CN100368490C - UV cured concealed fluorescent frequency conversion ink - Google Patents
UV cured concealed fluorescent frequency conversion ink Download PDFInfo
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- CN100368490C CN100368490C CNB2005100430195A CN200510043019A CN100368490C CN 100368490 C CN100368490 C CN 100368490C CN B2005100430195 A CNB2005100430195 A CN B2005100430195A CN 200510043019 A CN200510043019 A CN 200510043019A CN 100368490 C CN100368490 C CN 100368490C
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Abstract
The present invention provides UV cured concealed fluorescent frequency conversion ink which can be printed on materials to be printed with absorbability or materials to be printed without absorbability by ultraviolet curing (UV curing). The present invention comprises components by weight percentage: 5% to 80% of ultraviolet fluorescence pigment and/or infrared upper transformation pigment, 5% to 50% of connection materials, 1% to 40% of acrylate monomer, 0.5% to 30% of light initiator, 0.1% to 5% of amine initiation assisting agent, 0.5% to 30% of filling materials and 0.5% to 10% of stabilizing agent. The present invention solves the defects of long drying time and unable to print on materials to be printed without absorbability of the prior art, and has the advantages of good anti-counterfeit performance, low printing cost, high printing efficiency, good printing adaptability and reprocessing performance, wide application ranges and good printing effect.
Description
Technical field
The present invention relates to a kind of printing ink based on artificial resin.
Background technology
Infraluminescence pigment (the infrared conversion pigment of going up) presents colourless state under visible light, visible emitting under 800-1500nm infrared light condition, peak absorption wavelength is at 980nm, the visible emitting wavelength is the ruddiness of 610-630nm, also can be the blue light of 370-440nm, can also be the green glow of 530-560nm.Ultraluminescence pigment presents colourless state equally under visible light, present red, yellow, blue, green, blue or green color under the 365nm UV-light.Fluorescent ink adopts this principle exactly, makes printing ink produce color fluorescence under the exciting of Infrared or ultraviolet light.The UV cured concealed fluorescent frequency conversion ink is a kind of in the fluorescent ink, and generally, the printed patterns water white transparency presents different color with the detection light source frequency change.Discoloration effect can take place in this printing ink under the exciting of infrared source and ultraviolet source, under the long wave ultraviolet light frequency range, can realize the fluorescence of colors such as red, orange, yellow, green, blue or green, indigo plant, under the infrared light frequency range detects, can realize the fluorescence of color such as red, green, blue.But Ultraluminescence color and infraluminescence color independent assortment are realized the false proof demand of concealed fluorescent frequency conversion, belong to the two wires anti-counterfeiting technology.The common dried forms of general fluorescent ink is the oxypolymerization drying, and oxypolymerization is long time of drying, can't print on the nonabsorbable stock.
Summary of the invention
The object of the invention provides a kind of employing ultraviolet curing (UV curing), can be printed on the UV cured concealed fluorescent frequency conversion ink on absorptivity stock or the nonabsorbable stock, the shortcoming that it has solved prior art length time of drying, can't print on the nonabsorbable stock.
Technology of the present invention solves its scheme:
A kind of UV cured concealed fluorescent frequency conversion ink, its weight percent is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～80% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～10%.
The preferable weight percent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～40% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～10%.
The preferable weight percent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed:
Ultraluminescence pigment and/or infrared conversion pigment 10%～30 % that goes up,
Connect material 10%～35%, acrylate monomer 10%～35%,
Light trigger 1%～15%, amine aided initiating 0.1%～5%,
Stablizer 1%～5%.
The optimum weight per-cent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed:
Ultraluminescence pigment and/or the infrared conversion pigment 15%～25% of going up,
Connect material 20%～35%, acrylate monomer 20%～35%,
Light trigger 2%～10%, amine aided initiating 1%～3%,
Stablizer 1%～2%.
Above-mentioned UV cured concealed fluorescent frequency conversion ink also can comprise 0.5%～30% stopping composition.
The preferable weight percent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～40% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～1 0%, stopping composition 0.5%～30%.
The preferable weight percent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed:
Ultraluminescence pigment and/or the infrared conversion pigment 10%～30% of going up,
Connect material 10%～35%, acrylate monomer 10%～35%,
Light trigger 1%～15%, amine aided initiating 0.1%～5%,
Stablizer 1%～5%, stopping composition 5%～15%.
The optimum weight per-cent of above-mentioned UV cured concealed fluorescent frequency conversion ink is formed:
Ultraluminescence pigment and/or the infrared conversion pigment 15%～25% of going up,
Connect material 20%～35%, acrylate monomer 20%～35%,
Light trigger 2%～10%, amine aided initiating 1%～3%,
Stablizer 1%～2%, stopping composition 5%～10%.
Above-mentioned stopping composition can be colloid calcium, lime carbonate or aerosil.
