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BR9904126A - Processo para fabricação de filamentos com denier elevado de polìmeros cristalinos lìquidos termotrópicos e suas composições - Google Patents

Processo para fabricação de filamentos com denier elevado de polìmeros cristalinos lìquidos termotrópicos e suas composições

Info

Publication number
BR9904126A
BR9904126A BR9904126-0A BR9904126A BR9904126A BR 9904126 A BR9904126 A BR 9904126A BR 9904126 A BR9904126 A BR 9904126A BR 9904126 A BR9904126 A BR 9904126A
Authority
BR
Brazil
Prior art keywords
filaments
spun
approximately
denier
liquid crystalline
Prior art date
Application number
BR9904126-0A
Other languages
English (en)
Inventor
John A Flint
M Ishaq Haider
Michael J Jaffe
Joseph J Dibiase
John E Cornetta
Original Assignee
Celanese Acetate Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Acetate Llc filed Critical Celanese Acetate Llc
Publication of BR9904126A publication Critical patent/BR9904126A/pt

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/82—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyester amides or polyether amides
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Polyamides (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

<B>PROCESSO PARA FABRICAçãO DE FILAMENTOS COM DENIER ELEVADO DE POLìMEROS CRISTALINOS LìQUIDOS TERMOTRóPICOS E SUAS COMPOSIçõES<D> A presente invenção revela e reivindica um processo novo para a formação de filamentos como fiado e tratado a quente com denier elevado de um polímero cristalino líquido termotrópico. As modalidades preferidas incluem processo para a formação de monofilamentos como fiados e tratados a quente de alguns poliésteres e poliesteramidas totalmente aromáticos. O processo envolve a) aquecimento de um polímero cristalino líquido termotrópico até acima de sua temperatura de transição de fusão; b) passagem do referido polímero fundido através de uma câmara de extrusão equipada com um capilar de extrusão que tem uma razão de aspecto maior do que aproximadamente 1 e menor do que aproximadamente 15 para formar um filamento; e c) enrolamento do filamento em uma razão de estiramento de pelo menos aproximadamente 4. Os filamentos assim formados são de pelo menos 50 denier por filamento (dpf) e apresentam orientação molecular essencialmente uniforme em seção transversal. Em uma etapa opcional final, os filamentos são tratados a quente em etapas para formar filamentos que apresentam propriedades de tração excelentes. Os filamentos tanto como fiado quanto tratados a quente apresentam propriedades de tração notavelmente boas, mantendo pelo menos 80 a 90% das propriedades esperadas dos filamentos convencionais com denier baixo (5 a 10 dpf).
BR9904126-0A 1998-09-10 1999-09-10 Processo para fabricação de filamentos com denier elevado de polìmeros cristalinos lìquidos termotrópicos e suas composições BR9904126A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/150,853 US5945216A (en) 1998-09-10 1998-09-10 Process for making high denier filaments of thermotropic liquid crystalline polymers and compositions thereof

Publications (1)

Publication Number Publication Date
BR9904126A true BR9904126A (pt) 2000-10-03

Family

ID=22536267

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9904126-0A BR9904126A (pt) 1998-09-10 1999-09-10 Processo para fabricação de filamentos com denier elevado de polìmeros cristalinos lìquidos termotrópicos e suas composições

Country Status (10)

