulsion.
Application example.
Make the test of preparation control sclerotinia rot of colza with embodiment.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, the contrast medicament be respectively commercially available agricultural chemicals 45% Prochloraz missible oil (EC) but and 40% dimethachlon wet-milling (WP) and blank clear water test.
2, each sub-district area of test method is 66.7m
2, repeat 3 times; Investigation method after investigation and the control, random sampling 10 points in the test treatment region, the sclerotinia rot of colza occurrence degree is checked in every 5 strain.
3, result of the test sees the following form:
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Field efficacy is the result show, Prochloraz and dimethachlon composition have good control efficiency to sclerotinia rot of colza, and control efficiency all is better than single agent kind.
Claims (3)
1. efficient bactericidal composite that contains Prochloraz or its manganese salt and dimethachlon, it is characterized in that it is is effective ingredient by Prochloraz or its manganese salt and dimethachlon, add auxiliary agent, the composite pulvis that forms of excipient, wetting powder, suspension emulsion, cream preparation, wherein the weight portion of Prochloraz or its manganese salt is 10～60, the weight portion of dimethachlon is 1～30, auxiliary agent is 0～15 part, and surplus is an excipients, and reaching total umber is 100 parts.
2. the efficient bactericidal composite that contains Prochloraz or its manganese salt and dimethachlon according to claim 1, the weight portion that it is characterized in that Prochloraz or its manganese salt is 15～50, the weight portion of dimethachlon is 2～30.
3. the described application of efficient bactericidal composite on the control sclerotinia rot of colza that contains Prochloraz or its manganese salt and dimethachlon of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943957A CN100382691C (en) | 2005-09-15 | 2005-09-15 | Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100943957A CN100382691C (en) | 2005-09-15 | 2005-09-15 | Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application |
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| Publication Number | Publication Date |
|---|---|
| CN1930965A CN1930965A (en) | 2007-03-21 |
| CN100382691C true CN100382691C (en) | 2008-04-23 |
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| CNB2005100943957A Expired - Fee Related CN100382691C (en) | 2005-09-15 | 2005-09-15 | Efficient germicide composition containing prochloraz or its manganese salt and dimetachlone and its application |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109983967A (en) * | 2019-05-13 | 2019-07-09 | 湖南省蚕桑科学研究所 | A method of prevention and treatment diseases of mulberry fruits |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1146853A (en) * | 1996-08-27 | 1997-04-09 | 山东青州市神星农药有限公司 | Wettable powder of 48% |
| CN1212834A (en) * | 1997-09-26 | 1999-04-07 | 化学工业部沈阳化工研究院 | Dimetachlone-chlorothalonil bactericidal agent |
| CN1217876A (en) * | 1998-10-28 | 1999-06-02 | 成都双流化学品厂 | Compounded bactericidal agents for plants |
| CN1293894A (en) * | 1999-10-25 | 2001-05-09 | 张砚祥 | Vegetable bactericide |
| CN1452865A (en) * | 2002-04-26 | 2003-11-05 | 沈阳化工研究院 | Bactericide composition |
-
2005
- 2005-09-15 CN CNB2005100943957A patent/CN100382691C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1146853A (en) * | 1996-08-27 | 1997-04-09 | 山东青州市神星农药有限公司 | Wettable powder of 48% |
| CN1212834A (en) * | 1997-09-26 | 1999-04-07 | 化学工业部沈阳化工研究院 | Dimetachlone-chlorothalonil bactericidal agent |
| CN1217876A (en) * | 1998-10-28 | 1999-06-02 | 成都双流化学品厂 | Compounded bactericidal agents for plants |
| CN1293894A (en) * | 1999-10-25 | 2001-05-09 | 张砚祥 | Vegetable bactericide |
| CN1452865A (en) * | 2002-04-26 | 2003-11-05 | 沈阳化工研究院 | Bactericide composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109983967A (en) * | 2019-05-13 | 2019-07-09 | 湖南省蚕桑科学研究所 | A method of prevention and treatment diseases of mulberry fruits |
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| Publication number | Publication date |
|---|---|
| CN1930965A (en) | 2007-03-21 |
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