Above-mentioned Ultraluminescence pigment can be one or more in organic fluorescence, inorganic fluorescence, the rare-earth fluorescent pigment;
Above-mentioned infrared upward conversion pigment is the rare earth infrared up-conversion material, and its matrix can be one or more in rare earth fluorine, rare-earth alkali metal and alkaline-earth metal complex fluoride, rare earth oxyhalide oxide compound, rare upward oxysulfide, rare earth oxide and the composite oxides;
Above-mentioned connection material can be an epoxy acrylic resin, polyalcohol modified epoxy acrylic resin, fatty acid modified epoxy acrylic resin, the epoxy soybean oil acrylic resin, acrylated polyurethane resin, polyether-modified acrylated polyurethane resin, fatty acid modified acrylic polyurethane resin, the polyester acrylic urethane resin, the epoxy methacrylic resin, polyalcohol modified epoxy methacrylic resin, fatty acid modified epoxy methacrylic resin, the epoxy soybean oil methacrylic resin, the methacrylic acid urethane resin, polyether-modified methacrylic acid urethane resin, fatty acid modified methacrylic acid urethane resin, in the polyester methacrylic acid urethane resin one or more;
The aforesaid propylene acid ester monomer can be the simple function group acrylate monomer, bifunctional acrylate's monomer, trifunctional group acrylate's monomer, the four-functional group propenoic acid ester monomer, five functional group's acrylate monomers, the water dispersible acrylate monomer, the simple function group methacrylate monomer, the bifunctional methacrylate monomer, the trifunctional methacrylate monomer, the four-functional group methacrylate monomer, five functional group's methacrylate monomer, in the water dispersible methacrylate monomer one or more;
Above-mentioned simple function group acrylate monomer can be the propoxylation allyl methacrylate(AMA), the methoxy poly (ethylene glycol) monomethacrylates, the ethoxyquin hydroxy ethyl methacrylate, the ethoxyquin hydroxyethyl meth acrylate, alkoxide tetrahydrofurfural acrylate, ethoxyquin nonylbenzene phenol methacrylic ester, allyl methacrylate(AMA), methacrylic acid tetrahydrofurfural ester, isodecyl methacrylate, ethoxy ethoxy ethyl propylene acid esters, the stearyl acrylate acid esters, vinylformic acid tetrahydrofurfural ester, the methacrylic acid laurate, the 2-phenoxyethyl acrylate, 2-phenoxy group ethyl-methyl acrylate, isodecyl acrylate, isobornyl methacrylate, Isooctyl acrylate monomer, vinylformic acid isotridecyl ester, methacrylic acid ester in three last of the ten Heavenly stems, the vinylformic acid caprolactone, ethoxyquin nonylbenzene phenol acrylate, isobornyl acrylate, in the polypropylene glycol monohydroxy acrylate one or more;
Above-mentioned bifunctional acrylate's monomer can be the cyclohexanedimethanol dimethacrylate, cyclohexane dimethanol diacrylate, the ethoxyquin bisphenol a dimethacrylate, the ethoxyquin bisphenol a diacrylate, the alkoxide hexanediol dimethacrylate, the alkoxide hexanediyl ester, the alkoxide cyclohexane dimethanol diacrylate, the Triethylene glycol dimethacrylate, the Triethylene glycol diacrylate, ethylene glycol dimethacrylate, the tetraethylene-glycol dimethacrylate, the tetraethylene-glycol diacrylate, polyethylene glycol dimethacrylate, 1, the 3-butylene glycol dimethacrylate, 1, the 3-butylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, 1, the 4-butylene glycol dimethacrylate, diethylene glycol diacrylate, the Diethylene Glycol dimethacrylate, 1, the 6-butylene glycol diacrylate, 1, the 6-hexanediol dimethacrylate, neopentylglycol diacrylate, new penta 2 glycol dimethacrylates, polyoxyethylene glycol (600) dimethacrylate, polyoxyethylene glycol (400) dimethacrylate, polyoxyethylene glycol (200) dimethacrylate, polyoxyethylene glycol (600) diacrylate, polyoxyethylene glycol (400) diacrylate, polyoxyethylene glycol (200) diacrylate, tri (propylene glycol) diacrylate, the ethoxyquin bisphenol a dimethacrylate, propylene glycol diacrylate, in the alkoxide aliphatics diacrylate one or more;
Above-mentioned trifunctional group acrylate's monomer can be one or more in the third oxidation Viscoat 295, trimethylolpropane trimethacrylate, Viscoat 295, three (2-hydroxyethyl) isocyanuric acid triacrylate, ethoxyquin Viscoat 295, pentaerythritol triacrylate, the third oxidation Viscoat 295, the glycerol propoxylate triacrylate;
The acrylate monomer of above-mentioned four-functional group and five functional groups can be one or more in tetramethylol methane tetraacrylate, Dipentaerythritol five acrylate, two-Viscoat 295, ethoxyquin tetramethylol methane tetraacrylate, five acrylate;
Above-mentioned water dispersible acrylate monomer can be the methoxy poly (ethylene glycol) monomethacrylates, the ethoxyquin bisphenol a diacrylate, polyoxyethylene glycol (600) dimethacrylate, ethoxy ethoxy ethyl propylene acid esters, polyoxyethylene glycol (200) diacrylate, polyoxyethylene glycol (400) diacrylate, the ethoxyquin Viscoat 295, polyoxyethylene glycol (400) dimethacrylate, polypropylene glycol monohydroxy acrylate, in polyoxyethylene glycol (600) diacrylate one or more;
Above-mentioned light trigger is a free radical photo-initiation; described free radical photo-initiation can be 2; 4,6-(trimethylbenzoyl) diphenyl phosphine oxide (TPO); 4-methylbenzene sulfenyl benzophenone (BMS); 2-methyl isophthalic acid-[4-methylthio group phenyl]-2-morpholinyl-1-acetone; 1-hydroxyl-cyclohexyl-phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; sec.-propyl thia anthraquinone (2; 4 isomer mixtures); 4-dimethylamino-ethyl benzoate; 4-dimethylamino-phenylformic acid (2-ethyl) ester; the benzoylbenzoic acid methyl esters; trisbromomethyl phenyl sulfone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; methyl o-benzoylbenzoate; benzophenone; benzophenone with to the mixture of methyldiphenyl ketone; in the benzoin dimethylether one or more.
Advantage of the present invention is:
1, anti-counterfeiting performance is good.The UV cured concealed fluorescent frequency conversion ink has multiple frequency conversion anti-counterfeiting performance, pattern water white transparency in visible-range with its printing, discoloration effect can take place under the exciting of infrared source and ultraviolet source, under the long wave ultraviolet light frequency range, can realize the fluorescence of colors such as red, orange, yellow, green, blue or green, indigo plant, under detecting, the infrared light frequency range can realize the fluorescence of color such as red, green, blue, but Ultraluminescence color and infraluminescence color independent assortment are realized the false proof demand of concealed fluorescent frequency conversion.Tie between Ultraluminescence pigment and the infraluminescence pigment, anti-counterfeiting characteristic is obvious, is easy to identification, is difficult to copy.
2, printing cost is low, efficient is high.Printing ink of the present invention adopts free radical initiation type UV-curing technology to realize the instantaneous drying of print product, has the characteristics of economy, energy-saving and environmental protection.
3, good printability and very strong re-workability.Printing ink of the present invention is fit to offset printing, carved gravure, shadow and writes gravure, protruding seal, flexo, screen printer print.
4, applied widely.Printing ink of the present invention can print on various paper products or film, can be printed on absorptivity stock or the nonabsorbable stock.
5, printing effect is good.Performed polymer in the printing ink of the present invention transmits on various printing press well, and thinner is high reactivity, hypotoxicity, has selected the efficiency light initiator for use, makes the false proof China ink of fluorescent frequency conversion become the ink system that is fit to ultraviolet light polymerization.
Embodiment
The present invention adopts UV-curing technology to realize the drying of various mode of printing down coversion printing ink such as offset printing, gravure, silk-screen, flexo, protruding seal.
Performed polymer in this printing ink transmits on various printing press well, and thinner is high reactivity, hypotoxicity, has selected the efficiency light initiator for use, makes the false proof China ink of fluorescent frequency conversion become the ink system that is fit to ultraviolet light polymerization.
The acrylic resin, acrylate monomer, light trigger, stopping composition and the ink addition agent that comprise Ultraluminescence pigment and/or infrared up-conversion material, photocuring in forming in this printing ink, the UV that gives the good printability of this printing ink, excellence solidifies instantaneous drying property and anti-counterfeit recognition function.
1, pigment: used Ultraluminescence pigment and/or infraluminescence pigment among the present invention, tied between two kinds of pigment, anti-counterfeiting characteristic is obvious, is easy to identification, is difficult to copy.
Connection material in the printing ink is the various acrylic resins that can carry out ultraviolet light polymerization.
3, acrylate monomer: also can be called reactive thinner, cross-linking monomer, be a kind of functional ingredient, regulates viscosity, curing speed and curing inks film properties in printing ink, can participate in photocuring reaction.
4, light trigger: printing ink of the present invention is free radical initiation type photocuring reaction.
Material therefor of the present invention is well known materials, and the printing industry those of ordinary skill can be obtained by commercial.
Below respectively select five prescriptions as embodiment (starting material of respectively filling a prescription all are weight percentage) at mode of printings such as offset printing, gravure, silk-screen, flexo, protruding seals:
Prescription 1: UV cured offset printing ink (1) with Ultraluminescence feature
Ultraluminescence pigment 5%,
Polyalcohol modified epoxy acrylic resin 15%,
Fatty acid modified epoxy acrylic resin 15%,
Polyether-modified acrylated polyurethane resin 10%,
Polyester acrylic urethane resin 15%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 17%,
Benzoin dimethylether 1%,
Tert-butyl phenol 1%.
Prescription 2: UV cured offset printing ink (2) with Ultraluminescence feature
Ultraluminescence pigment 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 1%.
Prescription 3: UV cured offset printing ink with infraluminescence feature
Infrared up-conversion material 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 1%.
Prescription 4: UV cured offset printing ink (1) with Ultraluminescence and infraluminescence feature
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 1%.
Prescription 5: UV cured offset printing ink (2) with Ultraluminescence and infraluminescence feature
Ultraluminescence pigment 40%,
Infrared up-conversion material 40%,
Epoxy acrylic resin 5%,
Epoxy soybean oil acrylic resin 5%,
Triethylene glycol diacrylate 4%,
Trimethylolpropane trimethacrylate 3%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 0.5%,
Benzophenone and methyldiphenyl ketone 0.5%,
Benzoin dimethylether 0.5%,
Tert-butyl phenol 0.5%.
The printing effect of prescription 1,2,3,4,5: high-speed offset press printing, speed are 8000～10000/hour, through printing complete drying under the ultraviolet high voltage mercury lamp radiation, lines are smooth, the site is full, does not fly China ink, emulsification, scumming and heap China ink phenomenon, and trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 1 and 2: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 3: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 4 and 5: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
Prescription 6: the UV with Ultraluminescence feature solidifies engraving intaglio printing ink
Ultraluminescence pigment 20%,
Epoxy acrylic resin 5%,
Acrylated polyurethane resin 5%,
Fatty acid modified acrylated polyurethane resin 5%,
Alkaline soluble acrylic resin 25%,
Triethylene glycol diacrylate 5%,
Ethoxyquin Viscoat 295 5%,
Ethoxyquin tetramethylol methane tetraacrylate 5%,
Polyoxyethylene glycol (200) diacrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 7: the UV with infraluminescence feature solidifies engraving intaglio printing ink (1)
Infrared up-conversion material 5%,
Polyalcohol modified epoxy acrylic resin 10%,
Acrylated polyurethane resin 10%,
Polyether-modified acrylated polyurethane resin 10%,
Alkaline soluble acrylic resin 10%,
Triethylene glycol diacrylate 10%,
Ethoxyquin Viscoat 295 10%,
Ethoxyquin tetramethylol methane tetraacrylate 5%,
Polyoxyethylene glycol (200) diacrylate 15%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 10%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 1%,
Tert-butyl phenol 1%.