Country Link
US (2) US5945216A (pt)
EP (1) EP0985750B1 (pt)
JP (1) JP2000096339A (pt)
KR (1) KR20000022984A (pt)
CN (1) CN1200153C (pt)
BR (1) BR9904126A (pt)
DE (1) DE69921410T2 (pt)
ES (1) ES2232050T3 (pt)
MY (1) MY124249A (pt)
TR (1) TR199902153A2 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4010572B2 (ja) * 1997-06-06 2007-11-21 ミシュラン ルシェルシュ エ テクニーク ソシエテ アノニム サーモトロピック芳香族ポリエステル（アミド）モノフィラメント
US6187437B1 (en) * 1998-09-10 2001-02-13 Celanese Acetate Llc Process for making high denier multilobal filaments of thermotropic liquid crystalline polymers and compositions thereof
US6475618B1 (en) 2001-03-21 2002-11-05 Kimberly-Clark Worldwide, Inc. Compositions for enhanced thermal bonding
JP5320756B2 (ja) * 2007-02-07 2013-10-23 東レ株式会社 液晶ポリエステル繊維の製造方法
JP5623292B2 (ja) * 2008-12-25 2014-11-12 株式会社クラレ 耐熱性に優れた高強力高弾性率溶融異方性ポリエステルアミド繊維
JP2010196214A (ja) * 2009-02-26 2010-09-09 Kuraray Co Ltd ベルト
JP5290808B2 (ja) * 2009-02-27 2013-09-18 株式会社クラレ ロープ構造体
EP2407583B1 (en) * 2009-03-11 2013-10-09 Toray Industries, Inc. Liquid crystal polyester fibers and method for producing the same
US8871658B2 (en) 2009-04-20 2014-10-28 Barrday Inc. Rigid ballistic composites made from poly-para-phenylene terephthalamide fibers having large denier per filament
WO2011006092A2 (en) * 2009-07-10 2011-01-13 North Carolina State University Highly oriented and crystalline thermoplastic filaments and method of making same
CN102071493B (zh) * 2011-01-20 2012-06-20 东华大学 一种热致性液晶聚芳酯纤维的制备方法
CN102443873B (zh) * 2011-08-18 2013-10-23 四川省纺织科学研究院 一种芳香族共聚酯液晶纤维及其制备方法
CN110978576B (zh) * 2019-12-20 2021-09-10 江门市德众泰工程塑胶科技有限公司 一种液晶聚合物薄膜的制备方法
CN117368250B (zh) * 2023-12-08 2024-02-20 烟台泰和新材高分子新材料研究院有限公司 一种定量分析液晶聚芳酯结构的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4183895A (en) * 1975-04-29 1980-01-15 E. I. Du Pont De Nemours And Company Process for treating anisotropic melt-forming polymeric products
US4910057A (en) * 1982-04-02 1990-03-20 Hoechst Celanese Corporation Melt extruded elongated member suitable for improved service as a stiffening support in an optical fiber cable
DE3364039D1 (en) * 1982-04-02 1986-07-17 Celanese Corp A melt extruded elongated member of a thermotropic liquid crystalline polymer for use as a stiffening support in an optical fiber cable and fiber optic cables containing such an elongated member
US4468364A (en) * 1983-04-28 1984-08-28 Celanese Corporation Process for extruding thermotropic liquid crystalline polymers
US4734240A (en) * 1986-01-24 1988-03-29 Hoechst Celanese Corporation Melt-extrusion of polymer which is capable of forming an anisotropic melt phase to form large shaped articles exhibiting improved polymeric orientation
KR0143889B1 (ko) * 1989-06-28 1998-07-15 미셸 헤리띠에 아라미드 단일 필라멘트와 그 제조방법
FR2671030A1 (fr) * 1990-12-27 1992-07-03 Michelin Rech Tech Assemblages de renfort avec monofilaments en polymeres organiques.
JPH04333616A (ja) * 1991-05-10 1992-11-20 Kuraray Co Ltd 高強力モノフィラメントの製造方法
JP4010572B2 (ja) * 1997-06-06 2007-11-21 ミシュラン ルシェルシュ エ テクニーク ソシエテ アノニム サーモトロピック芳香族ポリエステル（アミド）モノフィラメント

Also Published As

Publication number Publication date
KR20000022984A (ko) 2000-04-25
JP2000096339A (ja) 2000-04-04
CN1200153C (zh) 2005-05-04
CN1252462A (zh) 2000-05-10
DE69921410T2 (de) 2006-02-16
TR199902153A3 (tr) 2000-06-21
EP0985750A2 (en) 2000-03-15
ES2232050T3 (es) 2005-05-16
EP0985750A3 (en) 2000-08-09
MY124249A (en) 2006-06-30
USRE37526E1 (en) 2002-01-22
TR199902153A2 (xx) 2000-06-21
EP0985750B1 (en) 2004-10-27
DE69921410D1 (de) 2004-12-02
US5945216A (en) 1999-08-31

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements