CA2129844A1 - Procede et composition pour l'elimination du depot sur les surfaces d'aluminium et d'alliages d'aluminium - Google Patents

Procede et composition pour l'elimination du depot sur les surfaces d'aluminium et d'alliages d'aluminium

Info

Publication number: CA2129844A1
Authority: CA; Canada
Prior art keywords: weight; acid; parts; deoxidizing; desmutting
Prior art date: 1992-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2129844

Other languages

English (en)

Inventor

Lawrence R. Carlson

Dennis A. Kent

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel Corp

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-02-25

Filing date

1993-02-19

Publication date

1993-09-02

1993-02-19 Application filed by Individual filed Critical Individual

1993-09-02 Publication of CA2129844A1 publication Critical patent/CA2129844A1/fr

Status Abandoned legal-status Critical Current

Links

229910052782 aluminium Inorganic materials 0.000 title claims abstract description 32
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 31
239000000203 mixture Substances 0.000 title claims description 63
238000000034 method Methods 0.000 title claims description 31
229910045601 alloy Inorganic materials 0.000 title claims description 15
239000000956 alloy Substances 0.000 title claims description 15
230000001590 oxidative effect Effects 0.000 claims abstract description 29
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 19
-1 fluoride ions Chemical class 0.000 claims abstract description 18
239000011572 manganese Substances 0.000 claims abstract description 12
239000007864 aqueous solution Substances 0.000 claims abstract description 11
229910000838 Al alloy Inorganic materials 0.000 claims abstract description 10
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 9
229910052748 manganese Inorganic materials 0.000 claims abstract description 7
230000003647 oxidation Effects 0.000 claims abstract description 7
238000007254 oxidation reaction Methods 0.000 claims abstract description 7
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
150000007522 mineralic acids Chemical class 0.000 claims abstract 14
239000002253 acid Substances 0.000 claims description 34
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 17
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 13
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
235000011007 phosphoric acid Nutrition 0.000 claims description 10
239000000243 solution Substances 0.000 claims description 10
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 9
239000008367 deionised water Substances 0.000 claims description 9
229910017604 nitric acid Inorganic materials 0.000 claims description 9
229910021641 deionized water Inorganic materials 0.000 claims description 8
229910052710 silicon Inorganic materials 0.000 claims description 8
239000010703 silicon Substances 0.000 claims description 8
229960000583 acetic acid Drugs 0.000 claims description 6
238000002156 mixing Methods 0.000 claims description 6
229910003638 H2SiF6 Inorganic materials 0.000 claims description 5
ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 claims description 5
239000007789 gas Substances 0.000 claims description 4
239000012362 glacial acetic acid Substances 0.000 claims description 4
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(II) nitrate Inorganic materials [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 4
150000007942 carboxylates Chemical group 0.000 claims description 3
238000011065 in-situ storage Methods 0.000 claims description 2
229910000147 aluminium phosphate Inorganic materials 0.000 claims 3
229960002163 hydrogen peroxide Drugs 0.000 claims 3
150000001735 carboxylic acids Chemical class 0.000 claims 2
239000006193 liquid solution Substances 0.000 claims 1
150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 3
CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 abstract description 2
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
238000011282 treatment Methods 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
229910001870 ammonium persulfate Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000000576 coating method Methods 0.000 description 2
229960002050 hydrofluoric acid Drugs 0.000 description 2
238000007654 immersion Methods 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
229910000360 iron(III) sulfate Inorganic materials 0.000 description 2
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000011701 zinc Substances 0.000 description 2
PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
235000019395 ammonium persulphate Nutrition 0.000 description 1
239000002585 base Substances 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 1
238000005266 casting Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000007739 conversion coating Methods 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229940071125 manganese acetate Drugs 0.000 description 1
229940099596 manganese sulfate Drugs 0.000 description 1
239000011702 manganese sulphate Substances 0.000 description 1
235000007079 manganese sulphate Nutrition 0.000 description 1
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical class [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
QHDUJTCUPWHNPK-UHFFFAOYSA-N methyl 7-methoxy-2h-indazole-3-carboxylate Chemical compound COC1=CC=CC2=C(C(=O)OC)NN=C21 QHDUJTCUPWHNPK-UHFFFAOYSA-N 0.000 description 1
QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
238000010422 painting Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1

Landscapes

Chemical Treatment Of Metals (AREA)

CA 2129844 1992-02-25 1993-02-19 Procede et composition pour l'elimination du depot sur les surfaces d'aluminium et d'alliages d'aluminium Abandoned CA2129844A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US846,299		1992-02-25
US84692292		1992-02-25

Publications (1)

Publication Number	Publication Date
CA2129844A1 true CA2129844A1 (fr)	1993-09-02

Family

ID=25299318

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2129844 Abandoned CA2129844A1 (fr)	1992-02-25	1993-02-19	Procede et composition pour l'elimination du depot sur les surfaces d'aluminium et d'alliages d'aluminium

Country Status (1)

Country	Link
CA (1)	CA2129844A1 (fr)

1993
- 1993-02-19 CA CA 2129844 patent/CA2129844A1/fr not_active Abandoned

Publication	Publication Date	Title
US5052421A (en)	1991-10-01	Treatment of aluminum with non-chrome cleaner/deoxidizer system followed by conversion coating
US5227016A (en)	1993-07-13	Process and composition for desmutting surfaces of aluminum and its alloys
EP0180908B1 (fr)	1989-05-03	Agent de nettoyage pour surfaces en aluminium
EP0714456B1 (fr)	1997-09-24	Compose et procede de decrassage/desoxydation sans reencrassage
US3140203A (en)	1964-07-07	Method of and composition for treating aluminum and aluminum alloys
US3634262A (en)	1972-01-11	Process and compositions for treating aluminum and aluminum alloys
WO1990008205A1 (fr)	1990-07-26	Desoxydant non-chromate destine aux alliages d'aluminium
US6858097B2 (en)	2005-02-22	Brightening/passivating metal surfaces without hazard from emissions of oxides of nitrogen
US3954645A (en)	1976-05-04	Additive for an acid cleaning bath for metal surfaces
US5514293A (en)	1996-05-07	Acidic cleaning aqueous solution for aluminum and aluminum alloy and process for cleaning the same
US7094327B2 (en)	2006-08-22	Compositions for the treatment of magnesium alloys
US20020162990A1 (en)	2002-11-07	Composition and process for etching and desmutting aluminum and its alloys
CA2129844A1 (fr)	1993-09-02	Procede et composition pour l'elimination du depot sur les surfaces d'aluminium et d'alliages d'aluminium
EP1242651B1 (fr)	2009-02-25	Brillantage/passivation de surfaces metalliques sans risques d'emissions d'oxydes d'azote
SE504733C2 (sv)	1997-04-14	Förfarande för betning
JP3160051B2 (ja)	2001-04-23	酸洗促進剤、酸洗促進剤を含んだ酸洗液組成物およびこれを用いる金属の酸洗促進方法
AU616776B2 (en)	1991-11-07	Non-chrome cleaner/deoxidizer system
CA2300492A1 (fr)	2001-09-13	Elimination des depots de cuivre « copper kiss » causes par le decapage d'alliages a haute teneur en cuivre
US5720823A (en)	1998-02-24	Composition and process for desmutting and deoxidizing without smutting
US5637252A (en)	1997-06-10	Inhibitor for aqueous liquid deoxidizing composition and process for aluminum, with reduced etching of titanium
WO1998020186A1 (fr)	1998-05-14	Composition et procede de revetement par conversion a phosphate
JPH0741972A (ja)	1995-02-10	アルミニウム系金属の酸性洗浄水溶液
JP3038111B2 (ja)	2000-05-08	アルミニウム系金属の酸性洗浄水溶液及び洗浄方法

Legal Events

Date	Code	Title	Description
2001-02-19	FZDE	Dead