Prescription 8: the UV with infraluminescence feature solidifies engraving intaglio printing ink (2)
Infrared up-conversion material 20%,
Epoxy acrylic resin 5%,
Acrylated polyurethane resin 5%,
Fatty acid modified acrylated polyurethane resin 5%,
Alkaline soluble acrylic resin 25%,
Triethylene glycol diacrylate 5%,
Ethoxyquin tetramethylol methane tetraacrylate 5%,
Ethoxyquin Viscoat 295 5%,
Polyoxyethylene glycol (200) acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 9: the UV with Ultraluminescence and infraluminescence feature solidifies engraving intaglio printing ink (1)
Ultraluminescence pigment 30%,
Infrared up-conversion material 30%,
Epoxy acrylic resin 3%,
Fatty acid modified acrylated polyurethane resin 3%,
Alkaline soluble acrylic resin 4%,
Triethylene glycol diacrylate 5%,
Ethoxyquin tetramethylol methane tetraacrylate 5%,
Polyoxyethylene glycol (200) diacrylate 5%,
Ethoxyquin Viscoat 295 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 3%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Tert-butyl phenol 5%.
Prescription 10: the UV with Ultraluminescence and infraluminescence feature solidifies engraving intaglio printing ink (2)
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 5%,
Acrylated polyurethane resin 5%,
Fatty acid modified acrylated polyurethane resin 5%,
Alkaline soluble acrylic resin 25%,
Triethylene glycol diacrylate 5%,
Ethoxyquin tetramethylol methane tetraacrylate 5%,
Ethoxyquin Viscoat 295 5%,
Polyoxyethylene glycol (200) diacrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 2%.
The printing effect of prescription 6,7,8,9,10: the printing of high speed carved gravure machine, speed is 4000～10000/hour, through ultraviolet high voltage mercury lamp radiation printing complete drying, lines are smooth, the site is full, does not fly China ink, wipes dirty, scumming and heap China ink phenomenon, and trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 6: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 7 and 8: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 9 and 10: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
Prescription 11: the UV with Ultraluminescence feature solidifies shadow and writes gravure ink (1)
Ultraluminescence pigment 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 5%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 12: the UV with Ultraluminescence feature solidifies shadow and writes gravure ink (2)
Ultraluminescence pigment 10%,
Polyalcohol modified epoxy acrylic resin 10%,
Fatty acid modified epoxy acrylic resin 5%,
Fatty acid modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Ethoxyquin hydroxy ethyl methacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 20%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 5%,
Amine aided initiating 5%,
Lime carbonate 5%,
Tert-butyl phenol 10%.
Prescription 13: the UV with infraluminescence feature solidifies shadow and writes gravure ink (1)
Infrared up-conversion material 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 5%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 14: the UV with infraluminescence feature solidifies shadow and writes gravure ink (2)
Infrared up-conversion material 35%,
Epoxy acrylic resin 5%,
Epoxy soybean oil acrylic resin 5%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 10%,
Ethoxyquin hydroxy ethyl methacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 10%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 5%,
Lime carbonate 5%,
Tert-butyl phenol 3%.
Prescription 15: the UV with Ultraluminescence and infraluminescence feature solidifies shadow and writes gravure ink
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 5%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 2%.
Prescription 11,12,13,14,15 printing effect: shadow is write the intaglio printing press printing, speed be 100-150 rice/minute, through printing complete drying under the ultraviolet high voltage mercury lamp radiation, lines are smooth, the site is full, trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 11 and 12: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 13 and 14: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 15: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
Prescription 16: the UV with Ultraluminescence feature solidifies letterpress printing ink (1)
Ultraluminescence pigment 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 20%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 17: the UV with Ultraluminescence feature solidifies letterpress printing ink (2)
Ultraluminescence pigment 40%,
Epoxy acrylic resin 10%,
Fatty acid modified epoxy acrylic resin 12%,
Polyether-modified acrylated polyurethane resin 10%,
Fatty acid modified acrylated polyurethane resin 5%,
Methacrylic acid urethane resin 10%,
Dipentaerythritol five acrylate 10%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 0.5%,
Benzoin dimethylether 0.4%,
Amine aided initiating 0.1%,
Lime carbonate 0.5%,
Tert-butyl phenol 0.5%.
Prescription 18: the UV with infraluminescence feature solidifies letterpress printing ink (1)
Infrared up-conversion material 10%,
Polyalcohol modified epoxy acrylic resin 15%,
Epoxy soybean oil acrylic resin 20%,
Polyester acrylic urethane resin 5%,
Methacrylic acid urethane resin 10%,
Trimethylolpropane trimethacrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 12%,
Benzophenone and methyldiphenyl ketone 2%,
Benzoin dimethylether 1%,
Amine aided initiating 3%,
Lime carbonate 7%,
Tert-butyl phenol 10%.
Prescription 19: the UV with infraluminescence feature solidifies letterpress printing ink (2)
Infrared up-conversion material 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 20%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 20: the UV with Ultraluminescence and infraluminescence feature solidifies letterpress printing ink
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 20%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 2%.
The printing effect of prescription 16,17,18,19,20: embossing machine printing, speed are 4000～8000/hour, and through printing complete drying under the ultraviolet high voltage mercury lamp radiation, lines are smooth, do not fly China ink, stick with paste sign indicating number, shallow colored phenomenon, and trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 16 and 17: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 18 and 19: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 20: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
Prescription 21: the UV with Ultraluminescence feature solidifies flexo printing ink (1)
Ultraluminescence pigment 36%,
Epoxy acrylic resin 5%,
Polyester acrylic urethane resin 3%,
Stearyl acrylate acid esters 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 20%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 5%,
Amine aided initiating 5%,
Lime carbonate 10%,
Tert-butyl phenol 10%.
Prescription 22: the UV with Ultraluminescence feature solidifies flexo printing ink (2)
Ultraluminescence pigment 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 23: the UV with infraluminescence feature solidifies flexo printing ink (1)
Infrared up-conversion material 5%,
Epoxy acrylic resin 5%,
Polyalcohol modified epoxy acrylic resin 10%,
Epoxy soybean oil acrylic resin 10%,
Fatty acid modified acrylated polyurethane resin 10%,
Stearyl acrylate acid esters 10%,
Dipentaerythritol five acrylate 10%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 10%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 5%,
Amine aided initiating 3%,
Lime carbonate 14%,
Tert-butyl phenol 3%.
Prescription 24: the UV with infraluminescence feature solidifies flexo printing ink (2)
Infrared up-conversion material 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 2%.
Prescription 25: the UV with Ultraluminescence and infraluminescence feature solidifies flexo printing ink
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Triethylene glycol diacrylate 5%,
Trimethylolpropane trimethacrylate 5%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 5%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 5%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 1%.
The printing effect of prescription 21,22,23,24,25: flexible printing press printing, speed are 6000～10000/hour, through printing complete drying under the ultraviolet high voltage mercury lamp radiation, lines are smooth, the site is full, does not fly China ink, scumming and heap China ink phenomenon, and trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 21 and 22: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 23 and 24: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 25: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
Prescription 26: the UV with Ultraluminescence feature solidifies silk-screen ink
Ultraluminescence pigment 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 1%.
Prescription 27: the UV with infraluminescence feature solidifies silk-screen ink (1)
Infrared up-conversion material 20%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Lime carbonate 10%,
Tert-butyl phenol 1%.
Prescription 28: the UV with infraluminescence feature solidifies silk-screen ink (2)
Infrared up-conversion material 30%,
Fatty acid modified epoxy acrylic resin 10%,
Fatty acid modified acrylated polyurethane resin 15%,
Triethylene glycol diacrylate 15%,
Dipentaerythritol five acrylate 10%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 1%,
Benzophenone and methyldiphenyl ketone 3%,
Benzoin dimethylether 1%,
Amine aided initiating 5%,
Lime carbonate 5%,
Tert-butyl phenol 5%.
Prescription 29: the UV with Ultraluminescence and infraluminescence feature solidifies silk-screen ink (1)
Ultraluminescence pigment 15%,
Infrared up-conversion material 15%,
Epoxy acrylic resin 15%,
Acrylated polyurethane resin 15%,
Polyether-modified acrylated polyurethane resin 5%,
Polyester acrylic urethane resin 5%,
Trimethylolpropane trimethacrylate 10%,
Pentaerythritol triacrylate 10%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 5%,
Benzophenone and methyldiphenyl ketone 1%,
Benzoin dimethylether 1%,
Amine aided initiating 1%,
Tert-butyl phenol 1%.
Prescription 30: the UV with Ultraluminescence and infraluminescence feature solidifies silk-screen ink (2)
Ultraluminescence pigment 25%,
Infrared up-conversion material 25%,
Polyalcohol modified epoxy acrylic resin 15%,
Ethoxyquin hydroxy ethyl methacrylate 8%,
Dipentaerythritol five acrylate 1%,
2,4,6-(trimethylbenzoyl) diphenyl phosphine oxide 0.3%,
Benzophenone and methyldiphenyl ketone 0.1%,
Benzoin dimethylether 0.1%,
Amine aided initiating 0.5%,
Lime carbonate 30%,
Tert-butyl phenol 5%.
The printing effect of prescription 26,27,28,29,30: the printing of silk screen machine, speed is 2000～6000/hour, and through printing complete drying under the ultraviolet high voltage mercury lamp radiation, lines are smooth, and the site is full, does not fly China ink, scumming phenomenon, and trace adheres to well.
The anti-counterfeiting performance evaluation of prescription 26: the water white transparency printing is presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The anti-counterfeiting performance evaluation of prescription 27 and 28: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.
The anti-counterfeiting performance evaluation of prescription 29 and 30: colourless printing is visible emitting under 800-1500nm infrared laser condition, and peak absorption wavelength is at 980nm, and the visible emitting wavelength is ruddiness or the blue light of 370-440nm or the green glow of 530-560nm of 610-630nm.Presenting red, yellow, blue, green, blue or green fluorescence under the irradiation under the 365nm UV-light.
The weight percent of UV cured concealed fluorescent frequency conversion ink of the present invention is formed as shown in table 1:
Table 1
| Flexographic ink | Engraving intaglio printing ink | Shadow is write gravure ink | Letterpress printing ink | Flexo printing ink | Silk-screen ink | |
| Ultraluminescence pigment and/or infrared up-conversion material | 1-40 | 1-40 | 1-40 | 1-40 | 1-40 | 1-40 |
| Epoxy acrylic resin | 0-40 | 0-40 | 0-40 | 0-40 | 1-40 | 0-40 |
| Polyalcohol modified epoxy acrylic resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Fatty acid modified epoxy acrylic resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Acrylated polyurethane resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| The epoxy soybean oil acrylic resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Polyether-modified acrylated polyurethane resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Fatty acid modified acrylated polyurethane resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| The polyester acrylic urethane resin | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Alkaline soluble acrylic resin | - | 0-40 | - | - | - | - |
| The simple function group acrylate monomer | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Bifunctional acrylate's monomer | 0-40 | 1-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Trifunctional group acrylate's monomer | 1-40 | 0-40 | 0-40 | 0-40 | 0-40 | 0-40 |
| Four-functional group propenoic acid ester monomer five functional group's acrylate monomers | 0-40 | 1-40 | 1-40 | 0-40 | 0-40 | 0-40 |
| The water dispersible acrylate monomer | - | 1-40 | - | - | - | - |
| Initiator 1 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 |
| Initiator 2 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 |
| Initiator 3 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 |
| The amine aided initiating | 0-5 | 0-5 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 |
| Stopping composition | 0-30 | 0-30 | 0-30 | 0-30 | 0-30 | 0-30 |
| Stablizer | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 | 0.1-10 |
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 |
The weight percent of 30 prescriptions of the specific embodiment of the invention form see Table 2, table 3 and table 4:
Table 2
| Ink formulations | Flexographic ink | Engraving intaglio printing ink | ||||||||
| Prescription 1 | Prescription 2 | Prescription 3 | Prescription 4 | Prescription 3 | Prescription 6 | Prescription | Prescription 8 | Prescription 9 | Prescription 10 | |
| Ultraluminescence pigment | 5 | 20 | 15 | 40 | 20 | 30 | 15 | |||
| Infrared up-conversion material | 20 | 15 | 40 | 5 | 20 | 30 | 15 | |||
| Epoxy acrylic resin | 15 | 15 | 15 | 5 | 5 | 5 | 3 | 5 | ||
| Polyalcohol modified epoxy acrylic resin | 15 | 10 | ||||||||
| Fatty acid modified epoxy acrylic resin | 15 | 3 | ||||||||
| Acrylated polyurethane resin | 15 | 15 | 15 | 5 | 10 | 5 | 5 | |||
| The epoxy soybean oil acrylic resin | 5 | |||||||||
| Polyether-modified acrylated polyurethane resin | 10 | 5 | 5 | 5 | 10 | |||||
| Fatty acid modified acrylated polyurethane resin | 5 | 5 | 5 | |||||||
| The polyester acrylic urethane resin | 15 | 5 | 5 | 5 | ||||||
| Alkaline soluble acrylic resin | 25 | 10 | 25 | 4 | 25 | |||||
| The simple function group acrylate monomer | ||||||||||
| Bifunctional acrylate's monomer | 5 | 5 | 5 | 4 | 5 | 10 | 5 | 5 | 5 | |
| Trifunctional group acrylate's monomer | 15 | 15 | 15 | 15 | 3 | 5 | 10 | 5 | 5 | |
| Four-functional group propenoic acid ester monomer and or five functional group's acrylate monomers | 5 | 1 | 1 | 1 | 1 | 5 | 5 | 5 | 5 | 5 |
| The water dispersible acrylate monomer | 5 | 15 | 10 | 5 | 5 | |||||
| Light trigger | 19 | 7 | 7 | 7 | 1.5 | 7 | 12 | 7 | 5 | 7 |
| The amine aided initiating | 1 | 1 | 1 | 1 | 1 | 1 | 1 | |||
| Stopping composition | 10 | 10 | 10 | 1 | 10 | |||||
| Stablizer | 1 | 1 | 1 | 1 | 0.5 | 2 | 1 | 2 | 5 | 2 |
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
Table 3
| Ink formulations | Shadow is write gravure ink | Letterpress printing ink | ||||||||
| Prescription 11 | Prescription 12 | Prescription 13 | Prescription 14 | Prescription 15 | Prescription 16 | Prescription 17 | Prescription 18 | Prescription 19 | Prescription 20 | |
| Ultraluminescence pigment | 20 | 10 | 15 | 20 | 40 | 15 | ||||
| Infrared up-conversion material | 20 | 35 | 15 | 10 | 20 | 15 | ||||
| Epoxy acrylic resin | 15 | 15 | 5 | 15 | 15 | 10 | 15 | 15 | ||
| Polyalcohol modified epoxy acrylic resin | 10 | 15 | ||||||||
| Fatty acid modified epoxy acrylic resin | 5 | 12 | ||||||||
| Acrylated polyurethane resin | 5 | 5 | 5 | 20 | 20 | 20 | ||||
| The epoxy soybean oil acrylic resin | 5 | 20 | ||||||||
| Polyether-modified acrylated polyurethane resin | 5 | 5 | 5 | 5 | 10 | |||||
| Fatty acid modified acrylated polyurethane resin | 5 | 5 | ||||||||
| The polyester acrylic urethane resin | 5 | 5 | 10 | 5 | 5 | 5 | 5 | |||
| Alkaline soluble acrylic resin | 5 | 5 | ||||||||
| The simple function group acrylate monomer | 5 | 10 | 10 | 10 | ||||||
| Bifunctional acrylate's monomer | 5 | 5 | 5 | 5 | ||||||
| Trifunctional group acrylate's monomer | 20 | 5 | 20 | 20 | 15 | 15 | 15 | |||
| Four-functional group propenoic acid ester monomer and or five functional group's acrylate monomers | 5 | 5 | 5 | 5 | 5 | 5 | 10 | 5 | 5 | |
| The water dispersible acrylate monomer | ||||||||||
| Light trigger | 7 | 30 | 7 | 12 | 7 | 7 | 1.9 | 15 | 7 | 7 |
| The amine aided initiating | 1 | 5 | 1 | 5 | 1 | 1 | 0.1 | 3 | 1 | 1 |
| Stopping composition | 10 | 5 | 10 | 5 | 10 | 0.5 | 7 | 10 | ||
| Stablizer | 2 | 10 | 2 | 3 | 2 | 2 | 0.5 | 10 | 2 | 2 |
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
Table 4
| Ink formulations | Flexo printing ink | Silk-screen ink | ||||||||
| Prescription 21 | Prescription 22 | Prescription 23 | Prescription 24 | Prescription 25 | Prescription 26 | Prescription 27 | Prescription 28 | Prescription 29 | Prescription 30 | |
| Ultraluminescence pigment | 36 | 20 | 15 | 20 | 15 | 25 | ||||
| Infrared up-conversion material | 5 | 20 | 15 | 20 | 30 | 15 | 25 | |||
| Epoxy acrylic resin | 5 | 15 | 5 | 15 | 15 | 15 | 15 | 15 | ||
| Polyalcohol modified epoxy acrylic resin | 10 | 5 | ||||||||
| Fatty acid modified epoxy acrylic resin | 10 | |||||||||
| Acrylated polyurethane resin | 15 | 15 | 15 | 15 | 15 | 15 | ||||
| The epoxy soybean oil acrylic resin | 10 | |||||||||
| Polyether-modified acrylated polyurethane resin | 5 | 5 | 5 | 5 | 5 | 5 | ||||
| Fatty acid modified acrylated polyurethane resin | 10 | 15 | ||||||||
| The polyester acrylic urethane resin | 3 | 5 | 5 | 5 | ||||||
| Alkaline soluble acrylic resin | ||||||||||
| The simple function group acrylate monomer | 1 | 10 | 8 | |||||||
| Bifunctional acrylate's monomer | 5 | 5 | 5 | 15 | ||||||
| Trifunctional group acrylate's monomer | 15 | 15 | 15 | 20 | 20 | 20 | ||||
| Four-functional group propenoic acid ester monomer and or five functional group's acrylate monomers | 5 | 10 | 5 | 1 | 1 | 1 | 10 | 1 | 1 | |
| The water dispersible acrylate monomer | ||||||||||
| Light trigger | 30 | 7 | 20 | 7 | 7 | 7 | 7 | 5 | 7 | 0.5 |
| The amine aided initiating | 5 | 1 | 3 | 1 | 1 | 1 | 1 | 5 | 1 | 0.5 |
| Stopping composition | 10 | 10 | 14 | 10 | 10 | 10 | 5 | 30 | ||
| Stablizer | 10 | 2 | 3 | 2 | 1 | 1 | 1 | 5 | 1 | 5 |
| Add up to | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | |
Claims (9)
1. a UV cured concealed fluorescent frequency conversion ink is characterized in that; The weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～80% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～10%;
Described Ultraluminescence pigment is one or more in organic fluorescence, inorganic fluorescence, the rare-earth fluorescent pigment;
Described infrared upward conversion pigment is the rare earth infrared up-conversion material, and its matrix is one or more in rare earth fluorine, rare-earth alkali metal and alkaline-earth metal complex fluoride, rare earth oxyhalide oxide compound, rare-earth oxide sulfate, rare earth oxide and the composite oxides;
Described connection material is an epoxy acrylic resin, polyalcohol modified epoxy acrylic resin, fatty acid modified epoxy acrylic resin, the epoxy soybean oil acrylic resin, acrylated polyurethane resin, polyether-modified acrylated polyurethane resin, fatty acid modified acrylated polyurethane resin, the polyester acrylic urethane resin, the epoxy methacrylic resin, polyalcohol modified epoxy methacrylic resin, fatty acid modified epoxy methacrylic resin, the epoxy soybean oil methacrylic resin, the methacrylic acid urethane resin, polyether-modified methacrylic acid urethane resin, fatty acid modified methacrylic acid urethane resin, in the polyester methacrylic acid urethane resin one or more;
Described acrylate monomer is the simple function group acrylate monomer, bifunctional acrylate's monomer, trifunctional group acrylate's monomer, the four-functional group propenoic acid ester monomer, five functional group's acrylate monomers, the water dispersible acrylate monomer, the simple function group methacrylate monomer, the bifunctional methacrylate monomer, the trifunctional methacrylate monomer, the four-functional group methacrylate monomer, five functional group's methacrylate monomer, in the water dispersible methacrylate monomer one or more;
Described simple function group acrylate monomer is the propoxylation allyl methacrylate(AMA), the methoxy poly (ethylene glycol) monomethacrylates, the ethoxyquin hydroxy ethyl methacrylate, the ethoxyquin hydroxyethyl meth acrylate, alkoxide tetrahydrofurfural acrylate, ethoxyquin nonylbenzene phenol methacrylic ester, allyl methacrylate(AMA), methacrylic acid tetrahydrofurfural ester, isodecyl methacrylate, ethoxy ethoxy ethyl propylene acid esters, the stearyl acrylate acid esters, vinylformic acid tetrahydrofurfural ester, the methacrylic acid laurate, the 2-phenoxyethyl acrylate, 2-phenoxy group ethyl-methyl acrylate, isodecyl acrylate, isobornyl methacrylate, Isooctyl acrylate monomer, vinylformic acid isotridecyl ester, methacrylic acid ester in three last of the ten Heavenly stems, the vinylformic acid caprolactone, ethoxyquin nonylbenzene phenol acrylate, isobornyl acrylate, in the polypropylene glycol monohydroxy acrylate one or more;
Described bifunctional acrylate's monomer is the cyclohexanedimethanol dimethacrylate, cyclohexane dimethanol diacrylate, the ethoxyquin bisphenol a dimethacrylate, the ethoxyquin bisphenol a diacrylate, the alkoxide hexanediol dimethacrylate, the alkoxide hexanediyl ester, the alkoxide cyclohexane dimethanol diacrylate, the Triethylene glycol dimethacrylate, the Triethylene glycol diacrylate, ethylene glycol dimethacrylate, the tetraethylene-glycol dimethacrylate, the tetraethylene-glycol diacrylate, polyethylene glycol dimethacrylate, 1, the 3-butylene glycol dimethacrylate, 1, the 3-butylene glycol diacrylate, 1, the 4-butylene glycol diacrylate, 1, the 4-butylene glycol dimethacrylate, diethylene glycol diacrylate, the Diethylene Glycol dimethacrylate, 1, the 6-butylene glycol diacrylate, 1, the 6-hexanediol dimethacrylate, neopentylglycol diacrylate, neopentylglycol dimethacrylate, polyoxyethylene glycol (600) dimethacrylate, polyoxyethylene glycol (400) dimethacrylate, polyoxyethylene glycol (200) dimethacrylate, polyoxyethylene glycol (600) diacrylate, polyoxyethylene glycol (400) diacrylate, polyoxyethylene glycol (200) diacrylate, tri (propylene glycol) diacrylate, the ethoxyquin bisphenol a dimethacrylate, propylene glycol diacrylate, in the alkoxide aliphatics diacrylate one or more;
Described trifunctional group acrylate's monomer is one or more in the third oxidation Viscoat 295, trimethylolpropane trimethacrylate, Viscoat 295, three (2-hydroxyethyl) isocyanuric acid triacrylate, ethoxyquin Viscoat 295, pentaerythritol triacrylate, the third oxidation Viscoat 295, the glycerol propoxylate triacrylate;
The acrylate monomer of described four-functional group and five functional groups is one or more in tetramethylol methane tetraacrylate, Dipentaerythritol five acrylate, two-Viscoat 295, ethoxyquin tetramethylol methane tetraacrylate, five acrylate;
Described water dispersible acrylate monomer is the methoxy poly (ethylene glycol) monomethacrylates, the ethoxyquin bisphenol a diacrylate, polyoxyethylene glycol (600) dimethacrylate, ethoxy ethoxy ethyl propylene acid esters, polyoxyethylene glycol (200) diacrylate, polyoxyethylene glycol (400) diacrylate, the ethoxyquin Viscoat 295, polyoxyethylene glycol (400) dimethacrylate, polypropylene glycol monohydroxy acrylate, in polyoxyethylene glycol (600) diacrylate one or more;
Described light trigger is a free radical photo-initiation; described free radical photo-initiation is 2; 4,6-(trimethylbenzoyl) diphenyl phosphine oxide; 4-methylbenzene sulfenyl benzophenone; 2-methyl isophthalic acid-[4-yl]-2-morpholinyl-1-acetone; 1-hydroxyl-cyclohexyl-phenyl ketone; 2-hydroxy-2-methyl-1-phenyl-1-acetone; sec.-propyl thia anthraquinone (2; 4 isomer mixtures); 4-dimethylamino-ethyl benzoate; 4-dimethylin-phenylformic acid (2-ethyl) ester; the benzoylbenzoic acid methyl esters; trisbromomethyl phenyl sulfone; the 4-chlorobenzophenone; 4-methyldiphenyl ketone; methyl o-benzoylbenzoate; benzophenone; benzophenone with to the mixture of methyldiphenyl ketone; in the benzoin dimethylether one or more.
2. UV cured concealed fluorescent frequency conversion ink according to claim 1 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～40% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～10%.
3. UV cured concealed fluorescent frequency conversion ink according to claim 1 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 10%～30% of going up,
Connect material 10%～35%, acrylate monomer 10%～35%,
Light trigger 1%～15%, amine aided initiating 0.1%～5%,
Stablizer 1%～5%.
4. UV cured concealed fluorescent frequency conversion ink according to claim 1 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 15%～25% of going up,
Connect material 20%～35%, acrylate monomer 20%～35%,
Light trigger 2%～10%, amine aided initiating 1%～3%,
Stablizer 1%～2%.
5. UV cured concealed fluorescent frequency conversion ink according to claim 1 is characterized in that: described UV cured concealed fluorescent frequency conversion ink also comprises 0.5%～30% stopping composition.
6. UV cured concealed fluorescent frequency conversion ink according to claim 5 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 5%～40% of going up,
Connect material 5%～50%, acrylate monomer 1%～40%,
Light trigger 0.5%～30%, amine aided initiating 0.1%～5%,
Stablizer 0.5%～10%, stopping composition 0.5%～30%.
7. UV cured concealed fluorescent frequency conversion ink according to claim 5 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 10%～30% of going up,
Connect material 10%～35%, acrylate monomer 10%～35%,
Light trigger 1%～15%, amine aided initiating 0.1%～5%,
Stablizer 1%～5%, stopping composition 5%～15%.
8. UV cured concealed fluorescent frequency conversion ink according to claim 5 is characterized in that: the weight percent of described UV cured concealed fluorescent frequency conversion ink is formed and is comprised:
Ultraluminescence pigment and/or the infrared conversion pigment 15%～25% of going up,
Connect material 20%～35%, acrylate monomer 20%～35%,
Light trigger 2%～10%, amine aided initiating 1%～3%,
Stablizer 1%～2%, stopping composition 5%～10%.
9. according to claim 5 or 6 or 7 or 8 described UV cured concealed fluorescent frequency conversion inks, it is characterized in that: described stopping composition is colloid calcium, lime carbonate or aerosil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100430195A CN100368490C (en) | 2005-07-28 | 2005-07-28 | UV cured concealed fluorescent frequency conversion ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100430195A CN100368490C (en) | 2005-07-28 | 2005-07-28 | UV cured concealed fluorescent frequency conversion ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1737067A CN1737067A (en) | 2006-02-22 |
| CN100368490C true CN100368490C (en) | 2008-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CNB2005100430195A Active CN100368490C (en) | 2005-07-28 | 2005-07-28 | UV cured concealed fluorescent frequency conversion ink |
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